Product Name

  • Name

    Potassium oleate

  • EINECS 205-590-5
  • CAS No. 143-18-0
  • Article Data7
  • CAS DataBase
  • Density >1.1 g/cm3
  • Solubility Soluble in water
  • Melting Point 235 - 240oC
  • Formula C18H33KO2
  • Boiling Point 360 °C at 760 mmHg
  • Molecular Weight 320.557
  • Flash Point 270.1 °C
  • Transport Information
  • Appearance brown solid or clear to amber liquid
  • Safety 26-36
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 143-18-0 (Potassium oleate)
  • Hazard Symbols IrritantXi
  • Synonyms 9-Octadecenoicacid (9Z)-, potassium salt (9CI);9-Octadecenoic acid (Z)-, potassium salt;Oleic acid, potassium salt (8CI);Century 1005;FR 14;FR 14(emulsifier);Nonsoul OK 1;Norfox KO;OS Soap;Potassium cis-9-octadecenoate;Potassium cis-9-octadecenoic acid;9-Octadecenoicacid (9Z)-, potassium salt (1:1);Trenamine D 200;TrenamineD 201;
  • PSA 40.13000
  • LogP 4.77380

Synthetic route

diethyl ether
60-29-7

diethyl ether

chloroform
67-66-3

chloroform

oleic acid ; compound of potassium oleate with oleic acid

oleic acid ; compound of potassium oleate with oleic acid

A

cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

B

potassium oleate
143-18-0

potassium oleate

cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

potassium oleate
143-18-0

potassium oleate

Conditions
ConditionsYield
With potassium hydroxide In methanol
With potassium hydroxide at 80℃; pH=10.4;
With potassium hydroxide In methanol at 65℃; for 0.000833333h; Industrial scale;
With potassium acetate at 80℃; for 0.5h;
potassium oleate
143-18-0

potassium oleate

allyl bromide
106-95-6

allyl bromide

Conditions
ConditionsYield
tetrabutylammomium bromide In dichloromethane at 20 - 22℃; for 40h;79%
2,2,2-trichloroethyl (2-(tert-butylcarbamoyl)phenyl)sulfamate

2,2,2-trichloroethyl (2-(tert-butylcarbamoyl)phenyl)sulfamate

potassium oleate
143-18-0

potassium oleate

N-(tert-butyl)-2-oleamidobenzamide

N-(tert-butyl)-2-oleamidobenzamide

Conditions
ConditionsYield
In chlorobenzene at 120℃; for 10h;64%
butyl chloroacetate
590-02-3

butyl chloroacetate

potassium oleate
143-18-0

potassium oleate

oleoyloxy-acetic acid butyl ester

oleoyloxy-acetic acid butyl ester

Conditions
ConditionsYield
With xylene at 170℃;
Methyl 2-bromopropionate
5445-17-0

Methyl 2-bromopropionate

potassium oleate
143-18-0

potassium oleate

2-oleoyloxy-propionic acid methyl ester

2-oleoyloxy-propionic acid methyl ester

Conditions
ConditionsYield
With xylene at 170℃;
1-bromo-hexane
111-25-1

1-bromo-hexane

potassium oleate
143-18-0

potassium oleate

cis-9-octadecenoic acid hexyl ester
20290-84-0

cis-9-octadecenoic acid hexyl ester

Conditions
ConditionsYield
With ethanol
n-butyl α-chloropropionate
54819-86-2

n-butyl α-chloropropionate

potassium oleate
143-18-0

potassium oleate

2-oleoyloxy-propionic acid butyl ester

2-oleoyloxy-propionic acid butyl ester

Conditions
ConditionsYield
With xylene at 170℃;
potassium oleate
143-18-0

potassium oleate

9-hydroxy-10-oxooctadecanoic acid
13985-41-6

9-hydroxy-10-oxooctadecanoic acid

Conditions
ConditionsYield
With potassium permanganate
potassium oleate
143-18-0

potassium oleate

(+/-)-threo-9-chloro-10-hydroxy-octadecanoic acid
2632-61-3, 13985-22-3, 13985-23-4

(+/-)-threo-9-chloro-10-hydroxy-octadecanoic acid

Conditions
ConditionsYield
With sodium hypochlorite; carbon dioxide; water
potassium oleate
143-18-0

potassium oleate

10-hydroxy-9-oxo-octadecanoic acid
13985-42-7

10-hydroxy-9-oxo-octadecanoic acid

Conditions
ConditionsYield
With potassium permanganate
potassium oleate
143-18-0

potassium oleate

stearic acid
57-11-4

stearic acid

Conditions
ConditionsYield
With colloid; water; hydrogen; palladium
potassium oleate
143-18-0

potassium oleate

methyl chloroacetate
96-34-4

methyl chloroacetate

oleoyloxy-acetic acid methyl ester
74275-78-8

oleoyloxy-acetic acid methyl ester

Conditions
ConditionsYield
With xylene at 170℃;
potassium oleate
143-18-0

potassium oleate

chloroacetic acid ethyl ester
105-39-5

chloroacetic acid ethyl ester

oleoyloxy-acetic acid ethyl ester
36557-00-3

oleoyloxy-acetic acid ethyl ester

Conditions
ConditionsYield
With xylene at 170℃;
potassium oleate
143-18-0

potassium oleate

Ethyl 2-bromopropionate
535-11-5, 41978-69-2

Ethyl 2-bromopropionate

2-oleoyloxy-propionic acid ethyl ester

2-oleoyloxy-propionic acid ethyl ester

Conditions
ConditionsYield
With xylene at 170℃;
potassium oleate
143-18-0

potassium oleate

ethyl iodide
75-03-6

ethyl iodide

oleic acid ethyl ester
111-62-6

oleic acid ethyl ester

Conditions
ConditionsYield
In water; acetone for 16h; Heating;
potassium oleate
143-18-0

potassium oleate

A

stearic acid
57-11-4

stearic acid

B

hydrazine stearate

hydrazine stearate

Conditions
ConditionsYield
With hydrazine hydrate
potassium oleate
143-18-0

potassium oleate

γ-chloro-propenylene glycol

γ-chloro-propenylene glycol

9-octadecenoic acid-2′,3′-dihydroxy propyl ester
251983-54-7

9-octadecenoic acid-2′,3′-dihydroxy propyl ester

Conditions
ConditionsYield
With carbonic-acid at 180℃; α monooleate of glycerol;
potassium oleate
143-18-0

potassium oleate

NaOCl

NaOCl

water

water

CO2

CO2

A

(+-)-threo-10-chloro-9-hydroxy-stearic acid

(+-)-threo-10-chloro-9-hydroxy-stearic acid

B

(+-)-threo-9-chloro-10-hydroxy-stearic acid

(+-)-threo-9-chloro-10-hydroxy-stearic acid

potassium oleate
143-18-0

potassium oleate

KMnO4

KMnO4

A

9-hydroxy-10-oxooctadecanoic acid
13985-41-6

9-hydroxy-10-oxooctadecanoic acid

C

10-hydroxy-9-oxo-octadecanoic acid
13985-42-7

10-hydroxy-9-oxo-octadecanoic acid

Conditions
ConditionsYield
at 8℃; in neutraler Loesung;
potassium oleate
143-18-0

potassium oleate

hydrogen

hydrogen

water

water

palladium

palladium

stearic acid
57-11-4

stearic acid

Conditions
ConditionsYield
at 25℃;
potassium oleate
143-18-0

potassium oleate

aqueous alkali

aqueous alkali

oxygen

oxygen

A

1,10-decanedioic acid
111-20-6

1,10-decanedioic acid

B

erythro-9,10-dihydroxy-octadecanoic acid (?)

erythro-9,10-dihydroxy-octadecanoic acid (?)

Conditions
ConditionsYield
at 120 - 130℃; under 73550.8 Torr; und Isomerisierung;
potassium oleate
143-18-0

potassium oleate

water

water

potassium hydroxide

potassium hydroxide

Conditions
ConditionsYield
Hydrolysis;
ethanol
64-17-5

ethanol

potassium oleate
143-18-0

potassium oleate

tetratriacontadiene-(9.25)

tetratriacontadiene-(9.25)

Conditions
ConditionsYield
Electrolysis;
potassium oleate
143-18-0

potassium oleate

aluminium salt

aluminium salt

oleic acid ; aluminium dioleate

oleic acid ; aluminium dioleate

potassium oleate
143-18-0

potassium oleate

CaCl2

CaCl2

(π-CH3CHCHCH2NiCl)2

(π-CH3CHCHCH2NiCl)2

potassium oleate
143-18-0

potassium oleate

2(CH3CHCHCH2)(1-)*2Ni(2+)*2(C17H33CO2)(1-)=(CH3CHCHCH2NiO2CC17H33)2

2(CH3CHCHCH2)(1-)*2Ni(2+)*2(C17H33CO2)(1-)=(CH3CHCHCH2NiO2CC17H33)2

Conditions
ConditionsYield
In benzene excess of KO2CC17H33;70-72
In benzene excess of KO2CC17H33;70-72
yttrium(III) nitrate
13494-98-9

yttrium(III) nitrate

potassium oleate
143-18-0

potassium oleate

yttrium oleate

yttrium oleate

Conditions
ConditionsYield
In water direct metathesis of potassium oleate with slight excess of aq. soln. of yttrium nitrate at 50-55°C, pptn.; ppt. washed (distd. water, acetone);

Potassium oleate Chemical Properties

Molecule structure of Potassium oleate (CAS NO.143-18-0):

IUPAC Name: Potassium (Z)-octadec-9-enoate 
Molecular Weight: 320.55172 g/mol
Molecular Formula: C18H33KO2 
Flash Point: 270.1 °C
Enthalpy of Vaporization: 66.53 kJ/mol
Boiling Point: 360 °C at 760 mmHg
Vapour Pressure: 3.7E-06 mmHg at 25 °C
H-Bond Acceptor: 2
Rotatable Bond Count: 15
Exact Mass: 320.211762
MonoIsotopic Mass: 320.211762
Topological Polar Surface Area: 40.1
Heavy Atom Count: 21
Canonical SMILES: CCCCCCCCC=CCCCCCCCC(=O)[O-].[K+]
Isomeric SMILES: CCCCCCCC/C=C\CCCCCCCC(=O)[O-].[K+]
InChI: InChI=1S/C18H34O2.K/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18(19)20;/h9-10H,2-8,11-17H2,1H3,(H,19,20);/q;+1/p-1/b10-9-;
InChIKey: MLICVSDCCDDWMD-KVVVOXFISA-M
EINECS: 205-590-5
Product Categories: Classes of Metal Compounds; K (Potassium) Compounds (excluding simple potassium salts); Typical Metal Compounds

Potassium oleate Uses

 Potassium oleate (CAS NO.143-18-0) is a potassium type catalyst which is widely used in poly-isocyanate bubble reaction.

Potassium oleate Toxicity Data With Reference

1.    

eye-rbt 12 mg/48H

   

JANCA2    Journal of the Association of Official Analytical Chemists. 56 (1973),905.

Potassium oleate Consensus Reports

Reported in EPA TSCA Inventory.

Potassium oleate Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing.
WGK Germany: 1
RTECS: RK1150000
An eye irritant. When heated to decomposition it emits toxic fumes of K2O.

Potassium oleate Specification

 Potassium oleate (CAS NO.143-18-0) is also named as 9-Octadecenoic acid (Z)-, potassium salt ; Caswell No. 698B ; EPA Pesticide Chemical Code 079095 ; HSDB 5643 ; Oleic acid, potassium salt ; Potassium 9-octadecenoate, (Z)- ; Potassium cis-9-octadecenoate ; Potassium cis-9-octadecenoic acid ; Trenamine D-200 ; Trenamine D-201 ; UNII-74WHF607EU . Potassium oleate (CAS NO.143-18-0) is brown solid or clear to amber liquid with a soapy odor. It can sinks and mix slowly with water. Salts, basic, such as Potassium oleate , generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Inhalation of dust causes irritation of nose and throat, coughing, and sneezing. Ingestion causes mild irritation of mouth and stomach. Contact with eyes causes irritation. Irritating vapors and toxic gases, such as carbon dioxide and carbon monoxide, may be formed when involved in fire.

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