NEROL supplier | CasNO.106-25-2

Name
2,6-Octadien-1-ol,3,7-dimethyl-, (2Z)-
EINECS 203-378-7
CAS No. 106-25-2
Article Data188
CAS DataBase
Density 0.866 g/cm³
Solubility 1.311g/L(25 oC)
Melting Point < -10oC
Formula C₁₀H₁₈O
Boiling Point 229.5 °C at 760 mmHg
Molecular Weight 154.252
Flash Point 76.7 °C
Transport Information
Appearance Clear colorless to almost colorless liquid
Safety 26-36
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms cis-Geraniol;b-Nerol;2,6-Octadien-1-ol,3,7-dimethyl-, (Z)- (8CI);Nerol (6CI);(2Z)-3,7-Dimethyl-2,6-octadien-1-ol;(Z)-3,7-Dimethyl-2,6-octadien-1-ol;(Z)-Geraniol;(Z)-Nerol;2-cis-3,7-Dimethyl-2,6-octadien-1-ol;3,7-Dimethyl-cis-2,6-octadien-1-ol;Nerol900;Neryl alcohol;cis-3,7-Dimethyl-2,6-octadien-1-ol;
PSA 20.23000
LogP 2.67140

Synthetic route

: Carbonic acid allyl ester (Z)-3,7-dimethyl-octa-2,6-dienyl ester

: 106-25-2
Nerol

Conditions

Conditions	Yield
With palladium diacetate; sodium azide; trisodium tris(3-sulfophenyl)phosphine In water; acetonitrile at 25℃; for 1h;	98%

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

: 106-25-2
Nerol

Conditions

Conditions	Yield
With isopropyl alcohol; zirconium(IV) oxide for 6h; Rate constant; Heating;	97%
With isopropyl alcohol; zirconium(IV) oxide for 6h; Heating;	97%
With sodium formate; RuCl2(m-SPPh2)2 In water at 80℃; for 7h;	95%

: 80873-76-3
1-(tert-butyldimethylsiloxy)-3,7-dimethyl-2,6-octadiene

: 106-25-2
Nerol

Conditions

Conditions	Yield
With acetonyltriphenylphosphonium bromide In methanol; dichloromethane at 20℃; for 0.0833333h;	95%
In methanol; dichloromethane for 3.66667h; Irradiation;
In methanol; dichloromethane for 3.66667h; Product distribution; Irradiation; other silyl ethers; phenanthrene, var. time;

: 2-((Z)-3,7-Dimethyl-octa-2,6-dienyloxymethyl)-1,3-dimethyl-benzene

: 106-25-2
Nerol

Conditions

Conditions	Yield
With lithium; ethylenediamine In tetrahydrofuran at -10℃; for 2h;	93%

: 52537-25-4
(Z)-1-(allyloxy)-3,7-dimethylocta-2,6-diene

: 106-25-2
Nerol

Conditions

Conditions	Yield
With samarium diiodide; water; isopropylamine In tetrahydrofuran at 20℃; for 0.0333333h;	88%

: 106-26-3
cis-3,7-dimethyl-2,6-octadienal

: 106-25-2
Nerol

Conditions

Conditions	Yield
With indium tri-isopropoxide supported on mesoporous SBA-15 In isopropyl alcohol at 80℃; for 7h; Reagent/catalyst; Meerwein-Ponndorf-Verley Reduction; Inert atmosphere; Schlenk technique; chemoselective reaction;	87.6%
With potassium hydroxide; isopropyl alcohol; dichlorotetrakis(dimethylsulfoxide)ruthenium at 20℃; for 3h;	86.8%
With Triisopropyl borate; isopropyl alcohol at 27℃; for 20h; Kinetics; Reagent/catalyst; Meerwein-Ponndorf-Verley reduction; Inert atmosphere; chemoselective reaction;	83.1%

: 70473-31-3
neryl 2-tetrahydropyranyl ether

: 106-25-2
Nerol

Conditions

Conditions	Yield
ammonium cerium(IV) nitrate In alkaline aq. solution; acetonitrile at 70℃; for 2h; pH=8; Decomposition;	86%
With tin(ll) chloride In methanol Substitution;	80%
With boron trifluoride diethyl etherate; dimethylthio-dimethyl-tin In toluene at -20 - 0℃; for 12h;	82 % Chromat.

: 13058-12-3
ethyl 3,7-dimethyl-2,6-octadienoate

: 106-25-2
Nerol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride	81%
With diisobutylaluminium hydride In diethyl ether; hexane at -78 - 20℃; for 12.5h;	0.9 g

: 74323-42-5
morpholide of 1-hydroxy-3,7-dimethylocta-2Z,6-diene-4-sulfonic acid

A: 106-25-2
Nerol

B: 16750-94-0
2,6-dimethyl-2,5-octadien-8-ol

Conditions

Conditions	Yield
With dibenzo-18-crown-6; sodium In tetrahydrofuran; benzene-d6 at -70℃; for 0.0333333h;	A 75% B 4%
With dibenzo-18-crown-6; sodium In ammonia at -70℃; for 2h;	A 75% B 4%
With sodium; tert-butyl alcohol In benzene-d6 at -70℃; Yield given. Yields of byproduct given;
With lithium; tert-butyl alcohol In ammonia at -70℃; Product distribution; also Na, (DB18C6) or Na, tBuOH in NH3;
With lithium In diethyl ether; ammonia at -65℃; Product distribution; other reagent, solvent, temperature;

: 141-12-8
neryl acetate

: 106-25-2
Nerol

Conditions

Conditions	Yield
With tris(2,4,6-trimethoxyphenyl)phosphine In methanol at 50℃; for 24h;	73%

: 106-24-1
Geraniol

A: 78-70-6
3,7-dimethylocta-1,6-dien-3-ol

B: 106-25-2
Nerol

C: 98-55-5
terpineol

Conditions

Conditions	Yield
With bis-trimethylsilanyl peroxide; bis(acetylacetonate)oxovanadium In dichloromethane at 25℃; for 7h;	A 68% B 8% C 2%
bis(acetylacetonate)oxovanadium; bis-trimethylsilanyl peroxide In dichloromethane at 25℃; for 7h;	A 68 % Chromat. B 8 % Chromat. C 2 % Chromat.
bis(acetylacetonate)oxovanadium; bis-trimethylsilanyl peroxide In dichloromethane at 25℃; for 7h; Product distribution;	A 68 % Chromat. B 8 % Chromat. C 2 % Chromat.

...Expand

: 50727-95-2
(2R*,3R*)-2,3-epoxy-3,7-dimethyl-6-octenyl acetate

A: 78-70-6
3,7-dimethylocta-1,6-dien-3-ol

B: 106-25-2
Nerol

Conditions

Conditions	Yield
With tellurium; lithium triethylborohydride In tetrahydrofuran for 0.25h; Ambient temperature;	A 62% B 5.5%
With tellurium; lithium triethylborohydride In tetrahydrofuran for 0.25h; Product distribution; Mechanism; Ambient temperature; other reducing Te agent; various time; also in the presence of fluoride ion;	A 62% B 5.5%

: 115-18-4
2-methyl-3-buten-2-ol

A: 106-25-2
Nerol

B: 106-24-1
Geraniol

C: 58461-27-1
(+/-)-lavandulol

D: 78-79-5
isoprene

Conditions

Conditions	Yield
With oxalic acid In water for 5h; Heating; Further byproducts given. Yields of byproduct given;	A n/a B n/a C n/a D 46%

...Expand

: 106-24-1
Geraniol

A: 106-22-9
Citronellol

B: 106-25-2
Nerol

C: 23062-07-9
(E)-2,6-dimethyl-oct-2-ene-1,8-diol

D: 26488-98-2
(2E,6Z)-2,6-dimethylocta-2,6-diene-1,8-diol

E: 26488-97-1
8-hydroxygeraniol

Conditions

Conditions	Yield
With 2,4-Dichlorophenoxyacetic acid; sucrose; cultured cells of Catharanthus roseus In water at 25℃; for 48h; Product distribution; other reaction time;	A n/a B n/a C 32.9% D 25.3% E 41.8%

...Expand

: 78-70-6
3,7-dimethylocta-1,6-dien-3-ol

A: 106-25-2
Nerol

B: 106-24-1
Geraniol

Conditions

Conditions	Yield
With hydrogen bromide Behandeln des erhaltenen Bromids mit Kaliumacetat in Dimethylformamid und Erwaermen des Reaktionsprodukts mit wss.Natronlauge;
pyridine; tungsten oxomethoxide at 200℃; for 3h;
pyridine; tungsten oxomethoxide at 200℃; for 3h; Product distribution; other catalysts and time;

: 555-31-7
aluminum isopropoxide

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 106-25-2
Nerol

B: 106-24-1
Geraniol

C: 67-64-1
acetone

Conditions

Conditions	Yield
analoge Reaktionen mit Aldehyden und Ketonen bei hoeherer Temperatur;

...Expand

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 106-25-2
Nerol

B: 106-24-1
Geraniol

Conditions

Conditions	Yield
With sodium amalgam; ethanol
With aluminum isopropoxide; isopropyl alcohol
With hydrotalcite; isopropyl alcohol at 82℃; for 5h; Title compound not separated from byproducts;

: 106-24-1
Geraniol

: 106-25-2
Nerol

Conditions

Conditions	Yield
beim Kochen der Natriumverbindung;
With hydrogen iodide; benzene und Erwaermen des Reaktionsproduktes mit alkoh.Natronlauge;
With hydrogen iodide; acetic acid und Erwaermen des Reaktionsproduktes mit alkoh.Natronlauge;

: 106-24-1
Geraniol

A: 78-70-6
3,7-dimethylocta-1,6-dien-3-ol

B: 106-25-2
Nerol

Conditions

Conditions	Yield
With hydrogen bromide; acetic acid und Abspaltung von HBr aus dem Reaktionsprodukts; isolinalool;

: 1862-61-9
methyl nerate

: 106-25-2
Nerol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride

: 2414-98-4
magnesium ethylate

: 67-63-0
isopropyl alcohol

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 106-25-2
Nerol

B: 106-24-1
Geraniol

...Expand

: 555-31-7
aluminum isopropoxide

: 67-63-0
isopropyl alcohol

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 106-25-2
Nerol

B: 106-24-1
Geraniol

...Expand

: 67-63-0
isopropyl alcohol

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 106-25-2
Nerol

B: 106-24-1
Geraniol

Conditions

Conditions	Yield
With magnesium ethylate
With magnesium ethylate

...Expand

: 106-24-1
Geraniol

: 71-43-2
benzene

: 106-25-2
Nerol

Conditions

Conditions	Yield
beim Erhitzen;

: 78-70-6
3,7-dimethylocta-1,6-dien-3-ol

A: 106-25-2
Nerol

B: 106-24-1
Geraniol

C: 98-55-5
terpineol

Conditions

Conditions	Yield
bis(acetylacetonate)oxovanadium; bis-trimethylsilanyl peroxide In dichloromethane at 25℃; for 12h; Product distribution;	A 5 % Chromat. B 8 % Chromat. C 2 % Chromat.
With dodecansulfonic acid; water at 25℃; Rate constant; other acids, other solvent and temperature;

...Expand

: 70473-50-6
2-(phenylthio)-3-methyl-3-buten-1-ol

: 870-63-3
prenyl bromide

A: 106-25-2
Nerol

B: 106-24-1
Geraniol

C: 58461-27-1
(+/-)-lavandulol

Conditions

Conditions	Yield
With hexamethyldistannane In benzene at 25℃; for 5h; Irradiation; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 6138-90-5
trans-geranyl bromide

A: 78-70-6
3,7-dimethylocta-1,6-dien-3-ol

B: 106-25-2
Nerol

Conditions

Conditions	Yield
With indium; oxygen 1.) DMF, 1 h, RT, 2.) room temperature, 3 h; Yield given. Multistep reaction. Yields of byproduct given;

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 106-22-9
Citronellol

B: 106-23-0, 26489-02-1
3,7-dimethyl-oct-6-enal

C: 106-25-2
Nerol

D: 106-24-1
Geraniol

Conditions

Conditions	Yield
With methanol; samarium diiodide In tetrahydrofuran for 24h; Ambient temperature; Yields of byproduct given. Title compound not separated from byproducts;	A 18 % Chromat. B 8 % Chromat. C n/a D n/a
With methanol; samarium diiodide In tetrahydrofuran for 24h; Ambient temperature; Yields of byproduct given. Title compound not separated from byproducts;
With hydrogen; MgCo6Ge6 In hexane at 174.84℃; under 56255.6 Torr; for 2.5h; Product distribution; Further Variations:; Catalysts; Pressures; time;

...Expand

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 106-22-9
Citronellol

B: 106-25-2
Nerol

Conditions

Conditions	Yield
With aluminum oxide; borane pyridine complex In cyclohexane for 10h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With carbon monoxide; water; hexarhodium hexadecacarbonyl; N,N,N'N'-tetramethyl-1,3-propanediamine In 2-ethoxy-ethanol at 30℃; under 7600 Torr; for 48h;	A 6 % Chromat. B 94 % Chromat.
With formic acid In water; N,N-dimethyl-formamide Product distribution; the effect of the nature and concentration of the acid on the yield and ratio of the products of electrochemical hydrogenation, other reagent;
With sodium tetrahydroborate; ErCpCl2(THF)3 In methanol for 6h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 106-22-9
Citronellol

B: 106-25-2
Nerol

C: 106-24-1
Geraniol

...Expand

: 106-25-2
Nerol

: 106-26-3
cis-3,7-dimethyl-2,6-octadienal

Conditions

Conditions	Yield
With oxygen; Pd561phen60(OAc)180 In acetic acid; benzene at 60℃; for 24h;	100%
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene In acetonitrile at 0℃; for 3h; pH=7; Inert atmosphere;	100%
With 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium perchlorate In dichloromethane	99%

: 106-25-2
Nerol

: 108-24-7
acetic anhydride

: 141-12-8
neryl acetate

Conditions

Conditions	Yield
With pyridine; dmap	100%
With pyridine; dmap for 18h;	100%
With dmap; triethylamine In dichloromethane at 0℃; for 0.333333h; Inert atmosphere;	98%

: 106-25-2
Nerol

: 75-36-5
acetyl chloride

: 141-12-8
neryl acetate

Conditions

Conditions	Yield
With pyridine In dichloromethane for 0.666667h;	100%
With pyridine In dichloromethane at 0℃; Inert atmosphere;	100%
With dmap; triethylamine at 0℃; for 3h;	95%
With N,N-dimethyl-aniline In diethyl ether for 2h; Heating;	90%

: 106-25-2
Nerol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 139109-03-8
(Z)-1-[(tert-butyldiphenylsilyl)oxy]-3,7-dimethyl-2,6-octadiene

Conditions

Conditions	Yield
With 1H-imidazole In N,N-dimethyl-formamide for 0.25h; Ambient temperature;	100%
With 1H-imidazole In N,N-dimethyl-formamide	99%
With 1H-imidazole In N,N-dimethyl-formamide at 20℃; for 16h;	98%
With 1H-imidazole In N,N-dimethyl-formamide at 20℃; for 16h;	98%
With 1H-imidazole In dichloromethane; N,N-dimethyl-formamide for 3h; Ambient temperature;	95%

: 106-25-2
Nerol

: 50727-94-1
[3-methyl-3-(4-methylpent-3-enyl)oxiran-2-yl]methanol

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium In chlorobenzene at 80℃; for 5h;	100%
With dihydrogen peroxide; Sucrose; molybdic acid In phosphate buffer at 2℃; for 48h; pH=7;	92%
With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium In decane; dichloromethane at 20℃; for 1.5h; Inert atmosphere;	75%

: 106-25-2
Nerol

: 106-95-6
allyl bromide

: 52537-25-4
(Z)-1-(allyloxy)-3,7-dimethylocta-2,6-diene

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; potassium hydroxide at 20℃; for 18h;	100%
With sodium hydride In tetrahydrofuran

: 106-25-2
Nerol

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With hydrogen; aluminum oxide; copper In isopropyl alcohol at 90℃; for 12h;	100%
With dichloro(η3:η2:η3-dodeca-2,6,10-triene-1,12-diyl)ruthenium(IV); caesium carbonate; isopropyl alcohol at 82℃; for 23h; Inert atmosphere; chemoselective reaction;	95 %Chromat.

: 106-25-2
Nerol

: 507-09-5
thioacetic acid

: thioacetic acid S-[(Z)-3,7-dimethylocta-2,6-dienyl] ester

Conditions

Conditions	Yield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran; toluene at 0℃; for 1h; Inert atmosphere;	100%

: 106-25-2
Nerol

: 64-19-7
acetic acid

: 141-12-8
neryl acetate

Conditions

Conditions	Yield
With Candida antarctica lipase B at 50℃; for 4h; Molecular sieve; Ionic liquid; Green chemistry; Enzymatic reaction;	99.9%
With N,N′,N′′,N′′′-hexadecyltrimethylammonium bis(trifluoromethylsulfonyl)imide; Novozym 435 (immobilized Candida antarctica lipase B) at 50℃; for 4h; Green chemistry; Enzymatic reaction;
at 59.84℃; for 3h;
With dmap; dicyclohexyl-carbodiimide In dichloromethane Steglich Esterification;

: 106-25-2
Nerol

: 107-92-6
butyric acid

: 999-40-6
butyric acid β-neryl ester

Conditions

Conditions	Yield
With Candida antarctica lipase B at 50℃; for 4h; Molecular sieve; Ionic liquid; Green chemistry; Enzymatic reaction;	99.9%
With dmap; dicyclohexyl-carbodiimide In dichloromethane Steglich Esterification;

: 106-25-2
Nerol

: 20536-36-1
neryl chloride

Conditions

Conditions	Yield
With N-chloro-succinimide; dimethylsulfide In dichloromethane at -40 - 0℃; for 2h;	99%
With chloro-trimethyl-silane; potassium carbonate In Petroleum ether at 0℃; for 2h;	93%
With dimethylsulfide; methanesulfonyl chloride; lithium chloride In N,N-dimethyl-formamide at 0 - 20℃; for 0.75h; Inert atmosphere;	90%

: 106-25-2
Nerol

: 25996-10-5
(Z)-neryl bromide

Conditions

Conditions	Yield
With carbon tetrabromide; triphenylphosphine In benzene at 0℃; for 2h;	99%
With carbon tetrabromide; triphenylphosphine In benzene at 0℃; for 2h;	99%
With 1H-imidazole; iodine In dichloromethane at 20℃; for 2h;	91%

: 75-11-6
diiodomethane

: 106-25-2
Nerol

: 97231-34-0, 98678-70-7, 109801-02-7, 109801-03-8
<(1RS,2RS)-2-methyl-2-(4'-methyl-3'-pentenyl)cyclopropyl>methanol

Conditions

Conditions	Yield
With samarium In tetrahydrofuran at -78 - 20℃;	99%

: 106-25-2
Nerol

: 4648-54-8
trimethylsilylazide

: 72237-31-1
O-(cis-3,7-dimethylocta-2,6-dien-1-yl)trimethylsilane

Conditions

Conditions	Yield
tetrabutylammomium bromide at 30℃; for 0.00333333h;	99%

: 106-25-2
Nerol

: 802294-64-0
propionic acid

: 105-91-9
(Z)-3,7-dimethyl-2,6-octadien-1-yl propanoate

Conditions

Conditions	Yield
With Candida antarctica lipase B at 50℃; for 4h; Molecular sieve; Ionic liquid; Green chemistry; Enzymatic reaction;	98.7%
With dmap; dicyclohexyl-carbodiimide In dichloromethane Steglich Esterification;

: 106-25-2
Nerol

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

Conditions

Conditions	Yield
With bis(pentafluorophenyl)borinic acid; magnesium sulfate; pivalaldehyde In toluene for 3h; Ambient temperature;	98%
With Ba In dichloromethane for 48h;	95%
With 4-acetylamino-2,2,6,6-tetramethylpiperidine-N-oxyl; toluene-4-sulfonic acid In dichloromethane 1) 0 deg C, 1 h, 2) r.t., 2 h;	91%

: 106-25-2
Nerol

: 102699-81-0, 103583-58-0
(E)-3-Methyl-oct-2-en-6-yn-1-ol

Conditions

Conditions	Yield
With sodium nitrite In water; acetic acid 1.) 0 deg C 2.) 60 deg C, 0.5 h;	98%

: 106-25-2
Nerol

: 116902-88-6
9-decenoic acid chloride

: dec-9-enoate cis-3,7-dimethyloct-2,6-dien-1-yl

Conditions

Conditions	Yield
With pyridine In dichloromethane at -78 - 20℃; for 1.08333h; Inert atmosphere; Schlenk technique; Cooling with acetone-dry ice;	98%
With pyridine In dichloromethane at -78℃; Inert atmosphere;

: 106-25-2
Nerol

: 109-52-4
valeric acid

: 10522-33-5
neryl valerate

Conditions

Conditions	Yield
With Candida antarctica lipase B at 50℃; for 4h; Molecular sieve; Ionic liquid; Green chemistry; Enzymatic reaction;	97.8%

: 106-25-2
Nerol

: 882-33-7
diphenyldisulfane

: 31162-76-2, 35162-74-4, 35162-79-9
(cis-3,7-Dimethyl-2,6-octadienyl) phenyl sulfide

Conditions

Conditions	Yield
With tributylphosphine In tetrahydrofuran for 2h; Ambient temperature;	97.2%

: 106-25-2
Nerol

: 593-71-5
Chloroiodomethane

: 499155-10-1
cis-1-(hydroxymethyl)-2-methyl-2-(4-methyl-3-pentenyl)cyclopropane

Conditions

Conditions	Yield
With samarium; mercury dichloride In tetrahydrofuran at -78 - 20℃;	97%

: 106-25-2
Nerol

: 824-94-2
p-methoxybenzyl chloride

: 1-({[(2Z)-3,7-dimethylocta-2,6-dien-1-yl]oxy}methyl)-4-methoxybenzene

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 7h;	97%
Stage #1: Nerol With sodium hydride In N,N-dimethyl-formamide at 20℃; for 1h; Stage #2: p-methoxybenzyl chloride With tetra-(n-butyl)ammonium iodide In N,N-dimethyl-formamide at 0 - 20℃; for 7h;

: 830-96-6
Indole-3-propionic acid

: 106-25-2
Nerol

: C21H27NO2

Conditions

Conditions	Yield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 22℃; for 1h; Inert atmosphere;	97%

: 106-25-2
Nerol

: 106-96-7
propargyl bromide

: 33470-50-7
(Z)-3,7-dimethyl-1-(prop-2-yn-1-yloxy)octa-2,6-diene

Conditions

Conditions	Yield
Stage #1: Nerol With sodium hydride In tetrahydrofuran at 40℃; for 15h; Inert atmosphere; Stage #2: propargyl bromide In tetrahydrofuran at 40℃; for 7h; Inert atmosphere;	97%

: 106-25-2
Nerol

A: 106-26-3
cis-3,7-dimethyl-2,6-octadienal

B: 141-27-5
3,7-dimethyl-2,6-octadienal

Conditions

Conditions	Yield
With sodium hydroxide; dipotassium peroxodisulfate; nickel(II) sulphate In dichloromethane; water for 24h; Ambient temperature; Yields of byproduct given;	A 94% B n/a
With 6C16H36N(1+)2Zn(2+)4Na(1+)*[Bi2Zn2(ZnW9O34)2](14-); urea hydrogen peroxide adduct In acetonitrile at 70℃; for 1h; Ene Reaction;	A 89% B 11%
With bis(cyclopentadienyl)dihydrozirconium; benzaldehyde In toluene at 110℃; for 8h;	A 83% B 12%

: 106-25-2
Nerol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 80873-76-3
1-(tert-butyldimethylsiloxy)-3,7-dimethyl-2,6-octadiene

Conditions

Conditions	Yield
With 1H-imidazole In N,N-dimethyl-formamide for 1h; Ambient temperature;	94%
With diisopropylamine In dichloromethane at 20℃; for 5h; Inert atmosphere;	64%

: 106-25-2
Nerol

: 62960-04-7
(+/-)-2,3-epoxygeraniol

Conditions

Conditions	Yield
With sodium hydroxide; sodium tungstate; aluminium trichloride; dihydrogen peroxide; toluene-4-sulfonic acid; magnesium chloride In methanol Ambient temperature;	94%

NEROL Chemical Properties

MF: C₁₀H₁₈O
Synonyms: (2Z)-3,7-Dimethyl-2,6-octadien-1-ol;(Z)-Geraniol;2,6-Octadien-1-ol,3,7-dimethyl-,(Z)-;2-cis-3,7-Dimethyl-2,6-octadien-1-ol;3,7-dimethyl-octa-2cis,6-dien-1-ol;6-Octadien-1-ol,3,7-dimethyl-,(Z)-2;7-dimethyl-6-octadien-1-o(z)-3;beta-nerol
MW: 154.25
EINECS: 203-378-7
bp : 103-105 °C9 mm Hg(lit.)
density : 0.876 g/mL at 25 °C(lit.)
refractive index : n20/D 1.474(lit.)
FEMA : 2770
Fp : 226 °F
Merck : 14,6475
BRN : 1722455

NEROL Uses

NEROL is used in perfumery.

NEROL Safety Profile

Hazard Codes : Xi
Risk Statements : 36/37/38
Safety Statements : 26-36
WGK Germany : 2
RTECS : RG5840000

Product Name

2,6-Octadien-1-ol,3,7-dimethyl-, (2Z)-

Synthetic route

NEROL Chemical Properties

NEROL Uses

NEROL Safety Profile

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