N-nitrobenzenesulfonimide
dibenzenesulfonamide
Conditions | Yield |
---|---|
With water | 100% |
N-fluorobis(benzenesulfon)imide
A
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical
B
dibenzenesulfonamide
Conditions | Yield |
---|---|
With 1,1,1,2,2,2-hexamethyldisilane; copper(l) chloride In acetonitrile at 70℃; for 1h; Schlenk technique; Inert atmosphere; | A 86% B 100% |
tert-butyl 2-phenoxyethaneperoxoate
N-fluorobis(benzenesulfon)imide
A
dibenzenesulfonamide
B
fluoromethyl phenyl ether
Conditions | Yield |
---|---|
In [D3]acetonitrile at 110℃; for 0.0833333h; Inert atmosphere; Sealed tube; | A 94% B n/a |
Conditions | Yield |
---|---|
With sodium hydroxide at 60℃; Concentration; | 93% |
With sodium hydroxide In isopropyl alcohol at 50 - 55℃; for 2h; pH=8 - 10; | 89% |
With dmap; triethylamine In dichloromethane for 2h; Reflux; | 80% |
N-chloro-N-(benzenesulfonyl)benzenesulfonamide
silver(I) trifluoromethanethiolate
A
dibenzenesulfonamide
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 2h; | A n/a B 74% |
2,2-dimethyl-N-(4-methylphenyl)propanamide
N-fluorobis(benzenesulfon)imide
A
N-(4-((N-( phenylsulfonyl)phenylsulfonamido)methyl)phenyl)pivalamide
B
dibenzenesulfonamide
Conditions | Yield |
---|---|
With palladium diacetate In 1,2-dichloro-ethane at 90℃; for 1.5h; | A 73% B 17% |
Conditions | Yield |
---|---|
With hydrogenchloride In acetone for 2h; | 72% |
Conditions | Yield |
---|---|
In acetone at 20℃; for 2h; Product distribution; other p-substituted arenesulfinic acids and their sodium salts, other N-sodio-N-chloroarenesulfonamides; | 64% |
In acetone at 20℃; for 2h; | 64% |
N-fluorobis(benzenesulfon)imide
dibenzenesulfonamide
Conditions | Yield |
---|---|
With copper(l) chloride In acetonitrile at 70℃; for 1h; Schlenk technique; Inert atmosphere; | 62% |
N-(4,5-dimethyl-[1,1'-biphenyl]-2-yl)pivalamide
N-fluorobis(benzenesulfon)imide
A
N-(4-methyl-5-((N-(phenylsulfonyl)phenylsulfonamido)methyl)biphenyl-2-yl)pivalamide
B
dibenzenesulfonamide
Conditions | Yield |
---|---|
With palladium diacetate; sodium hydrogencarbonate In 1,2-dichloro-ethane at 90℃; for 13h; | A 58% B 15% |
N-fluorobis(benzenesulfon)imide
A
dibenzenesulfonamide
Conditions | Yield |
---|---|
With 2.9-dimethyl-1,10-phenanthroline; copper(ll) bromide In acetonitrile at 25℃; for 6h; Inert atmosphere; | A 15.8% B 14% C 54% D 6.6% |
Conditions | Yield |
---|---|
With ammonium chloride In acetone |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 88 percent / ammonia 2: 53 percent / OH- / 50 - 55 °C View Scheme |
N-fluorobis(benzenesulfon)imide
dibenzenesulfonamide
Conditions | Yield |
---|---|
With 3-fluoro-1-nitrobenzene; C20H28N4O2Pd*2CHF3O3S In [D3]acetonitrile at 50℃; Kinetics; Inert atmosphere; Sealed tube; | |
With 3-fluoro-1-nitrobenzene; C20H28N4O2Pd(2+)*2CF3O3S(1-) In [D3]acetonitrile at 50℃; Kinetics; Inert atmosphere; |
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical
N-fluorobis(benzenesulfon)imide
A
2,2,6,6-tetramethyl-piperidinium cation
B
dibenzenesulfonamide
Conditions | Yield |
---|---|
With methanol; copper acetylacetonate; N-methyl-N-phenylmethacrylamide; water In acetonitrile at 80℃; for 24h; Schlenk technique; Inert atmosphere; |
Conditions | Yield |
---|---|
Stage #1: dibenzenesulfonamide With sodium hydrogencarbonate In water at 15 - 20℃; for 0.25h; Stage #2: With chlorine In water | 98% |
With tert-butylhypochlorite In methanol at 20℃; for 0.0833333h; Time; | 95% |
With chlorine; sodium hydrogencarbonate In water at 15 - 20℃; | 94% |
Conditions | Yield |
---|---|
With N-Bromosuccinimide In 1,2-dichloro-ethane at 20℃; for 12h; | 96% |
dibenzenesulfonamide
Conditions | Yield |
---|---|
With n-butyllithium In pyridine Heating; | 94% |
dibenzenesulfonamide
2-thiophen-3-yl-4,5-dihydrooxazole
Conditions | Yield |
---|---|
In 1,4-dioxane for 2h; Reflux; Inert atmosphere; | 94% |
dibenzenesulfonamide
2-(thiophen-2-yl)-4,5-dihydrooxazole
Conditions | Yield |
---|---|
In 1,4-dioxane for 2h; Reflux; Inert atmosphere; | 93% |
Conditions | Yield |
---|---|
In 1,4-dioxane for 0.75h; Reflux; Inert atmosphere; | 93% |
dibenzenesulfonamide
Conditions | Yield |
---|---|
With 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione In dichloromethane at 20℃; for 7h; Inert atmosphere; Darkness; | 93% |
Multi-step reaction with 2 steps 1.1: dichloromethane / 0.5 h / 20 °C / Inert atmosphere 1.2: 2 h / 20 °C / Inert atmosphere 2.1: sodium hydrogencarbonate / dichloromethane / 0.17 h / 20 °C / Inert atmosphere; Darkness 2.2: 5 h / 20 °C / Inert atmosphere; Darkness View Scheme |
dibenzenesulfonamide
methyl iodide
N-(benzenesulfonyl)-N-methyl-benzenesulfonamide
Conditions | Yield |
---|---|
Stage #1: dibenzenesulfonamide With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: methyl iodide In N,N-dimethyl-formamide at 20℃; for 4h; Inert atmosphere; | 92% |
With silver(l) oxide 1.) H2O, 2.) Et2O, reflux, 6 h; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; copper diacetate In nitromethane at 120℃; for 14h; regioselective reaction; | 91% |
Conditions | Yield |
---|---|
Stage #1: phthalimide With bis(benzonitrile)palladium(II) dichloride In 1,2-dichloro-ethane at 70℃; for 1h; Stage #2: cis-1-phenyl-1-propylene; dibenzenesulfonamide With 4-tert-Butylcatechol; bis(tertbutylcarbonyloxy)iodobenzene In 1,2-dichloro-ethane at 70℃; for 20h; diastereoselective reaction; | 90% |
dibenzenesulfonamide
Conditions | Yield |
---|---|
In chloroform at 25℃; for 0.5h; | 90% |
dibenzenesulfonamide
Conditions | Yield |
---|---|
In 1,4-dioxane for 2h; Reflux; Inert atmosphere; | 90% |
dibenzenesulfonamide
N,N-dimethyl-formamide
N,N-dimethyl-N′-(phenylsulfonyl)formimidamide
Conditions | Yield |
---|---|
With triethylamine; p-toluenesulfonyl chloride at 25℃; for 4h; | 90% |
Conditions | Yield |
---|---|
With 2-iodo-1,3-dimethoxybenzene; 3-chloro-benzenecarboperoxoic acid In acetonitrile at 20℃; | 90% |
With 2-iodo-1,3-dimethoxybenzene; 3-chloro-benzenecarboperoxoic acid In acetonitrile at 20℃; for 5h; | 86% |
dibenzenesulfonamide
benzene
N-phenyl-N-(phenylsulfonyl)benzenesulfonamide
Conditions | Yield |
---|---|
With tert.-butylnitrite; 2,3-dicyano-5,6-dichloro-p-benzoquinone In acetonitrile at 25℃; for 24h; Irradiation; | 89% |
1-methyl-4-isopropenylbenzene
dibenzenesulfonamide
N-(2-(p-tolyl)allyl)benzenesulfonamide
Conditions | Yield |
---|---|
With N-Bromosuccinimide In dichloromethane at 20℃; | 88% |
Conditions | Yield |
---|---|
for 3h; Ambient temperature; | 87% |
Conditions | Yield |
---|---|
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; 1-(benzyloxy)-1λ3-benzo[d][1,2]iodaoxol-3(1H)-one In 1,2-dichloro-ethane at 40℃; for 12h; Irradiation; Inert atmosphere; | 87% |
(4-biphenylyl)acetic acid
dibenzenesulfonamide
N-([1,1'-diphenyl]-4-ylmethyl)-N-(phenylsulfonyl)benzenesulfonamide
Conditions | Yield |
---|---|
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; 1-butoxy-1λ3-benzo[d][1,2]iodaoxol-3(1H)-one In dichloromethane at 40℃; for 24h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Schlenk technique; Irradiation; | 87% |
Conditions | Yield |
---|---|
With N-Bromosuccinimide In dichloromethane at 20℃; | 86% |
4-tolylacetic acid
dibenzenesulfonamide
N-(4-methylbenzyl)-N-(phenylsulfonyl)benzenesulfonamide
Conditions | Yield |
---|---|
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; 1-butoxy-1λ3-benzo[d][1,2]iodaoxol-3(1H)-one In dichloromethane at 40℃; for 24h; Inert atmosphere; Schlenk technique; Irradiation; | 86% |
Conditions | Yield |
---|---|
With N-Bromosuccinimide In dichloromethane at 20℃; | 85% |
Conditions | Yield |
---|---|
Stage #1: [bis(acetoxy)iodo]benzene; dibenzenesulfonamide In acetonitrile at 40℃; for 0.5h; Stage #2: N-pivaloyl indole In acetonitrile at 20℃; for 7h; | 85% |
Stage #1: [bis(acetoxy)iodo]benzene; dibenzenesulfonamide In acetonitrile at 40℃; for 0.5h; Inert atmosphere; Stage #2: N-pivaloyl indole In acetonitrile at 40℃; for 7h; Inert atmosphere; | 79% |
Stage #1: [bis(acetoxy)iodo]benzene; dibenzenesulfonamide In acetonitrile at 20℃; for 0.5h; Inert atmosphere; Stage #2: N-pivaloyl indole In acetonitrile at 40℃; for 7h; Inert atmosphere; | 75% |
ethyl 2-phenyldiazoacetate
dibenzenesulfonamide
Conditions | Yield |
---|---|
In chloroform at 25℃; for 0.5h; Solvent; Temperature; | 84% |
dibenzenesulfonamide
Conditions | Yield |
---|---|
In chloroform at 25℃; for 1h; | 84% |
Conditions | Yield |
---|---|
With dipotassium peroxodisulfate In tetrahydrofuran at 80℃; for 12h; | 84% |
EINECS of Dibenzenesulfonimide (CAS NO.2618-96-4): 220-051-4
Empirical Formula: C12H11NO4S2
Molecular Weight: 297.35 g/mol
Index of Refraction: 1.61
Density: 1.418 g/cm3
Flash Point: 244.5 °C
Melting point: 150-155 °C
Enthalpy of Vaporization: 74.52 kJ/mol
Boiling Point: 480.6 °C at 760 mmHg
Vapour Pressure: 2.13E-09 mmHg at 25 °C
Structure of Dibenzenesulfonimide (CAS NO.2618-96-4):
IUPAC Name: N-(Benzenesulfonyl)benzenesulfonamide
Dibenzenesulfonimide (CAS NO.2618-96-4) can be used for electroplating additive intermediate for the preparation of electroless nickel plating brightener with a good soft and light effect.
Safety Statements: 22-24/25
S22:Do not breathe dust.
S24/25:Avoid contact with skin and eyes.
Dibenzenesulfonimide , its cas register number is 2618-96-4. It also can be N-(Phenylsulphonyl)benzenesulphonamide ; Bis(benzene sulphonyl)-imide ; and BBI .
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