D-Tartaric acid supplier | CasNO.147-71-7

Name
D-Tartaric acid
EINECS 205-695-6
CAS No. 147-71-7
Article Data67
CAS DataBase
Density 1.886 g/cm³
Solubility water: 1394 g/L (20 °C)
Melting Point 172-174 °C(lit.)
Formula C₄H₆O₆
Boiling Point 399.3 °C at 760 mmHg
Molecular Weight 150.088
Flash Point 209.4 °C
Transport Information
Appearance white crystals
Safety 26-37/39
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms (-)-(S,S)-Tartaric acid;(-)-D-Tartaric acid;(2S,3S)-(-)-Tartaric acid;(S,S)-(-)-Tartaric acid;
PSA 115.06000
LogP -2.12260

Synthetic route

: 2364-65-0, 120399-40-8
(2S,3S)-diethyl 2,3-diacetoxysuccinate

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With water; sodium hydroxide In N,N-dimethyl-formamide at 60℃; for 10h; Time;	91.2%
With water; sodium hydroxide In N,N-dimethyl-formamide at 60℃; for 10h; Time;	91.2%

: D-sodium hydrogen tartrate

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With sulfuric acid In ethanol at 20℃; for 0.75h;	83%
With sulfuric acid In methanol at 20℃; for 1h;	82%

: L-1-phenyl-2-(1-pyrrolidinyl)-1-propanone-D-(-)-tartaric acid

A: 19134-50-0
(SR)-(+/-)-1-phenyl-2-(1-pyrrolidinyl)-1-propanone

B: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With hydrogenchloride; ammonia In water; ethyl acetate at 70℃; for 6h; pH=5 - 11;	A 82.31% B n/a

: 57341-16-9
L(+)-potassium hydrogen tartrate

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With sulfuric acid In ethanol at 20℃; for 0.75h;	25%

: 74-90-8
hydrogen cyanide

: 453-17-8
D-Glyceraldehyde

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
Hydrolyse des Oxynitrils; Oxydation des Reaktionsprodukts;

: 2418-52-2
D-threitol

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With nitric acid

: 1113-60-6
3-hydroxy-2-oxopropionic acid

: 151-50-8
potassium cyanide

A: 147-71-7
D-tartaric acid

B: 147-73-9
meso-tartaric acid

Conditions

Conditions	Yield
beim Kochen des Reaktionsprodukts mit verd.Schwefelsaeure;

...Expand

: 95-43-2
D-threose

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With nitric acid at 50℃;

: 133-37-9
DL-tartaric acid

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
Spaltung mit Cinchonin;
With sodium ammoniumracemat durch Krystallisation;
With sodium ammoniumracemat; water durch Krystallisation; hierbei scheidet sich ein mechanisch trennbares Gemisch gleicher Teile der enantiostereomeren Natriumammoniumtartrate aus;

: 685-73-4
D-galacturonic acid

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With sodium hydroxide; oxygen unter Druck;

: 133-37-9
DL-tartaric acid

: 118-10-5
Cinchonin

: 147-71-7
D-tartaric acid

: 63-42-3
D-(+)-lactose

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With calcium hydroxide bei der Einw. des Reaktionsprodukts mit Salpetersaeure;

: 147-73-9
meso-tartaric acid

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
Yield given;

: 87-69-4
tartaric acid

: 147-71-7
D-tartaric acid

: 7697-37-2
nitric acid

: 23732-41-4
D-threono-1,4-lactone

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
at 50 - 60℃;

β-chloro-malic acid: β-chloro-malic acid

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With water

: 64-17-5
ethanol

: 133-37-9
DL-tartaric acid

2--benzimidazole: 2--benzimidazole

: 147-71-7
D-tartaric acid

...Expand

: 7632-10-2
methamphetamin

: 133-37-9
DL-tartaric acid

: 7732-18-5
water

: 147-71-7
D-tartaric acid

...Expand

: 165877-67-8
(+)(2R:3R)-3-chloro-2-hydroxy-succinic acid

: 7732-18-5
water

: 147-71-7
D-tartaric acid

: 2418-52-2
D-threitol

: 7697-37-2
nitric acid

: 147-71-7
D-tartaric acid

: 67968-47-2
D-5-deoxy-arabinose

: 7732-18-5
water

: 7697-37-2
nitric acid

: 147-71-7
D-tartaric acid

...Expand

D-gulonic acid γ lactone: D-gulonic acid γ lactone

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With sodium vanadate; nitric acid

D-threonic acid: D-threonic acid

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With nitric acid at 50℃;

l-tartaric acid dialdehyde α-bis-phenylhydrazone: l-tartaric acid dialdehyde α-bis-phenylhydrazone

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With ethanol; benzaldehyde anschliessend Behandeln mit Bromwasser im Rohr bei 50grad;

l-threonic acid-lactone: l-threonic acid-lactone

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With nitric acid at 50 - 60℃;

parasaccharinacidic barium: parasaccharinacidic barium

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With nitric acid

parasaccharin: parasaccharin

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
With nitric acid

potassium-sodium DL-tartrate: potassium-sodium DL-tartrate

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
Spaltung durch Krystallsisation aus Wasser;

sodium ammonium salt of/the/ DL-tartaric acid: sodium ammonium salt of/the/ DL-tartaric acid

: 147-71-7
D-tartaric acid

Conditions

Conditions	Yield
Darstellung von linksweinsaurem Natriumammonium;

: 67-56-1
methanol

: 147-71-7
D-tartaric acid

: 13171-64-7
Dimethyl D-tartrate

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In toluene Fischer-Speier Esterification;	100%
With thionyl chloride at 0℃; for 4h; Inert atmosphere; Reflux;	100%
With hydrogenchloride ice bath;	57%

: 64-17-5
ethanol

: 147-71-7
D-tartaric acid

: 13811-71-7
diethyl (2S,3S)-tartrate

Conditions

Conditions	Yield
With thionyl chloride at 20℃;	100%
With thionyl chloride at 20℃;	100%
With hydrogenchloride In chloroform; water for 60h; Catalytic behavior; Reflux; enantioselective reaction;	99.6%

: 147-71-7
D-tartaric acid

: 77-76-9
2,2-dimethoxy-propane

: 37031-29-1, 6134-82-3, 6135-80-4, 90613-41-5, 116499-08-2, 37031-30-4
(+)-dimethyl-2,3-O-isopropylidene-D-tartrate

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In methanol; cyclohexane at 52 - 54℃;	100%
With toluene-4-sulfonic acid Heating;	91%
With toluene-4-sulfonic acid In methanol; cyclohexane at 102℃; for 0.25h; Reflux;	88%

: 147-71-7
D-tartaric acid

: 77-76-9
2,2-dimethoxy-propane

: 126581-14-4
D-2,3-isopropylidene tartaric acid

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In deuteromethanol	100%
With cyclohexane; toluene-4-sulfonic acid In methanol Heating;
With toluene-4-sulfonic acid In methanol at 65℃; for 16h; Inert atmosphere;

: 391677-98-8
(4R)-4-methyl-4-[2-(thiophen-2-yl)ethyl]-1,3-oxazolidin-2-one

: 147-71-7
D-tartaric acid

: (2R)-amino-2-methyl-4-thiophen-2-ylbutan-1-ol 1/2D-(-)-tartrate

Conditions

Conditions	Yield
Stage #1: (4R)-4-methyl-4-[2-(thiophen-2-yl)ethyl]-1,3-oxazolidin-2-one With potassium hydroxide In tetrahydrofuran; methanol; dichloromethane at 80℃; for 48h; Stage #2: D-tartaric acid In ethanol	99.7%

: 147-71-7
D-tartaric acid

: 694-83-7
1,2-diaminocyclohexane

: (R,R)-1,2-diaminocyclohexane tartrate

Conditions

Conditions	Yield
With acetic acid In water	99%

: 147-71-7
D-tartaric acid

: (R)-7-[3-amino-4-(2,4,5-trifluorophenyl)butanoyl]-3-trifluoromethyl-5,6,7,8-tetrahydro-imidazo [1,5-a]pyrazine-1-carboxylic acid

: (R)-7-[3-amino-4-(2,4,5-trifluorophenyl)butanoyl]-3-trifluoromethyl-5,6,7,8-tetrahydro-imidazo[1,5-a]pyrazine-1-carboxylic acid (2S,3S)-2,3-dihydroxybutanedioic acid

Conditions

Conditions	Yield
In methanol; water for 0.5h;	99%

: 147-71-7
D-tartaric acid

: 1174122-63-4
(R)-7-[3-amino-4-(2,4,5-trifluorophenyl)-butyryl]-3-trifluoromethyl-5,6,7,8-tetrahydro-imidazo [1,5-a]pyrazine-1-carboxylic acid

: 1242332-81-5
(R)-7-[3-Amino-4-(2,4,5-trifluorophenyl)butanoyl]-3-trifluoromethyl-5,6,7,8-tetrahydro-imidazo[1,5-a]pyrazine-1-carboxylic acid (2S,3S)-2,3-dihydroxybutanedioic acid

Conditions

Conditions	Yield
In methanol; water for 0.5h;	99%

: 125278-10-6
(S)-1,1,1-trifluoropropan-2-amine

: 147-71-7
D-tartaric acid

: 249648-15-5
C3H6F3N*C4H6O6

Conditions

Conditions	Yield
In methanol Reflux;	99%

: 147-71-7
D-tartaric acid

: 1-[{3-(1H-1,2,3-triazol-1-yl)propyl}piperidin-4-yl]methanamine

: 1-[{3-(1H-1,2,3-triazol-1-yl)propyl}piperidin-4-yl]methanamine D-tartrate

Conditions

Conditions	Yield
In diethyl ether; ethanol for 4h;	99%

: 147-71-7
D-tartaric acid

: 1-[{3-(1H-1,2,3-triazol-1-yl)propyl}piperidin-4-yl]methanamine

: 1-[{3-(1H-1,2,3-trizol-1-yl)propyl}piperidin-4-yl]methanamine D-tartrate

Conditions

Conditions	Yield
In diethyl ether; ethanol for 4h;	99%

: 147-71-7
D-tartaric acid

: 3,3'-di-n-decyl-1,1'-(1,4-phenylenedimethylene)diimidazolium dibromide

: 3,3'-di-n-decyl-1,1'(1,4-phenylenedimethylene)diimidazolium D-tartrate

Conditions

Conditions	Yield
Stage #1: 3,3'-di-n-decyl-1,1'-(1,4-phenylenedimethylene)diimidazolium dibromide With Amberlite resin IRA-400 (hydroxide form) In methanol; water Stage #2: D-tartaric acid In methanol; water	99%

: 147-71-7
D-tartaric acid

: (1R/S,2S)-1-phenyl-2-(pyrrolidin-1-yl)propan-1-ol

: (1R,2S)-1-phenyl-2-(pyrrolidin-1-yl)propan-1-ol D-tartrate

Conditions

Conditions	Yield
In ethanol at 20 - 30℃; for 2h; Reflux;	99%

: 147-71-7
D-tartaric acid

: 7732-18-5
water

: 62-54-4
calcium acetate

: 5892-21-7, 22547-87-1, 60295-80-9, 66018-88-0, 66905-75-7, 92752-17-5, 134841-46-6, 3164-34-9
calcium l-tartrate*4H2O

Conditions

Conditions	Yield
In acetic acid addn. of 15 ml 95 % ethanol to mixture of 50 ml 1 % l-tartaric acid soln. and 10 ml Ca(CH3CO2)2 soln. (preparation for 1 l: 32 g CaCO3, 120 ml pure acetic acid, rest H2O); add. of further 15 ml 95 % ethanol after 24 hs; complete pptn. after 48 hs;; washing 3 times by decantation, pressing on filter paper, drying at ambient temp.;;	98.95%
In acetic acid addn. of 1 l acetic Ca(CH3CO2)2 soln. (32 g CaCO3, 120 ml pure acetic acid, rest H2O) to 2 l 1 % d-tartaric acid soln.; complete pptn. after 24 hs;; washing 3 times by decantation, pressing on filter paper, drying at ambient temp.;;
In acetic acid

...Expand

: 869116-46-1
(R)-3,3-dimethyl-1-phenyl-2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazine

: 147-71-7
D-tartaric acid

: (R)-Betti base (-)-tartaric acid

Conditions

Conditions	Yield
In water; acetone at 20℃; for 3h;	98%

: 147-71-7
D-tartaric acid

: 106650-56-0
didesmethylsibutramine

: 259729-92-5
didesmethylsibutramine (D)-tartrate

Conditions

Conditions	Yield
In water; acetone; toluene for 0.5h; Heating / reflux;	98%
In water; acetone; toluene at 70 - 80℃; for 0.5h; Heating / reflux;	98%

: 147-71-7
D-tartaric acid

: 5970-45-6
zinc(II) acetate dihydrate

: zinc(II) d-tartarate

Conditions

Conditions	Yield
In water stirring (room temp., 1 h), standing overnight (pptn.); washing (water, methanol), drying (150°C, 1 Torr, 5 h); elem. anal.;	98%

: lanthanum(III) nitrate hexahydrate

: 147-71-7
D-tartaric acid

: 107-21-1
ethylene glycol

: La(3+)*CHOHCOOHCHOHCOO(1-)*CH(OH)COO(CH2)2OHCHOHCOO(1-)*0.5CHOHCOOCHOHCOO(2-)*0.5HOCH2CH2OH*2H2O=C13H23LaO19

Conditions

Conditions	Yield
In ethylene glycol tartaric acid, La(NO3)3*6H2O added to HOCH2CH2OH with stirring; soln. agitated in a vessel for 30 min at 120.+-.3°C; soln. cooled to room temp., acetone added, precipitate separated, soakedfor 24 h in acetone, filtered, dried for 2 h in air, then over CaCl2; e lem. anal.;	98%

...Expand

: 147-71-7
D-tartaric acid

: 950830-89-4
2-(4-chlorobenzylidene)-5,5-dimethyl-1-(dimethylaminomethyl)-1-cyclopentanol

: C4H6O6*C17H24ClNO

Conditions

Conditions	Yield
In acetone at 18 - 24℃; for 0.25h; Resolution of racemate;	98%

: 147-71-7
D-tartaric acid

: 2301-80-6
N-methyl-4-methylpyridinium iodide

Conditions

Conditions	Yield
With silver hydroxide In water for 24h;	98%

: 147-71-7
D-tartaric acid

: 1-ethyl-3-methylimidazolium hydroxide

: 1-ethyl-3-methylimidazolium hydrogen (2S,3S)-tartrate

Conditions

Conditions	Yield
In water at 20℃; for 2h; Darkness;	98%

: 147-71-7
D-tartaric acid

: 1-ethyl-3-methylimidazolium hydroxide

: 1-ethyl-3-methylimidazolium (2S,3S)-tartrate

Conditions

Conditions	Yield
In water at 20℃; for 2h; Darkness;	98%

: hexaammonium heptamolybdate tetrahydrate

: 147-71-7
D-tartaric acid

: 7732-18-5
water

: 10138-52-0
gadolinium(III) chloride

: NH4(1+)*2Mo(6+)*4O(2-)*Gd(3+)*10H2O*2(OCHCO2)2(4-)=NH4[Mo2O4Gd(H2O)6((OCHCO2)2)2]*4H2O

Conditions

Conditions	Yield
With HCl In water pH of soln. adjusted to 0.80 by HCl (10 %), 2 wk; elem. anal.;	97.9%

...Expand

: samarium(III) oxide

: hexaammonium heptamolybdate tetrahydrate

: 147-71-7
D-tartaric acid

: NH4[Mo2O4Sm(H2O)6(L-C4H2O6)2]*4H2O

Conditions

Conditions	Yield
With HCl In hydrogenchloride Sm2O3 was dissolved in concd. HCl under heating for about 5 min; soln. was added to aq. acidified soln. of Mo compd. in presence of tartaric acid; HCl was added to pH 0.8; stored for 1 wk; elem. anal.;	97.9%

...Expand

: 147-71-7
D-tartaric acid

: 20439-47-8
(1R,2R)-1,2-diaminocyclohexane

: 116407-32-0
(1R,2R)-(-)-1,2-diammoniumcyclohexane mono-L-(+)-tartrate

Conditions

Conditions	Yield
In tetrahydrofuran for 36h; Reflux;	97%
Stage #1: D-tartaric acid; (1R,2R)-1,2-diaminocyclohexane In water at 25 - 90℃; Stage #2: With acetic acid In water at 85 - 90℃; for 2h;	55.8%

: 147-71-7
D-tartaric acid

: 149-73-5
trimethyl orthoformate

: 13171-64-7
Dimethyl D-tartrate

Conditions

Conditions	Yield
With Dowex 50W X8 (H+ form) In methanol at 50℃; for 22h; Inert atmosphere;	97%

: 239463-72-0
5-[(2R)-2-aminopropyl]-2,3-dihydro-1-[3-(benzoyloxy)propyl]-1H-indole-7-carbonitrile

: 147-71-7
D-tartaric acid

: 5-[(2R)-2-(tert-butoxycarbonyl)aminopropyl]-1-[3-(benzoyloxy)propyl]-2,3-dihydro-7-cyano-1H-indole

: (R)-1-(1-(3-(benzoyloxy)propyl)-7-cyanoindolin-5-yl)propan-2-aminium (2S,3S)-3-carboxy-2,3-dihydroxypropanoate

Conditions

Conditions	Yield
Stage #1: 5-[(2R)-2-(tert-butoxycarbonyl)aminopropyl]-1-[3-(benzoyloxy)propyl]-2,3-dihydro-7-cyano-1H-indole With hydrogenchloride In methanol at -5 - 20℃; Stage #2: 5-[(2R)-2-aminopropyl]-2,3-dihydro-1-[3-(benzoyloxy)propyl]-1H-indole-7-carbonitrile; D-tartaric acid In tetrahydrofuran	97%

...Expand

: 147-71-7
D-tartaric acid

: 2-fluoro-3-(5-fluoro-6-{3-[(methoxy-d3)imino]azetidin-1-yl}pyridin-3-yl)benzyl carbamimidoylcarbamate

: C18H15(2)H3F2N6O3*0.5C4H6O6

Conditions

Conditions	Yield
In dimethyl sulfoxide; ethyl acetate at 20 - 50℃; for 16h;	97%

: 147-71-7
D-tartaric acid

: Λ-[Co((S,S)-1,2-diphenylethylenediamine)3]3+2Cl−B(3,5-C6H3(CF3)2)4·2H2O

: C32H12BF24(1-)*C4H4O6(2-)*C42H48CoN6(3+)

Conditions

Conditions	Yield
Stage #1: D-tartaric acid With sodium hydroxide In water at 20℃; for 0.5h; Stage #2: Λ-[Co((S,S)-1,2-diphenylethylenediamine)3]3+2Cl−B(3,5-C6H3(CF3)2)4·2H2O In dichloromethane; water at 20℃;	97%

: 147-71-7
D-tartaric acid

: (E)-N-((1s,4s)-4-(dimethylamino)-1,4-diphenylcyclohexyl)-N-methylcinnamamide

: (E)-N-((1s,4s)-4-(dimethylamino)-1,4-diphenylcyclohexyl)-N-methylcinnamamide hemi-(D)-tartrate

Conditions

Conditions	Yield
In isopropyl alcohol at 30℃;	96.16%

D-Tartaric acid Specification

The D-Tartaric acid, with the cas registry number 147-71-7, has the IUPAC name of (2S,3S)-2,3-dihydroxybutanedioic acid. This is a kind of white crystals, and it is sensitive to light. Besides, it is stable chemically and is incompatible with oxidizing agents, bases, reducing agents. In addition, its product categories are various, including FINE Chemical & INTERMEDIATES; Chiral Compounds; Carboxylic Acids (Chiral); Chiral Building Blocks; for Resolution of Bases; Optical Resolution; Synthetic Organic Chemistry; Chiral chemicals.

The characteristics of this chemical are as follows: (1)ACD/LogP: -1.43; (2)# of Rule of 5 Violations: 0 ; (3)ACD/BCF (pH 5.5): 1; (4)ACD/BCF (pH 7.4): 1; (5)ACD/KOC (pH 5.5): 1; (6)ACD/KOC (pH 7.4): 1; (7)#H bond acceptors: 6; (8)#H bond donors: 4; (9)#Freely Rotating Bonds: 5; (10)Polar Surface Area: 71.06; (11)Index of Refraction: 1.585; (12)Molar Refractivity: 26.69 cm³; (13)Molar Volume: 79.5 cm³; (14)Polarizability: 10.58 ×10^-24 cm³; (15)Surface Tension: 119.4 dyne/cm; (16)Density: 1.886 g/cm³; (17)Flash Point: 209.4 °C; (18)Enthalpy of Vaporization: 75.13 kJ/mol; (19)Boiling Point: 399.3 °C at 760 mmHg; (20)Vapour Pressure: 4.93E-08 mmHg at 25°C; (21)Exact Mass: 150.016438; (22)MonoIsotopic Mass: 150.016438; (23)Topological Polar Surface Area: 115; (24)Heavy Atom Count: 10; (25)Formal Charge: 0; (26)Complexity: 134.

D-Tartaric acid is mainly present in the form of potassium salt in a variety of plants, fruits. There also a small amount present in free species. In the field of practical application of tartaric acid, they usually mainly use the L(+)tartaric acid or its salts. The industrial way to get L(+)tartaric acid is through fermentation of glucose; raceme fumaric acid can be obtained with the potassium permanganate oxidation.

As to its usage, it is usually applied in many ways. It could be used as colour spectrum analysis reagent and screening agent; It could also used as pharmaceutic resolving agent, food additives, biochemical reagents; It is widely used in food industry, such as beer foaming agent, food acidity regulations, Flavoring agent and also in soft drink, sweet, fruit juice, ferment powder and others.

When you are dealing with this chemical, you should be very careful and then take some measures to protect yourself. Being a kind of irritant chemical to eyes, respiratory system and skin, it may cause inflammation to the skin or other mucous membranes. Therefore, you should take the following instructions. Wear suitable protective clothing, gloves and eye/face protection, and if in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Additionally, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: C(C(C(=O)O)O)(C(=O)O)O
(2)Isomeric SMILES: [C@H]([C@@H](C(=O)O)O)(C(=O)O)O
(3)InChI: InChI=1S/C4H6O6/c5-1(3(7)8)2(6)4(9)10/h1-2,5-6H,(H,7,8)(H,9,10)/t1-,2-/m0/s1
(4)InChIKey: FEWJPZIEWOKRBE-LWMBPPNESA-N

Product Name

D-Tartaric acid

Synthetic route

D-Tartaric acid Specification

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