Product Name

  • Name

    DICYCLOHEXYL KETONE

  • EINECS
  • CAS No. 119-60-8
  • Article Data71
  • CAS DataBase
  • Density 0.97g/cm3
  • Solubility
  • Melting Point 57°C
  • Formula C13H22 O
  • Boiling Point 266.4°Cat760mmHg
  • Molecular Weight 194.317
  • Flash Point 123.4°C
  • Transport Information
  • Appearance
  • Safety Poison by intravenous route. See also KETONES. A flammable liquid. When heated to decomposition it emits acrid and irritating fumes.
  • Risk Codes
  • Molecular Structure Molecular Structure of 119-60-8 (DICYCLOHEXYL KETONE)
  • Hazard Symbols
  • Synonyms Cyclohexylketone (7CI,8CI); Bicyclohexyl ketone; Dicyclohexyl ketone;Dicyclohexylmethanone; NSC 49725; NSC 60007
  • PSA 17.07000
  • LogP 3.71610

Synthetic route

Dicyclohexylmethanol
4453-82-1

Dicyclohexylmethanol

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With 6C6H15P*4CF3O3S(1-)*2Ru(2+); acetone In 2,2,2-trifluoroethanol at 20℃; for 3h; Reagent/catalyst;99%
With tetra-O-acetyl riboflavin; lithium trifluoromethanesulfonate; 1,3-diisopropylthiourea In water; acetonitrile at 22℃; for 24h; Inert atmosphere; Sealed tube; Irradiation;90%
With isobutyl 4-[bis(acetoxy)iodo]phenylsulfonate; ruthenium trichloride In water; acetonitrile at 20℃; for 8h;89%
cyclohexanylcarbonyl chloride
2719-27-9

cyclohexanylcarbonyl chloride

cyclohexyltrifluoro-λ4-borane potassium salt
446065-11-8

cyclohexyltrifluoro-λ4-borane potassium salt

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With potassium fluoride; (1,2-dimethoxyethane)dichloronickel(II); Ir(dF(CF3)ppy)2(bpy)PF6; 4,4'-di-tert-butyl-2,2'-bipyridine In 1,2-dimethoxyethane at 24℃; for 24h; Inert atmosphere; Sealed tube; Irradiation;84%
tricyclohexylborane
1088-01-3

tricyclohexylborane

lithium tris(phenylthio)methanide
14572-78-2

lithium tris(phenylthio)methanide

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With sodium hydroxide; dihydrogen peroxide Ambient temperature;80%
dicyclohexyl ketone oxime
6316-03-6

dicyclohexyl ketone oxime

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With tetraethyl ammonium permanganate at 20℃; for 0.666667h;80%
Dicyclohexylmethanol
4453-82-1

Dicyclohexylmethanol

A

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

B

cyclohexanone

cyclohexanone

Conditions
ConditionsYield
With air; sodium nitrite In trifluoroacetic acid at 0 - 20℃; for 5h;A 79%
B n/a
1-iodocyclohexane
626-62-0

1-iodocyclohexane

chloroformic acid ethyl ester
541-41-3

chloroformic acid ethyl ester

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With [2,2]bipyridinyl; chloro-trimethyl-silane; nickel(II) bromide 2-methoxyethyl ether complex; zinc In tetrahydrofuran; N,N-dimethyl acetamide at 40℃; for 2h; Sealed tube; Inert atmosphere;76%
2'-cyclohexyl-2'-phenylsulfinylspiro
95110-49-9

2'-cyclohexyl-2'-phenylsulfinylspiro

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With sodium phenylselenide In ethanol for 16h; Heating;75%
With sodium phenylselenide In ethanol for 16h; Heating;75%
1,1'-carbonyldiimidazole
530-62-1

1,1'-carbonyldiimidazole

cyclohexylmagnesium bromide
931-50-0

cyclohexylmagnesium bromide

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
In tetrahydrofuran at -80 - 20℃; Inert atmosphere;75%
1,1-Diphenylmethanol
91-01-0

1,1-Diphenylmethanol

A

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

B

Dicyclohexylmethanol
4453-82-1

Dicyclohexylmethanol

C

cyclohexylphenylmethanol
945-49-3

cyclohexylphenylmethanol

Conditions
ConditionsYield
With hydrogen In water at 50℃; under 15001.5 Torr; for 6h; chemoselective reaction;A 7 %Spectr.
B 75%
C 17%
dicyclohexylacetic acid
52034-92-1

dicyclohexylacetic acid

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With (2,2'-dipyridyl)bis(5-methyl-2-(4-fluoro)phenylpyridine-N,C)iridium(III) hexafluorophosphate; oxygen; sodium carbonate; 1,1'-diethyl-4,4'-bipyridinium diperchlorate In dimethyl sulfoxide at 20℃; under 760.051 Torr; for 16h; Irradiation;65%
1-bromocyclohexane
108-85-0

1-bromocyclohexane

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
Stage #1: 1-bromocyclohexane With magnesium In tetrahydrofuran at 20℃; for 1h;
Stage #2: cyclohexanecarbaldehyde In tetrahydrofuran at 0 - 20℃; for 2h;
Stage #3: With 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione; potassium carbonate In tetrahydrofuran; tert-butyl alcohol for 20h; Reflux; Darkness;
60%
cyclohexane
110-82-7

cyclohexane

1-(cyclohexanecarbonyl)pyrrolidine-2,5-dione

1-(cyclohexanecarbonyl)pyrrolidine-2,5-dione

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With (1,2-dimethoxyethane)dichloronickel(II); [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; potassium carbonate; 4,4'-di-tert-butyl-2,2'-bipyridine In benzene at 20℃; for 16h; Irradiation; Inert atmosphere;60%
With potassium phosphate; sodium tungstate (VI) dihydrate; [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; Ni[(4,4′-di-tert-butyl-2,2′-bipyridine)(H2O)4]Cl2; lithium chloride In benzene at 20℃; for 24h; Inert atmosphere; Sealed tube; Schlenk technique; Irradiation;52%
cyclohexanecarboxylic acid anhydride
22651-87-2

cyclohexanecarboxylic acid anhydride

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With [2,2]bipyridinyl; (1,2-dimethoxyethane)dichloronickel(II); Ir[dF(OMe)ppy]2-(dtbbpy)PF6; 1,8-diazabicyclo[5.4.0]undec-7-ene In 1,4-dioxane at 25℃; for 36h; Sealed tube; Inert atmosphere; Irradiation;50%
cyclohexylmercury bromide
10192-55-9

cyclohexylmercury bromide

Ni(CO)4

Ni(CO)4

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With potassium iodide In N,N-dimethyl-formamide at 80℃; for 20h;47%
trimethyl<<(1Z)-1-cyclohexylhepta-1,6-dienyl>oxy>silane
141694-46-4

trimethyl<<(1Z)-1-cyclohexylhepta-1,6-dienyl>oxy>silane

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With 9,10-Dicyanoanthracene In acetonitrile for 120h; Irradiation;37%
With 9,10-Dicyanoanthracene In acetonitrile for 65h; Irradiation;37 % Chromat.
2,6-diisopropylphenyl isocyanate
28178-42-9

2,6-diisopropylphenyl isocyanate

C24H26NO4Si(1-)

C24H26NO4Si(1-)

A

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

B

1,3-bis(2,6-diisopropylphenyl)urea

1,3-bis(2,6-diisopropylphenyl)urea

Conditions
ConditionsYield
With Ru photocatalyst; Ni catalyst In N,N-dimethyl-formamide Mechanism; Irradiation;A n/a
B 16%
carbon dioxide
124-38-9

carbon dioxide

cyclohexylmagnesiumchloride
931-51-1

cyclohexylmagnesiumchloride

trans-2-iodocyclohexanecarboxylic acid

trans-2-iodocyclohexanecarboxylic acid

B

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
Stage #1: cyclohexylmagnesiumchloride With titanium(IV) isopropylate In diethyl ether at -78 - -30℃; for 0.166667h;
Stage #2: carbon dioxide In diethyl ether at -30 - 0℃; for 0.25h;
Stage #3: With iodine In diethyl ether at 20℃; for 2h;
A 14%
B 0.12 g
cyclohexane
110-82-7

cyclohexane

carbon monoxide
201230-82-2

carbon monoxide

A

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

B

Cyclohexyl methyl ketone
823-76-7

Cyclohexyl methyl ketone

C

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

D

Cyclohexanecarboxylic acid
98-89-5

Cyclohexanecarboxylic acid

Conditions
ConditionsYield
With tris(tetrabutylammonium)12-tungstophosphate In acetonitrile at 25℃; under 760 Torr; for 16h; Product distribution; Mechanism; Irradiation; other alkanes and aromatic reactants; var. solvents and times;A 4.1 % Turnov.
B 2.7 % Turnov.
C 8%
D n/a
oxalyl dichloride
79-37-8

oxalyl dichloride

cyclohexyl magnesium (1+); bromide

cyclohexyl magnesium (1+); bromide

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

diethyl ether
60-29-7

diethyl ether

ethyl cyclohexanecarboxylate
3289-28-9

ethyl cyclohexanecarboxylate

cyclohexylmagnesiumchloride
931-51-1

cyclohexylmagnesiumchloride

A

cyclohexylcyclohexane
92-51-3

cyclohexylcyclohexane

B

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

C

α,α-dicyclohexyl-cyclohexanemethanol
17687-74-0

α,α-dicyclohexyl-cyclohexanemethanol

cyclohexyl chloride
542-18-7

cyclohexyl chloride

ethyl cyclohexanecarboxylate
3289-28-9

ethyl cyclohexanecarboxylate

A

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

B

α,α-dicyclohexyl-cyclohexanemethanol
17687-74-0

α,α-dicyclohexyl-cyclohexanemethanol

Conditions
ConditionsYield
With diethyl ether; magnesium
With sodium; pentane
ethyl cyclohexanecarboxylate
3289-28-9

ethyl cyclohexanecarboxylate

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With diethyl ether; cyclohexylmagnesiumchloride
With diethyl ether; tert.-butyl lithium
With tert.-butyl lithium In diethyl ether Heating;
exifone
56547-92-3

exifone

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With ethyl acetate; platinum Hydrogenation;
dicyclohexyl-hydroxy-acetic acid
6313-70-8

dicyclohexyl-hydroxy-acetic acid

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With sulfuric acid
oxalyl dichloride
79-37-8

oxalyl dichloride

cyclohexylmagnesium bromide
931-50-0

cyclohexylmagnesium bromide

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

cyclohexylmagnesium bromide
931-50-0

cyclohexylmagnesium bromide

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With oxalyl dichloride
With cyclohexanylcarbonyl chloride
Multi-step reaction with 3 steps
1: benzene
2: KOH-solution
3: concentrated sulfuric acid
View Scheme
1,1-Dicyclohexyl-2-methoxy-ethanol
66031-37-6

1,1-Dicyclohexyl-2-methoxy-ethanol

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
(electrochemical oxidation);
Dicyclohexyl-chlor-methylboronsaeuredimethylester
52712-18-2

Dicyclohexyl-chlor-methylboronsaeuredimethylester

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
With sodium hydroxide; dihydrogen peroxide
1-Cyclohexanecarbonyl-cyclohexanecarboxylic acid; compound with diisopropyl-amine
61259-06-1

1-Cyclohexanecarbonyl-cyclohexanecarboxylic acid; compound with diisopropyl-amine

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
at 150 - 200℃;
N-phenyl-benzimidoyl chloride
4903-36-0

N-phenyl-benzimidoyl chloride

C19H33BN(1-)*K(1+)

C19H33BN(1-)*K(1+)

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Conditions
ConditionsYield
(i) THF, (ii) aq. NaOH, H2O2; Multistep reaction;
α-picoline
109-06-8

α-picoline

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

1,1-dicyclohexyl-2-(pyridin-2-yl)ethanol
102658-00-4

1,1-dicyclohexyl-2-(pyridin-2-yl)ethanol

Conditions
ConditionsYield
Stage #1: α-picoline With n-butyllithium In tetrahydrofuran; hexane at -78 - -20℃; Inert atmosphere;
Stage #2: dicyclohexyl ketone In tetrahydrofuran; hexane at -20℃; Inert atmosphere;
Stage #3: With water; ammonium chloride In tetrahydrofuran; hexane
100%
4-Phenyl-1-butyne
16520-62-0

4-Phenyl-1-butyne

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

1,1-dicyclohexyl-5-phenyl-2-pentyn-1-ol
1393658-19-9

1,1-dicyclohexyl-5-phenyl-2-pentyn-1-ol

Conditions
ConditionsYield
Stage #1: 4-Phenyl-1-butyne With n-butyllithium In tetrahydrofuran; hexanes at -78℃; for 1h;
Stage #2: dicyclohexyl ketone In tetrahydrofuran; hexanes at -78 - 20℃; for 3.5h;
100%
triethylsilane
617-86-7

triethylsilane

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

(dicyclohexylmethoxy)(triethyl)silane

(dicyclohexylmethoxy)(triethyl)silane

Conditions
ConditionsYield
With (N,N'-dicyclohexyl-2H-imidazol-2-ylidene)CuCl; sodium t-butanolate In toluene at 80℃; for 0.5h;99%
With sodium t-butanolate; [CuCl(N,N'-bis(cyclohexyl)imidazol-2-ylidene)] In toluene at 80℃; for 0.5h;99%
With (1,3-bis(9-ethyl-9H-fluoren-9-yl)imidazol-2-ylidene)copper(I) chloride; potassium tert-butylate In tetrahydrofuran at 65℃; for 4h; Catalytic behavior; Solvent; Time; Reagent/catalyst; Temperature; Inert atmosphere; Schlenk technique;98%
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

dicyclohexylmethan-d-ol

dicyclohexylmethan-d-ol

Conditions
ConditionsYield
With sodium borodeuteride In methanol at 25℃; for 2h; Cooling with ice; Inert atmosphere;99%
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Dicyclohexylmethanol
4453-82-1

Dicyclohexylmethanol

Conditions
ConditionsYield
Stage #1: dicyclohexyl ketone With bis-{[N,N′-bis(2,6-(di-isopropyl)phenyl)imidazol-2-ylidene]-(1H-1,2,4-triazol-1-yl)}copper(I) In tetrahydrofuran at 55℃; for 14h;
Stage #2: With sodium hydroxide In methanol; water at 25℃; for 1.5h;
97%
With methanol; sodium tetrahydroborate at 0 - 20℃;96%
With methanol; sodium tetrahydroborate at 0 - 20℃;96%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

1,1-dicyclohexyl-1-pentanol

1,1-dicyclohexyl-1-pentanol

Conditions
ConditionsYield
In tetrahydrofuran; hexane at -78℃; for 5h;96%
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

1,1-dicyclohexylprop-2-yn-1-ol
10562-70-6

1,1-dicyclohexylprop-2-yn-1-ol

Conditions
ConditionsYield
Stage #1: trimethylsilylacetylene With n-butyllithium In tetrahydrofuran; hexane at -10℃; for 1h; Inert atmosphere;
Stage #2: dicyclohexyl ketone In tetrahydrofuran; hexane at -10 - 0℃; for 3h; Inert atmosphere;
Stage #3: With sodium hydroxide In tetrahydrofuran; methanol; hexane at 0 - 20℃; Inert atmosphere;
94%
2,2-dimethyl-1,3-dioxolane
2916-31-6

2,2-dimethyl-1,3-dioxolane

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

2,2-Dicyclohexyl-[1,3]dioxolane

2,2-Dicyclohexyl-[1,3]dioxolane

Conditions
ConditionsYield
With Montmorillonite clay KSF at 110℃; for 0.25h; Irradiation;92%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Dicyclohexyltrimethylsilylenolether
66534-90-5

Dicyclohexyltrimethylsilylenolether

Conditions
ConditionsYield
With lithium hexamethyldisilazane92%
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

C17H32O2

C17H32O2

Conditions
ConditionsYield
With Montmorillonite clay KSF at 75℃; for 0.0333333h; Irradiation;91%
triethylsilane
617-86-7

triethylsilane

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

A

(cyclohexylidenemethyl)cyclohexane
27428-33-7

(cyclohexylidenemethyl)cyclohexane

B

(dicyclohexylmethoxy)(triethyl)silane

(dicyclohexylmethoxy)(triethyl)silane

Conditions
ConditionsYield
With [(SIMes)PFMe2][B(C6F5)4]2 In dichloromethane-d2 at 20℃; for 1h; Temperature; Reagent/catalyst; Inert atmosphere; Schlenk technique; Glovebox;A 11%
B 89%
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

1,2-dichlorovinyl phenyl ether
89894-42-8

1,2-dichlorovinyl phenyl ether

1,1-dicyclohexyl-3-phenoxyprop-2-yn-1-ol

1,1-dicyclohexyl-3-phenoxyprop-2-yn-1-ol

Conditions
ConditionsYield
Stage #1: 1,2-dichlorovinyl phenyl ether With n-butyllithium In diethyl ether; hexane at -78 - -20℃; for 2h;
Stage #2: dicyclohexyl ketone In diethyl ether; hexane at -78 - 20℃;
88%
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

1,2-Epoxy-3-bromopropane
3132-64-7

1,2-Epoxy-3-bromopropane

4-Bromomethyl-2,2-dicyclohexyl-[1,3]dioxolane
91540-05-5

4-Bromomethyl-2,2-dicyclohexyl-[1,3]dioxolane

Conditions
ConditionsYield
With tin(IV) chloride In tetrachloromethane for 2.5h; Ambient temperature;86.8%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

aniline
62-53-3

aniline

C20H28N2

C20H28N2

Conditions
ConditionsYield
With Fe3O4(at)cellulose-OSO3H nanocomposite In ethanol at 20℃; for 1.5h; Green chemistry;85%
1-Pentyne
627-19-0

1-Pentyne

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

1,1-dicyclohexylhex-2-yn-1-ol

1,1-dicyclohexylhex-2-yn-1-ol

Conditions
ConditionsYield
Stage #1: 1-Pentyne With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: dicyclohexyl ketone In tetrahydrofuran; hexane at -78 - 20℃; for 3h; Inert atmosphere;
85%
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

1-phenyl-2-bromoethane
103-63-9

1-phenyl-2-bromoethane

1,1-dicyclohexyl-3-phenyl-propan-1-ol
1262387-08-5

1,1-dicyclohexyl-3-phenyl-propan-1-ol

Conditions
ConditionsYield
Stage #1: 1-phenyl-2-bromoethane With magnesium In tetrahydrofuran at -20℃; for 1h; Inert atmosphere;
Stage #2: dicyclohexyl ketone In tetrahydrofuran at 20℃; for 3.25h;
84%
3,4-dihydro-2H-pyran
110-87-2

3,4-dihydro-2H-pyran

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

C18H30O2

C18H30O2

Conditions
ConditionsYield
Stage #1: 3,4-dihydro-2H-pyran With n-butyllithium In tetrahydrofuran; hexane at 0 - 20℃; for 3.16667h; Inert atmosphere;
Stage #2: dicyclohexyl ketone In tetrahydrofuran; hexane at -78 - 20℃; for 2h;
83%
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

2-(tert-butyldimethylsilyloxy)ethyl bromide
86864-60-0

2-(tert-butyldimethylsilyloxy)ethyl bromide

C21H42O2Si

C21H42O2Si

Conditions
ConditionsYield
Stage #1: 2-(tert-butyldimethylsilyloxy)ethyl bromide With magnesium In diethyl ether at 25℃; for 1h; Inert atmosphere;
Stage #2: dicyclohexyl ketone In diethyl ether for 3h; Inert atmosphere;
82.2%
1,3-Benzothiazole
95-16-9

1,3-Benzothiazole

dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

1-(2-benzothiazolyl)-1,1-dicyclohexylmethanol
1401254-53-2

1-(2-benzothiazolyl)-1,1-dicyclohexylmethanol

Conditions
ConditionsYield
Stage #1: 1,3-Benzothiazole; dicyclohexyl ketone With tetrakis{[tris(dimethylamino)phosphoranyliden]amino}phosphonium fluoride; tris(trimethylsilyl)amine In toluene at 20℃; for 24h; Inert atmosphere;
Stage #2: In tetrahydrofuran
82%
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

3-(benzotriazol-1-yl)-3-ethoxy-1-propene
161607-20-1

3-(benzotriazol-1-yl)-3-ethoxy-1-propene

4-(Benzotriazol-1-yl)-1,1-dicyclohexyl-4-ethoxybut-3-en-1-ol

4-(Benzotriazol-1-yl)-1,1-dicyclohexyl-4-ethoxybut-3-en-1-ol

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran 1.) -78 deg C, 10 min, 2.) -78 deg C, 3 h; 20 deg C, 12 h;81%
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

A

(cyclohexylidenemethyl)cyclohexane
27428-33-7

(cyclohexylidenemethyl)cyclohexane

B

dicyclohexylmethane
3178-23-2

dicyclohexylmethane

Conditions
ConditionsYield
With triethylsilane; [(SIMes)PFMe2][B(C6F5)4]2 In dichloromethane-d2 at 50℃; for 24h; Temperature; Reagent/catalyst; Inert atmosphere; Glovebox; Schlenk technique;A 19%
B 81%
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

A

1,5-dicyclohexyl-1H-tetrazole
92107-64-7

1,5-dicyclohexyl-1H-tetrazole

B

1-cyclohexyl-5-cyclohexylaminotetrazole
73565-25-0

1-cyclohexyl-5-cyclohexylaminotetrazole

Conditions
ConditionsYield
With trifluorormethanesulfonic acid; trimethylsilylazide In dichloromethane at 20℃; for 5h; Inert atmosphere; regioselective reaction;A 80%
B 12%
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

cyclohexylidene cyclohexane

cyclohexylidene cyclohexane

Conditions
ConditionsYield
With naphthalene; lithium In tetrahydrofuran for 6.5h; McMurry olefination; Heating;78%
With titanium(III) chloride In tetrahydrofuran 1.) reflux, 1 h, 2.) reflux, 10 h;20%
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

Methyltriphenylphosphonium bromide
1779-49-3

Methyltriphenylphosphonium bromide

ethene-1,1-diyldicyclohexane
57013-04-4

ethene-1,1-diyldicyclohexane

Conditions
ConditionsYield
Stage #1: Methyltriphenylphosphonium bromide With n-butyllithium In tetrahydrofuran at 0℃; for 2.75h; Inert atmosphere;
Stage #2: dicyclohexyl ketone In tetrahydrofuran at 0 - 20℃; Inert atmosphere;
78%
Stage #1: Methyltriphenylphosphonium bromide With sodium hexamethyldisilazane; sodium t-butanolate In tetrahydrofuran at 0℃; for 0.5h;
Stage #2: dicyclohexyl ketone In tetrahydrofuran at 20℃;
75%
Stage #1: Methyltriphenylphosphonium bromide With sodium hexamethyldisilazane In tetrahydrofuran at 0℃; for 1h;
Stage #2: dicyclohexyl ketone In tetrahydrofuran at 0 - 20℃;
41%
With n-butyllithium In tetrahydrofuran at 0 - 20℃; for 48h;
Stage #1: Methyltriphenylphosphonium bromide With n-butyllithium In tetrahydrofuran at 0 - 20℃; for 3h; Inert atmosphere;
Stage #2: dicyclohexyl ketone at 0 - 20℃; for 48h; Inert atmosphere;
dicyclohexyl ketone
119-60-8

dicyclohexyl ketone

4-t-butylbenzenethiol
2396-68-1

4-t-butylbenzenethiol

C22H35OPS

C22H35OPS

Conditions
ConditionsYield
With lithium tert-butoxide In chloroform at 25℃; for 0.5h; Atherton-Todd Synthesis;76%

Dicyclohexyl ketone Chemical Properties

Empirical Formula: C13H22O
Molecular Weight: 194.3132 g/mol
EINECS: 204-336-0 
Index of Refraction: 1.49
Density: 0.97 g/cm3
Flash Point: 123.4 °C
Enthalpy of Vaporization: 50.43 kJ/mol
Boiling Point: 266.4 °C at 760 mmHg
Vapour Pressure: 0.00868 mmHg at 25 °C 
Structure of Dicyclohexyl ketone (CAS NO.119-60-8):
                   
IUPAC Name of Dicyclohexyl ketone (CAS NO.119-60-8): Dicyclohexylmethanone
Canonical SMILES: C1CCC(CC1)C(=O)C2CCCCC2
InChI: InChI=1S/C13H22O/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
InChIKey: TWXWPPKDQOWNSX-UHFFFAOYSA-N
Product Categories of Dicyclohexyl ketone (CAS NO.119-60-8): Carbonyl Compounds;Ketones

Dicyclohexyl ketone Toxicity Data With Reference

1.    

ivn-mus LD50:56 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#06751 .

Dicyclohexyl ketone Consensus Reports

Reported in EPA TSCA Inventory.

Dicyclohexyl ketone Safety Profile

Poison by intravenous route. See also KETONES. A flammable liquid. When heated to decomposition it emits acrid and irritating fumes.
Safety Statements: 23-24/25 
S23:Do not breathe vapour. 
S24/25:Avoid contact with skin and eyes.

Dicyclohexyl ketone Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid

Dicyclohexyl ketone Specification

 Dicyclohexyl ketone ,its cas register number is 119-60-8. It also can be called Methanone, dicyclohexyl- ; Dicyclohexylmethanone ; Ketone, dicyclohexyl ;and Cyclohexyl ketone .

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