Methyl (R)-(-)-3-hydroxybutyrate supplier

Name
Methyl (R)-(-)-3-hydroxybutyrate
EINECS 223-610-0
CAS No. 3976-69-0
Article Data174
CAS DataBase
Density 1.05 g/cm³
Solubility Slightly soluble in water.
Melting Point
Formula C₅H₁₀O₃
Boiling Point 161.9 °C at 760 mmHg
Molecular Weight 118.133
Flash Point 71.7 °C
Transport Information
Appearance clear colorless liquid
Safety 26-36/37-24/25-23
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Methyl (3R)-3-hydroxybutanoate;(R)- (-)-3-Hydroxybutyric acid methyl ester;Methyl (R)-3-Hydroxybutyrate;
PSA 46.53000
LogP -0.06970

Synthetic route

: 186581-53-3, 908094-01-9
diazomethane

: 625-72-9
(R)-3-hydroxybutyric acid

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
In diethyl ether	100%
In methanol; diethyl ether at -10℃;	76%

: 105-45-3
acetoacetic acid methyl ester

A: 53562-86-0
(S)-3-hydroxybutyric acid methyl ester

B: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With Ru2Cl4-(S)-(2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)2*NEt3; hydrogen In methanol at 35℃; under 76000.1 Torr; for 48h; Title compound not separated from byproducts;	A 100% B n/a
With <((R)-(1,1'-binaphthyl-2,2'-diyl)bis(diphenylphosphine))RuCl2>2NEt3; hydrogen In methanol at 35℃; under 76000.1 Torr; for 48h; Title compound not separated from byproducts;	A n/a B 100%
With hydrogen; Ru(BICP)Br2 In methanol at 40 - 65℃; under 750.075 - 3750.38 Torr;	A n/a B 95%

: 105-45-3
acetoacetic acid methyl ester

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With cat; hydrogen In methanol; dichloromethane at 25℃; under 77572.2 Torr; for 48h;	100%
With (R)-MeOBiphepRuBr2; hydrogen In methanol at 50℃; under 15200 Torr; for 48h;	100%
With (S)-4,12-bis(diphenylphosphino)-<2.2>paracyclophane-Ru(II)bis(trifluoroacetate); hydrogen; tetra-(n-butyl)ammonium iodide In methanol; water at -5℃; under 2585.7 Torr; for 18h;	100%

: 67-56-1
methanol

: 24915-95-5
Ethyl (R)-3-hydroxybutanoate

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
scandium tris(trifluoromethanesulfonate) at 64℃; for 10h;	98%
(EtO)3TiO(CH2)2OTi(OEt)3 autoclave, 1.) 160 deg C, 17 bar, 2 h; 2.) 115 deg C, 3.5 bar, 27 h;	82%

: 1694-31-1
tert-butyl acetoacetate

A: 3976-69-0
Methyl (R)-3-hydroxybutyrate

B: 110171-06-7
tert-butyl (R)-3-hydroxybutanoate

Conditions

Conditions	Yield
With hydrogenchloride; hydrogen; [RuCl2-((R)-binap)]*NEt3 In methanol at 40℃; under 2585.7 Torr; for 8h; Kinetics; effect of acid, other substrate;	A 3% B 97%
With hydrogenchloride; hydrogen; <(R)-(BINAP)RuCl2>2*NEt3 In methanol at 40℃; under 2585.7 Torr; for 8h;	A 3% B 97%

: 105-45-3
acetoacetic acid methyl ester

A: 53562-86-0
(S)-3-hydroxybutyric acid methyl ester

B: 3976-69-0
Methyl (R)-3-hydroxybutyrate

C: 29267-46-7
3,3-bismethoxybutyric acid methyl ester

Conditions

Conditions	Yield
With hydrogen; {RuI((R)-2,2'-bis(diphenylphospino)-1,1'-binaphthyl)(p-cymene)}I In methanol at 30℃; under 76000 Torr; for 35h; Product distribution; other: catalysts, solvents, time, pressure, temperatures;	A 97% B n/a C 3%

...Expand

: 67-56-1
methanol

: 201230-82-2
carbon monoxide

: 15448-47-2
(R)-propylene oxide

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With 3-HYDROXYPYRIDINE; dicobalt octacarbonyl In tetrahydrofuran at 65℃; under 31028.9 Torr; for 9h;	92%

...Expand

(S)-3-Hydroxy-4-((R)-toluene-4-sulfinyl)-butyric acid methyl ester: 142176-67-8
(S)-3-Hydroxy-4-((R)-toluene-4-sulfinyl)-butyric acid methyl ester

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With nickel	90%

: 67-56-1
methanol

PHB/PHV biopolymer: PHB/PHV biopolymer

A: 42558-50-9, 56009-31-5, 60793-22-8, 133098-13-2
methyl (3R)-3-hydroxypentanoate

B: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With sulfuric acid In 1,2-dichloro-ethane for 48h; Heating;	A 62% B 87%

...Expand

: 114607-86-2
Methyl (S)-4-(p-Chlorophenylthio)-3-hydroxybutanoate

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
nickel	80%

: 67-56-1
methanol

poly(3(R)-hydroxybutyric acid): poly(3(R)-hydroxybutyric acid)

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With sulfuric acid In dichloromethane for 48h; Heating;	78%

: (2R,3R)-3-Hydroxy-2-phenylsulfanyl-butyric acid methyl ester

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With nickel In ethanol for 0.5h; Ambient temperature;	75%

: 67-56-1
methanol

poly([R]-3-hydroxybutyrate): poly([R]-3-hydroxybutyrate)

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With sulfuric acid In 1,2-dichloro-ethane at 80℃; for 120h; Heating / reflux;	73%

poly[(R)-3-hydroxy butyric acid]: poly[(R)-3-hydroxy butyric acid]

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With sulfuric acid In methanol; 1,2-dichloro-ethane for 72h; depolymerization; Heating;	71%

: 166020-21-9
(R)-methyl 3-(dimethyl(phenyl)silyl)butanoate

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With peracetic acid; palladium diacetate; mercury(II) diacetate In acetic acid for 2h; Ambient temperature;	43%

: 186581-53-3, 908094-01-9
diazomethane

: 300-85-6, 625-71-8
3-Hydroxybutyric acid

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
In diethyl ether

: (S)-4-Benzenesulfonyl-3-hydroxy-butyric acid methyl ester

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With Raney Ni W-4 Yield given;

: 116761-24-1
(R)-3-(benzyloxy)butanoic acid methyl ester

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With hydrogen; palladium on activated charcoal In acetic acid Product distribution; Ambient temperature;

: 67-56-1
methanol

poly(R)-3-hydroxybutanoic acid (PHB): poly(R)-3-hydroxybutanoic acid (PHB)

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With sulfuric acid

: 67-56-1
methanol

poly-(R)-3-hydroxybuttersaeure: poly-(R)-3-hydroxybuttersaeure

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With sulfuric acid 1.) 1,2-dichloroethane, reflux, 2 h; 2.) reflux, 48 h; Yield given. Multistep reaction;

: 67-56-1
methanol

Biopol (73percent (R)-3-hydroxybutanoic acid - 27percent (R)-3-hydroxyvaleric acid copolymer): Biopol (73percent (R)-3-hydroxybutanoic acid - 27percent (R)-3-hydroxyvaleric acid copolymer)

A: 42558-50-9, 56009-31-5, 60793-22-8, 133098-13-2
methyl (3R)-3-hydroxypentanoate

B: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With sulfuric acid 1.) 1,2-dichloroethane, reflux, 1 h; 2.) 1,2-dichloroethane, reflux, 3 d; Yield given. Multistep reaction. Yields of byproduct given;

...Expand

: 67-56-1
methanol

poly<(R)-3-hydroxybutanoic acid>: poly<(R)-3-hydroxybutanoic acid>

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With sulfuric acid; toluene-4-sulfonic acid 1.) 1,2-dichloroethane, reflux, 34 h; 2.) 1,2-dichloroethane, reflux, 12 h; Yield given; Multistep reaction;

: 186581-53-3, 908094-01-9
diazomethane

: 200335-76-8
(+)-macrosphelide E

A: 3976-69-0
Methyl (R)-3-hydroxybutyrate

B: 63357-08-4
methyl (E,4R,5S)-4,5-dihydroxy-2-hexenoate

Conditions

Conditions	Yield
Stage #1: (+)-macrosphelide E With potassium carbonate In methanol at 20℃; Stage #2: diazomethane In diethyl ether at 20℃; for 2h; Further stages.;

...Expand

: 67-56-1
methanol

: 200335-76-8
(+)-macrosphelide E

A: 3976-69-0
Methyl (R)-3-hydroxybutyrate

B: 63357-08-4
methyl (E,4R,5S)-4,5-dihydroxy-2-hexenoate

Conditions

Conditions	Yield
With sulfuric acid at 20℃; Title compound not separated from byproducts.;

...Expand

: 1487-49-6
3-hydroxybutyric acid methyl ester

A: 53562-86-0
(S)-3-hydroxybutyric acid methyl ester

B: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With air; cells of Geotrichum candidum IFO5767 In water at 30℃; for 24h; Product distribution;
With pentyl cage-coated capillary column Resolution of racemate;
With homochiral metal-organic cage [Zn3(deprotonated [3+3] macrocyclic Schiff base of trans-1,2-diaminocyclohexane and 4-tert-butyl-2,6-diformylphenol)2] coated capillary column In dichloromethane at 112℃; Resolution of racemate; enantioselective reaction;

: 105-45-3
acetoacetic acid methyl ester

: 67-63-0
isopropyl alcohol

A: 3976-69-0
Methyl (R)-3-hydroxybutyrate

B: 3,3-diisopropoxy-butyric acid methyl ester

Conditions

Conditions	Yield
With hydrogen; (S)-Ru-BINAP at 60℃; under 30002.4 Torr; for 1h; Product distribution; Further Variations:; Reagents; Solvents;

...Expand

: 625-72-9
(R)-3-hydroxybutyric acid

: 18107-18-1
diazomethyl-trimethyl-silane

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 114607-75-9
Methyl 4-(4-Chlorophenylthio)-3-oxobutanoate

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: Candida guilliermondii 2: 80 percent / Raney nickel View Scheme

: (4S,5R)-5-Methyl-2-oxo-[1,3]dioxolane-4-carboxylic acid methyl ester

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 89 percent / Et3N / tetrahydrofuran / 1 h / 0 °C 2: 75 percent / Raney nickel / ethanol / 0.5 h / Ambient temperature View Scheme

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 126249-06-7, 122358-09-2
methyl 3(R)-<oxy>butanoate

Conditions

Conditions	Yield
With 2,6-dimethylpyridine for 3h; Ambient temperature;	100%
With 2,6-dimethylpyridine In dichloromethane at 0 - 20℃; for 3h; Inert atmosphere;	95%

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 18162-48-6
tert-butyldimethylsilyl chloride

: 104524-19-8
methyl (R)-(-)-3-(tert-butyldimethylsilyloxy)butyrate

Conditions

Conditions	Yield
With 1H-imidazole In N,N-dimethyl-formamide at 23℃; for 12h; Addition;	100%
With 1H-imidazole In dichloromethane at 0 - 20℃; for 18h; Inert atmosphere;	100%
With 1H-imidazole In dichloromethane at 0 - 20℃; for 18h; Inert atmosphere;	100%

: 20445-33-4, 39637-99-5
(R)-methoxytrifluoromethylphenylacetyl chloride

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: methyl (3R)-3-<(S)-(-)-α-methoxy-α-(trifluoromethyl)phenylacetyl>butyrate

Conditions

Conditions	Yield
With pyridine In tetrachloromethane for 12h; Ambient temperature;	100%

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 25197-75-5
(S)-chlorofluoroacetic acid

: Methyl (3R)-3-[(2S)-2-chloro-2-fluoroacetoxy]butanoate

Conditions

Conditions	Yield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; Esterification;	100%

: 1510836-92-6
{ONOMe,Cumyl}Y[N(SiHMe2)2](THF)(Et2O)

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: {ONOMe,Cumyl}Y((R)-OCH(CH3)CH2COOMe)

Conditions

Conditions	Yield
In benzene-d6 for 0.166667h; Inert atmosphere; Glovebox;	99%

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 100-46-9
benzylamine

: 146679-25-6
(R)-N-benzyl-3-hydroxybutanamide

Conditions

Conditions	Yield
With ammonium nitrate In neat (no solvent) at 20℃; for 12h; Green chemistry;	99%

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 109-92-2
ethyl vinyl ether

: 208459-11-4
methyl (1'RS,3R)-3-(1-ethoxyethoxy)butyrate

Conditions

Conditions	Yield
With trifluoroacetic acid for 12h; Ambient temperature;	98%
With trifluoroacetic acid 1) 0 deg C, 22 h, 2) r.t., 3 h;	94%
With pyridinium p-toluenesulfonate In dichloromethane at 20℃; for 24h;

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 98-59-9
p-toluenesulfonyl chloride

: 91366-12-0
methyl (R)-3-(p-toluenesulfonyloxy)butyrate

Conditions

Conditions	Yield
With pyridine at 0℃; for 24h;	98%
With pyridine; triethylamine In toluene at 0 - 20℃; Inert atmosphere;	84%
With pyridine Ambient temperature;	82.4%

: 3970-21-6
2-Methoxyethoxymethyl chloride

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 160482-01-9
(R)-3-(2-Methoxy-ethoxymethoxy)-butyric acid methyl ester

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine In dichloromethane Ambient temperature;	98%

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 107-30-2
chloromethyl methyl ether

: 99274-56-3
(R)-methyl 3-(methoxy)methoxybutyrate

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine	97%
With N-ethyl-N,N-diisopropylamine In dichloromethane at 25℃; for 42h;	95%
With N-ethyl-N,N-diisopropylamine In dichloromethane
With N-ethyl-N,N-diisopropylamine In dichloromethane for 42h; Ambient temperature;

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 58479-61-1
tert-butylchlorodiphenylsilane

: 178246-78-1
(R)-3-(tert-Butyldiphenylsilanyloxy)butyric acid methyl ester

Conditions

Conditions	Yield
Stage #1: Methyl (R)-3-hydroxybutyrate With 1H-imidazole In dichloromethane at 0℃; for 0.166667h; Stage #2: tert-butylchlorodiphenylsilane In dichloromethane at 25℃; for 4h; Further stages.;	97%
Stage #1: Methyl (R)-3-hydroxybutyrate With 1H-imidazole In dichloromethane at 0℃; for 0.166667h; silylation; Stage #2: tert-butylchlorodiphenylsilane In dichloromethane at 0 - 25℃; for 4h; silylation; Further stages.;	97%
With 1H-imidazole In dichloromethane at 20℃; for 4.5h;	91.2%

: 110-87-2
3,4-dihydro-2H-pyran

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 77234-51-6
methyl (R)-3-tetrahydropyranyloxybutanoate

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In dichloromethane at 0℃; for 2h; Etherification;	96%
With toluene-4-sulfonic acid In diethyl ether for 10h; Ambient temperature;	91%
With toluene-4-sulfonic acid In diethyl ether at 0 - 25℃;	65%

: 67373-56-2
chlorodimethyl(1,1,2-trimethylpropyl)silane

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 133260-92-1
(R)-3-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-butyric acid methyl ester

Conditions

Conditions	Yield
	96%

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 874-60-2
4-methyl-benzoyl chloride

: 4-Methyl-benzoic acid (R)-2-methoxycarbonyl-1-methyl-ethyl ester

Conditions

Conditions	Yield
With 4-vinylpyridine In dichloromethane at 20℃; for 6h;	96%

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 89238-99-3
O-(4-methoxybenzyl)-trichloroacetimidate

: 185030-60-8
(R)-methyl 3-((4-methoxybenzyl)oxy)butanoate

Conditions

Conditions	Yield
With camphor-10-sulfonic acid In dichloromethane at 20℃; for 36h; Etherification;	95%
With camphorsulfonic acid In dichloromethane at 20℃; Inert atmosphere;	94%
With camphor-10-sulfonic acid In dichloromethane at 20℃; Inert atmosphere;	93.7%

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 4637-24-5
N,N-dimethyl-formamide dimethyl acetal

: C8H15NO3

Conditions

Conditions	Yield
In 2-methyltetrahydrofuran at 90℃; for 3h; Solvent; Temperature; Large scale;	95%
In dichloromethane at 90℃; for 4h; Solvent; Temperature; Large scale;

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 625-72-9
(R)-3-hydroxybutyric acid

Conditions

Conditions	Yield
Stage #1: Methyl (R)-3-hydroxybutyrate With potassium hydroxide In water at 0 - 20℃; for 48h; Inert atmosphere; Stage #2: With hydrogenchloride In water pH=1; Inert atmosphere;	94%
With potassium hydroxide In water at 4℃; for 480h;	91%
Stage #1: Methyl (R)-3-hydroxybutyrate With potassium hydroxide; water at 0℃; for 25.5h; Stage #2: With hydrogenchloride; water at 5℃;	87%

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 62-53-3
aniline

A: 63430-94-4
methyl (R)-3-(phenylamino)butanoate

B: 142826-92-4
(S)-phenylamino-butyric acid methyl ester

Conditions

Conditions	Yield
Stage #1: Methyl (R)-3-hydroxybutyrate With trifluoromethanesulfonic acid anhydride; diisopropylamine In dichloromethane at -78℃; for 1h; Stage #2: aniline at -78 - -40℃; for 16h;	A n/a B 94%

...Expand

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 100-39-0
benzyl bromide

: 116761-24-1
(R)-3-(benzyloxy)butanoic acid methyl ester

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; sodium hydride In tetrahydrofuran at 20℃; Inert atmosphere;	94%

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 89238-99-3
O-(4-methoxybenzyl)-trichloroacetimidate

: (R)-methyl 3-((4-methoxybenzyl)oxy)butanoate

Conditions

Conditions	Yield
With camphor-10-sulfonic acid In dichloromethane at 0 - 20℃;	94%

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 13613-65-5
sodium (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With water; sodium hydroxide In methanol at 15℃; for 12h; Inert atmosphere;	93.69%
With sodium hydroxide In water at 10 - 30℃; for 6h;	85%

: 75-77-4
chloro-trimethyl-silane

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 104524-19-8
methyl (R)-(-)-3-(tert-butyldimethylsilyloxy)butyrate

Conditions

Conditions	Yield
With 1H-imidazole In dichloromethane at 20℃; for 23h;	92%

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: calcium (R)-3-hydroxybutyrate

Conditions

Conditions	Yield
With calcium hydroxide In water at 8℃; for 6h;	91.1%

Methyl (R)-(-)-3-hydroxybutyrate Chemical Properties

Molecular Structure of Methyl (R)-(-)-3-hydroxybutyrate (CAS NO.3976-69-0):

IUPAC Name: Methyl (3R)-3-hydroxybutanoate
Molecular Formula: C₅H₁₀O₃
Molecular Weight: 118.13
EINECS: 223-610-0
XLogP3-AA: -0.2
H-Bond Donor: 1
H-Bond Acceptor: 3
Storage temp.: 0-6 °C
Index of Refraction: 1.42
Molar Refractivity: 28.48 cm³
Molar Volume: 112.4 cm³
Surface Tension: 33.2 dyne/cm
Density: 1.05 g/cm³
Flash Point: 71.7 °C
Enthalpy of Vaporization: 46.4 kJ/mol
Boiling Point: 161.9 °C at 760 mmHg
Vapour Pressure: 0.768 mmHg at 25 °C
Appearance: clear colorless liquid
Canonical SMILES: CC(CC(=O)OC)O
Isomeric SMILES: C[C@H](CC(=O)OC)O
InChI: InChI=1S/C5H10O3/c1-4(6)3-5(7)8-2/h4,6H,3H2,1-2H3/t4-/m1/s1
InChIKey: LDLDJEAVRNAEBW-SCSAIBSYSA-N
Product Categories: Alcohols, Hydroxy Esters and Derivatives; Chiral Compounds; Building Blocks for Liquid Crystals; Chiral Building Blocks; Chiral Compounds (Building Blocks for Liquid Crystals); Functional Materials; Simple Alcohols (Chiral); Synthetic Organic Chemistry; Chiral Building Blocks; Esters; Organic Building Blocks; Chiral Alcohols

Methyl (R)-(-)-3-hydroxybutyrate Safety Profile

Safety Information of Methyl (R)-(-)-3-hydroxybutyrate (CAS NO.3976-69-0):
Hazard Codes: Irritant Xi
Risk Statements: 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37-24/25-23
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37:Wear suitable protective clothing and gloves.
S24/25:Avoid contact with skin and eyes.
S23:Do not breathe vapour.
WGK Germany: 3

Methyl (R)-(-)-3-hydroxybutyrate Specification

Methyl (R)-(-)-3-hydroxybutyrate (CAS NO.3976-69-0), its Synonyms are (R)-(-)-3-Hydroxybutyric acid methyl ester ; Methyl (3R)-3-hydroxybutanoate ; Methyl R-3-hydroxybutanoate ; Methyl 3-hydroxybutanoate .

Product Name

Methyl (R)-(-)-3-hydroxybutyrate

Synthetic route

Methyl (R)-(-)-3-hydroxybutyrate Chemical Properties

Methyl (R)-(-)-3-hydroxybutyrate Safety Profile

Methyl (R)-(-)-3-hydroxybutyrate Specification

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