Lithium carbonate supplier

Name
Lithium carbonate
EINECS 209-062-5
CAS No. 554-13-2
Article Data117
CAS DataBase
Density 2.11 g/cm³
Solubility water: 13 g/L (20 °C)
Melting Point 720 °C
Formula Li₂CO₃
Boiling Point 333.6 °C at 760 mmHg
Molecular Weight 73.8912
Flash Point 169.8 °C
Transport Information UN 3264 8/PG 3
Appearance white fine crystalline powder
Safety 8-43-45-37/39-26-36/37-24/25-36/37/39-16-7/8-3/7/9
Risk Codes 36/38-41-36/37/38-22-36-34-20/21/22-15-14-11
Molecular Structure
Hazard Symbols Xn,C,F
Synonyms Lithane;Lithium carbonate;Lithiumcarbonate;Plenur;Liticar;Litard;Limas;Eutimin;Lithea;Priadel;Li2CO3;Phasal;
PSA 63.19000
LogP -2.44700

Synthetic route

: 124-38-9
carbon dioxide

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
With C14H14B2(2-)*2Li(1+) In tetrahydrofuran at 25℃; under 760.051 Torr; Sealed tube; Cooling with liquid nitrogen; Inert atmosphere;	83%
With Tri-n-octylamine; water; lithium chloride In butan-1-ol under 7.50075E-06 Torr;
With lithium hydroxide monohydrate In water for 2.68333h; Kinetics; Time;
With C2H3OS2(1-)*Li(1+) In methanol

: 2Li(1+)*W(CO)5(2-)=Li2{W(CO)5}

: 124-38-9
carbon dioxide

A: 14040-11-0
tungsten hexacarbonyl

B: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In tetrahydrofuran reductive disproportionation; mechanism discussed;; IR;;	A 82% B 74%
In tetrahydrofuran soln. of the W-compound was treated with gasous CO2 at -78°C, warmed to 25°C; solvent removed (vac.), extd. (diethyl ether), ether removed (vac.); IR, MAS;	A 82% B 74%

...Expand

: 584-08-7
potassium carbonate

: lithium chloride

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In not given pptn. from concd. LiCl soln. with excess of K2CO3;;
In not given pptn. from concd. LiCl soln. with excess of K2CO3;;

: lithium nitrate

: 584-08-7
potassium carbonate

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In not given pptn. from concd. LiNO3 soln. with excess of K2CO3;;
In not given pptn. from concd. LiNO3 soln. with excess of K2CO3;;

: lithium sulfate

: 584-08-7
potassium carbonate

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In not given
In not given pptn. from concd. Li2SO4 soln. with excess of K2CO3;;
In not given
In not given pptn. from concd. Li2SO4 soln. with excess of K2CO3;;

: 6108-17-4, 61013-21-6, 61013-23-8, 67299-15-4, 116277-84-0
lithium acetate dihydrate

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
With poly(methyl methacrylate); oxalic acid; Ni(CH3COO)2*4H2O In methanol byproducts: NiO; poly(methyl methacrylate) added; pptd. by adding of oxalic acid soln.; calcined at 298-400°C for 1-15 h in mixed atm. air/N2, at 400-600°C in air or O2; powder XRD;
In neat (no solvent, solid phase) heated for 1 h at 500°C; XRD;

: 6108-17-4, 61013-21-6, 61013-23-8, 67299-15-4, 116277-84-0
lithium acetate dihydrate

: 6018-89-9
nickel(II) acetate tetrahydrate

A: 1313-99-1
nickel(II) oxide

B: lithium nickelate(III)

C: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In water mixt. stirred, heated at 120 °C to remove water, heated at 250 °C for 24 h or at 370 °C for 24 h; detd. by XRD;

...Expand

: 1310-66-3
lithium hydroxide monohydrate

: 6018-89-9
nickel(II) acetate tetrahydrate

A: 1313-99-1
nickel(II) oxide

B: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In neat (no solvent) LiOH*H2O and Ni acetate separately dissolved in H2O; mixed; pH adjusted to 8.5-9.5; heated at 110°C until they were dry; calcined at 300-500°C; monitored by X-ray diffraction;

...Expand

: 1310-66-3
lithium hydroxide monohydrate

: 6018-89-9
nickel(II) acetate tetrahydrate

A: Li2Ni8O10

B: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In neat (no solvent) LiOH*H2O and Ni acetate separately dissolved in H2O; mixed; pH adjusted to 8.5-9.5; heated at 110°C until they were dry; calcined at 600°C; monitored by X-ray diffraction;

...Expand

: lithium peroxide

: 124-38-9
carbon dioxide

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
High Pressure; at 400°C, pressure of CO2: 2100 at for 6 h;

: ammonium carbonate

: lithium chloride

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In not given pptn. from concd. LiCl soln. with excess of (NH4)2CO3;;
In water pptn. from aq. purified LiCl soln. (addn. of NH4 oxalate and Ba(OH)2 to LiCl soln., pptn. with H2SO4, filtration, vaporization to dryness, exhausting with alcohol) with (NH4)2CO3;; repeated recrystn. till residue is Na free, removal of LiCl traces by changing into sulfate and pptn. as carbonate; pure Li2CO3;;
In water pptn. from aq. purified LiCl soln. (addn. of NH4 oxalate and Ba(OH)2 to LiCl soln., pptn. with H2SO4, filtration, vaporization to dryness, exhausting with alcohol) with (NH4)2CO3;; repeated recrystn. till residue is Na free, removal of LiCl traces by changing into sulfate and pptn. as carbonate; pure Li2CO3;;
In not given pptn. from concd. LiCl soln. with excess of (NH4)2CO3;;

: ammonium carbonate

: spodumene

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Al carbonate; calcination of spondumene with KOH, vaporization with HNO3, pptn. of Ca and Al with (NH4)2CO3, vaporization of filtrate to dryness, mixing residue containing alkalies with coal, heating, extraction of K2CO3 with H2O;;

: ammonium carbonate

: 1310-65-2
lithium hydroxide

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In ammonia from final liquor of Li mineral;;
In ammonia aq. ammonia=NH3; from final liquor of Li mineral;;

: ammonium carbonate

lepidolite=Lepidolith Si3O9Al2(Li,K)2F2#Si3O9Al2(Li,K)2(OH)2, lepidolite: lepidolite=Lepidolith Si3O9Al2(Li,K)2F2#Si3O9Al2(Li,K)2(OH)2, lepidolite

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
With potassium sulfate; sulfuric acid In ammonia byproducts: Al alum; digeration of lepidolite in warm concd. H2SO4, calcination, extraction with H2O, pptn. of Al with K2SO4 and lime milk, pptn. of sulfates with BaCl2, vaporization to dryness, extraction with abs. alcohol, vaporization, pptn. with (NH4)2C2O4 and (NH4)2S;; vaporization in silver vessel, pptn. from ammoniacal soln. with (NH4)2CO3;;
With gypsum In neat (no solvent) byproducts: K2SO4, CaSO4; 2 h calcination of mixt. of gypsum and lepidolite at red heat till sintering, extraction with hot water, concg., pptn. of heavy- and alkaline earth metals with mixt. of NH3, (NH4)2S and ammonium oxalate, filtration, addn. of (NH4)2CO3 to filtrate;; washing with cold water; solving again and renewened pptn. for further purification;;

: 108-32-7
1,2-propylene cyclic carbonate

: lithium perchlorate

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In further solvent(s) Electrochem. Process; Li2CO3 formed in aged films on SnO2 or WO3 electrode surfaces obtained from 1 M LiClO4 soln. in propylene carbonate; detn. by XRD, IR, XPS;

: 497-19-8
sodium carbonate

: lithium chloride

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In not given pptn. from concd. LiCl soln. with excess of Na2CO3;;
In not given pptn. from concd. LiCl soln. with excess of Na2CO3;;

: 124-38-9
carbon dioxide

: lithium chloride

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
With NH3 In not given precipitation with NH3 soln. and CO2;;

: silicic acid

: 80937-33-3
oxygen

: 57-13-6
urea

: 1310-65-2
lithium hydroxide

A: lithium metasilicate

B: lithium silicate

C: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In water combustion synthesis; LiOH, H2SiO3, urea suspended in H2O, evapd., heated in air at 650-1100°C; not isolated, detected by XRD, IR;

...Expand

: silicic acid

: 80937-33-3
oxygen

: 57-13-6
urea

: 1310-65-2
lithium hydroxide

A: lithium silicate

B: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In water combustion synthesis; LiOH, H2SiO3, urea suspended in H2O, evapd., heated in air at 900-1100°C; not isolated, detected by XRD, IR;

...Expand

: lithium cation

: 497-19-8
sodium carbonate

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In not given
In not given

lithiophilite LiFePO4: lithiophilite LiFePO4

: 3812-32-6
carbonate(2-)

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In hydrogenchloride; nitric acid byproducts: FePO4, Mn oxide; solving triphylite in mixt. of HNO3 in concd. HCl, decantation, addn. of FeCl3, vaporization to dryness, boiling residue with H2O, addn. of BaS, boiling on air, filtration, pptn. of Ba with H2SO4, filtration, vaporization to dryness, melting;; solving melt in concd. NH3, pptn. with carbonate;;
In hydrogenchloride; nitric acid byproducts: FePO4, Mn oxide; solving triphylite in mixt. of HNO3 in concd. HCl, decantation, vaporization to dryness, boiling residue with H2O, addn. of Ca(OH)2 excess, boiling on air, filtration, pptn. of Ca with (NH4)2CO3 and NH4OH, filtration, vaporization to dryness, melting;; solving melt in concd. NH3, pptn. with carbonate;;

Li{Al(F,OH)}PO4 Li(AlOH)PO4, amblygonite: Li{Al(F,OH)}PO4 Li(AlOH)PO4, amblygonite

: 3812-32-6
carbonate(2-)

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
With potassium sulfate In melt melting of amblygonite with K2SO4, quenching with water, extraction, removal of K2SO4 by fractionated crystn.;; pptn. with carbonate; pure LiCO3;;
With potassium sulfate In melt melting of amblygonite with K2SO4, quenching with water, extraction, removal of K2SO4 by fractionated crystn.;; pptn. with carbonate; pure LiCO3;;

lepidolite=Lepidolith Si3O9Al2(Li,K)2F2#Si3O9Al2(Li,K)2(OH)2, lepidolite: lepidolite=Lepidolith Si3O9Al2(Li,K)2F2#Si3O9Al2(Li,K)2(OH)2, lepidolite

: 3812-32-6
carbonate(2-)

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
With sulfuric acid In melt melting of lepidolite, decompn. with H2SO4, pptn. of Al, pptn. of Li2SO4 with acetate, calcination with carbonate, separation of alkali carboantes from Li;;
With potassium sulfate In water byproducts: SiO2, Al2O3, potassium silicate; heating mixt. of lepidolite and crude K2SO4, extraction with water, removal of Mn from soln. with KOH, filtration;; pptn. of Li from filtrate with carbonate; pure Li2CO3;;
With potassium sulfate In sulfuric acid byproducts: SiO2, Al alum; heating finely powderd lepidolite in H2SO4 from 112 to 340°C within 8 hs, extraction of residue with H2O at elevated temp., addn. of K2SO4, centrifugation after 6 days, addn. of CaCO3, pptn. with Al(OH)3, pptn. of Al rest, Ca, Fe and Mn;; pptn. with carbonate;;
With potassium sulfate In melt melting finely powderd lepidolite and crude potassium sulfate, extraction with hot water, removal of Mn by KOH, pptn. of Li in filtrate with CO3(2-);;
In sulfuric acid decompn. of lepidolite with H2SO4, calcination, extraction with H2O, removal of impurities with lime, pptn. of Mn with caustic lime, pptn. of alkali sulfates with excess of Li2CO3;; pptn. of Li from filtrate with carbonate; high degree of purity;;

: spodumene

: 124-38-9
carbon dioxide

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
With Ca(OH)2
With calcium hydroxide In not given on heating β-spodumene with Ca(OH)2, formation of a 1-4% soln. of LiOH, precipitation of Li2CO3 with CO2;;

: 556-63-8
lithium formate

: 1310-65-2
lithium hydroxide

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: H2; formation at 280°C from Li formiate and LiOH;;	>99
In neat (no solvent) byproducts: H2; formation at 280°C from Li formiate and LiOH;;	>99

: 124-38-9
carbon dioxide

: 1310-65-2
lithium hydroxide

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In neat (no solvent) storage LiOH on air for a longer period of time;;
In neat (no solvent) storage LiOH on air for a longer period of time;;
In not given from final liquor of Li mineral, precipitation with CO2 at 60°C;;

: 546-89-4
lithium acetate

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In solid heating at 380-438°C;
In neat (no solvent) calcination till complete decompn., exhausting, vaporization;;
In neat (no solvent) byproducts: acetone; destructive distn., pptn. of pure Li2CO3 and acetone at low temp.;; pure Li2CO3;;
In neat (no solvent) calcination till complete decompn., exhausting, vaporization;;
In neat (no solvent) byproducts: acetone; destructive distn., pptn. of pure Li2CO3 and acetone at low temp.;; pure Li2CO3;;

: lithium nitrate

: 497-19-8
sodium carbonate

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In not given pptn. from concd. LiNO3 soln. with excess of Na2CO3;;
In not given pptn. from concd. LiNO3 soln. with excess of Na2CO3;;

lepidolite=Lepidolith Si3O9Al2(Li,K)2F2#Si3O9Al2(Li,K)2(OH)2, lepidolite: lepidolite=Lepidolith Si3O9Al2(Li,K)2F2#Si3O9Al2(Li,K)2(OH)2, lepidolite

: 497-19-8
sodium carbonate

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In melt byproducts: SiO2; melting of lepidolite, fine powdering, slurrying, addn. of concd. HCl, pptn. of SiO2 on vaporization with HCl, filtration from SiO2, addn. of HNO3 to oxidate Fe, filtration, pptn. of impurities with Na2CO3, filtration, pptn. of Li with Na2CO3;;
With Phosphate; potassium carbonate In sulfuric acid byproducts: Al alum, Li3PO4; melting of lepidolite, quenching with H2O, digeration with H2SO4 at elevated temp. for few hours and 24 hs in coldness, diluting with H2O, boiling, filtration, vaporization, pptn. of RbCl and CsCl on cooling, pptn. of Al with K2CO3;; pptn. of LiCO3 from mother lye with Na2CO3, pptn. of rest in ammoniacal soln. with PO4(3-); purification;;

Yield

In melt byproducts: SiO2; melting of lepidolite, fine powdering, slurrying, addn. of concd. HCl, pptn. of SiO2 on vaporization with HCl, filtration from SiO2, addn. of HNO3 to oxidate Fe, filtration, pptn. of impurities with Na2CO3, filtration, pptn. of Li with Na2CO3;;

With Phosphate; potassium carbonate In sulfuric acid byproducts: Al alum, Li3PO4; melting of lepidolite, quenching with H2O, digeration with H2SO4 at elevated temp. for few hours and 24 hs in coldness, diluting with H2O, boiling, filtration, vaporization, pptn. of RbCl and CsCl on cooling, pptn. of Al with K2CO3;; pptn. of LiCO3 from mother lye with Na2CO3, pptn. of rest in ammoniacal soln. with PO4(3-); purification;;

: titanium(IV) oxide bis(2,4-pentanedionate)

: 19261-03-1
1,1'-Biphenyl-2,2',3,3'-tetrol

: 7732-18-5
water

: 554-13-2
lithium carbonate

: 4Li(1+)*Ti2(C6H3(O)2C6H3(O)2)3(4-)*12H2O=Li4[Ti2(C6H3(O)2C6H3(O)2)3]*12H2O

Conditions

Conditions	Yield
In methanol phenol-compd.:Ti-compd.:alkali-compd. molar ratio was 3:2:2, stirring overnight; solvent was removed in vac., residue was purified by filtration through Sephadex LH 20, elem. anal.;	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: 7732-18-5
water

: 554-13-2
lithium carbonate

: 214823-41-3
1,1':4',1"-terphenyl-2,2",3,3"-tetraol

: 4Li(1+)*[C6H3(O)2C6H4C6H3(O)2]3Ti2(4-)*8H2O=Li4[[C6H3(O)2C6H4C6H3(O)2]3Ti2]*8H2O

Conditions

Conditions	Yield
In methanol phenol-compd.:Ti-compd.:alkali-compd. molar ratio was 3:2:2, stirring overnight; solvent was removed in vac., residue was purified by filtration through Sephadex LH 20, elem. anal.;	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: 175844-48-1
3,3'-ethane-1,2-diylbis(1,2-benzendiol)

: 554-13-2
lithium carbonate

: 4Li(1+)*[Ti2((O2C6H3CH2)2)3](4-)*5CH3OH*6H2O=Li4[Ti2((O2C6H3CH2)2)3]*5CH3OH*6H2O

Conditions

Conditions	Yield
2 equiv. of Ti complex, 2 equiv. of Li2CO3;	100%

...Expand

: gold(III) hydroxide

: 1493-13-6
trifluorormethanesulfonic acid

: 554-13-2
lithium carbonate

: 1446355-29-8
lithium tetrakis(trifluoromethanesulfonato)aurate

Conditions

Conditions	Yield
at 150℃; for 24h; Sealed tube;	100%

...Expand

: 1451250-34-2
6-(sulfomethyl)pyridine-2-carboxylic acid

: 554-13-2
lithium carbonate

: 1451194-09-4
monolithium salt of 6-(sulfomethyl)pyridine-2-carboxylic acid

Conditions

Conditions	Yield
In water	100%

: TiO(acac)2

: 554-13-2
lithium carbonate

: 105603-49-4
methyl 5-bromo-2,3-dihydroxybenzoate

: C48H30Br6Li3O24Ti2(1-)*Li(1+)*2CH4O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: TiO(acac)2

: 4,5-dibromo-2,3-dihydroxymethylbenzoate

: 554-13-2
lithium carbonate

: C48H24Br12Li3O24Ti2(1-)*Li(1+)*4CH4O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: TiO(acac)2

: 554-13-2
lithium carbonate

: 125629-12-1
methyl 2,3-dihydroxy-5-nitrobenzoate

: 2Li(1+)*C24H15N3O18Ti(2-)

Conditions

Conditions	Yield
In methanol	100%

...Expand

: TiO(acac)2

: 56128-66-6
2,3,4-trihydroxybenzoic acid methyl ester

: 554-13-2
lithium carbonate

: C48H36Li3O30Ti2(1-)*Li(1+)*3CH4O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: TiO(acac)2

: 5-bromo-2,3-dihydroxyethylbenzoate

: 554-13-2
lithium carbonate

: C54H42Br6Li3O24Ti2(1-)*Li(1+)*2H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: TiO(acac)2

: 4,5-dibromo-2,3-dihydroxyethylbenzoate

: 554-13-2
lithium carbonate

: C54H36Br12Li3O24Ti2(1-)*Li(1+)*8CH4O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: TiO(acac)2

: 5-nitro-2,3-dihydroxyethylbenzoate

: 554-13-2
lithium carbonate

: C54H42Li3N6O36Ti2(1-)*Li(1+)*9H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: TiO(acac)2

: 5-phenyl-2,3-dihydroxyethylbenzoate

: 554-13-2
lithium carbonate

: C90H72Li3O24Ti2(1-)*Li(1+)*9H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: 3-pentyl-2,3-dihydroxybenzoate

: 7732-18-5
water

: 554-13-2
lithium carbonate

: C72H84Li3O24Ti2(1-)*Li(1+)*5H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: 67-56-1
methanol

: titanium(IV) oxide bis(2,4-pentanedionate)

: propyl 2,3-dihydroxybenzoate

: 554-13-2
lithium carbonate

: C60H60Li3O24Ti2(1-)*Li(1+)*3CH4O

Conditions

Conditions	Yield
	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: butyl-2,3-dihydroxybenzoate

: 7732-18-5
water

: 554-13-2
lithium carbonate

: C66H72Li3O24Ti2(1-)*Li(1+)*4H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: 1245829-49-5
pentyl 2,3-dihydroxybenzoate

: 7732-18-5
water

: 554-13-2
lithium carbonate

: C72H84Li3O24Ti2(1-)*Li(1+)*2H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: hexyl-2,3-dihydroxybenzoate

: 7732-18-5
water

: 554-13-2
lithium carbonate

: C78H96Li3O24Ti2(1-)*Li(1+)*4H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: heptyl-2,3-dihydroxybenzoate

: 7732-18-5
water

: 554-13-2
lithium carbonate

: C84H108Li3O24Ti2(1-)*Li(1+)*3H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: 7732-18-5
water

: 554-13-2
lithium carbonate

: octyl-2,3-dihydroxybenzoate

: C90H120Li3O24Ti2(1-)*Li(1+)*2H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: 7732-18-5
water

: 554-13-2
lithium carbonate

: nonyl 2,3-dihydroxybenzoate

: C96H132Li3O24Ti2(1-)*Li(1+)*2H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: 1245829-56-4
decyl-2,3-dihydroxybenzoate

: 7732-18-5
water

: 554-13-2
lithium carbonate

: C102H144Li3O24Ti2(1-)*Li(1+)*4H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: undecyl-2,3-dihydroxybenzoate

: 7732-18-5
water

: 554-13-2
lithium carbonate

: C108H156Li3O24Ti2(1-)*Li(1+)*4H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: 3,3,3-trifluoropropyl-2,3-dihydroxybenzoate

: 7732-18-5
water

: 554-13-2
lithium carbonate

: C60H42F18Li3O24Ti2(1-)*Li(1+)*23H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: 3,3,4,4,4-pentafluorobutyl-2,3-dihydroxybenzoate

: 7732-18-5
water

: 554-13-2
lithium carbonate

: C66H42F30Li3O24Ti2(1-)*Li(1+)*33H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: titanium(IV) oxide bis(2,4-pentanedionate)

: 3,3,4,4,5,5,6,6,6-nonafluorohexyl-2,3-dihydroxybenzoate

: 7732-18-5
water

: 554-13-2
lithium carbonate

: C78H42F54Li3O24Ti2(1-)*Li(1+)*30H2O

Conditions

Conditions	Yield
In methanol	100%

...Expand

: 67-56-1
methanol

: titanium(IV) oxide bis(2,4-pentanedionate)

: cyclobutyl-2,3-dihydroxybenzoate

: 554-13-2
lithium carbonate

: C66H60Li3O24Ti2(1-)*Li(1+)*4CH4O

Conditions

Conditions	Yield
	100%

...Expand

: 67-56-1
methanol

: titanium(IV) oxide bis(2,4-pentanedionate)

: cyclopentyl-2,3-dihydroxybenzoate

: 554-13-2
lithium carbonate

: C72H72Li3O24Ti2(1-)*Li(1+)*4CH4O

Conditions

Conditions	Yield
	100%

...Expand

: 67-56-1
methanol

: titanium(IV) oxide bis(2,4-pentanedionate)

: cyclohexyl-2,3-dihydroxybenzoate

: 554-13-2
lithium carbonate

: C78H84Li3O24Ti2(1-)*Li(1+)*8CH4O

Conditions

Conditions	Yield
	100%

...Expand

: 67-56-1
methanol

: titanium(IV) oxide bis(2,4-pentanedionate)

: cycloheptyl-2,3-dihydroxybenzoate

: 554-13-2
lithium carbonate

: C84H96Li3O24Ti2(1-)*Li(1+)*4CH4O

Conditions

Conditions	Yield
	100%

...Expand

Lithium carbonate Specification

Lithium carbonate, its cas register number is 554-13-2. It also can be called Lithonate; Lithium hydroxide, solution; Eskalith; and Lithobid. Lithium carbonate, the most widely used of the compounds, is employed in the production of lithium metal and ft-its and enamels. Together with lithium fluoride (LiF), it serves as an additive for cryolite in the elec-trolytic pot line production of primary aluminum. It also is used to treat manic states and bipolar disorder, and is used in the manufacture of most LITHIUM-ion battery cathodes, which are made of lithlum cobalt oxide. It is manufactured from spodumene, which is by far the most important lithium-containing ore.

Physical properties about Lithium carbonate are: (1)ACD/LogP: -0.809; (2)ACD/LogD (pH 5.5): -1.98; (3)ACD/LogD (pH 7.4): -3.77; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)ACD/KOC (pH 5.5): 1.00; (7)ACD/KOC (pH 7.4): 1.00; (8)#H bond acceptors: 3; (9)#H bond donors: 2; (10)Flash Point: 169.8 °C; (11)Enthalpy of Vaporization: 63.37 kJ/mol; (12)Boiling Point: 333.6 °C at 760 mmHg; (13)Vapour Pressure: 2.58E-05 mmHg at 25°C

You can still convert the following datas into molecular structure:
(1)InChI=1S/CH2O3.2Li/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2;
(2)InChIKey=XGZVUEUWXADBQD-UHFFFAOYSA-L;
(3)SmilesC(=O)([O-])[O-].[Li+].[Li+];

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
dog	LD50	oral	500mg/kg (500mg/kg)		"Psychotropic Drugs and Related Compounds," 2nd ed., Usdin, E., and D.H. Efron, Washington, DC, 1972Vol. -, Pg. 436, 1972.
human	TDLo	oral	4111mg/kg (4111mg/kg)	GASTROINTESTINAL: OTHER CHANGES BEHAVIORAL: TREMOR BEHAVIORAL: MUSCLE WEAKNESS	New England Journal of Medicine. Vol. 287, Pg. 867, 1972.
man	TDLo	oral	8mg/kg (8mg/kg)	GASTROINTESTINAL: NAUSEA OR VOMITING SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE"	American Journal of Psychiatry. Vol. 141, Pg. 909, 1984.
man	TDLo	oral	54mg/kg (54mg/kg)	BEHAVIORAL: SLEEP BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS"	New Zealand Medical Journal. Vol. 97, Pg. 23, 1984.
man	TDLo	oral	1080mg/kg/13W (1080mg/kg)	SKIN AND APPENDAGES (SKIN): "DERMATITIS, ALLERGIC: AFTER SYSTEMIC EXPOSURE"	Journal of Clinical Psychiatry. Vol. 47, Pg. 330, 1986.
man	TDLo	oral	25gm/kg/4Y-I (25000mg/kg)	BEHAVIORAL: TREMOR SENSE ORGANS AND SPECIAL SENSES: MIOSIS (PUPILLARY CONSTRICTION): EYE	Journal of Clinical Psychiatry. Vol. 46, Pg. 292, 1985.
mouse	LD50	intraperitoneal	236mg/kg (236mg/kg)	BEHAVIORAL: ATAXIA BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) BEHAVIORAL: EXCITEMENT	Kiso to Rinsho. Clinical Report. Vol. 7, Pg. 1273, 1973.
mouse	LD50	intravenous	497mg/kg (497mg/kg)	LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)	Kiso to Rinsho. Clinical Report. Vol. 7, Pg. 1273, 1973.
mouse	LD50	oral	531mg/kg (531mg/kg)		Russian Pharmacology and Toxicology Vol. 33, Pg. 266, 1970.
mouse	LD50	subcutaneous	413mg/kg (413mg/kg)		Russian Pharmacology and Toxicology Vol. 33, Pg. 266, 1970.
rat	LD50	intraperitoneal	156mg/kg (156mg/kg)	GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)	Kiso to Rinsho. Clinical Report. Vol. 7, Pg. 1273, 1973.
rat	LD50	intravenous	241mg/kg (241mg/kg)	BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION	Kiso to Rinsho. Clinical Report. Vol. 7, Pg. 1273, 1973.
rat	LD50	oral	525mg/kg (525mg/kg)	LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"	Kiso to Rinsho. Clinical Report. Vol. 7, Pg. 1273, 1973.
rat	LD50	subcutaneous	434mg/kg (434mg/kg)	SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION SKIN AND APPENDAGES (SKIN): HAIR: OTHER	Kiso to Rinsho. Clinical Report. Vol. 7, Pg. 1273, 1973.
women	TDLo	oral	120mg/kg/10D- (120mg/kg)	BEHAVIORAL: EXCITEMENT	Journal of Clinical Psychiatry. Vol. 48, Pg. 81, 1987.
women	TDLo	oral	612mg/kg/44D- (612mg/kg)	SKIN AND APPENDAGES (SKIN): "DERMATITIS, ALLERGIC: AFTER SYSTEMIC EXPOSURE" BEHAVIORAL: SLEEP	American Journal of Psychiatry. Vol. 152, Pg. 956, 1995.
women	TDLo	oral	8760mg/kg/2Y- (8760mg/kg)	ENDOCRINE: EVIDENCE OF THYROID HYPERFUNCTION ENDOCRINE: THYROID WEIGHT (GOITER)	American Journal of Medicine. Vol. 99, Pg. 575, 1995.
women	TDLo	oral	36500mg/kg/10 (36500mg/kg)	ENDOCRINE: DIABETES INSIPIDUS (NEPHROGENIC OR CNS) KIDNEY, URETER, AND BLADDER: URINE VOLUME INCREASED KIDNEY, URETER, AND BLADDER: "CHANGES IN TUBULES (INCLUDING ACUTE RENAL FAILURE, ACUTE TUBULAR NECROSIS)"	Annales de Medecine Interne. Vol. 148, Pg. 284, 1997.
women	TDLo	unreported	556mg/kg/32D (556mg/kg)	BEHAVIORAL: TOXIC PSYCHOSIS	JAMA, Journal of the American Medical Association. Vol. 213, Pg. 865, 1970.

Product Name

Lithium carbonate

Synthetic route

Lithium carbonate Specification

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