Hydrazine, 2-propenyl-(9CI) supplier

Name
ALLYLHYDRAZINE
EINECS
CAS No. 7422-78-8
Article Data13
CAS DataBase
Density 0.841 g/cm³
Solubility
Melting Point
Formula C₃H₈N₂
Boiling Point 157.8 °C at 760 mmHg
Molecular Weight 72.1099
Flash Point 52.6 °C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Hydrazine,allyl- (7CI,8CI);(2-Propenyl)hydrazine;Allylhydrazine;prop-2-en-1-ylhydrazine;hydrazine, 2-propen-1-yl-;Hydrazine, 2-propenyl-;Hydrazine, allyl-;
PSA 38.05000
LogP 0.72690

Synthetic route

: 107-11-9
1-amino-2-propene

: 7422-78-8
allylhydrazine

Conditions

Conditions	Yield
With sodium hydroxide; chloroamine In water at 35 - 45℃;	80%
With chloroamine

: 107-05-1
3-chloroprop-1-ene

: 7422-78-8
allylhydrazine

Conditions

Conditions	Yield
With hydrazine hydrate at 100℃;

: 70629-56-0
C15H17N2OP

: 7422-78-8
allylhydrazine

Conditions

Conditions	Yield
With hydrogenchloride Heating;

: α-Allyl-Nβ-isopropyliden-hydrazino>-triphenyl-phosphoniumiodid

: 7422-78-8
allylhydrazine

Conditions

Conditions	Yield
(i) aq. Na2CO3, (ii) AcOH, PhCHO; Multistep reaction;

: 463-49-0
1,2-propanediene

A: 5281-20-9
acetone hydrazone

B: 7422-78-8
allylhydrazine

Conditions

Conditions	Yield
With C24H20B(1-)C27H39AuClNK(1+); hydrazine at 130℃; for 14h; Inert atmosphere;

: 202980-98-1
N'-[(tert-butoxy)carbonyl]-N'-(prop-2-en-1-yl)(tert-butoxy)carbohydrazide

: 7422-78-8
allylhydrazine

Conditions

Conditions	Yield
With trifluoroacetic acid In dichloromethane at 0 - 20℃; for 1h;

: 1193-21-1
4,6-dichloropyrimidine

: 7422-78-8
allylhydrazine

: 4,6-bis[1-(prop-2-enyl)hydrazino]pyrimidine

Conditions

Conditions	Yield
for 3h; Heating;	100%

: 7422-78-8
allylhydrazine

: 29681-98-9
p-fluorobenzoylacetone

: 1221503-18-9
1-allyl-5-(4-fluorophenyl)-3-methyl-1H-pyrazole

Conditions

Conditions	Yield
With triethylamine; trifluoroacetic acid In isopropyl alcohol at 80℃; for 1h;	95%

: 7422-78-8
allylhydrazine

: 66-99-9
β-naphthaldehyde

: 1097191-46-2
1-allyl-2-(naphthalen-2-ylmethylene)hydrazine

Conditions

Conditions	Yield
In ethanol; water at 20℃; for 12h; Inert atmosphere;	94%

: 7422-78-8
allylhydrazine

: 141-78-6
ethyl acetate

: 64632-82-2
1-acetyl-2-allylhydrazide

Conditions

Conditions	Yield
at 150℃; for 19h; sealed tube;	92%
In water

: 71126-50-6
(3Z)-3-(4-methoxyphenylmethylidene)-2-benzofuran-1(3H)-one

: 7422-78-8
allylhydrazine

: 2-allyl-4-(4-methoxy-benzyl)-2H-phthalazin-1-one

Conditions

Conditions	Yield
	90%

: 105279-16-1
(Z)-3-(4-chlorophenyl)methylidenephthalide

: 7422-78-8
allylhydrazine

: 2-allyl-4-(4-chlorobenzyl)phthalazin-1(2H)-one

Conditions

Conditions	Yield
	89%

: 7422-78-8
allylhydrazine

: 105-36-2
ethyl bromoacetate

: ethyl 2-(1-allylhydrazinyl)acetate

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃; for 25h; Reflux;	87%

: (Z)-3-(4-methylsulfanylbenzylidene)isobenzofuran-1-one

: 7422-78-8
allylhydrazine

: 2-allyl-4-(4-methylsulfanyl-benzyl)-2H-phthalazin-1-one

Conditions

Conditions	Yield
	85%

: 148345-07-7
(Z)-3-(3,4-dimethoxybenzylidene)isobenzofuran-1(3H)-one

: 7422-78-8
allylhydrazine

: 2-allyl-4-(3,4-dimethoxy-benzyl)-2H-phthalazin-1-one

Conditions

Conditions	Yield
	70%

: 7422-78-8
allylhydrazine

: 3173-56-6
benzyl isothiocyanate

: 4-benzyl-2-allylsemicarbazide

Conditions

Conditions	Yield
In chloroform at 0℃; for 2h;	70%

: 7422-78-8
allylhydrazine

: 1235493-42-1
methyl N-4-(4-chloro-1H-imidazol-1-yl)-3-methoxyphenyl-N'-(2-(4-fluorophenyl)pent-4-enoyl)carbamimidothioate

: 1235493-43-2
1-allyl-N-(4-(4-chloro-1H-imidazol-1-yl)-3-methoxyphenyl)-5-(1-(4-fluorophenyl)but-3-enyl)-1H-1,2,4-triazol-3-amine

Conditions

Conditions	Yield
In ethanol; water at 80℃; for 3h;	69%

: 7422-78-8
allylhydrazine

: 91440-79-8
1,4-di(benzyloxy)-5,8-dichloro-9,10-dihydro-9,10-anthracenedione

: 111425-44-6
2-Allyl-7,10-bis-benzyloxy-5-chloro-2H-dibenzo[cd,g]indazol-6-one

Conditions

Conditions	Yield
With potassium fluoride; potassium hydrogencarbonate In dimethyl sulfoxide at 80℃; for 18h;	53%

: 7422-78-8
allylhydrazine

: 106-96-7
propargyl bromide

: 54362-42-4
N-Allyl-N-prop-2-ynyl-hydrazine

Conditions

Conditions	Yield
In diethyl ether	45%

: 1722-12-9
2-chloropyrimidine

: 7422-78-8
allylhydrazine

: 2-(1-allylhydrazinyl)pyrimidine

Conditions

Conditions	Yield
With caesium carbonate In N,N-dimethyl-formamide at 75℃; for 12h;	38%

: 7422-78-8
allylhydrazine

: (S)-1-(1-((4-fluorophenyl)sulfonyl)-6-(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)-1,2,3,4-tetrahydroquinolin-2-yl)but-3-yn-2-one

A: (S)-2-(2-((1-allyl-1H-pyrazol-5-yl)methyl)-1-((4-fluorophenyl)sulfonyl)-1,2,3,4-tetrahydroquinolin-6-yl)-1,1,1,3,3,3-hexafluoropropan-2-ol

B: (S)-2-(2-((1-allyl-1H-pyrazol-3-yl)methyl)-1-((4-fluorophenyl)sulfonyl)-1,2,3,4-tetrahydroquinolin-6-yl)-1,1,1,3,3,3-hexafluoropropan-2-ol

Conditions

Conditions	Yield
In methanol at 20℃; for 1h;	A 21% B 21%

...Expand

: 51483-92-2
6-bromo-1-benzopyran-4(4H)-one

: 7422-78-8
allylhydrazine

: 2-(1-allyl-1H-pyrazol-3-yl)-4-bromophenol

Conditions

Conditions	Yield
In dimethyl sulfoxide at 100℃;	21%
In dimethyl sulfoxide at 100℃; for 36h;	50 mg

: 7422-78-8
allylhydrazine

: 10191-60-3
dimethyl N-cyanodithioiminocarbonate

A: 84827-81-6
1-Allyl-5-methylsulfanyl-1H-[1,2,4]triazol-3-ylamine

B: 84827-80-5
1-allyl-5-amino-3-methylthio-1,2,4-triazole

Conditions

Conditions	Yield
In ethanol for 3h; Heating;	A 8% B 16%

...Expand

: 5617-74-3
3-oxabicyclo[3.1.0]hexane-2,4-dione

: 7422-78-8
allylhydrazine

: (1S,6R)-3-Allyl-3,4-diaza-bicyclo[4.1.0]heptane-2,5-dione

Conditions

Conditions	Yield
In ethanol for 12h; Heating;	16%

: 7422-78-8
allylhydrazine

: 103-72-0
phenyl isothiocyanate

: 21076-33-5
2-allyl-4-phenyl thiosemicarbazide

Conditions

Conditions	Yield

In diethyl ether

: 590-28-3
potassium cyanate

: 1467-70-5
furan-2-yl-oxo-acetic acid

: 7422-78-8
allylhydrazine

: 26216-81-9
2-allyl-6-furan-2-yl-2H-[1,2,4]triazine-3,5-dione

Conditions

Conditions	Yield
(i) aq. HCl, (ii) /BRN= 115630/; Multistep reaction;

...Expand

: 50-00-0
formaldehyd

: 7422-78-8
allylhydrazine

: 36214-52-5
N-Allyl-N'-methylene-hydrazine

Conditions

Conditions	Yield

: 590-42-1
tert-butyl isothiocyanate

: 7422-78-8
allylhydrazine

: 21076-15-3
4-tert.-Butyl-2-allyl-thiosemicarbazid

Conditions

Conditions	Yield
In diethyl ether

: 7422-78-8
allylhydrazine

: 29518-83-0
S-Methyl-monothiokohlensaeure-tert.-butylester

: 21075-86-5
(tert-butoxy)-N-(prop-2-en-1-yl)carbohydrazide

Conditions

Conditions	Yield

: 7422-78-8
allylhydrazine

: 60246-54-0
4-Butyloxy-dithiobenzoesaeure-(carboxy-methylester)

: 98528-41-7
4-Butyloxy-thiobenzoesaeure-(N1-allyl-hydrazid)

Conditions

Conditions	Yield
With sodium hydroxide

: 7422-78-8
allylhydrazine

: 13292-22-3
3-formylrifamycin SV

: 39976-77-7
3-(allylhydrazono-methyl)-rifamycin

Conditions

Conditions	Yield
In tetrahydrofuran for 0.5h; Ambient temperature;

: 7422-78-8
allylhydrazine

: 556-61-6
methyl thioisocyanate

: 21198-39-0
4-Methyl-2-allyl-thiosemicarbazid

Conditions

Conditions	Yield
In diethyl ether

Hydrazine, 2-propenyl-(9CI) Specification

The Hydrazine, 2-propenyl-(9CI), with the CAS registry number 7422-78-8, has the systematic name of prop-2-en-1-ylhydrazine. It is a kind of organics, and should be stored in the dry and cool environment. And the molecular formula of the chemical is C₃H₈N₂.

The characteristics of Hydrazine, 2-propenyl-(9CI) are as followings: (1)ACD/LogP: -0.22; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -2.73; (4)ACD/LogD (pH 7.4): -1.03; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 2.81; (9)#H bond acceptors: 2; (10)#H bond donors: 3; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 6.48 Å²; (13)Index of Refraction: 1.445; (14)Molar Refractivity: 22.8 cm³; (15)Molar Volume: 85.6 cm³; (16)Polarizability: 9.03×10^-24cm³; (17)Surface Tension: 28.2 dyne/cm; (18)Density: 0.841 g/cm³; (19)Flash Point: 52.6 °C; (20)Enthalpy of Vaporization: 39.45 kJ/mol; (21)Boiling Point: 157.8 °C at 760 mmHg; (22)Vapour Pressure: 2.71 mmHg at 25°C.

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: C=C\CNN
(2)InChI: InChI=1/C3H8N2/c1-2-3-5-4/h2,5H,1,3-4H2
(3)InChIKey: ZTILHLWDFSMCLZ-UHFFFAOYAA

Product Name

ALLYLHYDRAZINE

Synthetic route

Hydrazine, 2-propenyl-(9CI) Specification

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