Diethylene glycol bis-glycidyl ether supplier

Name
DIETHYLENGLYKOL-DIGLYCIDYLETHER
EINECS
CAS No. 4206-61-5
Article Data8
CAS DataBase
Density 1.165g/cm³
Solubility
Melting Point
Formula C10H18 O5
Boiling Point 313°Cat760mmHg
Molecular Weight 218.25
Flash Point 127.3°C
Transport Information
Appearance
Safety Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.
Risk Codes 19
Molecular Structure
Hazard Symbols
Synonyms Ether,bis[2-(2,3-epoxypropoxy)ethyl] (6CI,7CI,8CI); 4,7,10-Trioxatridecane,1,2:12,13-diepoxy-; Diethylene glycol bis-glycidyl ether; Diethylene glycoldiglycidyl ether; Diglycidyl diethyleneglycol ether; NSC 517936
PSA 52.75000
LogP -0.16620

Synthetic route

: 57947-82-7
bis(allyloxy)diethylene glycol

: 4206-61-5
diethylene glycol diglycidyl ether

Conditions

Conditions	Yield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃; for 24h; Inert atmosphere;	98%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 20℃; for 24h;

: 106-89-8
epichlorohydrin

: 111-46-6
diethylene glycol

: 4206-61-5
diethylene glycol diglycidyl ether

Conditions

Conditions	Yield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate at 40℃; for 0.75h;	68%
With sodium hydroxide; tetrabutyl-ammonium chloride In water at 40℃; for 0.75h;	33.7%
Stage #1: diethylene glycol Stage #2: epichlorohydrin

: 4206-61-5
diethylene glycol diglycidyl ether

: 540-63-6
ethane-1,2-dithiol

: 1273318-55-0
C12H24O5S2

Conditions

Conditions	Yield
With N-benzyl-trimethylammonium hydroxide at 25℃; for 0.5h; Neat (no solvent); regiospecific reaction;	94%

: 4206-61-5
diethylene glycol diglycidyl ether

: 1,13-dihydrazino-4,7,10-trioxatridecane-2,12-diol

Conditions

Conditions	Yield
With hydrazine hydrate In chloroform at 10℃; for 60h;	86%

: 4206-61-5
diethylene glycol diglycidyl ether

: 111-26-2
hexan-1-amine

: 92237-83-7
1-Hexylamino-3-{2-[2-(3-hexylamino-2-hydroxy-propoxy)-ethoxy]-ethoxy}-propan-2-ol

Conditions

Conditions	Yield
at 120℃; for 4h;	85%

: 4206-61-5
diethylene glycol diglycidyl ether

: 103-71-9
phenyl isocyanate

: 1,9-bis(3-phenyloxazolidin-2-on-5-yl)-2,5,8-trioxanonane

Conditions

Conditions	Yield
Stage #1: diethylene glycol diglycidyl ether With Tributylphosphine oxide; lithium bromide In toluene for 2h; Heating; Stage #2: phenyl isocyanate In toluene for 18h; Heating; Further stages.;	83%

: 4206-61-5
diethylene glycol diglycidyl ether

: C10H20N6O5

Conditions

Conditions	Yield
With sodium azide; ammonium chloride In methanol; water at 80℃; for 24h;	83%
With sodium azide In methanol; water at 80℃;

: 4206-61-5
diethylene glycol diglycidyl ether

: 111-36-4
n-butyl isocyanide

: 1,9-bis(3-butyloxazolidin-2-on-5-yl)-2,5,8-trioxanonane

Conditions

Conditions	Yield
Stage #1: diethylene glycol diglycidyl ether With Tributylphosphine oxide; lithium bromide In toluene for 2h; Heating; Stage #2: n-butyl isocyanide In toluene for 21h; Heating; Further stages.;	80%

: 75-15-0
carbon disulfide

: 4206-61-5
diethylene glycol diglycidyl ether

: 1,9-bis(oxathiolane-2-thione-5-yl)-2,5,8-trioxanonane

Conditions

Conditions	Yield
Stage #1: diethylene glycol diglycidyl ether With lithium bromide In dichloromethane for 2h; Heating; Stage #2: carbon disulfide In dichloromethane for 16h; Heating; Further stages.;	79%

: 75-15-0
carbon disulfide

: 4206-61-5
diethylene glycol diglycidyl ether

: 103-71-9
phenyl isocyanate

: 5-(9-oxathiolan-2-thione-2,5,8-trioxanonan-5-yl)-3-phenyloxazolidin-2-one

Conditions

Conditions	Yield
Stage #1: diethylene glycol diglycidyl ether With lithium bromide In tetrahydrofuran for 0.5h; Inert atmosphere; Reflux; Stage #2: phenyl isocyanate In tetrahydrofuran Inert atmosphere; Reflux; Stage #3: carbon disulfide In tetrahydrofuran at 20℃; for 10h; Inert atmosphere;	73%

...Expand

: 4206-61-5
diethylene glycol diglycidyl ether

: 112-53-8
1-dodecyl alcohol

: 2-<(dodecyloxy)methyl>-12-hydroxy-13-crown-4

Conditions

Conditions	Yield
With lithium at 60℃; for 20h;	72%

: 4206-61-5
diethylene glycol diglycidyl ether

: 74-89-5
methylamine

: 344336-10-3
1-{2-[2-(2-Hydroxy-3-methylamino-propoxy)-ethoxy]-ethoxy}-3-methylamino-propan-2-ol

Conditions

Conditions	Yield
for 50h; Ambient temperature;	71%

: 4206-61-5
diethylene glycol diglycidyl ether

: 75-04-7
ethylamine

: 92237-86-0
Bistetraethylene glycol

Conditions

Conditions	Yield
In water for 50h; Ambient temperature;	70%

: 75-15-0
carbon disulfide

: 4206-61-5
diethylene glycol diglycidyl ether

: 3173-53-3
Cyclohexyl isocyanate

: 5-(6-oxathiolan-2-thione-2,5,8-trioxanonan-5-yl)-3-cyclohexyloxazolidin-2-one

Conditions

Conditions	Yield
Stage #1: diethylene glycol diglycidyl ether With lithium bromide In tetrahydrofuran for 0.5h; Inert atmosphere; Reflux; Stage #2: Cyclohexyl isocyanate In tetrahydrofuran Inert atmosphere; Reflux; Stage #3: carbon disulfide In tetrahydrofuran at 20℃; for 13h; Inert atmosphere;	70%

...Expand

: 4206-61-5
diethylene glycol diglycidyl ether

: 103-71-9
phenyl isocyanate

: 5-(9-oxiran-2,5,8-trioxanonan-5-yl)-3-phenyloxazolidin-2-one

Conditions

Conditions	Yield
Stage #1: diethylene glycol diglycidyl ether With lithium bromide In tetrahydrofuran for 0.5h; Inert atmosphere; Reflux; Stage #2: phenyl isocyanate In tetrahydrofuran for 8h; Inert atmosphere; Reflux;	68%

: 75-15-0
carbon disulfide

: 4206-61-5
diethylene glycol diglycidyl ether

: 5-[9-oxiran-2,5,8-trioxanonan]-1,3-oxathiolane-2-thione

Conditions

Conditions	Yield
With lithium bromide In dichloromethane for 8h; Inert atmosphere; Reflux; regioselective reaction;	67%

: 4206-61-5
diethylene glycol diglycidyl ether

: 3173-53-3
Cyclohexyl isocyanate

: 5-(9-oxiran-2,5,8-trioxanonan-5-yl)-3-cyclohexyloxazolidin-2-one

Conditions

Conditions	Yield
Stage #1: diethylene glycol diglycidyl ether With lithium bromide In tetrahydrofuran for 0.5h; Inert atmosphere; Reflux; Stage #2: Cyclohexyl isocyanate In tetrahydrofuran for 12h; Inert atmosphere; Reflux;	65%

: 110-78-1
Propyl isocyanate

: 4206-61-5
diethylene glycol diglycidyl ether

: 5-(9-oxiran-2,5,8-trioxanonan-5-yl)-3-propyloxazolidin-2-one

Conditions

Conditions	Yield
Stage #1: diethylene glycol diglycidyl ether With lithium bromide In tetrahydrofuran for 0.5h; Inert atmosphere; Reflux; Stage #2: Propyl isocyanate In tetrahydrofuran for 12h; Inert atmosphere; Reflux;	60%

: 75-15-0
carbon disulfide

: 110-78-1
Propyl isocyanate

: 4206-61-5
diethylene glycol diglycidyl ether

: 5-(6-oxathiolan-2-thione-2,5,8-trioxanonan-5-yl)-3-propyloxazolidin-2-one

Conditions

Conditions	Yield
Stage #1: diethylene glycol diglycidyl ether With lithium bromide In tetrahydrofuran for 0.5h; Inert atmosphere; Reflux; Stage #2: Propyl isocyanate In tetrahydrofuran Inert atmosphere; Reflux; Stage #3: carbon disulfide In tetrahydrofuran at 20℃; for 15h; Inert atmosphere;	60%

...Expand

: 97-99-4
Tetrahydrofurfuryl alcohol

: 4206-61-5
diethylene glycol diglycidyl ether

: 2-(tetrahydrofurfuryl)-12-hydroxy-13-crown-4

Conditions

Conditions	Yield
With lithium In tert-butyl alcohol at 60℃; for 30h;	59%

: 4206-61-5
diethylene glycol diglycidyl ether

: 100228-56-6
9,13-dihydroxy-1,4,7-trioxa-11-thiacyclotetradecane

Conditions

Conditions	Yield
With sodium hydrogensulfide In water at 60℃; for 0.5h;	58%

: 4206-61-5
diethylene glycol diglycidyl ether

: 2781-02-4
1,11-dimercapto-3,6,9-trioxaundecane

: C18H36O8S2

Conditions

Conditions	Yield
With potassium carbonate In methanol at 65℃; for 3h;	51.8%

: 4206-61-5
diethylene glycol diglycidyl ether

: 33966-50-6
SEC-BUTYLAMINE

: 90655-84-8
11-sec-Butyl-1,4,7-trioxa-11-aza-cyclotetradecane-9,13-diol

Conditions

Conditions	Yield
In methanol at 55℃; for 7h;	49%

: 4206-61-5
diethylene glycol diglycidyl ether

: 62-53-3
aniline

: 90655-87-1
11-Phenyl-1,4,7-trioxa-11-aza-cyclotetradecane-9,13-diol

Conditions

Conditions	Yield
In methanol for 100h; Ambient temperature;	48%

: 4206-61-5
diethylene glycol diglycidyl ether

: 124-38-9
carbon dioxide

: 116146-29-3
C12H18O9

Conditions

Conditions	Yield
With choline iodide In ethanol at 85℃; under 7500.75 Torr; for 6h; Solvent;	46%

: 3511-19-1
2,3-dichlorotetrahydrofuran

: 4206-61-5
diethylene glycol diglycidyl ether

: 137675-80-0
1,15-di(3-chloro-2-tetrahydrofuryl)-3,13-dichloro-1,5,8,11,15-pentaoxapentadecane

Conditions

Conditions	Yield
With zinc(II) chloride In tetrachloromethane at 40℃; for 1h;	45.5%

: 4206-61-5
diethylene glycol diglycidyl ether

: 2016-57-1
1-aminodecane

: 90655-86-0
11-Decyl-9,13-dihydroxy-1,4,7-trioxa-11-azacyclotetradecane

Conditions

Conditions	Yield
In methanol for 50h; Ambient temperature;	43%

: 4206-61-5
diethylene glycol diglycidyl ether

: 2150-02-9
bis(2-mercaptoethyl)ether

: C14H28O6S2

Conditions

Conditions	Yield
With sodium carbonate In methanol at 65℃; for 3h;	42%

: 4206-61-5
diethylene glycol diglycidyl ether

: 294-92-8
diaza[12]crown-4

A: 119017-30-0
3,13,23,33-tetrahydroxy-5,8,11,18,25,28,31,38,43,48-decaoxa-1,15,21,35-tetraazatricyclo<33.33.5.51,35>pentacontane

B: 173396-16-2
meso-3,13-dihydroxy-5,8,11,18,23-pentaoxa-1,15-diazabicyclo<13.5.5>pentacosane

Conditions

Conditions	Yield
In tetrahydrofuran; ethanol for 10h; Heating;	A 6% B 41%
In tetrahydrofuran; ethanol for 10h; Heating;

...Expand

: 4206-61-5
diethylene glycol diglycidyl ether

: 75-04-7
ethylamine

: 90655-79-1
11-Ethyl-1,4,7-trioxa-11-aza-cyclotetradecane-9,13-diol

Conditions

Conditions	Yield
In methanol; water for 50h; Ambient temperature;	38%

Diethylene glycol bis-glycidyl ether Chemical Properties

Chemical Name: Diethylenglykol-diglycidylether
IUPAC NAME: 2-[2-[2-(Oxiran-2-ylmethoxy)ethoxy]ethoxymethyl]oxirane
CAS No.: 4206-61-5
EINECS: 224-122-0
RTECS: KN2330000
Molecular Formula: C₁₀H₁₈O₅
Molecular Weight: 218.25 g/mol
Density: 1.165 g/cm³
Flash Point: 127.3 °C
Boiling Point: 313 °C at 760 mmHg
Following is the structure of Diethylene glycol bis-glycidyl ether (4206-61-5):

The chemical synonymous of Diethylene glycol bis-glycidyl ether (4206-61-5) are Diethylenglykol-diglycidylether ; 2,2’-(Oxybis(2,1-ethanediyloxymethylene))bis-oxiran ; 2,2’-(Oxybis(2,1-ethanediyloxymethylene))bisoxirane ; Diglycidyldiethyleneglycolether ; 2,2'-[Oxybis(ethyleneoxymethylene)]bisoxirane ; Diglycidyl diglycol

Diethylene glycol bis-glycidyl ether Toxicity Data With Reference

cyt-rat-ipr 100 mg/kg

BJPCAL British Journal of Pharmacology and Chemotherapy. 6 (1951),235.

Diethylene glycol bis-glycidyl ether Consensus Reports

Glycol ether compounds are on the Community Right-To-Know List.

Diethylene glycol bis-glycidyl ether Safety Profile

Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.

Product Name

DIETHYLENGLYKOL-DIGLYCIDYLETHER

Synthetic route

Diethylene glycol bis-glycidyl ether Chemical Properties

Diethylene glycol bis-glycidyl ether Toxicity Data With Reference

Diethylene glycol bis-glycidyl ether Consensus Reports

Diethylene glycol bis-glycidyl ether Safety Profile

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