Conditions | Yield |
---|---|
With bis(cyclopentadienyl)-titanium(III) chloride In tetrahydrofuran at -78 - 20℃; | 68% |
With acetic acid; zinc | |
elektrolytische Reduktion; | |
With alkali elektrolytische Reduktion; | |
Electrolysis; |
Conditions | Yield |
---|---|
With potassium permanganate at 0℃; |
Conditions | Yield |
---|---|
With hydrogenchloride |
Conditions | Yield |
---|---|
With nitric acid |
Conditions | Yield |
---|---|
With nitric acid |
Conditions | Yield |
---|---|
With hydroquinone |
Conditions | Yield |
---|---|
unter Waermeentwicklung; | |
With water |
Conditions | Yield |
---|---|
at 200℃; |
Conditions | Yield |
---|---|
With water | |
With hydrogenchloride | |
With hydrogenchloride im geschlossenen Rohr; | |
With sodium hydroxide; water |
Conditions | Yield |
---|---|
With sodium hydroxide | |
With potassium hydroxide | |
With sodium hydroxide Racemisierung; |
Conditions | Yield |
---|---|
With nitric acid |
Conditions | Yield |
---|---|
With nitric acid |
meso-galactaric acid
DL-tartaric acid
Conditions | Yield |
---|---|
With nitric acid | |
With potassium permanganate | |
With permanganate(VII) ion |
Conditions | Yield |
---|---|
With potassium permanganate at 0℃; |
Conditions | Yield |
---|---|
With zinc |
Conditions | Yield |
---|---|
With water |
DL-tartaric acid
Conditions | Yield |
---|---|
With alkaline permanganate |
Conditions | Yield |
---|---|
With sulfuric acid bei der elektrolytischen Oxydation an einer PbO2-Anode; |
Conditions | Yield |
---|---|
With sodium hydroxide; dihydrogen peroxide at 70 - 80℃; |
Conditions | Yield |
---|---|
With hydrogenchloride | |
With water | |
With alkaline solution |
Conditions | Yield |
---|---|
With aluminium salt | |
With water at 175℃; |
Conditions | Yield |
---|---|
With sulfuric acid; lead dioxide bei der elektrolytischen Oxydation; | |
With dihydrogen peroxide; tungsten(VI) oxide | |
With dihydrogen peroxide; tungsten(VI) oxide |
Conditions | Yield |
---|---|
With sodium chlorate; osmium(VIII) oxide; water | |
With sodium chlorate; osmium(VIII) oxide; water at 50℃; | |
With osmium(VIII) oxide; potassium chlorate; water at 50℃; |
Conditions | Yield |
---|---|
With osmium(VIII) oxide; dihydrogen peroxide; tert-butyl alcohol at 0℃; | |
With osmium(VIII) oxide; dihydrogen peroxide; tert-butyl alcohol at 0℃; |
Conditions | Yield |
---|---|
With sodium hydroxide; dihydrogen peroxide | |
With sodium hydroxide; dihydrogen peroxide at 70 - 80℃; |
Conditions | Yield |
---|---|
With sodium amalgam; ethanol Produkt: Traubensaeureester; |
Conditions | Yield |
---|---|
With hydrazine at 190 - 250℃; |
Conditions | Yield |
---|---|
With sulfuric acid elektrolytische Oxydation; |
Conditions | Yield |
---|---|
In diethyl ether byproducts: H2, cyclopentadiene; Ar atmosphere; 20 h, 95°C; ppt. was filtered off, washed with ether, and dried; elem. anal.; | 93% |
Conditions | Yield |
---|---|
Stage #1: DL-tartaric acid With lithium hydroxide monohydrate In water for 0.166667h; Darkness; Stage #2: Pt(2,2':6',2''-terpyridine)Cl for 0.166667h; | 92% |
ethyl 3-amino-5-fluoro-4,4-dimethoxypentanoate
DL-tartaric acid
Conditions | Yield |
---|---|
In water; isopropyl alcohol at 20℃; for 4h; | 87.1% |
Conditions | Yield |
---|---|
With Dowex 50W-X8 (H+) In benzene Heating; | 82% |
With hydrogenchloride | |
With hydrogenchloride |
Conditions | Yield |
---|---|
In water High Pressure; reaction of In(OH)3, organic ligand and H2O at 110°C for 2 days; elem. anal.; | 75% |
DL-tartaric acid
cyclohexanol
dicyclohexyl tartrate
Conditions | Yield |
---|---|
With acidic ion exchange resin In chloroform for 40h; Heating; | 73% |
DL-tartaric acid
strontium d,l-tartrate
Conditions | Yield |
---|---|
With strontium(II) acetate In water at 100℃; for 48h; Autoclave; | 73% |
DL-tartaric acid
Conditions | Yield |
---|---|
With calcium acetate In water at 60℃; for 48h; | 72% |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In toluene for 12h; Dean-Stark; Reflux; | 72% |
Conditions | Yield |
---|---|
With hydrogenchloride for 24h; Heating; | 70% |
Conditions | Yield |
---|---|
In water soln. of ammonium heptamolybdate tetrahydrate and D,L-tartaric acid in water treated with soln. of H2O2 (35 wt.-%) and aq. ammonia, stirred for 2 h; EtOH added, soln. stored at room temp. for 24 h, ppt. filtered off, washed with EtOH and air-dried; elem. anal.; | 69% |
DL-tartaric acid
tert-butyl 4'-[[2-n-propyl-4-methyl-6-(1-methylbenzimidazol-2-yl)-benzimidazol-1-yl]-methyl]-biphenyl-2-carboxylate
Conditions | Yield |
---|---|
In methanol for 5h; Reflux; | 68.64% |
Conditions | Yield |
---|---|
With arsenic(III) trioxide In water at 20℃; for 48h; | 68% |
Conditions | Yield |
---|---|
With 1-hydroxybenzotriazol-hydrate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 20℃; | 55% |
Conditions | Yield |
---|---|
With sulfuric acid at 80℃; for 1h; | 53% |
2-vinylpyridine
DL-tartaric acid
piperazine dihydrochloride hydrate
1-<2-(2-pyridyl)ethyl>piperazine DL-tartrate
Conditions | Yield |
---|---|
1.) excess piperazine, water, 1 h, reflux; | 34% |
Conditions | Yield |
---|---|
With hydrogenchloride |
methanol
DL-tartaric acid
(+/-)-monomethyltartaric acid
Conditions | Yield |
---|---|
With hydrogenchloride |
ethanol
DL-tartaric acid
DL-tartaric acid monoethyl ester
(+/-)-diethyl tartrate
Conditions | Yield |
---|---|
With hydrogenchloride |
(2S)-2-methyl-1-butanol
DL-tartaric acid
tartaric acid bis-(2-methyl-butyl ester)
Conditions | Yield |
---|---|
With hydrogenchloride di--racemat; |
1. Introduction of DL-Tartaric Acid
DL-Tartaric Acid is a kind of food acidifier, it is crystalline powder. The IUPAC Name of it is 2,3-Dihydroxybutanedioic acid.
2. Properties of DL-Tartaric Acid
H bond acceptors: 6
H bond donors: 4
Freely Rotating Bonds: 5
Polar Surface Area: 71.06 Å2
Index of Refraction: 1.585
Molar Refractivity: 26.69 cm3
Molar Volume: 79.5 cm3
Surface Tension: 119.4 dyne/cm
Density: 1.886 g/cm3
Flash Point: 209.4 °C
Enthalpy of Vaporization: 75.13 kJ/mol
Boiling Point: 399.3 °C at 760 mmHg
Vapour Pressure: 4.93E-08 mmHg at 25°C
Melting Point: 210-212 °C(lit.)
Solubility H2O: 0.1 g/mL, clear
Stability: Stable. Incompatible with bases, oxidizing agents, reducing agents, silver.
Appearance: white crystalline powder
Product Categories of DL-Tartaric Acid: Food & Feed ADDITIVES
3. Structure Descriptors of DL-Tartaric Acid
SMILES: O=C(O)C(O)C(O)C(=O)O
InChI: InChI=1/C4H6O6/c5-1(3(7)8)2(6)4(9)10/h1-2,5-6H,(H,7,8)(H,9,10)
InChIKey: FEWJPZIEWOKRBE-UHFFFAOYAZ
Std. InChI: InChI=1S/C4H6O6/c5-1(3(7)8)2(6)4(9)10/h1-2,5-6H,(H,7,8)(H,9,10)
Std. InChIKey: FEWJPZIEWOKRBE-UHFFFAOYSA-N
4.Safety Information of DL-Tartaric Acid
Hazard Symbols:Xi
Risk Codes:
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Description:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37:Wear suitable protective clothing and gloves.
5. Preparation of DL-Tartaric Acid
DL-Tartaric acid is mainly present in the form of potassium salt in a variety of plants, fruits. There also a small amount present in free species. Industrial fermentation of glucose to the system used to take D-tartaric acid; raceme fumaric acid can be obtained with the potassium permanganate oxidation; in racemic maleic acid can be obtained with the potassium permanganate oxidation; L-acid wine can be split to obtain raceme.
6. Use of DL-Tartaric Acid
1) DL-Tartaric acid is widely used as beverages and other food acidifier, similar to the use and citric acid. Combination of tartaric acid and tannin can be used as mordant acid dyes, but also for the photographic industry, and the fixation of certain imaging operations, which have a photosensitive iron salts, it can be used to produce a blueprint.
2) DL-Tartaric acid with a variety of metal ions complexation can be used for metal surface cleaning agents and polishing agents.
3) DL-Tartaric acid can be prepared Fehling, but also used in medicine as laxatives and diuretics, but also as a Sims can be fun intermediates.
4) The crystal has piezoelectric properties can be used for the electronics industry.
5) DL-Tartaric Acid is used for chromatographic analysis of reagent and a masking agent. And it also used as split agent for pharmaceutical, food additives, chemical and biological reagents.
6) DL-Tartaric Acid is widely used in food industry, such as beer foam, food sour agent, Jiao flavor agent and used in soft drinks, candy, fruit juice, sauces, cold dish, and baking powder and so on. This product is in line with Japanese food additives Kimisada book.
7. Other details of DL-Tartaric Acid
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Store in a tightly closed container.
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