ETHYLENEIMINE supplier | CasNO.151-56-4

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Name
Ethyleneimine
EINECS 205-793-9
CAS No. 151-56-4
Article Data63
CAS DataBase
Density 0.874 g/cm³
Solubility miscible with water
Melting Point -78 °C
Formula C₂H₅N
Boiling Point 56.999 °C at 760 mmHg
Molecular Weight 43.0684
Flash Point -11 °C
Transport Information UN 1185
Appearance colourless liquid with an ammonia-like smell
Safety 45-53-61
Risk Codes 11-26/27/28-34-45-46-51/53
Molecular Structure
Hazard Symbols F,T
Synonyms Azacyclopropane;Aziran;Binary Ethyleneimine;Dimethylenimine;EI;Q 043;Q 043 (amine);Soluol XC 100;Aziridina;
PSA 21.94000
LogP -0.08160

Synthetic route

: 671-50-1
methyl aziridine-1-carboxylate

: 62-53-3
aniline

A: 151-56-4
ethyleneimine

B: 79143-47-8
(2-Phenylamino-ethyl)-carbamic acid methyl ester

Conditions

Conditions	Yield
In ethanol at 18 - 25℃; for 480h;	A n/a B 98%

...Expand

: 13279-22-6
1-(phenylaminocarbonyl)aziridine

: 124-40-3
dimethyl amine

A: 151-56-4
ethyleneimine

B: 101-42-8
fenuron

Conditions

Conditions	Yield
In ethanol at 18 - 25℃; for 168h;	A n/a B 94%

...Expand

: 110-89-4
piperidine

: 671-50-1
methyl aziridine-1-carboxylate

A: 151-56-4
ethyleneimine

B: 79143-49-0
(2-Piperidin-1-yl-ethyl)-carbamic acid methyl ester

Conditions

Conditions	Yield
In ethanol at 18 - 25℃; for 24h;	A n/a B 92%

...Expand

: 13279-22-6
1-(phenylaminocarbonyl)aziridine

: 74-89-5
methylamine

A: 151-56-4
ethyleneimine

B: 1007-36-9
1-methyl-3-phenylurea

Conditions

Conditions	Yield
In ethanol at 18 - 25℃; for 168h;	A n/a B 92%

...Expand

: 671-50-1
methyl aziridine-1-carboxylate

A: 151-56-4
ethyleneimine

B: 598-55-0
methyl carbamate

Conditions

Conditions	Yield
With ammonia In ethanol at 18 - 25℃; for 24h;	A n/a B 90%

: 141-43-5
ethanolamine

: 151-56-4
ethyleneimine

Conditions

Conditions	Yield
With 1 M DTPP at 60℃; for 48h;	90%
With BNTP In dichloromethane at 40℃; for 24h;	98 % Chromat.
With potassium hydroxide; sulfuric acid 1.) 80 deg C, overnight; Multistep reaction;
With cesium nitrate; iron nitrate; magnesium nitrate on fluoridated P2O5/SiO2/TiO2 at 370℃; for 8h; Temperature; Reagent/catalyst; Inert atmosphere; chemoselective reaction;

: 110-91-8
morpholine

: 671-50-1
methyl aziridine-1-carboxylate

A: 151-56-4
ethyleneimine

B: 79143-50-3
(2-Morpholin-4-yl-ethyl)-carbamic acid methyl ester

Conditions

Conditions	Yield
In ethanol at 18 - 25℃; for 24h;	A n/a B 88%

...Expand

: 13279-22-6
1-(phenylaminocarbonyl)aziridine

A: 151-56-4
ethyleneimine

B: 64-10-8
phenyl carbamate

Conditions

Conditions	Yield
With ammonia In ethanol at 18 - 25℃; for 168h;	A n/a B 88%

: 671-50-1
methyl aziridine-1-carboxylate

: 124-40-3
dimethyl amine

A: 151-56-4
ethyleneimine

B: 79143-42-3
1-methoxycarbonylamino-2-dimethylaminoethane

Conditions

Conditions	Yield
In ethanol at 18 - 25℃; for 24h;	A n/a B 82%

...Expand

: 3634-89-7
N-(p-toluenesulfonyl)aziridine

: 151-56-4
ethyleneimine

Conditions

Conditions	Yield
With carbon dioxide; DBN; lithium iodide In toluene at 90℃; for 5h; Inert atmosphere;	82%

: 671-50-1
methyl aziridine-1-carboxylate

A: 151-56-4
ethyleneimine

B: 79143-51-4
(2-Aziridin-1-yl-ethyl)-carbamic acid methyl ester

Conditions

Conditions	Yield
In ethanol at 18 - 25℃; for 24h;	A n/a B 75%

: 870-24-6
2-chloroethanamine hydrochloride

: 151-56-4
ethyleneimine

Conditions

Conditions	Yield
With sodium hydroxide In water at 50℃; for 2h; Inert atmosphere;	75%
With sodium hydroxide In water at 50℃; for 2.5h;	74%
With sodium hydroxide at 50℃; under 25 Torr; for 2h;	70%

: 671-50-1
methyl aziridine-1-carboxylate

: 75-31-0
isopropylamine

A: 151-56-4
ethyleneimine

B: 79143-44-5
(2-Isopropylamino-ethyl)-carbamic acid methyl ester

Conditions

Conditions	Yield
In ethanol at 18 - 25℃; for 24h;	A n/a B 72%

...Expand

: 671-50-1
methyl aziridine-1-carboxylate

: 108-91-8
cyclohexylamine

A: 151-56-4
ethyleneimine

B: 79143-46-7
(2-Cyclohexylamino-ethyl)-carbamic acid methyl ester

Conditions

Conditions	Yield
In ethanol at 18 - 25℃; for 24h;	A n/a B 63%

...Expand

: 926-39-6
sulfuric acid mono-(2-amino-ethyl ester)

: 151-56-4
ethyleneimine

Conditions

Conditions	Yield
With sodium hydroxide In water Heating;	60%
With sodium hydroxide
With potassium hydroxide

: 67-56-1
methanol

: 141-43-5
ethanolamine

A: 151-56-4
ethyleneimine

B: 110-85-0
piperazine

C: 280-57-9
1,4-diaza-bicyclo[2.2.2]octane

D: 109-83-1
(2-hydroxyethyl)(methyl)amine

Conditions

Conditions	Yield
With Cs-P-Si mixed-oxide at 300℃; under 750.06 Torr; Title compound not separated from byproducts;	A 37 % Chromat. B n/a C n/a D 6%

...Expand

: 56-23-5
tetrachloromethane

: 926-39-6
sulfuric acid mono-(2-amino-ethyl ester)

: 151-56-4
ethyleneimine

: 2576-47-8
2-bromoethylamine hydrobromide

: 151-56-4
ethyleneimine

Conditions

Conditions	Yield
With water; silver(l) oxide
With potassium hydroxide
With alkaline solution

: 107-09-5
2-bromoethylamine

: 151-56-4
ethyleneimine

Conditions

Conditions	Yield
With potassium perchlorate In acetic acid at 25℃; Rate constant;
With tetramethyl ammoniumhydroxide In water; dimethyl sulfoxide at 17.9℃; Rate constant; Kinetics; Thermodynamic data; var. temp., var. solvents mixtures, var. bases, ΔGa, ΔHa, ΔSa;
With ammonium bromide In water; dimethyl sulfoxide at 60.3℃; Thermodynamic data; other halide, ΔH(excit.), ΔG(excit.), ΔS(excit.);

: 689-98-5
chloroethylamine

: 151-56-4
ethyleneimine

Conditions

Conditions	Yield
With water In 1,4-dioxane at 39 - 59℃; Kinetics;
With tetramethyl ammoniumhydroxide In water; dimethyl sulfoxide at 31.4℃; Rate constant; Kinetics; Thermodynamic data; var. temp., var. solvents mixtures, var. bases, ΔGa, ΔHa, ΔSa;
With ammonium chloride In water; dimethyl sulfoxide at 60.3℃; Thermodynamic data; other halide, ΔH(excit.), ΔG(excit.), ΔS(excit.);

: 372-47-4
3-Fluoropyridine

: 24151-28-8
Aziridin-Kation

A: 151-56-4
ethyleneimine

B: 59278-67-0
2-fluoropyridine-H(1+)

Conditions

Conditions	Yield
Thermodynamic data;

...Expand

: 626-60-8
3-Chloropyridine

: 24151-28-8
Aziridin-Kation

A: 151-56-4
ethyleneimine

B: 53760-42-2
3-chloropyridinium

Conditions

Conditions	Yield
Thermodynamic data;

...Expand

: 7646-66-4
N-benzoylaziridine

A: 151-56-4
ethyleneimine

B: 532-32-1
sodium benzoate

Conditions

Conditions	Yield
With sodium hydroxide In acetonitrile at 25℃; Rate constant; var. pH (from 13 to neutral);

: 1195-69-3
amide P,P-bis (1-aziridinyl) N,N-dimethyl phosphinique

A: 151-56-4
ethyleneimine

B: 124-40-3
dimethyl amine

C: 2-(dimethylamino)-3H-1,3,2-oxazaphospholidine-2-oxide

D: C6H16N3O2P

Conditions

Conditions	Yield
In water-d2 Mechanism; other aziridinyl phosphoramides, other products;

...Expand

: 18292-63-2
1-(p-bromobenzoyl)aziridine

A: 151-56-4
ethyleneimine

B: 2532-15-2
sodium 4-bromobenzoate

Conditions

Conditions	Yield
With sodium hydroxide In acetonitrile at 25℃; Rate constant; var. pH (from 13 to neutral);

: 15269-50-8
1-(4-methoxy-benzoyl)-aziridine

A: 151-56-4
ethyleneimine

B: 536-45-8
sodium anisate

Conditions

Conditions	Yield
With sodium hydroxide In acetonitrile at 25℃; Rate constant; var. pH (from 13 to neutral);

: 19614-29-0
1-(p-nitrobenzoyl)aziridine

A: 151-56-4
ethyleneimine

B: 3847-57-2
sodium 4-nitrobenzoate

Conditions

Conditions	Yield
With sodium hydroxide In acetonitrile at 25℃; Rate constant; var. pH (from 13 to neutral);

: 74-85-1
ethene

: 151-56-4
ethyleneimine

Conditions

Conditions	Yield
With tris-(2-chloro-ethyl)-amine Mechanism; Irradiation; also with propene; rel. rate constants;

: 74734-25-1
N,N'-Bis(2-oxo-3-oxazolidin-3-ylcarbonyl)-1,6-hexanediamine

A: 151-56-4
ethyleneimine

B: 497-25-6
dimethylenecyclourethane

C: 925-91-7
Acetonitrile oxide

D: 54680-52-3
trans-nitrosoethylene

E: C5H6N2O3*H(1+)

F: 2-Oxo-oxazolidine-3-carboxylic acid cyclohexylamide

Conditions

Conditions	Yield
at 200 - 600℃; Product distribution; pyrolysis;

...Expand

: 671-50-1
methyl aziridine-1-carboxylate

: 75-04-7
ethylamine

A: 151-56-4
ethyleneimine

B: 6135-31-5
methyl N-ethylcarbamate

C: 79143-43-4
(2-Ethylamino-ethyl)-carbamic acid methyl ester

Conditions

Conditions	Yield
In ethanol at 18 - 25℃; for 24h;	A n/a B 35 % Chromat. C 65 % Chromat.

...Expand

: 151-56-4
ethyleneimine

: 78993-89-2
2-chloro-3,6-diphenyl-3,4-dihydro-1,3,2-oxazophosporin-2-oxide

: 95886-05-8
2-Aziridin-1-yl-3,6-diphenyl-3,4-dihydro-[1,3,2]oxazaphosphinine 2-oxide

Conditions

Conditions	Yield
In benzene for 0.5h; Ambient temperature;	100%

: 151-56-4
ethyleneimine

: 78993-90-5
2-Chloro-6-phenyl-3-p-tolyl-3,4-dihydro-[1,3,2]oxazaphosphinine 2-oxide

: 95886-04-7
2-(1-Aziridinyl)-6-phenyl-3-(p-tolyl)-3,4-dihydro-1,3,2-oxazaphosphorin-2-oxide

Conditions

Conditions	Yield
In benzene for 0.5h; Ambient temperature;	100%

: 151-56-4
ethyleneimine

: 78993-91-6
2-Chloro-3-(4-methoxy-phenyl)-6-phenyl-3,4-dihydro-[1,3,2]oxazaphosphinine 2-oxide

: 95886-03-6
2-Aziridin-1-yl-3-(4-methoxy-phenyl)-6-phenyl-3,4-dihydro-[1,3,2]oxazaphosphinine 2-oxide

Conditions

Conditions	Yield
In benzene for 0.5h; Ambient temperature;	100%

: 151-56-4
ethyleneimine

: 10165-13-6
1-chloroaziridine

Conditions

Conditions	Yield
With N-chloro-succinimide at 20℃; under 0.1 Torr;	99%
With sodium hypochlorite; water at -10℃;
With N-chloro-succinimide under 0.001 Torr; Ambient temperature;

: 151-56-4
ethyleneimine

: 32837-87-9
3-hydroxy-3-methyl-1-cyano-1-butyne

: (Z)-4-hydroxy-4-methyl-3-ethyleneimino-2-pentenenitrile

Conditions

Conditions	Yield
In chloroform at 10℃; for 2h;	99%

: 151-56-4
ethyleneimine

: 40920-46-5
3-chloro-2-phenyl-1-indenone

: 94796-57-3
3-aziridino-2-phenyl-1-indenone

Conditions

Conditions	Yield
With triethylamine for 0.5h;	99%

: 151-56-4
ethyleneimine

: 94796-76-6
3-chloro-2-(4-chlorophenyl)-1-indenone

: 94796-59-5
3-aziridino-2-(4-chlorophenyl)-1-indenone

Conditions

Conditions	Yield
With triethylamine for 0.5h;	99%

: 151-56-4
ethyleneimine

: 94796-75-5
3-chloro-2-(4-methoxyphenyl)-1-indenone

: 94796-58-4
3-aziridino-2-(4-methoxyphenyl)-1-indenone

Conditions

Conditions	Yield
With triethylamine for 0.5h;	99%

: 151-56-4
ethyleneimine

: 94796-77-7
3-chloro-2-(1-naphthyl)-1-indenone

: 94796-60-8
3-aziridino-2-(1-naphthyl)-1-indenone

Conditions

Conditions	Yield
With triethylamine for 0.5h;	99%

: 151-56-4
ethyleneimine

: 84336-27-6
diethoxyphosphoryldichloroacetaldehyde

: β-hydroxy-β-ethyleneimino-α,α-dichloroethylphosphonic acid diethyl ester

Conditions

Conditions	Yield
In ethanol at 5 - 10℃; for 1h; Addition;	99%

: 151-56-4
ethyleneimine

: 864467-21-0
1-{2-[1,3-(oxytetraethylenoxy)-3,5,5-trichloro-cyclotriphosphazatrien-1-yl]-aminoethylamino}anthraquinone

: 1-{2-[1,3-(oxytetraethylenoxy)-3,5,5-tri(1-aziridinyl)cyclotriphosphazatrien-1-yl]-aminoethylamino}anthraquinone

Conditions

Conditions	Yield
With sodium hydroxide In benzene at 20℃; for 21.5h;	99%

: 17084-13-8
potassium hexafluorophosphate

: 151-56-4
ethyleneimine

: (C5H5)Fe(CO)3(1+)*CF3SO3(1-)=(C5H5)Fe(CO)3CF3SO3

: 69532-52-1
[C5H5(CO)2Fe(COCH2CH2NH)](1+)*PF6(1-)=[C5H5(CO)2Fe(COCH2CH2NH)]PF6

Conditions

Conditions	Yield
With catalyst: (BrCH2CH2NH3)Br In acetonitrile addn. of aziridine to soln. of complex and bromide via syringe; stirring for 10 min at 25°C under N2; adding an excess of KPF6; stirringfor 5 min; evapn.; washing (Et2O); extg. (CH2Cl29; filtration through MgSO4; reducing volume until crystn. occured; adding Et2O; keeping at -20°C overnight; crystn.; drying in vac.; elem. anal.;	99%
With catalyst: (BrCH2CH2CH2NH3)Br In acetonitrile addn. of aziridine to soln. of complex and bromide via syringe; stirring for 10 min at 25°C under N2; adding an excess of KPF6; stirringfor 5 min; evapn.; washing (Et2O); extg. (CH2Cl29; filtration through MgSO4; reducing volume until crystn. occured; adding Et2O; keeping at -20°C overnight; crystn.; drying in vac.; elem. anal.;	89%

...Expand

: 151-56-4
ethyleneimine

: 12354-84-6, 12354-85-7
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

: 1018682-30-8
[IrCl(Cp(*))(aziridine)2]Cl

Conditions

Conditions	Yield
In dichloromethane (Ar); 5 equiv. of aziridine added to metal-complex in CH2Cl2; stirred atroom temp. for 2 h; solvent removed in vacuo; purified by stirring in dry n-hexane overnight; decanted; dried in vacuo; elem. anal.;	99%

: 151-56-4
ethyleneimine

: 73954-60-6
bis(N,N-diethylamido)-N1-ethyl(bromo)imidophosphate

: 2,2-bis(diethylamino)-3-ethyl-1,3,2-diazaphospholidinium bromide

Conditions

Conditions	Yield
In benzene at 10℃;	98%

: 151-56-4
ethyleneimine

: 90429-62-2
8-Methoxy-5-quinolinesulfonyl chloride

: 98267-09-5
N-(8-methoxy-5-quinolylsulfonyl)aziridine

Conditions

Conditions	Yield
With triethylamine In benzene for 3h; O deg C - 20 deg C;	98%

: 151-56-4
ethyleneimine

: 107036-23-7
Acetic acid 4-[(1S,2R)-2-(4-acetoxy-phenyl)-1-chlorocarbonyl-butyl]-phenyl ester

: 107036-26-0
(2R*,3S*)-1-<2,3-bis(4-acetoxyphenyl)-1-pentanoyl>aziridine

Conditions

Conditions	Yield
With triethylamine In diethyl ether 1.) -4 deg C, 20 min, 2.) RT, 1 h;	98%

: 151-56-4
ethyleneimine

: 73954-61-7
pentapropylphosphorodiamidimidic bromide

: 2,2-bis(dipropylamino)-3-propyl-1,3,2-diazaphospholidinium bromide

Conditions

Conditions	Yield
In benzene at 10℃;	98%

: 151-56-4
ethyleneimine

: 3988-03-2
bis(4-bromophenyl)methanone

: 4,4'-bis(aziridin-1-yl)benzophenone

Conditions

Conditions	Yield
With caesium carbonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; palladium diacetate In toluene at 100℃; for 24h;	98%

: 151-56-4
ethyleneimine

: geldanamycin

: 17-aziridino-17-demethoxy GM

Conditions

Conditions	Yield
In chloroform for 2h; darkness;	98%

: 151-56-4
ethyleneimine

: 38834-26-3
(η5-Cp)Fe(CO)3PF6

: 69532-52-1
[C5H5(CO)2Fe(COCH2CH2NH)](1+)*PF6(1-)=[C5H5(CO)2Fe(COCH2CH2NH)]PF6

Conditions

Conditions	Yield
sodium bromide In acetonitrile ratio of educts and catalyst: 1:1:1; evapn. in vac. to dryness, extrd. with CH2Cl2, pptd. with ether at -20°C;	98%
With catalyst: (nBu)4N(1+)Br(1-) or (nBu4)N(1+)I(1-) In acetonitrile ratio of educts and catalyst: 1:1:1; evapn. in vac. to dryness, extrd. with CH2Cl2, pptd. with ether at -20°C;	98%
With catalyst: Br(CH2)2NH3(1+)*Br(1-) In acetonitrile ratio of educts and catalyst: 1:1:1; evapn. in vac. to dryness, extrd. with CH2Cl2, pptd. with ether at -20°C;	98%
With catalyst: Br(CH2)3NH3(1+)*Br(1-) In acetonitrile ratio of educts and catalyst: 1:1:1; evapn. in vac. to dryness, extrd. with CH2Cl2, pptd. with ether at -20°C;	98%
With catalyst: Et3NH(1+)*Br(1-) In acetonitrile ratio of educts and catalyst: 1:1:1; evapn. in vac. to dryness, extrd. with CH2Cl2, pptd. with ether at -20°C;	98%

: 151-56-4
ethyleneimine

: (η5-C5H5)(Me)(NO)(PPh3)rhenium(II)

: 1493-13-6
trifluorormethanesulfonic acid

: (C5H5)Re(NO)(P(C6H5)3)(C2H4NH)(1+)*CF3SO3(1-)={(C5H5)Re(NO)(P(C6H5)3)(C2H4NH)}{CF3SO3}

Conditions

Conditions	Yield
In toluene (Schlenk flask); soln. of Re-complex is cooled to -45°C (CH3CN/CO2), CF3SO3H is added dropwise, after 5 min cyclic amine is added and the cold bath is removed; after 60 min hexane is added with stirring, filtrate is washed with hexane and dried under vacuum, elem. anal.;	98%

...Expand

: 151-56-4
ethyleneimine

: 7646-85-7
zinc(II) chloride

: 27184-23-2
(aziridine)2ZnCl2

Conditions

Conditions	Yield
In dichloromethane anhydrous metal chloride suspd. in dry CH2Cl2; 5 equiv. of aziridine added; stirred overnight at 21°C; filtered off; solvent removed in vacuo; purified by stirring in dry n-hexane overnight at ambient temp.; n-hexane phase removed by decantation; dried in vacuo; elem. anal.;	98%
In not given (Ar); mole ratio ZnCl2:ethylenimine = 1:2; soln. of ethylenimine added dropwise to a soln. of ZnCl2 with stirring and cooling to -20°C; stirred for 3-4 h; ppt. sepd.; washed (cold soln.); dried (vac.); elem. anal.;

: 151-56-4
ethyleneimine

: palladium dichloride

: 92344-36-0, 21654-58-0
trans-[bis(aziridine)dichloridopalladium(II)]

Conditions

Conditions	Yield
In dichloromethane anhydrous metal chloride suspd. in dry CH2Cl2; 2 equiv. of aziridine added; stirred overnight at 21°C; filtered off; solvent removed in vacuo; purified by stirring in dry n-hexane overnight at ambient temp.; n-hexane phase removed by decantation; dried in vacuo; elem. anal.;	98%

: 151-56-4
ethyleneimine

: 1521-38-6
2,3-dimethoxybenzoic acid

: C11H13NO3

Conditions

Conditions	Yield
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran at 0 - 20℃; for 2h; Temperature;	97.5%

: 151-56-4
ethyleneimine

: 81675-82-3
pentabutylphosphorodiamidimic bromide

: 2,2-bis(dibutylamino)-3-butyl-1,3,2-diazaphospholidinium bromide

Conditions

Conditions	Yield
In benzene at 10℃;	97%

: 151-56-4
ethyleneimine

: amino(1-aziridinyl)bis(diethylamino)phosphonium chloride

: C12H31N5P(1+)*Cl(1-)

Conditions

Conditions	Yield
at 20℃; for 1h;	97%

: 151-56-4
ethyleneimine

: 59848-50-9
4-(bis-methylsulfanyl-methylene)-2-phenyl-5-p-tolyl-2,4-dihydro-pyrazol-3-one

: 61254-28-2
4-<(N-aziridinomethylthio)methylene>-3-(p-methylphenyl)-5-oxo-1-phenyl-Δ2-pyrazoline

Conditions

Conditions	Yield
In diethyl ether at 0 - 20℃; for 3h;	97%

: 151-56-4
ethyleneimine

: cis-bromoamminebis(1,2-diaminoethane)cobalt(III) bromide monohydrate

: cis-{Co(en)2(aziridine)(NH3)}Br3*EtOH

Conditions

Conditions	Yield
With C2H5OH In neat (no solvent) careful addn. of aziridine to solid cis-(Co(NH3)(en)2Br)Br2*H2O under stirring and cooling in a dry ice/acetone bath in N2 atm.; stirring at room temp. for 6 h; pptn. by slow addn. of ethanol and diethyl ether;; filtration; washing with ether; drying in vac. over P2O5; elem. anal.;;	97%

: 151-56-4
ethyleneimine

: {Pt(CF3)(P(C6H5)3)2(NCC2H5)}(1+)*BF4(1-)={Pt(CF3)(P(C6H5)3)2(NCC2H5)}BF4

: {Pt(CF3)(P(C6H5)3)2(NHCH2CH2)}(1+)*BF4(1-)={Pt(CF3)(P(C6H5)3)2(NHCH2CH2)}BF4

Conditions

Conditions	Yield
In tetrahydrofuran reaction under N2: a suspn. of Pt-complex in THF is treated with aziridine at 0°C, removing the ice-bath, warming to room temp., stirring for 5 h; reaction is controlled by IR-spectroscopy, filtn., vac. drying, elem. anal.;	97%

ETHYLENEIMINE Chemical Properties

MF: C₂H₅N
MW: 43.07
EINECS: 205-793-9
Product Categories: Pharmaceutical Intermediates
Mol File: 151-56-4.mol
mp： -78°C
bp： 56°C
density： 0,83 g/cm³
Fp： -11°C
Water Solubility： miscible
Synonyms:AZIRIDINE;ETHYLENEIMINE;ETHYLENIMINE;Dimethyleneimine;1H-Azirine, dihydro-;Aethylenimin;Aminoethylene;Azacyclopropane
The structure of Ethyleneimine(151-56-4) is:

ETHYLENEIMINE Toxicity Data With Reference

1.	eye-mus 2 ppm/1M	JIHTAB Journal of Industrial Hygiene and Toxicology. 30 (1948),7.
2.	skn-rbt 10 mg/24H open	JIHTAB Journal of Industrial Hygiene and Toxicology. 30 (1948),63.
3.	eye-rbt 2 mg SEV	AJOPAA American Journal of Ophthalmology. 29 (1946),1363.
4.	sln-dmg-mul 1 pph/8H-C	GNKAA5 Genetika. 21 (1985),958.
5.	mnt-nml-mul 5000 ppm/8D-C	MUREAV Mutation Research. 125 (1984),275.
6.	cyt-hmn:lng 1 µmol/L	EVSRBT Environmental Science Research. 24 (1981),433.
7.	dns-mus-par 5 mg/kg	EVSRBT Environmental Science Research. 24 (1981),943.
8.	dlt-mus-ipr 5 mg/kg	EVSRBT Environmental Science Research. 24 (1981),943.
9.	msc-ham:ovr 2 mg/L	MUREAV Mutation Research. 94 (1982),449.

ETHYLENEIMINE Consensus Reports

Community Right-To-Know List. EPA Extremely Hazardous Substances List. Ethyleneimine(151-56-4) is reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

ETHYLENEIMINE Safety Profile

Hazard Codes： F;T,T,F,N,T+
Risk Statements：Very Toxic by inhalation；Very Toxic in contact with skin；Very Toxic if swallowed
Safety Statements：In case of accident or if you feel unwell, seek medical advice immediately；Avoid exposure - obtain special instruction before use
RIDADR： 1185
HazardClass： 6.1(a)
PackingGroup： I
Hazardous Substances Data： 151-56-4(Hazardous Substances Data)
Poison by ingestion, skin contact, inhalation, and intraperitoneal routes. Human mutation data reported. A skin, mucous membrane, and severe eye irritant. An allergic sensitizer of skin. Causes opaque cornea, keratoconus, and necrosis of cornea (experimentally). Has been known to cause severe human eye injury. Drinking of carbonated beverages is recommended as an antidote to this material in stomach.

ETHYLENEIMINE Standards and Recommendations

OSHA PEL: TWA 1 mg/m³ (skin); Cancer Suspect Agent
ACGIH TLV: TWA 0.5 ppm (skin); Animal Carcinogen
DFG MAK: DFG TRK: Animal Carcinogen, Suspected Human Carcinogen
NIOSH REL: (Ethyleneimine) TWA use 29 CFR 1910.1012
DOT Classification: 6.1; Label: Poison, Flammable Liquid

ETHYLENEIMINE Analytical Methods

For occupational chemical analysis use NIOSH: Ethylenimine, P&CAM 300.

ETHYLENEIMINE Specification

1、Exposure
Inhalation and direct contact. It is noted in some reports that even when gloves have been used these have not prevented permeation of aziridine. It is therefore important that users check the breakthrough permeation times for gloves and pay scrupulous attention to avoiding contamination when degloving.
2、Sensitisation
Aziridine rapidly penetrates skin on skin contact.
Skin sensitiser - causing allergic contact dermatitis and urticaria.
Respiratory sensitiser - causing occupational asthma

Product Name

Ethyleneimine

Synthetic route

ETHYLENEIMINE Chemical Properties

ETHYLENEIMINE Toxicity Data With Reference

ETHYLENEIMINE Consensus Reports

ETHYLENEIMINE Safety Profile

ETHYLENEIMINE Standards and Recommendations

ETHYLENEIMINE Analytical Methods

ETHYLENEIMINE Specification

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