Conditions | Yield |
---|---|
With 1-pyrrolidone In 1,1,2-Trichloro-1,2,2-trifluoroethane; N,N-dimethyl-formamide at 20℃; for 6h; Reagent/catalyst; Temperature; Solvent; Sealed tube; | 95.6% |
With sodium hypochlorite; sodium hydroxide In water; acetonitrile at -5 - 10℃; under 3750.38 Torr; Product distribution / selectivity; | 69% |
With borax; sodium perchlorate; sodium hydroxide In water; toluene at 0℃; pH=9.7 - 10.5; Reagent/catalyst; pH-value; | 37.7% |
perfluoropropylene
A
polytetrafluoroethylene
B
Hexafluoropropene oxide
C
trifluoroacetyl fluoride
D
1,1,2,2,3,3-Hexafluoro-cyclopropane
Conditions | Yield |
---|---|
With oxygen In tetrachloromethane at 155℃; for 3h; | A n/a B 62% C n/a D n/a |
Conditions | Yield |
---|---|
With oxygen In various solvent(s) at 140℃; | A 61.5% B 7% |
Conditions | Yield |
---|---|
With xenon bis-pentafluoroseleniumoxide at 65℃; for 84h; | A 36% B n/a C 51% D 11% |
perfluoropropylene
A
Hexafluoropropene oxide
B
bis(pentafluoropropionyl)peroxide
Conditions | Yield |
---|---|
With potassium hydroxide; dihydrogen peroxide In methanol at -37℃; for 0.333333h; | A 35 g B 3% |
Conditions | Yield |
---|---|
Elektrolyse in fluessigem Fluorwasserstoff; |
perfluoropropylene
difluorodioxirane
A
Hexafluoropropene oxide
B
Carbonyl fluoride
Conditions | Yield |
---|---|
In trichlorofluoromethane at 22℃; for 4h; other reaction partners: CF2CFCl, CF2CFH; reaction without solvent; | A 95 % Spectr. B n/a |
Conditions | Yield |
---|---|
With difluorodioxirane In trichlorofluoromethane at 22℃; for 4h; Title compound not separated from byproducts; | A 95 % Spectr. B n/a |
perfluoropropylene
A
Hexafluoropropene oxide
B
Carbonyl fluoride
C
trifluoroacetyl fluoride
Conditions | Yield |
---|---|
With oxygen at -60.15℃; under 750.06 Torr; Product distribution; Activation energy; Further Variations:; Temperatures; Pressures; Oxidation; |
perfluoropropylene
A
Hexafluoropropene oxide
B
bis(pentafluoropropionyl)peroxide
C
trifluoroacetic acid
Conditions | Yield |
---|---|
With potassium hydroxide; dihydrogen peroxide In methanol; water at -37℃; Product distribution; Mechanism; molar ratio of H2O2:HFP and of KOH:HFP;; |
perfluoropropylene
A
Hexafluoropropene oxide
B
Carbonyl fluoride
C
trifluoroacetyl fluoride
Conditions | Yield |
---|---|
With oxygen at 29.9℃; under 11025.9 Torr; Mechanism; Irradiation; stainless steel reactor; hexafluoropropene consumption rate, perfluoropolyetherpolyperoxide and carbonyl fluoride formation rate; different concentrations of hexafluoropropene and O2 pressures; |
perfluoropropylene
A
Hexafluoropropene oxide
B
1,2-Dinitro-hexafluorpropan
C
nitropentafluoroacetone
Conditions | Yield |
---|---|
With Nitrogen dioxide at 139.95 - 159.65℃; Kinetics; |
Conditions | Yield |
---|---|
With carbon dioxide; sulfuric acid In water; dimethyl sulfoxide |
Hexafluoropropene oxide
α,α-dihydroxyperfluoropropionic acid
Conditions | Yield |
---|---|
With water In tetrahydrofuran at 20℃; for 6h; | 100% |
With water; silica gel In diethyl ether | |
With water In 1,4-dioxane |
Conditions | Yield |
---|---|
at 85℃; for 10h; | 100% |
Conditions | Yield |
---|---|
With methylamine at 150℃; under 750.075 Torr; for 10h; Gas phase; | 99.2% |
Hexafluoropropene oxide
2-Isopropylimino-2-phenylethane
Conditions | Yield |
---|---|
In diethyl ether at -60℃; for 9h; | 99% |
Conditions | Yield |
---|---|
With bis[di(2-hydroxyethyl)amino]methane In acetonitrile at 25℃; | 99% |
Conditions | Yield |
---|---|
Stage #1: Hexafluoropropene oxide; perfluorobutyryl fluoride With potassium fluoride In diethylene glycol dimethyl ether for 24h; Stage #2: diethyl sulfate With potassium fluoride at 52℃; for 48h; Stage #3: With potassium hydroxide In diethylene glycol dimethyl ether; water at 65℃; for 5h; | 98.8% |
Hexafluoropropene oxide
perfluoro(3-oxapentanoyl) fluoride
2,3,3,3-Tetrafluoro-2-(1,1,2,2-tetrafluoro-2-pentafluoroethyloxy-ethoxy)-propionyl fluoride
Conditions | Yield |
---|---|
With bis(diethylamino)methane In diethylene glycol dimethyl ether at -15 - -10℃; | 98% |
With cesium fluoride In diethylene glycol dimethyl ether |
Hexafluoropropene oxide
trifluoroacetyl fluoride
2,3,3,3-tetrafluoro-2-(pentafluoroethoxy)propionic acid fluoride
Conditions | Yield |
---|---|
With bis(dimethylamino)methane In acetonitrile at -20℃; | 98% |
Hexafluoropropene oxide
perfluoropropanoyl fluoride
perfluoro(2-propoxypropionyl) fluoride
Conditions | Yield |
---|---|
With bis(diethylamino)methane In acetonitrile at -15℃; | 98% |
With potassium fluoride In diethylene glycol dimethyl ether |
Hexafluoropropene oxide
Perfluoro pentanoyl fluoride
Perfluor-2-n-pentoxypropionylfluorid
Conditions | Yield |
---|---|
With dimorpholinomethane In diethylene glycol dimethyl ether at 15℃; | 98% |
Conditions | Yield |
---|---|
With TiClF3; SbF4Cl; hydrogen fluoride for 12h; Reagent/catalyst; Autoclave; | 97.3% |
With hydrogen fluoride; antimonypentachloride; titanium tetrachloride at 55℃; for 12h; Reagent/catalyst; Autoclave; | 97.5% |
Conditions | Yield |
---|---|
In water at 50℃; for 3h; Temperature; Reagent/catalyst; Large scale; | 97% |
With aluminum chlorofluoride at 25℃; for 1h; | 96% |
With aluminum chlorofluoride at 25℃; for 1h; | 95% |
With antimony pentafluoride at 60℃; Temperature; Inert atmosphere; | 165.37 g |
Hexafluoropropene oxide
4,1-polyisoprene-b-poly(ethylethylene) diblock copolymer, 1.4 percent hydrogenated isoprene units, PDI 1.08 (SEC), polyisoprene block 7.1 kg/mol, poly(ethylethylene) block 4.4 kg/mol; monomer(s): isoprene; sec-butyllithium; 1,3-butadiene
difluorocarbene-modified 4,1-polyisoprene-b-poly(ethylethylene), PDI 1.09 (SEC), polyisoprene block 7.1 kg/mol, poly(ethylethylene) block 4.4 kg/mol; monomer(s): isoprene; sec-butyllithium; 1,3-butadiene; perfluoropropylene oxide
Conditions | Yield |
---|---|
In cyclohexane at 180℃; for 4h; | 97% |
Conditions | Yield |
---|---|
With dipiperidinomethane In acetonitrile at 15℃; | 97% |
Hexafluoropropene oxide
Carbonyl fluoride
2,3,3,3-tetrafluoro-2-(trifluoromethoxy)propionic acid fluoride
Conditions | Yield |
---|---|
With dipiperidinomethane In acetonitrile at -20℃; | 97% |
Stage #1: Carbonyl fluoride With potassium fluoride; 18-crown-6 ether In diethylene glycol dimethyl ether at -5 - 0℃; under 11251.1 Torr; for 2h; Inert atmosphere; Autoclave; Large scale; Stage #2: Hexafluoropropene oxide In diethylene glycol dimethyl ether at -5 - 0℃; for 8h; Reagent/catalyst; Temperature; Pressure; Solvent; Large scale; | 4 kg |
Hexafluoropropene oxide
difluorobromoacetyl fluoride
Conditions | Yield |
---|---|
With dipiperidinomethane In acetonitrile at -15℃; | 97% |
Hexafluoropropene oxide
4,5-dimethyl-1,2-phenylenediamine
6,7-dimethyl-3-(trifluoromethyl)-2(1H)-quinoxalinone
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In diethyl ether; dichloromethane for 12h; Ambient temperature; | 96% |
polytetrafluoroethylene
Hexafluoropropene oxide
2,2-bis(trifluoromethyl)-3,3,4,4-tetrafluorooxetane
Conditions | Yield |
---|---|
With aluminum chlorofluoride at 60℃; for 48h; | 96% |
methanol
Hexafluoropropene oxide
2-fluoro-2-methoxy trifluoropropanoic acid methyl ester
Conditions | Yield |
---|---|
With sodium carbonate at 20℃; | 95% |
Heating; | 73% |
Inert atmosphere; | 27% |
Hexafluoropropene oxide
Difluoro-[1,1,2,2-tetrafluoro-2-(1,1,2,2-tetrafluoro-2-pentafluoroethyloxy-ethoxy)-ethoxy]-acetyl fluoride
Conditions | Yield |
---|---|
With potassium fluoride; Tetraethylene glycol dimethyl ether at 25 - 31℃; for 0.666667h; Autoclave; | 94.2% |
Hexafluoropropene oxide
ethanol
2-fluoro-2-ethoxy-trifluoropropionic acid ethyl ester
Conditions | Yield |
---|---|
With sodium hydroxide at 20℃; Reagent/catalyst; | 93% |
a) 1 h, b) 100 deg C, 3 h; | 55% |
Hexafluoropropene oxide
o-xylene
4,4'-(perfluoropropane-2,2-diyl)bis(1,2-dimethylbenzene)
Conditions | Yield |
---|---|
With TiClF3; hydrogen fluoride for 11h; Autoclave; Large scale; | 92.4% |
With aluminum (III) chloride; hydrogen fluoride at 130℃; for 16h; Inert atmosphere; | 107.67 g |
Hexafluoropropene oxide
ethanolamine
N-pentafluoropropionyl-2-aminoethanol
Conditions | Yield |
---|---|
In acetonitrile for 0.5h; Ambient temperature; | 92% |
Hexafluoropropene oxide
1,1,2-trifluoro-4-bromobut-1-ene
Conditions | Yield |
---|---|
at 190℃; for 12h; | 92% |
at 190℃; for 6h; | 92% |
Hexafluoropropene oxide
perfluoro(5-oxa-6-heptenyl) cyanide
perfluoro(8-cyano-2,5-dimethyl-3,6-dioxanonanoyl) fluoride
Conditions | Yield |
---|---|
In further solvent(s) | 91.3% |
Conditions | Yield |
---|---|
91% |
Hexafluoropropene oxide
Conditions | Yield |
---|---|
In dichloromethane absence of air and moisture; stirring in (CF3)CFCOCF2-atmosphere for 1 h(pptn.); ether addn., stirring for 2 h, collection (filtration), washing (ether);elem. anal.; | 91% |
Hexafluoropropene oxide
1,2-diamino-benzene
3-(trifluoromethyl)quinoxalin-2-ol
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In diethyl ether at -78 - 20℃; for 16h; | 91% |
Hexafluoropropene oxide
toluene
1,1,1,3,3,3-hexafluoro-2,2-di(p-tolyl)propane
Conditions | Yield |
---|---|
With SbF4Cl; hydrogen fluoride for 12h; Autoclave; Large scale; | 90.6% |
Reported in EPA TSCA Inventory.
DOT Classification: 2.2; Label: Nonflammable Gas
The Hexafluoropropene epoxide , with the CAS register number 428-59-1, has other names as hfpo ; hexafluoro-1,2-epoxypropane ; hexafluoropropylene oxide ; hexafluoropropene oxide ; hexafluoroepoxypropane ; 1,2-epoxy-1,1,2,3,3,3-hexafluoropropane ; trifluoro(trifluoromethyl)oxirane ; (trifluoromethyl)trifluorooxirane .
The physical properties of this chemcial are as followings: (1)ACD/LogP: 2.43 ; (2)ACD/LogD (pH 5.5): 2.43 ; (3)ACD/LogD (pH 7.4): 2.43 ; (4)ACD/BCF (pH 5.5): 41.45 ; (5)ACD/BCF (pH 7.4): 41.45 ; (6)ACD/KOC (pH 5.5): 500.53 ; (7)ACD/KOC (pH 7.4): 500.53 ; (8)#H bond acceptors: 1; (9)Polar Surface Area: 12.53 ; (10)Index of Refraction: 1.262 ; (11)Molar Refractivity: 16.36 cm3 ; (12)Molar Volume: 98.9 cm3 ; (13)Polarizability: 6.48 ×10-24 cm3 ; (14)Surface Tension: 12.1 dyne/cm ; (15)Density: 1.67 g/cm3 ; (16)Enthalpy of Vaporization: 20.49 kJ/mol ; (17)Vapour Pressure: 7100 mmHg at 25°C.
Hexafluoropropylene oxide is a kind of gas with no color and odor. When shipped, it usually be made as a liquefied gas under its vapor pressure and if contacting with the liquid, it can cause frostbite. And the product categories belong to the fluoromonomer and organic Fluorides.
Being a kind of irritant chemical to eyes, respiratory system and skin, it may cause inflammation to the skin or other mucous membranes. And it has risk of explosion if heated under confinement. This chemical can cause asphyxiation by the displacement of air and the exposure of the container to prolonged heat or fire may cause it to rupture violently and rocket So while dealing with this chemical, you should be very cautious. Wear suitable gloves and eye/face protection , and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice. Keep container tightly closed and if in case of insufficient ventilation, wear suitable respiratory equipment. And you could also get the safety information from WGK Germany 3.
Additionally, you could convert the following data information into the molecular structure:
SMILES:FC(F)(F)C1(F)OC1(F)F
InChI:InChI=1/C3F6O/c4-1(2(5,6)7)3(8,9)10-1
InChIKey:PGFXOWRDDHCDTE-UHFFFAOYAQ
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