N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE supplier

Name
N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine
EINECS 212-344-0
CAS No. 793-24-8
Article Data19
CAS DataBase
Density 1.039 g/cm³
Solubility <0.1 g/100 mL at 17 °C in water
Melting Point 45-46 °C
Formula C₁₈H₂₄N₂
Boiling Point 412.3 °C at 760 mmHg
Molecular Weight 268.402
Flash Point 245.8 °C
Transport Information
Appearance Purple flakes
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms 1,4-Benzenediamine,N-(1,3-dimethylbutyl)-N'-phenyl- (9CI);p-Phenylenediamine,N-(1,3-dimethylbutyl)-N'-phenyl- (7CI,8CI);4-(1,3-Dimethylbutylamino)diphenylamine;6PPD;Antage 6C;Antozite 67;CD 13;CI;DBDA;DMBPD;Diafen FDMB;Flexzone 7F;Flexzone 7P;Forte 6C;N-(1,3-Dimethylbutyl)-N'-phenyl-1,4-benzenediamine;N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine;N-Phenyl-N'-(1,3-dimethylbutyl)-1,4-phenylenediamine;Nocrac 6C;Ozonone 6C;Permanax 120;Santoflex 13F;UOP 562;UOP 588;Vulkanox 4020;Vulkanox 4020LG;Wingstay 300;
PSA 24.06000
LogP 5.42270

Synthetic route

: 108-10-1
4-methyl-2-pentanone

: 101-54-2
N-phenylphenylene-1,4-diamine

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
With hydrogen at 99.84℃; under 18751.9 Torr; for 4h; Catalytic behavior; Reagent/catalyst; Time; Autoclave;	100%
With hydrogen; pyrographite at 20 - 150℃; under 22052.2 Torr; for 0.1h; Autoclave;	99.4%
With platinum on activated charcoal; isopropyl alcohol at 50 - 150℃; under 36775.4 Torr; Hydrogenation;

: 63302-40-9
C18H22N2

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
With palladium on activated charcoal; hydrogen In 5,5-dimethyl-1,3-cyclohexadiene at 100℃; under 7500.75 Torr; Solvent; Temperature;	92.6%

: 156-10-5
p-nitrosodiphenylamine

: 108-10-1
4-methyl-2-pentanone

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
With platinum on activated charcoal; isopropyl alcohol at 50 - 150℃; under 25742.8 Torr; Hydrogenation;

: 836-30-6
4-ntrophenyl(phenyl)amine

: 108-10-1
4-methyl-2-pentanone

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
With platinum on activated charcoal; isopropyl alcohol at 50 - 150℃; under 25742.8 Torr; Hydrogenation;

: N-[1,3-Dimethyl-but-(E)-ylidene]-N'-phenyl-benzene-1,4-diamine

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
With formic acid; palladium on activated charcoal at 85℃; Yield given;

: 836-30-6
4-ntrophenyl(phenyl)amine

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 5percent Pd/C 2: 5percent palladium-on-carbon / 85 °C 3: HCOOH / 5percent Pd/C / 85 °C View Scheme
Multi-step reaction with 3 steps 1: formic acid / 5percent Pd/C / 85 °C 2: 5percent palladium-on-carbon / 85 °C 3: HCOOH / 5percent Pd/C / 85 °C View Scheme

: 108-10-1
4-methyl-2-pentanone

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 5percent palladium-on-carbon / 85 °C 2: HCOOH / 5percent Pd/C / 85 °C View Scheme

: 101-54-2
N-phenylphenylene-1,4-diamine

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 5percent palladium-on-carbon / 85 °C 2: HCOOH / 5percent Pd/C / 85 °C View Scheme

: 15761-50-9, 34017-11-3, 54548-48-0, 108-09-8
2-amino-4-methylpentane

: 2406-04-4
4-(phenylimino)cyclohexa-2,5-dienone

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
In methanol

: 108-10-1
4-methyl-2-pentanone

: 101-54-2
N-phenylphenylene-1,4-diamine

A: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

B: 63302-40-9
C18H22N2

Conditions

Conditions	Yield
With palladium on activated charcoal; hydrogen at 200℃; under 30003 Torr; Reagent/catalyst;
With hydrogen at 160℃; under 22502.3 Torr; for 4h; Autoclave;

...Expand

: 108-10-1
4-methyl-2-pentanone

: 101-54-2
N-phenylphenylene-1,4-diamine

A: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

B: 62-53-3
aniline

Conditions

Conditions	Yield
With 10% Pd/C; hydrogen at 160℃; under 22502.3 Torr; for 4h; Autoclave;

...Expand

: 141-79-7
4-methyl-pent-3-en-2-one

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: hydrogen 2: pyrographite; ; hydrogen / 0.1 h / 20 - 150 °C / 22052.2 Torr / Autoclave View Scheme

: 71-43-2
benzene

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: sulfuric acid; nitric acid / chloroform; benzene / 5 h / 50 °C / Industrial scale 2: tetramethyl ammoniumhydroxide; platinum on carbon; hydrogen / water / 80 °C / 11251.1 Torr 3: pyrographite; ; hydrogen / 0.1 h / 20 - 150 °C / 22052.2 Torr / Autoclave View Scheme
Multi-step reaction with 4 steps 1: sulfuric acid; nitric acid / chloroform; benzene / 5 h / 50 °C / Industrial scale 2: hydrogen / 200 °C / Industrial scale 3: tetramethyl ammoniumhydroxide; platinum on carbon; hydrogen / water / 80 °C / 11251.1 Torr 4: pyrographite; ; hydrogen / 0.1 h / 20 - 150 °C / 22052.2 Torr / Autoclave View Scheme

: 108-95-2
phenol

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: ammonia / 450 °C / 760.05 Torr / Industrial scale 2: tetramethyl ammoniumhydroxide; platinum on carbon; hydrogen / water / 80 °C / 11251.1 Torr 3: pyrographite; ; hydrogen / 0.1 h / 20 - 150 °C / 22052.2 Torr / Autoclave View Scheme

: 98-95-3
nitrobenzene

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: hydrogen / 200 °C / Industrial scale 2: tetramethyl ammoniumhydroxide; platinum on carbon; hydrogen / water / 80 °C / 11251.1 Torr 3: pyrographite; ; hydrogen / 0.1 h / 20 - 150 °C / 22052.2 Torr / Autoclave View Scheme
Multi-step reaction with 3 steps 1: tetramethyl ammoniumhydroxide / water / 2.1 h / 75 °C / 55 Torr / Dean-Stark 2: hydrogen; 5%-palladium/activated carbon / 0.5 h / 80 °C / 11251.1 Torr / Autoclave 3: 3 % platinum on carbon; hydrogen / 0.5 h / 155 °C / 26252.6 Torr / Autoclave View Scheme

: 62-53-3
aniline

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: tetramethyl ammoniumhydroxide / water / 2.1 h / 75 °C / 55 Torr / Dean-Stark 2: hydrogen; 5%-palladium/activated carbon / 0.5 h / 80 °C / 11251.1 Torr / Autoclave 3: 3 % platinum on carbon; hydrogen / 0.5 h / 155 °C / 26252.6 Torr / Autoclave View Scheme

: 79-37-8
oxalyl dichloride

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

: N,N'-bis(4-anilinophenyl)-N,N'-bis(4-methylpentan-2-yl)oxamide

Conditions

Conditions	Yield
With pyridine In tetrahydrofuran at 20℃; for 48h; Cooling with ice;	86%

: 870-23-5
prop-2-ene-1-thiol

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

: 3-(allylsulfanyl)-N1-(4-methyl-2-pentyl)-N4-phenyl-1,4-benzenediamine

Conditions

Conditions	Yield
Stage #1: N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine With magnesium sulfate; silver(l) oxide In toluene at 25℃; for 15h; Stage #2: prop-2-ene-1-thiol In ethanol at 25℃;	65%

: 74-85-1
ethene

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

A: 944727-84-8
C22H32N2

B: C24H36N2

C: 944727-85-9
C24H36N2

Conditions

Conditions	Yield
diethylaluminium chloride In hexane for 12 - 16h; Product distribution / selectivity;	A 47.2% B n/a C n/a

...Expand

: 124-04-9
Adipic acid

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

: N,N'-bis(4-anilinophenyl)-N,N'-bis(4-methylpentan-2-yl)adipamide

Conditions

Conditions	Yield
Stage #1: Adipic acid With thionyl chloride; N,N-dimethyl-formamide In tetrahydrofuran; chloroform for 8h; Reflux; Stage #2: N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine With pyridine In tetrahydrofuran at 20℃; Cooling with ice;	39%

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

: 2-methyl-N4-(4-methyl-2-pentyl)-N7-phenyl-2,3-dihydro-1-benzothiophene-4,7-diamine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1.1: Ag2O; MgSO4 / toluene / 15 h / 25 °C 1.2: 65 percent / ethanol / 25 °C 2.1: 75 percent / 150 - 155 °C View Scheme

: 463-71-8
thiophosgene

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

: 584-08-7
potassium carbonate

: 118745-60-1
N-(4-anilinophenyl)-N-(1,3-dimethyl-butyl)-thiocarbamate-O-methyl ester

Conditions

Conditions	Yield
In methanol; chloroform

...Expand

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

: 74-88-4
methyl iodide

: 118745-59-8
N-(4-anilinophenyl)-N-(1,3-dimethyl-butyl)-dithiocarbamate methyl ester

Conditions

Conditions	Yield
With carbon disulfide; sodium hydroxide In tetrahydrofuran

: 872-05-9
1-Decene

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

: N'-phenyl-N-2-isohexyl-[2-(2-isodecyl)-p-phenylene]diamine

Conditions

Conditions	Yield
With tetrabutylammomium bromide; aluminum (III) chloride at 160 - 170℃; for 27h; Friedel Crafts Alkylation;

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

: 20170-32-5
4-hydroxy-3,5-di-tert-butylphenylpropionic acid

: 3-(3,5-di-tert-butyl-4-hydroxy-phenyl)-N-(1,3-dimethyl-butyl)-N-(4-phenylamino-phenyl)propionamide

Conditions

Conditions	Yield
With boric acid In toluene for 15h; Dean-Stark; Inert atmosphere; Reflux;

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

: 6386-38-5
methyl 3-(4-hydroxy-3,5-di-tert-butyl)phenylpropanoate

: 3-(3,5-di-tert-butyl-4-hydroxy-phenyl)-N-(1,3-dimethyl-butyl)-N-(4-phenylamino-phenyl)propionamide

Conditions

Conditions	Yield
With boric acid In toluene for 15h; Dean-Stark; Inert atmosphere; Reflux; Molecular sieve;

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 36294-23-2
4-(3-hydroxypropyl)-2,6-di-tert-butylphenol

: 793-24-8
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine

: 4-(3-{4,6-bis-[(1,3-dimethyl-butyl)-(4-phenylamino-phenyl)amino]-[1,3,5]triazin-2-yloxy}propyl)-2,6-di-tert-butyl-phenol

Conditions

Conditions	Yield
Stage #1: 1,3,5-trichloro-2,4,6-triazine; 4-(3-hydroxypropyl)-2,6-di-tert-butylphenol With triethylamine In tetrahydrofuran at 0℃; for 4h; Inert atmosphere; Stage #2: N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine In tetrahydrofuran at 65℃; for 15h; Inert atmosphere;

...Expand

N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE Chemical Properties

IUPAC Name: 1-N-(4-methylpentan-2-yl)-4-N-Phenylbenzene-1,4-diamine
Synonyms:1,4-Benzenediamine, N~1~-(1,3-dimethylbutyl)-N~4~-phenyl- ; 1,4-Benzenediamine, N~1~-(1,3-dimethylbutyl)-N~4~-phenyl- ; N-(1,3-dimethylbutyl)-N'-Phenylbenzene-1,4-diamine ; N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine ; N-(4-Methyl-2-pentanyl)-N'-phenyl-1,4-benzenediamine
Product Categories: Industrial/Fine Chemicals;Antidegradants
Molecular Structure :
Molecular Formula: C₁₈H₂₄N₂
Molecular Weight : 268.40
CAS NO: 793-24-8
EINECS: 212-344-0
Mol File: 793-24-8.mol
Melting point: 45-46 ºC
Boiling point: 260 ºC
Flash point: 204 ºC
Density: 1.039 g/cm3
Appearance:Purple flakes
Index of Refraction: 1.599
Surface Tension: 40.9 dyne/cm
Enthalpy of Vaporization: 66.49 kJ/mol
Vapour Pressure: 5.22E-07 mmHg at 25°C
Water solubility <0.1 g/100 mL at 17 ºC
Appearance: N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine (CAS NO. 793-24-8) is gray-black solid

N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE Uses

1.N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine (CAS NO. 793-24-8) is used for anti-ozone agents and antioxidants for natural rubber and synthetic rubber.
2.N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine (CAS NO. 793-24-8) is used for fine effectiveness on the protection of ozone and flex fatigue cracking .

N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE Production

Using the 4 - amino-2-aniline and methyl isobutyl ketone, catalytic,with hydrogenation condensation, Then, N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine (CAS NO. 793-24-8) is derived.

N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rabbit	LD50	skin	> 7940mg/kg (7940mg/kg)	BEHAVIORAL: FOOD INTAKE (ANIMAL) BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)	Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 67, 1990.
rat	LD50	oral	3580mg/kg (3580mg/kg)	SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE BEHAVIORAL: FOOD INTAKE (ANIMAL) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"	Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 67, 1990.

N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE Safety Profile

RTECS ST0900000

N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE Specification

1.Air & Water Reactions :N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine may be sensitive to prolonged exposure to air. Insoluble in water.
2.Reactivity Profile :You should protect N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine (CAS NO. 793-24-8) from exposure to strong oxidizing agents such as chlorine or hydrogen peroxide. N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine will ignite if heated strongly.
3.Fire Hazard: N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine is combustible.

Product Name

N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine

Synthetic route

N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE Chemical Properties

N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE Uses

N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE Production

N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE Toxicity Data With Reference

N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE Safety Profile

N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-P-PHENYLENEDIAMINE Specification

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