Peroxymonosulfuric Acid supplier

Name
peroxomonosulphuric acid
EINECS
CAS No. 7722-86-3
Article Data82
CAS DataBase
Density 2.239g/cm³
Solubility
Melting Point 45, decomposing [HAW93]
Formula H₂O₅S
Boiling Point
Molecular Weight 114.079
Flash Point
Transport Information
Appearance
Safety Strong irritant. Powerful oxidizer. An explosive. Explosive reaction acetone; alcohols; aromatics (e.g., aniline; benzene; phenol); platinum; manganese dioxide; silver. Incompatible with acetone; catalysts; fibers. When heated to decomposition it emits toxic fumes of SO_x. See also PEROXIDES, INORGANIC; PEROXIDES, ORGANIC.
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Peroxomonosulphuric acid;
PSA 79.44000
LogP 0.13700

Synthetic route

: 7790-94-5
chlorosulfonic acid

: 7722-84-1
dihydrogen peroxide

: 7722-86-3
caro's acid

Conditions

Conditions	Yield
in traces H2O2, Cl2, H2S2O8;	96.6%
in traces H2O2, Cl2, H2S2O8;	96.6%

: 50981-12-9, 10193-30-3
sulfuric acid monohydrate

: ammonium sulfate-hydrogen peroxide(1/1)

A: 7722-86-3
caro's acid

B: 7722-84-1
dihydrogen peroxide

C: 13445-49-3
Marshall's acid

Conditions

Conditions	Yield
without water, -10°C;	A 93.5% B 1.4% C 5.1%
without water, -10°C;	A 93.5% B 1.4% C 5.1%

...Expand

: 7446-11-9
sulfur trioxide

: 7722-84-1
dihydrogen peroxide

: 7722-86-3
caro's acid

Conditions

Conditions	Yield
With H2SO4 In neat (no solvent) 87.3% H2O2 added to 65% oleum at 0-10°C within 1 h; crystals isolated by slow cooling to -20°C for 24 h;	62.9%
In neat (no solvent) reaction with anhydrous H2O2, cooling;;
under heat evolution, in water proof condition forming very little product;
In water -5°C;

: 7782-99-2
sulphurous acid

A: 7722-86-3
caro's acid

B: 13445-49-3
Marshall's acid

Conditions

Conditions	Yield
With ozone In water	A n/a B 1%
With ozone In water	A n/a B 1%
With ozone ozonisated H2SO3 soln.;	A n/a B <1
With ozone ozonisated H2SO3 soln.;	A n/a B <1

: 7446-11-9
sulfur trioxide

: 7732-18-5
water

: 7722-84-1
dihydrogen peroxide

A: 7722-86-3
caro's acid

B: 7664-93-9
sulfuric acid

C: 13445-49-3
Marshall's acid

Conditions

Conditions	Yield
at 13 - 15℃; for 5.5 - 7h;

...Expand

: 7664-93-9
sulfuric acid

: 7722-84-1
dihydrogen peroxide

: 7722-86-3
caro's acid

Conditions

Conditions	Yield
In water Kinetics; byproducts: H2O; slow addn. of H2O2 to H2SO4 soln.; react. carried out in temp. range 283-323 K, thermostated; titrimetry;
In not given concd. H2SO4;
In water at 2 - 8℃; for 3.5h; Product distribution / selectivity;
at 92℃; Product distribution / selectivity; Cooling;
In not given concd. H2SO4;

: 7722-84-1
dihydrogen peroxide

: 13445-49-3
Marshall's acid

: 7722-86-3
caro's acid

Conditions

Conditions	Yield
In neat (no solvent) cooling;;
	>98.5
	>98.5

: 7446-11-9
sulfur trioxide

: 7722-84-1
dihydrogen peroxide

A: 7722-86-3
caro's acid

B: 7664-93-9
sulfuric acid

Conditions

Conditions	Yield
In sulfuric acid addition of H2O2 (100%) to oleum;;

...Expand

: 7664-93-9
sulfuric acid

: 7722-86-3
caro's acid

Conditions

Conditions	Yield
With ozone In water	<1
In water Electrolysis; anodic process;
In not given
With O3 In water	<1

: 7664-93-9
sulfuric acid

A: 7722-86-3
caro's acid

B: 7722-84-1
dihydrogen peroxide

C: 80937-33-3
oxygen

D: 13445-49-3
Marshall's acid

Conditions

Conditions	Yield
In water Electrolysis; glow discharge electrolysis by alternating current; mechanismus discussed;
In water Electrolysis; glow discharge electrolysis by alternating current; 12°C; C(val) H2SO4 = 1-10; 50 Hz; current density 0.04 A/cm2; p = 11 torr;
In water Electrolysis; glow discharge electrolysis by alternating current; 12°C; C(val) H2SO4 = 1-10; 50 Hz; current density 0.04 A/cm2; p = 11 torr;
In water Electrolysis; glow discharge electrolysis by alternating current; mechanismus discussed;
In water Electrolysis; glow discharge electrolysis by alternating current; mechanismus discussed;

...Expand

: 7664-93-9
sulfuric acid

A: 7722-86-3
caro's acid

B: 7722-84-1
dihydrogen peroxide

C: 13445-49-3
Marshall's acid

Conditions

Conditions	Yield
In water Electrolysis; glow discharge electrolysis; 10°C; C(val) H2SO4 = 0.5-4 as well as 36% H2SO4;
In water Electrolysis; glow discharge electrolysis; ambient temp. and -50°C; 11-55 % H2SO4 ; 13 torr;
Electrolysis; anod in gas-filled room, alternating or continuous current, glow discharge;

...Expand

: 7722-84-1
dihydrogen peroxide

: 7722-86-3
caro's acid

Conditions

Conditions	Yield
With sulfuric acid In not given cooling;;
With sulfuric acid In water byproducts: H2O;
With sulfuric acid In not given byproducts: H2O;

: 7790-94-5
chlorosulfonic acid

: 7722-84-1
dihydrogen peroxide

A: 7722-86-3
caro's acid

B: 13445-49-3
Marshall's acid

Conditions

Conditions	Yield
In not given slow addition of H2O2 to HOSO2Cl, cooling; ratio of products depending on amount of used H2O2;;
In not given
In not given

...Expand

: 13445-49-3
Marshall's acid

: 7722-86-3
caro's acid

Conditions

Conditions	Yield
With dihydrogen peroxide In neat (no solvent) product crystallises;
With HNO3 hydrolysis;
With H2O2 In neat (no solvent) product crystallises;

: 13445-49-3
Marshall's acid

A: 7722-86-3
caro's acid

B: 7664-93-9
sulfuric acid

Conditions

Conditions	Yield
With water In not given byproducts: H2O2;
In water during storage of H2SO4 solns. having been previously electrolysed;
With H2O In not given byproducts: H2O2;

: 7732-18-5
water

: 13445-49-3
Marshall's acid

A: 7722-86-3
caro's acid

B: 7664-93-9
sulfuric acid

Conditions

Conditions	Yield
hydrolysis;
hydrolysis;

...Expand

: 7664-93-9
sulfuric acid

: 13445-49-3
Marshall's acid

: 7722-86-3
caro's acid

Conditions

Conditions	Yield
hydrolysis, faster with concd. than with dild. H2SO4;
40% H2SO4;	>99

: 7664-93-9
sulfuric acid

: 10028-15-6
ozone

A: 7722-86-3
caro's acid

B: 13445-49-3
Marshall's acid

Conditions

Conditions	Yield
In not given	A 0% B 0%

...Expand

: dipotassium peroxodisulfate

: 7722-86-3
caro's acid

Conditions

Conditions	Yield
With sulfuric acid concd. H2SO4;
With H2SO4 concd. H2SO4;

: dipotassium peroxodisulfate

A: 7722-86-3
caro's acid

B: 7664-93-9
sulfuric acid

Conditions

Conditions	Yield
With water In sulfuric acid byproducts: H2O2; effect of H2SO4 concn. on the H2O2/H2SO5 ratio;

: dipotassium peroxodisulfate

A: 7646-93-7
potassium hydrogensulfate

B: 7722-86-3
caro's acid

Conditions

Conditions	Yield
With sulfuric acid; water In water Kinetics; byproducts: O2; with over 15% H2SO4 ; at 98 °C;
With H2SO4; H2O In water Kinetics; byproducts: O2; with over 15% H2SO4 ; at 98 °C;

: sulfur tetroxide

: 7722-86-3
caro's acid

Conditions

Conditions	Yield
With water In water no hydrolysis; evidence by a number of reacts., which do not take place;;	0%

: 7664-93-9
sulfuric acid

: 7446-11-9
sulfur trioxide

A: 7722-86-3
caro's acid

B: 13445-49-3
Marshall's acid

Conditions

Conditions	Yield
In neat (no solvent) reaction by influence of a O3-O2 mixture on fuming H2SO4 (with a content of free SO3 between 38.21-76.59%);;
In neat (no solvent) reaction by influence of a O3-O2 mixture on fuming H2SO4 (with a content of free SO3 between 38.21-76.59%);;

...Expand

: ammonium sulfate-hydrogen peroxide(1/1)

A: 7722-86-3
caro's acid

B: 13445-49-3
Marshall's acid

Conditions

Conditions	Yield
With sulfuric acid

: ammonium sulfate-hydrogen peroxide(1/1)

: 7664-93-9
sulfuric acid

A: 7722-86-3
caro's acid

B: 13445-49-3
Marshall's acid

Conditions

Conditions	Yield
In not given -10°C; with the exclusion of water;	A n/a B >99
In not given -10°C; with the exclusion of water;	A n/a B >99

...Expand

: barium peroxodisulfate

A: barium sulfate

B: 7722-86-3
caro's acid

Conditions

Conditions	Yield
Ba-peroxodisulfat /containing crystal water/ standing for a week;

: 14996-02-2
hydrogensulfate

A: 7722-86-3
caro's acid

B: 7789-21-1
fluorosulphonic acid

C: 13445-49-3
Marshall's acid

Conditions

Conditions	Yield
With water; fluorine In water

...Expand

: 7664-93-9
sulfuric acid

A: 7722-86-3
caro's acid

B: 13445-49-3
Marshall's acid

Conditions

Conditions	Yield
In water Kinetics; Electrolysis; effect of electrol. duration discussed; 14.1 n-H2SO4; 7°C; 0.75 A/cm2; Pt anod;
With ozone In not given fuming H2SO4;
In water Kinetics; Electrolysis; 15 n-H2SO4; 30 A/dm2;

: sodium peroxide

: 7664-93-9
sulfuric acid

: 7722-86-3
caro's acid

Conditions

Conditions	Yield
byproducts: ozone; under cooling, concd. H2SO4;
byproducts: ozone; under cooling, concd. H2SO4;

: 7722-86-3
caro's acid

: 3736-92-3
4-[2-(phenylthio)ethyl]-1,2-diphenyl-3,5-pyrazolidinedione

: 57-96-5
4-[2-(phenylsulfinyl)ethyl]-1,2-diphenyl-3,5-pyrazolidinedione

Conditions

Conditions	Yield
With sodium hydrogencarbonate; sodium hydrogensulfite In water; acetic acid; ethyl acetate; toluene	60%

: 7722-86-3
caro's acid

: 13445-49-3
Marshall's acid

Conditions

Conditions	Yield
decompn. during storage (8 days);	15.3%
With chlorosulfonic acid
With HSO3Cl

: 7722-86-3
caro's acid

: 584-08-7
potassium carbonate

PMPS triple salt: PMPS triple salt

Conditions

Conditions	Yield
In water at 11 - 17℃; for 0.3h; Product distribution / selectivity;

: 7722-86-3
caro's acid

: 584-08-7
potassium carbonate

PMPS triple salt: PMPS triple salt

Conditions

Conditions	Yield
In water

: 7722-86-3
caro's acid

: 120131-05-7
fluoromalonaldehyde bis(diethyl acetal)

: 685-88-1
fluoromalonic acid diethyl ester

Conditions

Conditions	Yield
With ammonium persulfate; sulfuric acid In ethanol; water

: 7722-86-3
caro's acid

: 10028-15-6
ozone

Conditions

Conditions	Yield
In not given reaction by let standing of 92% concd. H2SO5 soln. shortly above 0 °C;; not isolated, detection by odor;;
In sulfuric acid decompn.;
In neat (no solvent) spontaneous decompn.;;

: 7722-86-3
caro's acid

: 10035-10-6, 12258-64-9
hydrogen bromide

: 7726-95-6
bromine

: 7722-86-3
caro's acid

: manganese(II)

: manganese(III) ion

: 7722-86-3
caro's acid

: 7664-93-9
sulfuric acid

Conditions

Conditions	Yield
With sulfur In sulfuric acid
With sulfur dioxide; water In water

: 7722-86-3
caro's acid

A: 7664-93-9
sulfuric acid

B: 80937-33-3
oxygen

: 7722-86-3
caro's acid

A: 7664-93-9
sulfuric acid

B: 7722-84-1
dihydrogen peroxide

Conditions

Conditions	Yield
With water In sulfuric acid hydrolysis faster in highe concn.;
With H2O hydrolysis;

: 7722-86-3
caro's acid

: 80937-33-3
oxygen

Conditions

Conditions	Yield
Irradiation (UV/VIS); blue light; 98.6°C, decomp. in 24 h;
platinum in presence of H2O2 faster than alone or H2O2 without Pt;
With potassium permanganate

: 7722-86-3
caro's acid

: 10058-23-8
oxone

Conditions

Conditions	Yield
With KOH In ethanol

: 7722-86-3
caro's acid

: 29683-94-1
hydroxyperoxide

Conditions

Conditions	Yield
In sulfuric acid aq. sulfuric acidic soln. of Caro's acid;;	0%
In sulfuric acid aq. sulfuric acidic soln. of Caro's acid;;
In sulfuric acid aq. H2SO4; aq. sulfuric acidic soln. of Caro's acid;;	0%
In sulfuric acid aq. H2SO4; aq. sulfuric acidic soln. of Caro's acid;;

: 7722-86-3
caro's acid

: 124-38-9
carbon dioxide

Conditions

Conditions	Yield
With pyrographite In sulfuric acid pulverised charcoal, heating;
With charcoal In sulfuric acid pulverised charcoal, heating;

: 7722-86-3
caro's acid

: ammonium chloride

A: 7647-01-0
hydrogenchloride

B: 52900-28-4
hydroxyl,ammonium,sulphate

...Expand

Peroxymonosulfuric Acid Chemical Properties

Chemistry informtion about Peroxymonosulfuric Acid (CAS NO.7722-86-3) is:
IUPAC Name: Tetraoxathiolane 5,5-Dioxide
Synonyms: Peroxomonosulphuric Acid ; Peroxysulfuric Acid ; Persulfuric Acid ; Sulfomonoperacid ; Peroxymonosulfuric Acid ; Caro Acid ; Peroxosulfuric Acid
MF: O₆S
MW: 128.0614
EINECS: 231-766-6
Density: 1.7-1.8 g/cm³
Following is the molecular structure of Peroxymonosulfuric Acid (CAS NO.7722-86-3) is:

Peroxymonosulfuric Acid History

Peroxymonosulfuric Acid was first described by Heinrich Caro, after whom it is named.

Peroxymonosulfuric Acid Uses

Peroxymonosulfuric Acid (CAS NO.7722-86-3) has been used for a variety of disinfectant and cleaning applications, e.g., swimming pool treatment and denture cleaning. Alkali metal salts of H₂SO₅ show promise for the delignification of wood. Ammonium, sodium, and potassium salts of Peroxymonosulfuric Acid are used in the plastics industry as polymerization initiators, etchants, desizing agents, soil conditioner, and for decolorizing and deodorizing oils. Potassium peroxymonosulfate, KHSO₅, is the potassium acid salt of peroxymonosulfuric acid. It is widely used as an oxidizing agent.

Peroxymonosulfuric Acid Safety Profile

Strong irritant. Powerful oxidizer. An explosive. Explosive reaction acetone; alcohols; aromatics (e.g., aniline; benzene; phenol); platinum; manganese dioxide; silver. Incompatible with acetone; catalysts; fibers. When heated to decomposition it emits toxic fumes of SO_x. See also PEROXIDES, INORGANIC; PEROXIDES, ORGANIC.
RIDADR: 1483
HazardClass: 5.1
PackingGroup: II

Peroxymonosulfuric Acid Analytical Methods

The laboratory scale preparation of Caro's acid involve the combination of chlorosulfuric acid and hydrogen peroxide.
H₂O₂ + ClSO₂OH → H₂SO₅ + HCl
Large scale production of Caro's acid is usually done on site, due to its instability. According to the patent by Martin, Caro's acid is produced by reacting >85% sulfuric acid and >50% hydrogen peroxide ("Piranha solution").
H₂O₂ + H₂SO₄ → H₂SO₅ + H₂O

Peroxymonosulfuric Acid Specification

Peroxymonosulfuric Acid (CAS NO.7722-86-3) is H₂SO₅, a liquid at room temperature. In this acid, the S(VI) center adopts its characteristic tetrahedral geometry; the connectivity is indicated by the formula HO-O-S(O)₂-OH. It is sometimes confused with H₂S₂O₈, known as peroxydisulfuric acid. The disulfuric acid, which appears to be more widely used as its alkali metal salts, has the structure HO-S(O)₂-O-O-S(O)₂-OH. As with all strong oxidizing agents, Peroxymonosulfuric Acid should be kept away from organic compounds such as ethers and ketones because of its ability to peroxidize the compound, creating a highly unstable molecule such as acetone peroxide.

Product Name

peroxomonosulphuric acid

Synthetic route

Peroxymonosulfuric Acid Chemical Properties

Peroxymonosulfuric Acid History

Peroxymonosulfuric Acid Uses

Peroxymonosulfuric Acid Safety Profile

Peroxymonosulfuric Acid Analytical Methods

Peroxymonosulfuric Acid Specification

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