Product Name

  • Name

    DL-Tartaric acid

  • EINECS 205-105-7
  • CAS No. 133-37-9
  • Article Data126
  • CAS DataBase
  • Density 1.886 g/cm3
  • Solubility soluble in water
  • Melting Point 210-212 °C(lit.)
  • Formula C4H6O6
  • Boiling Point 399.3 °C at 760 mmHg
  • Molecular Weight 150.088
  • Flash Point 209.4 °C
  • Transport Information
  • Appearance white crystalline powder
  • Safety 26-37/39
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 133-37-9 (DL-Tartaric acid)
  • Hazard Symbols IrritantXi
  • Synonyms DL-Dihydroxysuccinic acid;
  • PSA 115.06000
  • LogP -2.12260

Synthetic route

Glyoxilic acid
298-12-4

Glyoxilic acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With bis(cyclopentadienyl)-titanium(III) chloride In tetrahydrofuran at -78 - 20℃;68%
With acetic acid; zinc
elektrolytische Reduktion;
With alkali elektrolytische Reduktion;
Electrolysis;
sorbic Acid
110-44-1

sorbic Acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With potassium permanganate at 0℃;
hydrogen cyanide
74-90-8

hydrogen cyanide

Glyoxal
131543-46-9

Glyoxal

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With hydrogenchloride
mannitol
69-65-8

mannitol

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With nitric acid
D-galactitol
608-66-2

D-galactitol

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With nitric acid
dihydroxyfumaric acid
133-38-0

dihydroxyfumaric acid

quinhydrone
106-34-3

quinhydrone

DL-tartaric acid
133-37-9

DL-tartaric acid

dihydroxyfumaric acid
133-38-0

dihydroxyfumaric acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With hydroquinone
D-tartaric acid
147-71-7

D-tartaric acid

L-Tartaric acid
87-69-4

L-Tartaric acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
unter Waermeentwicklung;
With water
meso-tartaric acid
147-73-9

meso-tartaric acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
at 200℃;
L-Tartaric acid
87-69-4

L-Tartaric acid

furan-2,3,5(4H)-trione pyridine (1:1)

furan-2,3,5(4H)-trione pyridine (1:1)

DL-tartaric acid
133-37-9

DL-tartaric acid

B

tartaric acid
87-69-4

tartaric acid

L-Tartaric acid
87-69-4

L-Tartaric acid

A

meso-tartaric acid
147-73-9

meso-tartaric acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With water
With hydrogenchloride
With hydrogenchloride im geschlossenen Rohr;
With sodium hydroxide; water
L-Tartaric acid
87-69-4

L-Tartaric acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With sodium hydroxide
With potassium hydroxide
With sodium hydroxide Racemisierung;
D-glucaric acid
87-73-0

D-glucaric acid

A

L-Tartaric acid
87-69-4

L-Tartaric acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With nitric acid
D-glucaric acid
87-73-0

D-glucaric acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With nitric acid
meso-galactaric acid
526-99-8, 1213827-87-2

meso-galactaric acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With nitric acid
With potassium permanganate
With permanganate(VII) ion
1,3-butadiene-1-carboxylic acid
626-99-3

1,3-butadiene-1-carboxylic acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With potassium permanganate at 0℃;
dihydroxytartaric acid
76-30-2

dihydroxytartaric acid

A

meso-tartaric acid
147-73-9

meso-tartaric acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With zinc
1,2-dihydroxy-ethane-1,1,2-tricarboxylic acid
639-51-0

1,2-dihydroxy-ethane-1,1,2-tricarboxylic acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With water
2-Methyl-1,4-benzoquinone
553-97-9

2-Methyl-1,4-benzoquinone

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With sulfuric acid bei der elektrolytischen Oxydation an einer PbO2-Anode;
benzene-1,2-diol
120-80-9

benzene-1,2-diol

DL-tartaric acid
133-37-9

DL-tartaric acid

B

cis-2,3-epoxysuccinic acid
16533-72-5

cis-2,3-epoxysuccinic acid

Conditions
ConditionsYield
With sodium hydroxide; dihydrogen peroxide at 70 - 80℃;
tartaric acid
87-69-4

tartaric acid

A

meso-tartaric acid
147-73-9

meso-tartaric acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With hydrogenchloride
With water
With alkaline solution
tartaric acid
87-69-4

tartaric acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With aluminium salt
With water at 175℃;
maleic acid
110-16-7

maleic acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With sulfuric acid; lead dioxide bei der elektrolytischen Oxydation;
With dihydrogen peroxide; tungsten(VI) oxide
With dihydrogen peroxide; tungsten(VI) oxide
(2E)-but-2-enedioic acid
110-17-8

(2E)-but-2-enedioic acid

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With sodium chlorate; osmium(VIII) oxide; water
With sodium chlorate; osmium(VIII) oxide; water at 50℃;
With osmium(VIII) oxide; potassium chlorate; water at 50℃;
(2E)-but-2-enedioic acid
110-17-8

(2E)-but-2-enedioic acid

DL-tartaric acid
133-37-9

DL-tartaric acid

B

oxalic acid
144-62-7

oxalic acid

Conditions
ConditionsYield
With osmium(VIII) oxide; dihydrogen peroxide; tert-butyl alcohol at 0℃;
With osmium(VIII) oxide; dihydrogen peroxide; tert-butyl alcohol at 0℃;
hydroquinone
123-31-9

hydroquinone

DL-tartaric acid
133-37-9

DL-tartaric acid

B

cis-2,3-epoxysuccinic acid
16533-72-5

cis-2,3-epoxysuccinic acid

Conditions
ConditionsYield
With sodium hydroxide; dihydrogen peroxide
With sodium hydroxide; dihydrogen peroxide at 70 - 80℃;
oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With sodium amalgam; ethanol Produkt: Traubensaeureester;
glycerol
56-81-5

glycerol

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With hydrazine at 190 - 250℃;
p-benzoquinone
106-51-4

p-benzoquinone

DL-tartaric acid
133-37-9

DL-tartaric acid

Conditions
ConditionsYield
With sulfuric acid elektrolytische Oxydation;
vanadocene

vanadocene

DL-tartaric acid
133-37-9

DL-tartaric acid

C5H5(1-)*V(3+)*C4H4O6(2-)=(C5H5)V(C4H4O6)

C5H5(1-)*V(3+)*C4H4O6(2-)=(C5H5)V(C4H4O6)

Conditions
ConditionsYield
In diethyl ether byproducts: H2, cyclopentadiene; Ar atmosphere; 20 h, 95°C; ppt. was filtered off, washed with ether, and dried; elem. anal.;93%
Pt(2,2':6',2''-terpyridine)Cl

Pt(2,2':6',2''-terpyridine)Cl

DL-tartaric acid
133-37-9

DL-tartaric acid

[PtCl(2,2′:6′,2′′-terpyridine)](DL-Hta)

[PtCl(2,2′:6′,2′′-terpyridine)](DL-Hta)

Conditions
ConditionsYield
Stage #1: DL-tartaric acid With lithium hydroxide monohydrate In water for 0.166667h; Darkness;
Stage #2: Pt(2,2':6',2''-terpyridine)Cl for 0.166667h;
92%
ethyl 3-amino-5-fluoro-4,4-dimethoxypentanoate
908253-60-1

ethyl 3-amino-5-fluoro-4,4-dimethoxypentanoate

DL-tartaric acid
133-37-9

DL-tartaric acid

1-ethoxy-5-fluoro-4,4-dimethoxy-1-oxopentan-3-aminium tartarate

1-ethoxy-5-fluoro-4,4-dimethoxy-1-oxopentan-3-aminium tartarate

Conditions
ConditionsYield
In water; isopropyl alcohol at 20℃; for 4h;87.1%
ethanol
64-17-5

ethanol

DL-tartaric acid
133-37-9

DL-tartaric acid

(+/-)-diethyl tartrate
57968-71-5

(+/-)-diethyl tartrate

Conditions
ConditionsYield
With Dowex 50W-X8 (H+) In benzene Heating;82%
With hydrogenchloride
With hydrogenchloride
indium(III) hydroxide

indium(III) hydroxide

DL-tartaric acid
133-37-9

DL-tartaric acid

water
7732-18-5

water

α-[InOH(D/L-tartrate)]*2H2O InOH(COOCHOHCHOHCOO)*2H2O, α, low temperature

α-[InOH(D/L-tartrate)]*2H2O InOH(COOCHOHCHOHCOO)*2H2O, α, low temperature

Conditions
ConditionsYield
In water High Pressure; reaction of In(OH)3, organic ligand and H2O at 110°C for 2 days; elem. anal.;75%
Conditions
ConditionsYield
With acidic ion exchange resin In chloroform for 40h; Heating;73%
DL-tartaric acid
133-37-9

DL-tartaric acid

strontium d,l-tartrate
868-19-9, 22438-83-1

strontium d,l-tartrate

Conditions
ConditionsYield
With strontium(II) acetate In water at 100℃; for 48h; Autoclave;73%
DL-tartaric acid
133-37-9

DL-tartaric acid

C4H4O6(2-)*Ca(2+)

C4H4O6(2-)*Ca(2+)

Conditions
ConditionsYield
With calcium acetate In water at 60℃; for 48h;72%
DL-tartaric acid
133-37-9

DL-tartaric acid

benzyl alcohol
100-51-6

benzyl alcohol

dibenzyl DL-tartrate

dibenzyl DL-tartrate

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 12h; Dean-Stark; Reflux;72%
DL-tartaric acid
133-37-9

DL-tartaric acid

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

1,2-bis(2-benzimidazyl)-1,2-ethanediol

1,2-bis(2-benzimidazyl)-1,2-ethanediol

Conditions
ConditionsYield
With hydrogenchloride for 24h; Heating;70%
hexaammonium heptamolybdate tetrahydrate

hexaammonium heptamolybdate tetrahydrate

ammonium hydroxide

ammonium hydroxide

DL-tartaric acid
133-37-9

DL-tartaric acid

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

(NH4)2[MoO(O2)2(tartrate(2-))]*2H2O

(NH4)2[MoO(O2)2(tartrate(2-))]*2H2O

Conditions
ConditionsYield
In water soln. of ammonium heptamolybdate tetrahydrate and D,L-tartaric acid in water treated with soln. of H2O2 (35 wt.-%) and aq. ammonia, stirred for 2 h; EtOH added, soln. stored at room temp. for 24 h, ppt. filtered off, washed with EtOH and air-dried; elem. anal.;69%
DL-tartaric acid
133-37-9

DL-tartaric acid

tert-butyl 4'-[[2-n-propyl-4-methyl-6-(1-methylbenzimidazol-2-yl)-benzimidazol-1-yl]-methyl]-biphenyl-2-carboxylate
144702-26-1

tert-butyl 4'-[[2-n-propyl-4-methyl-6-(1-methylbenzimidazol-2-yl)-benzimidazol-1-yl]-methyl]-biphenyl-2-carboxylate

telmisartan tert-butyl ester DL-tartarate

telmisartan tert-butyl ester DL-tartarate

Conditions
ConditionsYield
In methanol for 5h; Reflux;68.64%
DL-tartaric acid
133-37-9

DL-tartaric acid

tetra(n-butyl)ammonium hydroxide
2052-49-5

tetra(n-butyl)ammonium hydroxide

2C16H36N(1+)*C8H4As2O12(2-)

2C16H36N(1+)*C8H4As2O12(2-)

Conditions
ConditionsYield
With arsenic(III) trioxide In water at 20℃; for 48h;68%
4-amino-2-nitrophenol
119-34-6

4-amino-2-nitrophenol

DL-tartaric acid
133-37-9

DL-tartaric acid

2,3-dihydroxy-N-(4-hydroxy-3-nitrophenyl)succinamic acid

2,3-dihydroxy-N-(4-hydroxy-3-nitrophenyl)succinamic acid

Conditions
ConditionsYield
With 1-hydroxybenzotriazol-hydrate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 20℃;55%
DL-tartaric acid
133-37-9

DL-tartaric acid

urea
57-13-6

urea

2-oxo-4-imidazoline-4-carboxylic acid
39828-47-2

2-oxo-4-imidazoline-4-carboxylic acid

Conditions
ConditionsYield
With sulfuric acid at 80℃; for 1h;53%
2-vinylpyridine
100-69-6

2-vinylpyridine

DL-tartaric acid
133-37-9

DL-tartaric acid

piperazine dihydrochloride hydrate
6091-62-9

piperazine dihydrochloride hydrate

1-<2-(2-pyridyl)ethyl>piperazine DL-tartrate
90125-80-7

1-<2-(2-pyridyl)ethyl>piperazine DL-tartrate

Conditions
ConditionsYield
1.) excess piperazine, water, 1 h, reflux;34%
methanol
67-56-1

methanol

DL-tartaric acid
133-37-9

DL-tartaric acid

dimethyl tartrate
405897-14-5

dimethyl tartrate

Conditions
ConditionsYield
With hydrogenchloride
methanol
67-56-1

methanol

DL-tartaric acid
133-37-9

DL-tartaric acid

(+/-)-monomethyltartaric acid
3333-46-8, 13856-18-3, 82796-94-9, 89395-25-5

(+/-)-monomethyltartaric acid

propan-1-ol
71-23-8

propan-1-ol

DL-tartaric acid
133-37-9

DL-tartaric acid

tartaric acid dipropyl ester
4181-80-0

tartaric acid dipropyl ester

Conditions
ConditionsYield
With hydrogenchloride
ethanol
64-17-5

ethanol

DL-tartaric acid
133-37-9

DL-tartaric acid

DL-tartaric acid monoethyl ester
608-89-9

DL-tartaric acid monoethyl ester

ethanol
64-17-5

ethanol

DL-tartaric acid
133-37-9

DL-tartaric acid

DL-tartaric acid monoethyl ester
608-89-9

DL-tartaric acid monoethyl ester

(+/-)-diethyl tartrate
57968-71-5

(+/-)-diethyl tartrate

Conditions
ConditionsYield
With hydrogenchloride
(2S)-2-methyl-1-butanol
1565-80-6

(2S)-2-methyl-1-butanol

DL-tartaric acid
133-37-9

DL-tartaric acid

tartaric acid bis-(2-methyl-butyl ester)
343326-54-5

tartaric acid bis-(2-methyl-butyl ester)

Conditions
ConditionsYield
With hydrogenchloride di--racemat;

DL-Tartaric Acid Specification

1. Introduction of DL-Tartaric Acid
DL-Tartaric Acid is a kind of food acidifier, it is crystalline powder. The IUPAC Name of it is 2,3-Dihydroxybutanedioic acid.

2. Properties of DL-Tartaric Acid
H bond acceptors: 6
H bond donors: 4
Freely Rotating Bonds: 5
Polar Surface Area: 71.06 Å2
Index of Refraction: 1.585
Molar Refractivity: 26.69 cm3
Molar Volume: 79.5 cm3
Surface Tension: 119.4 dyne/cm
Density: 1.886 g/cm3
Flash Point: 209.4 °C
Enthalpy of Vaporization: 75.13 kJ/mol
Boiling Point: 399.3 °C at 760 mmHg
Vapour Pressure: 4.93E-08 mmHg at 25°C
Melting Point: 210-212 °C(lit.)
Solubility H2O: 0.1 g/mL, clear
Stability: Stable. Incompatible with bases, oxidizing agents, reducing agents, silver.
Appearance: white crystalline powder
Product Categories of DL-Tartaric Acid: Food & Feed ADDITIVES  

3. Structure Descriptors of DL-Tartaric Acid
SMILES: O=C(O)C(O)C(O)C(=O)O
InChI: InChI=1/C4H6O6/c5-1(3(7)8)2(6)4(9)10/h1-2,5-6H,(H,7,8)(H,9,10)
InChIKey: FEWJPZIEWOKRBE-UHFFFAOYAZ
Std. InChI: InChI=1S/C4H6O6/c5-1(3(7)8)2(6)4(9)10/h1-2,5-6H,(H,7,8)(H,9,10)
Std. InChIKey: FEWJPZIEWOKRBE-UHFFFAOYSA-N

4.Safety Information of DL-Tartaric Acid
Hazard Symbols:IrritantXi
Risk Codes:
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Description:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37:Wear suitable protective clothing and gloves. 

5. Preparation of DL-Tartaric Acid
DL-Tartaric acid is mainly present in the form of potassium salt in a variety of plants, fruits. There also a small amount present in free species. Industrial fermentation of glucose to the system used to take D-tartaric acid; raceme fumaric acid can be obtained with the potassium permanganate oxidation; in racemic maleic acid can be obtained with the potassium permanganate oxidation; L-acid wine can be split to obtain raceme.

6. Use of DL-Tartaric Acid
1) DL-Tartaric acid is widely used as beverages and other food acidifier, similar to the use and citric acid. Combination of tartaric acid and tannin can be used as mordant acid dyes, but also for the photographic industry, and the fixation of certain imaging operations, which have a photosensitive iron salts, it can be used to produce a blueprint.
2) DL-Tartaric acid with a variety of metal ions complexation can be used for metal surface cleaning agents and polishing agents.
3) DL-Tartaric acid can be prepared Fehling, but also used in medicine as laxatives and diuretics, but also as a Sims can be fun intermediates.
4) The crystal has piezoelectric properties can be used for the electronics industry.
5) DL-Tartaric Acid is used for chromatographic analysis of reagent and a masking agent. And it also used as split agent for pharmaceutical, food additives, chemical and biological reagents.
6) DL-Tartaric Acid is widely used in food industry, such as beer foam, food sour agent, Jiao flavor agent and used in soft drinks, candy, fruit juice, sauces, cold dish, and baking powder and so on. This product is in line with Japanese food additives Kimisada book.

7. Other details of DL-Tartaric Acid
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Store in a tightly closed container.

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