Methyl decanoate supplier | CasNO.110-42-9

Name
METHYL DECANOATE
EINECS 203-766-6
CAS No. 110-42-9
Article Data106
CAS DataBase
Density 0.872 g/cm³
Solubility Soluble in alcohol. Insoluble in water.
Melting Point -14--11 °C (lit.)
Formula C₁₁H₂₂O₂
Boiling Point 224 °C at 760 mmHg
Molecular Weight 186.294
Flash Point 94.4 °C
Transport Information
Appearance Clear colorless liquid
Safety 24/25
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms C 1098;Capric acid methyl ester;Estasol MD 10;Metholene 2095;Methyl caprate;Methylcaprinate;Methyl n-caprate;Methyl n-decanoate;NSC 3713;Pastell M 10;Uniphat A 30;
PSA 26.30000
LogP 3.30010

Synthetic route

: 67-56-1
methanol

: 334-48-5
1-decanoic acid

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With tetrachloromethane at 20℃; for 12h; UV-irradiation;	99%
With Mesoscopically Assembled SulfatedZirconia Nanoparticles at 49.84℃; for 8h; Catalytic behavior; Reagent/catalyst; Temperature;	97%
With sulfuric acid; acetonitrile at 80 - 85℃; for 16 - 18h;	97%

: 4353-06-4
2-n-nonyl-1,3-dioxolane

: 67-56-1
methanol

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With hydrogenchloride; dihydrogen peroxide	98%

: 109-87-5
Dimethoxymethane

: 112-13-0
n-decanoyl chloride

A: 110-42-9
Methyl decanoate

B: 107-30-2
chloromethyl methyl ether

Conditions

Conditions	Yield
sulfuric acid at 55 - 60℃; for 2h; exchange reaction;	A n/a B 97%

...Expand

: 1634-04-4
tert-butyl methyl ether

: 334-48-5
1-decanoic acid

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With sulfuric acid Reflux; regioselective reaction;	97%

: 67-56-1
methanol

: 7779-41-1
1,1-dimethoxy decane

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With hydrogenchloride; dihydrogen peroxide 1.) <20 deg C, 30 min; 2.) 40 deg C, 3 h;	96%

: 104383-13-3
1-tert-Butylperoxy-1-methoxy-decane

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
In methanol at 60℃;	94%

: Decanoic acid, tert-butyldimethylsilyl ester

: 67-56-1
methanol

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
Stage #1: Decanoic acid, tert-butyldimethylsilyl ester; methanol; carbon tetrabromide at 20℃; for 0.5h; Irradiation; Stage #2: at 20℃; for 3h;	92%

: 67-56-1
methanol

: 112-30-1
1-Decanol

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With [bis(acetoxy)iodo]benzene; iodine at 20℃; for 4h;	91%
With pyridine; tert-butylhypochlorite In dichloromethane for 1h;	99 % Chromat.
With (2-hydroxyethyl)(methyl)amine; bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; caesium carbonate In acetone at 25℃; for 24h; Inert atmosphere;	82 %Chromat.

: 67-56-1
methanol

: 112-31-2
caprinaldehyde

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With hydrogenchloride; dihydrogen peroxide	90%
With potassium bromide for 1.8h; Ambient temperature; anode, platinum plate; cathode, carbon rod;	85%
With ammonium cerium (IV) nitrate; lithium bromide In neat liquid at 35 - 40℃; for 3.5h;	74%

: 67-56-1
methanol

: 621-71-6
capric acid triglyceride

A: 110-42-9
Methyl decanoate

B: 56-81-5
glycerol

Conditions

Conditions	Yield
bis(trimethylsilyl)sulphate In dichloromethane; 1,2-dichloro-ethane for 8.5h; Heating;	A 89% B 82%

...Expand

: 866096-42-6
C19H40O2Si

: 67-56-1
methanol

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
Stage #1: C19H40O2Si; methanol; carbon tetrabromide at 20℃; for 0.5h; Irradiation; Stage #2: at 20℃; for 8h;	89%

: 67-56-1
methanol

: 112-31-2
caprinaldehyde

A: 334-48-5
1-decanoic acid

B: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With dipyridinium dichromate In N,N-dimethyl-formamide for 20h; Ambient temperature;	A n/a B 87%

...Expand

: 67-56-1
methanol

: 143006-23-9
decanoyltriphenylsilane

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With tetraethylammonium tosylate Ambient temperature; electrolysis;	87%

: 67-56-1
methanol

: 110-38-3
decanoic acid ethyl ester

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With (N3/phenyl-/(diethylamino)methyl-triazolyl)-modified DMOF [DMOF= Zn2(2-amino-terephthalate)2(dabco)] at 130℃; for 20h;	84%
With di(n-butyl)tin oxide In methanol for 12h; Heating;	80%
With lanthanum complex grafted upon hydrotalcite for 8h; pH=10; Reflux;	56%
With nitrogen-functionalized metal-organic framework catalyst at 180℃; for 24h; Inert atmosphere;

: 7289-52-3
1-methoxydecane

A: 110-42-9
Methyl decanoate

B: 5451-52-5
n-decyl methanoate

Conditions

Conditions	Yield
With sodium periodate; ruthenium trichloride In tetrachloromethane; water; acetonitrile for 8h; Ambient temperature;	A 83% B n/a

: C26H38O2Si

: 67-56-1
methanol

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
Stage #1: C26H38O2Si; methanol; carbon tetrabromide at 20℃; for 0.5h; Irradiation; Stage #2: at 20℃; for 9h;	81%

: 67-56-1
methanol

: 142981-56-4
1-(Methyl-diphenyl-silanyl)-decan-1-one

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With tetraethylammonium tosylate Ambient temperature; electrolysis;	77%

: 67-56-1
methanol

: 125828-13-9
decanoyldimethyl(phenyl)silane

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With tetraethylammonium tosylate Ambient temperature; electrolysis;	76%

: 7779-41-1
1,1-dimethoxy decane

A: 18207-21-1
2-bromo-1,1-dimethoxydecane

B: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With methanol; tetrabutylammomium bromide; bromine In dichloromethane for 0.5h; Yields of byproduct given;	A 69% B n/a
With methanol; tetrabutylammomium bromide; bromine In dichloromethane for 0.5h; Yield given;	A 69% B n/a

: 14202-22-3
C22H38O4

A: 110-42-9
Methyl decanoate

B: 1472-93-1
dimethyl 1,18-octadecanedioate

C: 108861-12-7
(R)-6-hexyl-tetrahydro-2H-pyran-2-one

Conditions

Conditions	Yield
Stage #1: C22H38O4 Stage #2: With hydrogen at 75℃; under 7500.75 Torr; for 14h; regioselective reaction;	A n/a B n/a C 66%

...Expand

: 79-20-9
acetic acid methyl ester

: 143-08-8
nonyl alcohol

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With C15H17ClIrNOP; potassium tert-butylate In neat (no solvent) at 60℃; for 12h; Schlenk technique; Inert atmosphere; Glovebox;	59%

: 67-56-1
methanol

: 30673-36-0
n-butyl decanoate

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With lanthanum complex grafted upon hydrotalcite for 8h; pH=10; Catalytic behavior; Time; Reagent/catalyst; Concentration; pH-value; Reflux;	55%

: 25601-41-6
methyl 9-decenoate

: 201230-82-2
carbon monoxide

A: 110-42-9
Methyl decanoate

B: 1931-65-3
methyl 11-oxoundecanoate

C: 171076-49-6
methyl 9-methyl-10-oxodecanoate

D: methyl 8-formyldecanoate

Conditions

Conditions	Yield
With dicarbonylacetylacetonato rhodium (I); hydrogen; triphenylphosphine at 60℃; under 30003 Torr; for 12h; Temperature; Pressure; Reagent/catalyst;	A 6% B 55% C 28% D 11%

...Expand

: 67-56-1
methanol

: 112-31-2
caprinaldehyde

A: 110-42-9
Methyl decanoate

B: 7357-56-4
methyl ester of α-bromodecanoic acid

Conditions

Conditions	Yield
Stage #1: caprinaldehyde With ammonium cerium (IV) nitrate; lithium bromide In neat liquid Stage #2: methanol In neat liquid at 35 - 40℃; for 3.5h;	A 29 %Chromat. B 53%

...Expand

: 142981-58-6
decanoylphenyldimethylsilane tosylhydrazone

A: 1975-78-6
n-decanenitrile

B: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With tetrabutylammonium tetrafluoroborate In methanol; dichloromethane electrolysis;	A 45% B 11%

: 67-56-1
methanol

: 2082-76-0
capric anhydride

: 27126-76-7
[hydroxy(tosyloxy)iodo]benzene

A: 591-50-4
iodobenzene

B: 110-42-9
Methyl decanoate

C: methyl 2-tosyloxydecanoate

Conditions

Conditions	Yield
Stage #1: capric anhydride; [hydroxy(tosyloxy)iodo]benzene at 100℃; for 0.333333h; Stage #2: methanol With toluene-4-sulfonic acid for 4h; Heating;	A n/a B n/a C 41%

...Expand

: 67-56-1
methanol

: δ-furfurylidenelevulinic acid methyl ester

A: 334-48-5
1-decanoic acid

B: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With palladium 10% on activated carbon; W(OTf)6; hydrogen at 180℃; under 15001.5 Torr; for 8h; Autoclave;	A 2.7% B 15.3%

...Expand

: 627-91-8
adipic acid monomethyl ester

: 142-62-1
hexanoic acid

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
With methanol; sodium Electrolysis.an Platin-Elektroden;

: 186581-53-3, 908094-01-9
diazomethane

: 334-48-5
1-decanoic acid

: 110-42-9
Methyl decanoate

Conditions

Conditions	Yield
for 0.5h;

: 186581-53-3, 908094-01-9
diazomethane

: 2379-98-8
methyl 8-hydroxyoctadecanoate

A: 110-42-9
Methyl decanoate

B: 1731-86-8
methyl undecanoate

C: 1732-08-7
dimethyl 1,7-heptanedioate

D: 1732-09-8
dimethyl subarate

Conditions

Conditions	Yield
With potassium permanganate In acetic acid Product distribution; oxidative degradation and methylation;

...Expand

: 110-42-9
Methyl decanoate

: 112-30-1
1-Decanol

Conditions

Conditions	Yield
With hydrogen In hexane at 200℃; under 15001.5 Torr; for 8h; Reagent/catalyst;	99.8%
Stage #1: Methyl decanoate With diethylzinc; lithium chloride In tetrahydrofuran; hexane at 20℃; for 6h; Inert atmosphere; Stage #2: With sodium hydroxide In tetrahydrofuran; hexane; water at 20℃; for 8h; Inert atmosphere; chemoselective reaction;	98%
With samarium diiodide; water; triethylamine In tetrahydrofuran at 20℃; for 15h; Inert atmosphere;	95%

: 112-50-5
monoethyl ether of triethylene glycol

: 110-42-9
Methyl decanoate

: 112-30-1
1-Decanol

Conditions

Conditions	Yield
With sodium borohydrid In 5,5-dimethyl-1,3-cyclohexadiene	99%

: 110-42-9
Methyl decanoate

A: 67-56-1
methanol

B: 112-30-1
1-Decanol

Conditions

Conditions	Yield
With C66H102N4OP2Ru; hydrogen In toluene at 105℃; under 22502.3 Torr; for 20h; Inert atmosphere; Glovebox;	A n/a B 99%
With C30H37ClN4ORu; hydrogen; sodium t-butanolate In toluene at 105℃; under 22502.3 Torr; for 20h; Glovebox; Sealed tube; Overall yield = >99 %;

: 110-42-9
Methyl decanoate

: 98-86-2
acetophenone

: 87202-38-8
decanoyl benzoyl methane

Conditions

Conditions	Yield
With sodium methylate In 5,5-dimethyl-1,3-cyclohexadiene for 1.25h; Claisen Condensation; Inert atmosphere; Reflux; Microwave irradiation;	98.3%

: 110-42-9
Methyl decanoate

: 925-90-6
ethylmagnesium bromide

: 127460-69-9
1-nonyl-1-cyclopropanol

Conditions

Conditions	Yield
With titanium(IV) isopropylate In diethyl ether at -78 - 0℃; for 0.5h;	98%
With titanium(IV) isopropylate In diethyl ether at 18 - 20℃;	97%
titanium(IV) isopropylate In diethyl ether at 18 - 20℃;	95%

: 112-34-5
Diethylene glycol monobutyl ether

: 110-42-9
Methyl decanoate

: 112-30-1
1-Decanol

Conditions

Conditions	Yield
With sodium borohydrid In 5,5-dimethyl-1,3-cyclohexadiene	98%

: 110-42-9
Methyl decanoate

: 42006-99-5
n-[1,1-2H2]decanol

Conditions

Conditions	Yield
With lithium aluminium deuteride In tetrahydrofuran at -78℃; Reflux;	98%

: 111-90-0
ethoxyethoxyethanol

: 110-42-9
Methyl decanoate

: 112-30-1
1-Decanol

Conditions

Conditions	Yield
With sodium borohydrid In 5,5-dimethyl-1,3-cyclohexadiene	97%

: 110-42-9
Methyl decanoate

: 100-51-6
benzyl alcohol

: 42175-41-7
benzyl decanoate

Conditions

Conditions	Yield
With 1,3-bis(3,5-bis(trifluoro-ethyl)phenyl)thiourea; 4-pyrrolidin-1-ylpyridine In n-heptane for 24h; Reflux;	96%

: 110-42-9
Methyl decanoate

: 456-56-4
phenyl trifluoromethylsulfide

: 26902-70-5
1,1,1-trifluoro-2-undecanone

Conditions

Conditions	Yield
With Triethylgermyl-natrium In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide at -60℃; for 1.5h;	95%

: 617-86-7
triethylsilane

: 110-42-9
Methyl decanoate

: C17H38O2Si

Conditions

Conditions	Yield
With decacarbonyldirhenium(0) In toluene at 30℃; for 9h; Inert atmosphere; UV-irradiation; Schlenk technique;	93%

: 110-42-9
Methyl decanoate

: 123820-43-9, 123820-44-0, 84393-12-4
[(1-methoxy-2-methyl-1-butenyl)oxy]trimethylsilane

A: methyl 2-ethyl-2-methyl-3-oxododecanoate

B: methyl 2-ethyl-2-methyl-3-(trimethylsiloxy)dodec-3-enoate

Conditions

Conditions	Yield
With sodium hydroxide In N,N-dimethyl-formamide at 20 - 25℃; for 1h; Claisen condensation; Inert atmosphere;	A 8% B 90%
With sodium hydroxide In N,N-dimethyl-formamide at 15 - 20℃; for 1h; crossed Claisen condensation;

...Expand

: 110-80-5
2-ethoxy-ethanol

: 110-42-9
Methyl decanoate

: 112-30-1
1-Decanol

Conditions

Conditions	Yield
With sodium borohydrid In 5,5-dimethyl-1,3-cyclohexadiene	90%

: 6156-25-8
tetrathioorthocarbonic acid tetramethyl ester

: 110-42-9
Methyl decanoate

: 1,1-Bis-methylsulfanyl-undecan-2-one

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane 1.) -95 deg C, 2 h, 2.) -78 deg C, 30 min;	89%

: 940867-32-3
2-(tert-butyldimethylsilyloxy)-1-methoxy-1-trimethylsilyloxy-1-propene

: 110-42-9
Methyl decanoate

: methyl 2-hydroxy-2-methyl-3-oxododecanoate

Conditions

Conditions	Yield
Stage #1: 2-(tert-butyldimethylsilyloxy)-1-methoxy-1-trimethylsilyloxy-1-propene; Methyl decanoate With sodium hydroxide In 1-methyl-pyrrolidin-2-one at 20 - 25℃; for 3h; Claisen condensation; Inert atmosphere; Stage #2: With tetrabutyl ammonium fluoride In tetrahydrofuran at 0 - 5℃; for 1h; Inert atmosphere;	89%

: 110-42-9
Methyl decanoate

: 3839-31-4
dimethyl(phenyl)silyllithium

: 155397-14-1
1,1-bisdecan-1-ol

Conditions

Conditions	Yield
In tetrahydrofuran at -78℃; for 3h;	88%

: 5418-86-0
tris(methylthio)methane

: 110-42-9
Methyl decanoate

A: 6156-25-8
tetrathioorthocarbonic acid tetramethyl ester

B: 1,1-Bis-methylsulfanyl-undecan-2-one

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane 1.) -95 deg C, 2 h, 2.) -78 deg C, 30 min;	A n/a B 88%

...Expand

: 13351-73-0
1-methyl-1H-benzo[d][1,2,3]triazole

: 110-42-9
Methyl decanoate

: 189343-46-2
1-Benzotriazol-1-yl-undecan-2-one

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 12h;	88%

: 110-42-9
Methyl decanoate

: 90965-06-3
dimethyl 1-(1-diazo-2-oxopropyl)phosphonate

: 2243-98-3
1-undecyne

Conditions

Conditions	Yield
Stage #1: Methyl decanoate With diisobutylaluminium hydride In n-heptane; dichloromethane at -78℃; Stage #2: dimethyl 1-(1-diazo-2-oxopropyl)phosphonate With potassium carbonate In methanol; n-heptane; dichloromethane at 20℃; Further stages.;	88%

Methyl decanoate Chemical Properties

Product Name: METHYL DECANOATE
The MF of METHYL DECANOATE(110-42-9) is C₁₁H₂₂O₂.

The MW of METHYL DECANOATE(110-42-9) is 186.29.
Synonyms: METHYL CAPRATE;METHYL CAPRINATE;METHYL N-CAPRATE;METHYL N-DECANOATE;DECANOIC ACID METHYL ESTER;C10:0 METHYL ESTER;METHYL DECANOATE
Product Categories: Analytical Chemistry;Fatty Acid Methyl Esters (GC Standard);Standard Materials for GC
Mol File: 110-42-9.mol
EINECS: 203-766-6
Surface Tension: 28.7 dyne/cm
Density: 0.872 g/ml
Flash Point: 94.4 °C
Enthalpy of Vaporization: 46.05 kJ/mol
Boiling Point: 224 °C at 760 mmHg
Vapour Pressure: 0.0934 mmHg at 25°C
BRN: 1759170
CAS DataBase Reference: 110-42-9(CAS DataBase Reference)
NIST Chemistry Reference: 110-42-9(NIST)
EPA Substance Registry System: 110-42-9(EPA Substance)

Methyl decanoate Toxicity Data With Reference

ivn-mus LDLo:48 mg/kg

RESJAS Journal of the Reticuloendothelial Society. (1964) 3 (1966),250.

Methyl decanoate Consensus Reports

Reported in EPA TSCA Inventory.

Methyl decanoate Safety Profile

Poison by intravenous route. When heated to decomposition it emits acrid smoke and irritating vapors.
Safety information of METHYL DECANOATE(110-42-9):
WGK Germany: 1
RTECS: HD9830000
Hazardous Substances Data: 110-42-9(Hazardous Substances Data)

Product Name

METHYL DECANOATE

Synthetic route

Methyl decanoate Chemical Properties

Methyl decanoate Toxicity Data With Reference

Methyl decanoate Consensus Reports

Methyl decanoate Safety Profile

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