Product Name

  • Name

    Hexafluoropropylene oxide

  • EINECS 207-050-4
  • CAS No. 428-59-1
  • Article Data28
  • CAS DataBase
  • Density 1.67 g/cm3
  • Solubility 16.3μg/L at 22.7℃
  • Melting Point -129 °C
  • Formula C3F6O
  • Boiling Point -42 °C
  • Molecular Weight 166.023
  • Flash Point
  • Transport Information UN 1956 2.2
  • Appearance colorless odorless gas
  • Safety 7-26-37/39-38
  • Risk Codes 36/37/38-44
  • Molecular Structure Molecular Structure of 428-59-1 (Hexafluoropropylene oxide)
  • Hazard Symbols IrritantXi
  • Synonyms Oxirane,trifluoro(trifluoromethyl)- (9CI);Propane, 1,2-epoxy-1,1,2,3,3,3-hexafluoro-(7CI,8CI);(Trifluoromethyl)trifluorooxirane;1,2-Epoxyhexafluoropropane;2,2,3-Trifluoro-3-(trifluoromethyl)oxirane;Hexafluoro-1,2-epoxypropane;Hexafluoroepoxypropane;Hexafluoropropene epoxide;Hexafluoropropene oxide;Hexafluoropropene-1,2-oxide;Hexafluoropropylene epoxide;Hexafluoropropyleneoxide;Perfluoro(methyloxirane);Perfluoropropene oxide;Perfluoropropene-1,2-oxide;Perfluoropropylene oxide;Propylene oxidehexafluoride;Trifluoro(trifluoromethyl)oxirane;
  • PSA 12.53000
  • LogP 1.83750

Synthetic route

perfluoropropylene
116-15-4

perfluoropropylene

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

Conditions
ConditionsYield
With 1-pyrrolidone In 1,1,2-Trichloro-1,2,2-trifluoroethane; N,N-dimethyl-formamide at 20℃; for 6h; Reagent/catalyst; Temperature; Solvent; Sealed tube;95.6%
With sodium hypochlorite; sodium hydroxide In water; acetonitrile at -5 - 10℃; under 3750.38 Torr; Product distribution / selectivity;69%
With borax; sodium perchlorate; sodium hydroxide In water; toluene at 0℃; pH=9.7 - 10.5; Reagent/catalyst; pH-value;37.7%
perfluoropropylene
116-15-4

perfluoropropylene

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

C

trifluoroacetyl fluoride
354-34-7

trifluoroacetyl fluoride

D

1,1,2,2,3,3-Hexafluoro-cyclopropane
931-91-9

1,1,2,2,3,3-Hexafluoro-cyclopropane

Conditions
ConditionsYield
With oxygen In tetrachloromethane at 155℃; for 3h;A n/a
B 62%
C n/a
D n/a
perfluoropropylene
116-15-4

perfluoropropylene

A

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

B

trifluoroacetyl fluoride
354-34-7

trifluoroacetyl fluoride

Conditions
ConditionsYield
With oxygen In various solvent(s) at 140℃;A 61.5%
B 7%
perfluoropropylene
116-15-4

perfluoropropylene

A

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

B

freon-218
76-19-7

freon-218

C

C3F12OSe

C3F12OSe

D

C3F16O2Se2

C3F16O2Se2

Conditions
ConditionsYield
With xenon bis-pentafluoroseleniumoxide at 65℃; for 84h;A 36%
B n/a
C 51%
D 11%
perfluoropropylene
116-15-4

perfluoropropylene

A

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

B

bis(pentafluoropropionyl)peroxide
356-45-6

bis(pentafluoropropionyl)peroxide

Conditions
ConditionsYield
With potassium hydroxide; dihydrogen peroxide In methanol at -37℃; for 0.333333h;A 35 g
B 3%
epichlorohydrin
106-89-8

epichlorohydrin

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

Conditions
ConditionsYield
Elektrolyse in fluessigem Fluorwasserstoff;
perfluoropropylene
116-15-4

perfluoropropylene

difluorodioxirane
96740-99-7

difluorodioxirane

A

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

B

Carbonyl fluoride
353-50-4

Carbonyl fluoride

Conditions
ConditionsYield
In trichlorofluoromethane at 22℃; for 4h; other reaction partners: CF2CFCl, CF2CFH; reaction without solvent;A 95 % Spectr.
B n/a
perfluoropropylene
116-15-4

perfluoropropylene

A

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

B

Carbonyl fluoride
353-50-4

Carbonyl fluoride

Conditions
ConditionsYield
With difluorodioxirane In trichlorofluoromethane at 22℃; for 4h; Title compound not separated from byproducts;A 95 % Spectr.
B n/a
perfluoropropylene
116-15-4

perfluoropropylene

A

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

B

Carbonyl fluoride
353-50-4

Carbonyl fluoride

C

trifluoroacetyl fluoride
354-34-7

trifluoroacetyl fluoride

Conditions
ConditionsYield
With oxygen at -60.15℃; under 750.06 Torr; Product distribution; Activation energy; Further Variations:; Temperatures; Pressures; Oxidation;
perfluoropropylene
116-15-4

perfluoropropylene

A

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

B

bis(pentafluoropropionyl)peroxide
356-45-6

bis(pentafluoropropionyl)peroxide

C

trifluoroacetic acid
76-05-1

trifluoroacetic acid

D

HF; CO2;

HF; CO2;

Conditions
ConditionsYield
With potassium hydroxide; dihydrogen peroxide In methanol; water at -37℃; Product distribution; Mechanism; molar ratio of H2O2:HFP and of KOH:HFP;;
perfluoropropylene
116-15-4

perfluoropropylene

A

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

B

Carbonyl fluoride
353-50-4

Carbonyl fluoride

C

trifluoroacetyl fluoride
354-34-7

trifluoroacetyl fluoride

D

perfluoropolyetherpolyperoxide

perfluoropolyetherpolyperoxide

Conditions
ConditionsYield
With oxygen at 29.9℃; under 11025.9 Torr; Mechanism; Irradiation; stainless steel reactor; hexafluoropropene consumption rate, perfluoropolyetherpolyperoxide and carbonyl fluoride formation rate; different concentrations of hexafluoropropene and O2 pressures;
perfluoropropylene
116-15-4

perfluoropropylene

A

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

B

1,2-Dinitro-hexafluorpropan
507-58-4

1,2-Dinitro-hexafluorpropan

C

nitropentafluoroacetone
3888-00-4

nitropentafluoroacetone

Conditions
ConditionsYield
With Nitrogen dioxide at 139.95 - 159.65℃; Kinetics;
polyoxyethylenelaurylether

polyoxyethylenelaurylether

perfluoropropylene
116-15-4

perfluoropropylene

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

perfluoro(propyl vinyl ether)
1623-05-8

perfluoro(propyl vinyl ether)

A

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

B

3-azido-2-heptafluoropropoxytrifluoropropionic acid hydrate

3-azido-2-heptafluoropropoxytrifluoropropionic acid hydrate

Conditions
ConditionsYield
With carbon dioxide; sulfuric acid In water; dimethyl sulfoxide
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

α,α-dihydroxyperfluoropropionic acid
10321-14-9

α,α-dihydroxyperfluoropropionic acid

Conditions
ConditionsYield
With water In tetrahydrofuran at 20℃; for 6h;100%
With water; silica gel In diethyl ether
With water In 1,4-dioxane
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

2,2-dimethyl-propanol-1
75-84-3

2,2-dimethyl-propanol-1

neopentyl 2-neopentoxy-2,3,3,3-tetrafluoropropionate

neopentyl 2-neopentoxy-2,3,3,3-tetrafluoropropionate

Conditions
ConditionsYield
at 85℃; for 10h;100%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

2,2,3,3,3-pentafluoropropionamide
354-76-7

2,2,3,3,3-pentafluoropropionamide

Conditions
ConditionsYield
With methylamine at 150℃; under 750.075 Torr; for 10h; Gas phase;99.2%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

2-Isopropylimino-2-phenylethane
109106-15-2

2-Isopropylimino-2-phenylethane

5-isopropylamino-1,1,1,2,2-pentafluoro-5-phenylpent-4-en-3-one

5-isopropylamino-1,1,1,2,2-pentafluoro-5-phenylpent-4-en-3-one

Conditions
ConditionsYield
In diethyl ether at -60℃; for 9h;99%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

perfluoropelargonoyl fluoride
558-95-2

perfluoropelargonoyl fluoride

FCF2OCFCF3COCF3CF2CF2CF2(CF2)4

FCF2OCFCF3COCF3CF2CF2CF2(CF2)4

Conditions
ConditionsYield
With bis[di(2-hydroxyethyl)amino]methane In acetonitrile at 25℃;99%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

diethyl sulfate
64-67-5

diethyl sulfate

perfluorobutyryl fluoride
335-42-2

perfluorobutyryl fluoride

1-{1-[(1-{[1-(ethoxydifluoromethyl)-1,2,2,2-tetrafluoroethoxy]difluoro-methyl}-1,2,2,2-tetrafluoroethoxy)difluoromethyl]-1,2,2,2-tetrafluoroethoxy}-1,1,2,2,3,3,3-heptafluoro-propane

1-{1-[(1-{[1-(ethoxydifluoromethyl)-1,2,2,2-tetrafluoroethoxy]difluoro-methyl}-1,2,2,2-tetrafluoroethoxy)difluoromethyl]-1,2,2,2-tetrafluoroethoxy}-1,1,2,2,3,3,3-heptafluoro-propane

Conditions
ConditionsYield
Stage #1: Hexafluoropropene oxide; perfluorobutyryl fluoride With potassium fluoride In diethylene glycol dimethyl ether for 24h;
Stage #2: diethyl sulfate With potassium fluoride at 52℃; for 48h;
Stage #3: With potassium hydroxide In diethylene glycol dimethyl ether; water at 65℃; for 5h;
98.8%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

perfluoro(3-oxapentanoyl) fluoride
13071-64-2

perfluoro(3-oxapentanoyl) fluoride

2,3,3,3-Tetrafluoro-2-(1,1,2,2-tetrafluoro-2-pentafluoroethyloxy-ethoxy)-propionyl fluoride
39187-45-6

2,3,3,3-Tetrafluoro-2-(1,1,2,2-tetrafluoro-2-pentafluoroethyloxy-ethoxy)-propionyl fluoride

Conditions
ConditionsYield
With bis(diethylamino)methane In diethylene glycol dimethyl ether at -15 - -10℃;98%
With cesium fluoride In diethylene glycol dimethyl ether
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

trifluoroacetyl fluoride
354-34-7

trifluoroacetyl fluoride

2,3,3,3-tetrafluoro-2-(pentafluoroethoxy)propionic acid fluoride
1682-78-6

2,3,3,3-tetrafluoro-2-(pentafluoroethoxy)propionic acid fluoride

Conditions
ConditionsYield
With bis(dimethylamino)methane In acetonitrile at -20℃;98%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

perfluoropropanoyl fluoride
422-61-7

perfluoropropanoyl fluoride

perfluoro(2-propoxypropionyl) fluoride
2062-98-8, 125037-08-3

perfluoro(2-propoxypropionyl) fluoride

Conditions
ConditionsYield
With bis(diethylamino)methane In acetonitrile at -15℃;98%
With potassium fluoride In diethylene glycol dimethyl ether
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

Perfluoro pentanoyl fluoride
375-62-2

Perfluoro pentanoyl fluoride

Perfluor-2-n-pentoxypropionylfluorid
13140-30-2

Perfluor-2-n-pentoxypropionylfluorid

Conditions
ConditionsYield
With dimorpholinomethane In diethylene glycol dimethyl ether at 15℃;98%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

phenol
108-95-2

phenol

4,4'-(hexafluoroisopropylidene)diphenol
1478-61-1

4,4'-(hexafluoroisopropylidene)diphenol

Conditions
ConditionsYield
With TiClF3; SbF4Cl; hydrogen fluoride for 12h; Reagent/catalyst; Autoclave;97.3%
With hydrogen fluoride; antimonypentachloride; titanium tetrachloride at 55℃; for 12h; Reagent/catalyst; Autoclave;97.5%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

Hexafluoroacetone
684-16-2

Hexafluoroacetone

Conditions
ConditionsYield
In water at 50℃; for 3h; Temperature; Reagent/catalyst; Large scale;97%
With aluminum chlorofluoride at 25℃; for 1h;96%
With aluminum chlorofluoride at 25℃; for 1h;95%
With antimony pentafluoride at 60℃; Temperature; Inert atmosphere;165.37 g
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

4,1-polyisoprene-b-poly(ethylethylene) diblock copolymer, 1.4 percent hydrogenated isoprene units, PDI 1.08 (SEC), polyisoprene block 7.1 kg/mol, poly(ethylethylene) block 4.4 kg/mol; monomer(s): isoprene; sec-butyllithium; 1,3-butadiene

4,1-polyisoprene-b-poly(ethylethylene) diblock copolymer, 1.4 percent hydrogenated isoprene units, PDI 1.08 (SEC), polyisoprene block 7.1 kg/mol, poly(ethylethylene) block 4.4 kg/mol; monomer(s): isoprene; sec-butyllithium; 1,3-butadiene

difluorocarbene-modified 4,1-polyisoprene-b-poly(ethylethylene), PDI 1.09 (SEC), polyisoprene block 7.1 kg/mol, poly(ethylethylene) block 4.4 kg/mol; monomer(s): isoprene; sec-butyllithium; 1,3-butadiene; perfluoropropylene oxide

difluorocarbene-modified 4,1-polyisoprene-b-poly(ethylethylene), PDI 1.09 (SEC), polyisoprene block 7.1 kg/mol, poly(ethylethylene) block 4.4 kg/mol; monomer(s): isoprene; sec-butyllithium; 1,3-butadiene; perfluoropropylene oxide

Conditions
ConditionsYield
In cyclohexane at 180℃; for 4h;97%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

2,2,3,3,4,4,5,5-octafluoro-pentanoyl fluoride
813-03-6

2,2,3,3,4,4,5,5-octafluoro-pentanoyl fluoride

FCF2OCFCF3COCF3CF2CF2CFH

FCF2OCFCF3COCF3CF2CF2CFH

Conditions
ConditionsYield
With dipiperidinomethane In acetonitrile at 15℃;97%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

Carbonyl fluoride
353-50-4

Carbonyl fluoride

2,3,3,3-tetrafluoro-2-(trifluoromethoxy)propionic acid fluoride
2927-83-5

2,3,3,3-tetrafluoro-2-(trifluoromethoxy)propionic acid fluoride

Conditions
ConditionsYield
With dipiperidinomethane In acetonitrile at -20℃;97%
Stage #1: Carbonyl fluoride With potassium fluoride; 18-crown-6 ether In diethylene glycol dimethyl ether at -5 - 0℃; under 11251.1 Torr; for 2h; Inert atmosphere; Autoclave; Large scale;
Stage #2: Hexafluoropropene oxide In diethylene glycol dimethyl ether at -5 - 0℃; for 8h; Reagent/catalyst; Temperature; Pressure; Solvent; Large scale;
4 kg
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

difluorobromoacetyl fluoride
38126-07-7

difluorobromoacetyl fluoride

2-(2-Bromo-1,1,2,2-tetrafluoro-ethoxy)-2,3,3,3-tetrafluoro-propionyl fluoride

2-(2-Bromo-1,1,2,2-tetrafluoro-ethoxy)-2,3,3,3-tetrafluoro-propionyl fluoride

Conditions
ConditionsYield
With dipiperidinomethane In acetonitrile at -15℃;97%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

6,7-dimethyl-3-(trifluoromethyl)-2(1H)-quinoxalinone
143309-78-8

6,7-dimethyl-3-(trifluoromethyl)-2(1H)-quinoxalinone

Conditions
ConditionsYield
With sodium hydrogencarbonate In diethyl ether; dichloromethane for 12h; Ambient temperature;96%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

2,2-bis(trifluoromethyl)-3,3,4,4-tetrafluorooxetane
718-61-6

2,2-bis(trifluoromethyl)-3,3,4,4-tetrafluorooxetane

Conditions
ConditionsYield
With aluminum chlorofluoride at 60℃; for 48h;96%
methanol
67-56-1

methanol

Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

2-fluoro-2-methoxy trifluoropropanoic acid methyl ester
10186-63-7

2-fluoro-2-methoxy trifluoropropanoic acid methyl ester

Conditions
ConditionsYield
With sodium carbonate at 20℃;95%
Heating;73%
Inert atmosphere;27%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

Difluoro-[1,1,2,2-tetrafluoro-2-(1,1,2,2-tetrafluoro-2-pentafluoroethyloxy-ethoxy)-ethoxy]-acetyl fluoride
13071-66-4

Difluoro-[1,1,2,2-tetrafluoro-2-(1,1,2,2-tetrafluoro-2-pentafluoroethyloxy-ethoxy)-ethoxy]-acetyl fluoride

C11F22O5

C11F22O5

Conditions
ConditionsYield
With potassium fluoride; Tetraethylene glycol dimethyl ether at 25 - 31℃; for 0.666667h; Autoclave;94.2%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

ethanol
64-17-5

ethanol

2-fluoro-2-ethoxy-trifluoropropionic acid ethyl ester
10186-66-0

2-fluoro-2-ethoxy-trifluoropropionic acid ethyl ester

Conditions
ConditionsYield
With sodium hydroxide at 20℃; Reagent/catalyst;93%
a) 1 h, b) 100 deg C, 3 h;55%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

o-xylene
95-47-6

o-xylene

4,4'-(perfluoropropane-2,2-diyl)bis(1,2-dimethylbenzene)
65294-20-4

4,4'-(perfluoropropane-2,2-diyl)bis(1,2-dimethylbenzene)

Conditions
ConditionsYield
With TiClF3; hydrogen fluoride for 11h; Autoclave; Large scale;92.4%
With aluminum (III) chloride; hydrogen fluoride at 130℃; for 16h; Inert atmosphere;107.67 g
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

ethanolamine
141-43-5

ethanolamine

N-pentafluoropropionyl-2-aminoethanol
6104-06-9

N-pentafluoropropionyl-2-aminoethanol

Conditions
ConditionsYield
In acetonitrile for 0.5h; Ambient temperature;92%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

1,1,2-trifluoro-4-bromobut-1-ene
10493-44-4

1,1,2-trifluoro-4-bromobut-1-ene

2-bromo-1-(1,2,2,3,3-pentafluorocyclopropyl)ethane

2-bromo-1-(1,2,2,3,3-pentafluorocyclopropyl)ethane

Conditions
ConditionsYield
at 190℃; for 12h;92%
at 190℃; for 6h;92%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

perfluoro(5-oxa-6-heptenyl) cyanide
54675-68-2

perfluoro(5-oxa-6-heptenyl) cyanide

perfluoro(8-cyano-2,5-dimethyl-3,6-dioxanonanoyl) fluoride
54716-83-5

perfluoro(8-cyano-2,5-dimethyl-3,6-dioxanonanoyl) fluoride

Conditions
ConditionsYield
In further solvent(s)91.3%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

1,1,2,2,3,3-Hexafluoro-cyclopropane
931-91-9

1,1,2,2,3,3-Hexafluoro-cyclopropane

Conditions
ConditionsYield
91%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

(5,7,12,14-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinate(2-))V=O

(5,7,12,14-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinate(2-))V=O

(5,7,12,14-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinate(2-))V(O(C(CF3)2)2O)

(5,7,12,14-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecinate(2-))V(O(C(CF3)2)2O)

Conditions
ConditionsYield
In dichloromethane absence of air and moisture; stirring in (CF3)CFCOCF2-atmosphere for 1 h(pptn.); ether addn., stirring for 2 h, collection (filtration), washing (ether);elem. anal.;91%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

3-(trifluoromethyl)quinoxalin-2-ol
58457-64-0

3-(trifluoromethyl)quinoxalin-2-ol

Conditions
ConditionsYield
With sodium hydrogencarbonate In diethyl ether at -78 - 20℃; for 16h;91%
Hexafluoropropene oxide
428-59-1

Hexafluoropropene oxide

toluene
108-88-3

toluene

1,1,1,3,3,3-hexafluoro-2,2-di(p-tolyl)propane
1095-77-8

1,1,1,3,3,3-hexafluoro-2,2-di(p-tolyl)propane

Conditions
ConditionsYield
With SbF4Cl; hydrogen fluoride for 12h; Autoclave; Large scale;90.6%

Hexafluoropropylene oxide Consensus Reports

Reported in EPA TSCA Inventory.

Hexafluoropropylene oxide Standards and Recommendations

DOT Classification:  2.2; Label: Nonflammable Gas

Hexafluoropropylene oxide Specification

The Hexafluoropropene epoxide , with the CAS register number 428-59-1, has other names as hfpo ; hexafluoro-1,2-epoxypropane ; hexafluoropropylene oxide ; hexafluoropropene oxide ; hexafluoroepoxypropane ; 1,2-epoxy-1,1,2,3,3,3-hexafluoropropane ; trifluoro(trifluoromethyl)oxirane ; (trifluoromethyl)trifluorooxirane .

The physical properties of this chemcial are as followings:  (1)ACD/LogP:  2.43 ; (2)ACD/LogD (pH 5.5):  2.43  ; (3)ACD/LogD (pH 7.4):  2.43  ; (4)ACD/BCF (pH 5.5):  41.45  ; (5)ACD/BCF (pH 7.4):  41.45  ; (6)ACD/KOC (pH 5.5):  500.53  ; (7)ACD/KOC (pH 7.4):  500.53  ; (8)#H bond acceptors:  1; (9)Polar Surface Area:  12.53  ; (10)Index of Refraction:  1.262  ; (11)Molar Refractivity:  16.36 cm ; (12)Molar Volume:  98.9 cm3  ; (13)Polarizability:  6.48 ×10-24 cm3  ; (14)Surface Tension:  12.1 dyne/cm  ; (15)Density:  1.67 g/cm3  ; (16)Enthalpy of Vaporization:  20.49 kJ/mol  ; (17)Vapour Pressure:  7100 mmHg at 25°C.

Hexafluoropropylene oxide is a kind of gas with no color and odor. When shipped, it usually be made as a liquefied gas under its vapor pressure and if contacting with the liquid, it can cause frostbite. And the product categories belong to the fluoromonomer and organic Fluorides.

Being a kind of irritant chemical to eyes, respiratory system and skin, it may cause inflammation to the skin or other mucous membranes. And it has risk of explosion if heated under confinement. This chemical can cause asphyxiation by the displacement of air and the exposure of the container to prolonged heat or fire may cause it to rupture violently and rocket So while dealing with this chemical, you should be very cautious. Wear suitable gloves and eye/face protection , and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice. Keep container tightly closed and if in case of insufficient ventilation, wear suitable respiratory equipment. And you could also get the safety information from WGK Germany  3.
 
Additionally, you could convert the following data information into the molecular structure:
SMILES:FC(F)(F)C1(F)OC1(F)F
InChI:InChI=1/C3F6O/c4-1(2(5,6)7)3(8,9)10-1
InChIKey:PGFXOWRDDHCDTE-UHFFFAOYAQ

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