• Name

  N,N-Dimethylcapramide

• EINECS 238-405-1
• CAS No. 14433-76-2
• Article Data13
• CAS DataBase
• Density 0.862 g/cm³
• Solubility Not miscible or difficult to mix with water.
• Melting Point
• Formula C₁₂H₂₅NO
• Boiling Point 259.6 °C at 760 mmHg
• Molecular Weight 199.337
• Flash Point 97.1 °C
• Transport Information
• Appearance
• Safety 24/25
• Risk Codes
• Molecular Structure
• Hazard Symbols
• Synonyms N,N-Dimethylcapramide;
• PSA 20.31000
• LogP 3.21530

Synthetic route

111-87-5

octanol

127-19-5

N,N-dimethyl acetamide

14433-76-2

N,N-dimethyldecanamide

Conditions

Conditions	Yield
With C19H26ClIrNOP; potassium tert-butylate In toluene at 80℃; for 12h; Schlenk technique; Inert atmosphere; Sealed tube; Green chemistry;	94%
With C29H55IrN3P2(1+)*Cl(1-); potassium tert-butylate In toluene at 120℃; for 15h; Schlenk technique; Inert atmosphere; Glovebox;	76%
With C20H37ClN2OPRu; potassium tert-butylate In neat liquid at 140℃; for 24h; Inert atmosphere;	36%

112-13-0

n-decanoyl chloride

124-40-3

dimethyl amine

14433-76-2

N,N-dimethyldecanamide

Conditions

Conditions	Yield
In benzene at 20℃;	93%
In benzene 1.) 0 deg C, 1 h, 2.) r.t., 1 h;

506-59-2

N,N-dimethylammonium chloride

112-13-0

n-decanoyl chloride

14433-76-2

N,N-dimethyldecanamide

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0 - 20℃;	76%

334-48-5

1-decanoic acid

68-12-2, 33513-42-7

N,N-dimethyl-formamide

14433-76-2

N,N-dimethyldecanamide

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; copper(II) perchlorate hexahydrate at 100℃; for 6h;	65%

51892-25-2

S-phenyl decanethioate

68-12-2, 33513-42-7

N,N-dimethyl-formamide

14433-76-2

N,N-dimethyldecanamide

Conditions

Conditions	Yield
With lithium perchlorate Electrochemical reaction;	32 % Spectr.

334-48-5

1-decanoic acid

124-40-3

dimethyl amine

14433-76-2

N,N-dimethyldecanamide

Conditions

Conditions	Yield
Stage #1: 1-decanoic acid; dimethyl amine In water Stage #2: In water at 240℃; under 15001.5 Torr; for 0.166667h; Product distribution / selectivity; Microvawe irradiation;

14433-76-2

N,N-dimethyldecanamide

1196877-69-6

1-dimethylaminodecyl-1,1-bisphosphonic acid

Conditions

Conditions	Yield
Stage #1: N,N-dimethyldecanamide With phosphorous acid; phosphorus trichloride at 70℃; for 2h; Stage #2: With water for 2h;	100%
Stage #1: N,N-dimethyldecanamide With phosphorous acid; phosphorus trichloride at 70℃; for 12h; Stage #2: With water for 2h;	100%
Stage #1: N,N-dimethyldecanamide With phosphonic Acid; phosphorus trichloride at 70℃; for 2h; Stage #2: With water at 100℃; for 3h;	100%

14433-76-2

N,N-dimethyldecanamide

1120-24-7

N,N-dimethyldecylamine

Conditions

Conditions	Yield
With tris(pentafluorophenyl)borate; [Ru(1,1,1-tris(di(3,5-dimethoxyphenyl)phosphino-methyl)ethane)(trimethylenemethane)]; hydrogen In tetrahydrofuran at 160℃; under 75007.5 Torr; for 16h;	97%
With 9-borabicyclo[3.3.1]nonane In tetrahydrofuran at 25℃; for 1h; Inert atmosphere;	88%
With n-pentyl methyl ketone; Dimethylphenylsilane; triethylamine; (μ3;η2;η3;η5-acenaphthylene)Ru3(CO)7 In various solvent(s) at 20℃; for 2h;	79%

14433-76-2

N,N-dimethyldecanamide

1-((5-phenylpent-1-en-2-yl)oxy)pyridin-1-ium bis((trifluoromethyl)sulfonyl)amide

2-oxo-5-phenylpentyl decanoate

Conditions

Conditions	Yield
With water In toluene at 80℃; for 3h;	85%
With water at 60℃; for 18h;	85%

14433-76-2

N,N-dimethyldecanamide

C2F6NO4S2(1-)*C14H20NO(1+)

3-cyclohexyl-2-oxopropyl decanoate

Conditions

Conditions	Yield
With water at 60℃; for 20h;	85%

14433-76-2

N,N-dimethyldecanamide

10237-16-8

N,N-dimethyldecane-1-amine hydrochloride

Conditions

Conditions	Yield
Stage #1: N,N-dimethyldecanamide With bis(cyclopentadienyl)dihydrozirconium; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane at 20℃; under 760.051 Torr; for 12h; Inert atmosphere; Stage #2: With hydrogenchloride In diethyl ether Inert atmosphere;	83%

14433-76-2

N,N-dimethyldecanamide

3839-31-4

dimethyl(phenyl)silyllithium

125828-13-9

decanoyldimethyl(phenyl)silane

Conditions

Conditions	Yield
In tetrahydrofuran at -78℃; for 1.5h;	82%

14433-76-2

N,N-dimethyldecanamide

64670-05-9

lithium sodium dianion of methyl acetoacetate

100420-13-1

methyl 3,5-dioxotetradecanoate

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In tetrahydrofuran; hexane at -78 - 0℃; for 2h;	74%
With boron trifluoride diethyl etherate; silica gel 1.)tetrahydrofuran, -78 --> 0 deg C, 2 h, 2.)room temp., overnight; Yield given. Multistep reaction;

14433-76-2

N,N-dimethyldecanamide

223801-43-2

α-(dimethylamino)decyl cyanide

Conditions

Conditions	Yield
Stage #1: N,N-dimethyldecanamide With bis(triphenylphosphine)iridium(I) carbonyl chloride In toluene at 20℃; for 0.0833333h; Stage #2: With 1,1,3,3-Tetramethyldisiloxane In toluene at 20℃; for 0.0833333h; Stage #3: With trimethylsilyl cyanide In toluene at 20℃; for 0.5h;	72%

14433-76-2

N,N-dimethyldecanamide

62-53-3

aniline

15473-32-2

decananilide

Conditions

Conditions	Yield
With sodium t-butanolate In neat (no solvent) at 80℃; for 12h; Temperature; Inert atmosphere; Glovebox;	72%

14433-76-2

N,N-dimethyldecanamide

6921-34-2

benzylmagnesium chloride

C19H33N

Conditions

Conditions	Yield
Stage #1: N,N-dimethyldecanamide With bis(triphenylphosphine)carbonyliridium(I) chloride; 1,1,3,3-Tetramethyldisiloxane In dichloromethane at 20℃; for 0.333333h; Stage #2: benzylmagnesium chloride at -78 - 20℃; for 4h;	58%

14433-76-2

N,N-dimethyldecanamide

112-30-1

1-Decanol

Conditions

Conditions	Yield
With ethanol; sodium In hexane; paraffin oil at 0℃; for 0.0833333h; Inert atmosphere;	42%

14433-76-2

N,N-dimethyldecanamide

113860-70-1

2-octyl-3-oxo-dodecanoic acid dimethylamide

Conditions

Conditions	Yield
With trichlorophosphate; benzene

14433-76-2

N,N-dimethyldecanamide

62-53-3

aniline

110357-22-7

N,N-dimethyl-N'-phenyl-decanamidine

Conditions

Conditions	Yield
With trichlorophosphate; benzene

109-97-7

pyrrole

14433-76-2

N,N-dimethyldecanamide

89789-55-9

1-(1H-pyrrol-2-yl)decan-1-one

Conditions

Conditions	Yield
With sodium hydroxide; water; trichlorophosphate 1) benzene, 18 h, 20 deg C, 2) 1 h, 20 deg C; Yield given. Multistep reaction;

628-71-7

1-Heptyne

14433-76-2

N,N-dimethyldecanamide

84907-65-3

Heptadec-6-yn-8-one

Conditions

Conditions	Yield
Yield given. Multistep reaction;

14433-76-2

N,N-dimethyldecanamide

A

112-30-1

1-Decanol

B

1120-24-7

N,N-dimethyldecylamine

Conditions

Conditions	Yield
With sodium dimethylaminoborohydride In tetrahydrofuran at 66℃; for 55h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With ethanol; sodium In hexane at 0℃; for 0.333333h; Inert atmosphere; Overall yield = 73 %; Overall yield = 57.8 mg; chemoselective reaction;

14433-76-2

N,N-dimethyldecanamide

536-74-3

phenylacetylene

84907-66-4

1-Phenyl-3-oxododec-1-yne

Conditions

Conditions	Yield
Yield given. Multistep reaction;

14433-76-2

N,N-dimethyldecanamide

((E)-Dec-1-enyl)-dimethyl-amine

Conditions

Conditions	Yield
With titanium(IV) isopropylate; diphenylsilane at 20℃; Yield given;

1618-26-4

2,4-dithiapentane

14433-76-2

N,N-dimethyldecanamide

1,1-Bis-methylsulfanyl-undecan-2-one

Conditions

Conditions	Yield
With n-butyllithium 1) THF, hexane, -78 deg C, 2) THF, hexane, -78 deg C, 30 min; Yield given. Multistep reaction;

1618-26-4

2,4-dithiapentane

14433-76-2

N,N-dimethyldecanamide

171897-83-9

1,1,1-Tris-methylsulfanyl-undecan-2-one

Conditions

Conditions	Yield
Yield given. Multistep reaction;

14433-76-2

N,N-dimethyldecanamide

112-31-2

caprinaldehyde

Conditions

Conditions	Yield
With bis-(1,2-dimethylpropyl)borane In tetrahydrofuran; dodecane at 25℃;	85 % Chromat.
Multi-step reaction with 2 steps 1: Ti(O-i-Pr)4, Ph2SiH2 / 20 °C 2: 1 M aq. HCl / tetrahydrofuran / 20 °C View Scheme
With C11H25AlNO4(1-)*Na(1+) In tetrahydrofuran; toluene at 0 - 20℃; for 0.5h;	> 99 %Chromat.
With benzoic acid ethyl ester; copper diisobutyl-t-butoxyaluminum hydride In tetrahydrofuran at 20℃; for 12h; Reagent/catalyst; Inert atmosphere; chemoselective reaction;	> 99 %Chromat.

14433-76-2

N,N-dimethyldecanamide

(Z)-N,N,N',N'-Tetramethyl-icos-10-ene-10,11-diamine

Conditions

Conditions	Yield
With dimethyl(phenyl)silyl lithium In tetrahydrofuran at -78 - -20℃; for 1h;
With dimethyl(phenyl)silyl lithium In tetrahydrofuran at -78 - -20℃; for 2h;

14433-76-2

N,N-dimethyldecanamide

11-(N,N-dimethyl)amino-10-eicosanone

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: PhMe2SiLi / tetrahydrofuran / 2 h / -78 - -20 °C 2: 243 mg / aq. HCl / 18 h / 70 °C View Scheme
Multi-step reaction with 2 steps 1: PhMe2SiLi / tetrahydrofuran / 1 h / -78 - -20 °C 2: H2O, HCl View Scheme

N,N-Dimethyldecanamide Chemical Properties

N,N-Dimethyldecanamide Toxicity Data With Reference

N,N-Dimethyldecanamide Consensus Reports

N,N-Dimethyldecanamide Safety Profile

N,N-Dimethyldecanamide Specification