Product Name

  • Name

    1,1,2,2-Tetrach loroethylene

  • EINECS 204-825-9
  • CAS No. 127-18-4
  • Article Data322
  • CAS DataBase
  • Density 1.653 g/cm3
  • Solubility 0.015 g/100 mL (20 °C) in water
  • Melting Point -22 °C
  • Formula C2Cl4
  • Boiling Point 119.1 °C at 760 mmHg
  • Molecular Weight 165.834
  • Flash Point 27.4 °C
  • Transport Information UN 1897 6.1/PG 3
  • Appearance colourless liquid with ether-like odour
  • Safety 23-36/37-61-45-24-16-7
  • Risk Codes 40-51/53-23/25-11-39/23/24/25-23/24/25
  • Molecular Structure Molecular Structure of 127-18-4 (1,1,2,2-Tetrach loroethylene)
  • Hazard Symbols HarmfulXn,DangerousN,ToxicT,FlammableF
  • Synonyms Ethene,tetrachloro- (9CI);Ethylene, tetrachloro- (8CI);1,1,2,2-Tetrachloroethene;Ankilostin;Antisal 1;Asahi Perchlor;Didakene;Dilatin PT;Ethylene tetrachloride;F 1110;F 1110 (halocarbon);Fedal-Un;Freon 1110;NSC 9777;Nema;PCE;PCE (chlorohydrocarbon);PerSec;Perchlorethylene;Perchloroethylene;Perclene;Perklone;PersaP 3;R 1110;Tetlen;Tetracap;Tetraguer;Tetraleno;Tetropil;
  • PSA 0.00000
  • LogP 3.06820

Synthetic route

N-(2,2,2-trichloroethylidene)benzenesulfonamide
55596-11-7

N-(2,2,2-trichloroethylidene)benzenesulfonamide

complex of sulfur dioxide with dimethylamine
21326-49-8

complex of sulfur dioxide with dimethylamine

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

chloroform
67-66-3

chloroform

C

N,N-dimethyl-N′-(phenylsulfonyl)formimidamide
13707-43-2

N,N-dimethyl-N′-(phenylsulfonyl)formimidamide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 24h;A n/a
B n/a
C 98%
N-(2,2,2-trichloroethylidene)benzenesulfonamide
55596-11-7

N-(2,2,2-trichloroethylidene)benzenesulfonamide

diethylamine
109-89-7

diethylamine

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

chloroform
67-66-3

chloroform

C

N1,N1-diethyl-N2-phenylsulfonylformamidine
29665-24-5

N1,N1-diethyl-N2-phenylsulfonylformamidine

Conditions
ConditionsYield
In dichloromethane at 0℃; for 24h;A n/a
B n/a
C 98%
hexachloroethane
67-72-1

hexachloroethane

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
In tetrachloromethane at 300℃; for 0.000555556h; Temperature; Flow reactor; Pyrolysis;97%
at 600℃;
With pyrographite at 700℃;
Hexachlorobutadiene
87-68-3

Hexachlorobutadiene

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
With aluminum (III) chloride; chlorine at 280 - 750℃; Temperature;95%
N-(2,2,2-trichloroethylidene)benzenesulfonamide
55596-11-7

N-(2,2,2-trichloroethylidene)benzenesulfonamide

dimethyl amine
124-40-3

dimethyl amine

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

chloroform
67-66-3

chloroform

C

N,N-dimethyl-N′-(phenylsulfonyl)formimidamide
13707-43-2

N,N-dimethyl-N′-(phenylsulfonyl)formimidamide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 24h;A n/a
B n/a
C 92%
N-(2,2,2-trichloroethylidene)benzenesulfonamide
55596-11-7

N-(2,2,2-trichloroethylidene)benzenesulfonamide

complex of sulfur dioxide with dimethylamine
21326-49-8

complex of sulfur dioxide with dimethylamine

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

chloroform
67-66-3

chloroform

C

N-Phenylsulfonyl-N,N'-dimethylformamidine hydrochloride

N-Phenylsulfonyl-N,N'-dimethylformamidine hydrochloride

Conditions
ConditionsYield
In Trichloroethylene at 20℃; for 24h;A n/a
B n/a
C 89%
octachloro-cyclobutane
7294-43-1

octachloro-cyclobutane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

Hexachlorobutadiene
87-68-3

Hexachlorobutadiene

C

hexachlorocyclobutene
6130-82-1

hexachlorocyclobutene

Conditions
ConditionsYield
at 506℃; Product distribution;A 0.3%
B 86%
C 1.2%
tetrachloromethane
56-23-5

tetrachloromethane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

methane
34557-54-5

methane

C

chloroform
67-66-3

chloroform

D

carbon monoxide
201230-82-2

carbon monoxide

Conditions
ConditionsYield
With iron(II,III) oxide; sodium chloride at 25℃; pH=8.9; Kinetics;A 0.01%
B 1%
C 5.2%
D 82%
With hydroxysulfate green rust In water at 20℃; for 575h; pH=7.6; Product distribution;
pentachloroethane
76-01-7

pentachloroethane

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
With methyl diethylphosphinate at 150℃; for 10h;75%
With chlorine at 379.84℃; Gas phase; chemoselective reaction;33.8%
With nickel dichloride at 330℃;
1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

Trichloroethylene
79-01-6

Trichloroethylene

Conditions
ConditionsYield
With hydrogenchloride; oxygen at 379.84℃; for 18h;A 20.8%
B 64.3%
With CuCl2/KCl/attapulgite; chlorine at 379.84℃; Gas phase; chemoselective reaction;A 16.6%
B 45%
1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

Trichloroethylene
79-01-6

Trichloroethylene

C

pentachloroethane
76-01-7

pentachloroethane

Conditions
ConditionsYield
With hydrogenchloride; oxygen at 379.84℃;A 20.8%
B 64.3%
C 6.1%
N,N-Dichlorobenzenesulfonamide
473-29-0

N,N-Dichlorobenzenesulfonamide

1,2-Dichloroethylene
540-59-0

1,2-Dichloroethylene

A

benzenesulfonamide
98-10-2

benzenesulfonamide

B

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

C

Trichloroethylene
79-01-6

Trichloroethylene

D

N-(2,2,2-trichloroethylidene)benzenesulfonamide
55596-11-7

N-(2,2,2-trichloroethylidene)benzenesulfonamide

E

N-(2,2-dichloroethylidene)benzenesulfonamide
113791-97-2

N-(2,2-dichloroethylidene)benzenesulfonamide

F

N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide
79054-58-3

N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide

Conditions
ConditionsYield
at 55℃; for 22h; Product distribution; other time, other temperature, other initiator;A n/a
B n/a
C n/a
D n/a
E n/a
F 54.1%
N,N-Dichlorobenzenesulfonamide
473-29-0

N,N-Dichlorobenzenesulfonamide

1,2-Dichloroethylene
540-59-0

1,2-Dichloroethylene

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

Trichloroethylene
79-01-6

Trichloroethylene

C

N-(2,2,2-trichloroethylidene)benzenesulfonamide
55596-11-7

N-(2,2,2-trichloroethylidene)benzenesulfonamide

D

N-(2,2-dichloroethylidene)benzenesulfonamide
113791-97-2

N-(2,2-dichloroethylidene)benzenesulfonamide

E

N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide
79054-58-3

N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide

F

1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
at 55℃; for 22h; Product distribution; other time, other temperature, other initiator;A n/a
B n/a
C n/a
D n/a
E 54.1%
F n/a
hexachloroethane
67-72-1

hexachloroethane

Ce(3+)*3C4H14NSi2(1-)*2C4H8O

Ce(3+)*3C4H14NSi2(1-)*2C4H8O

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

tetramethyldisilazane

tetramethyldisilazane

Conditions
ConditionsYield
In toluene for 18h; Reagent/catalyst; Solvent; Time; Inert atmosphere;A n/a
B 45%
1,2-Dichloroethylene
540-59-0

1,2-Dichloroethylene

N,N-dichloro-4-chlorobenzenesulfonamide
17260-65-0

N,N-dichloro-4-chlorobenzenesulfonamide

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

4-Chlorobenzenesulfonamide
98-64-6

4-Chlorobenzenesulfonamide

C

N-(2,2,2-trichloroethylidene)-4-chlorobenzenesulfonamide
81924-15-4

N-(2,2,2-trichloroethylidene)-4-chlorobenzenesulfonamide

D

N-(2,2-dichloroethylidene)-p-chlorobenzenesulfonamide
113791-98-3

N-(2,2-dichloroethylidene)-p-chlorobenzenesulfonamide

E

N-<2,2-dichloro-1-(N-p-chlorobenzenesulfonamido)ethyl>-p-chlorobenzenesulfonamide
113792-01-1

N-<2,2-dichloro-1-(N-p-chlorobenzenesulfonamido)ethyl>-p-chlorobenzenesulfonamide

F

1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
at 55℃; for 22h; Product distribution; other time, other temperature, other initiator;A n/a
B n/a
C n/a
D n/a
E 40.4%
F n/a
(2,2-dichloro-vinyl)-trimethyl-silane
18163-67-2

(2,2-dichloro-vinyl)-trimethyl-silane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

Trichloroethylene
79-01-6

Trichloroethylene

C

Trimethyl-(1,2,2,2-tetrachloro-ethyl)-silane

Trimethyl-(1,2,2,2-tetrachloro-ethyl)-silane

D

Chloromethyl-dimethyl-(1,2,2,2-tetrachloro-ethyl)-silane

Chloromethyl-dimethyl-(1,2,2,2-tetrachloro-ethyl)-silane

Conditions
ConditionsYield
With chlorine for 3h; Further byproducts given;A 1%
B 5%
C 30%
D 33%
With chlorine for 3h; Further byproducts given;A 1%
B 7%
C 30%
D 33%
Trichloroethylene
79-01-6

Trichloroethylene

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

pentachloroethane
76-01-7

pentachloroethane

Conditions
ConditionsYield
With chlorine at 379.84℃; Reagent/catalyst; Temperature;A 8.1%
B 11.2%
tetrachloromethane
56-23-5

tetrachloromethane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

hexachloroethane
67-72-1

hexachloroethane

Conditions
ConditionsYield
at 580℃; for 0.00433333h; Rate constant; Mechanism; several condition investigated;A 10.18%
B 2.51%
at 394.5 - 445.3℃; under 83.3 - 161.6 Torr; Kinetics; Equilibrium constant; Thermodynamic data; eq. const. at 696.6 K; ΔH at 298 K;
at 600 - 1500℃;
pentacarbonyl(methoxyphenylmethylene)tungsten(0)
37823-96-4

pentacarbonyl(methoxyphenylmethylene)tungsten(0)

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

methylene chloride
74-87-3

methylene chloride

C

dichloromethane
75-09-2

dichloromethane

D

chloroform
67-66-3

chloroform

Conditions
ConditionsYield
In tetrachloromethane byproducts: HCl, Cl2; further products; N2; stirred; gas-chromy., MAS; elem. anal.;A 6.8%
B 2%
C 0.2%
D 3.6%
piperidine
110-89-4

piperidine

tetrachloromethane
56-23-5

tetrachloromethane

pentachloroethane
76-01-7

pentachloroethane

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
at 20℃;
tetrachloromethane
56-23-5

tetrachloromethane

Isobutane
75-28-5

Isobutane

hexachloroethane
67-72-1

hexachloroethane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

tertiary butyl chloride
507-20-0

tertiary butyl chloride

Conditions
ConditionsYield
at 140℃;
tetrachloromethane
56-23-5

tetrachloromethane

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
Beim Durchleiten durch ein rotgluehendes Rohr;
at 1300 - 1400℃;
With hydrogen
tetrachloromethane
56-23-5

tetrachloromethane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

hexachlorobenzene
118-74-1

hexachlorobenzene

Conditions
ConditionsYield
at 700℃;
propene
187737-37-7

propene

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
With tetrachloromethane; chlorine at 800℃;
diethyl ether
60-29-7

diethyl ether

hexachloroethane
67-72-1

hexachloroethane

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

1,1,1,2-tetrachoroethane
630-20-6

1,1,1,2-tetrachoroethane

C

pentachloroethane
76-01-7

pentachloroethane

D

1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

diethyl ether
60-29-7

diethyl ether

hexachloroethane
67-72-1

hexachloroethane

sodium ethanolate
141-52-6

sodium ethanolate

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
at 140℃;
diethyl ether
60-29-7

diethyl ether

hexachloroethane
67-72-1

hexachloroethane

phenylmagnesium bromide

phenylmagnesium bromide

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

1,1,1,2-tetrachoroethane
630-20-6

1,1,1,2-tetrachoroethane

C

pentachloroethane
76-01-7

pentachloroethane

D

1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

1,1-dichloroethane
75-34-3

1,1-dichloroethane

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
With chlorine; pyrographite at 450℃;
pentachloropropionyl chloride
812-25-9

pentachloropropionyl chloride

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

hexachloroethane
67-72-1

hexachloroethane

Conditions
ConditionsYield
With aluminium trichloride at 60℃;
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

hypofluorous acid trifluoromethyl ester
373-91-1

hypofluorous acid trifluoromethyl ester

1,1,2,2-tetrachloro-1-fluoro-2-trifluoromethoxyethane
136649-69-9

1,1,2,2-tetrachloro-1-fluoro-2-trifluoromethoxyethane

Conditions
ConditionsYield
at 40.6℃;99.5%
at 160 - 195℃; under 750.075 Torr; for 31h;84.3%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

5-methyl-1H-2-benzothiopyran-1-one
681141-90-2

5-methyl-1H-2-benzothiopyran-1-one

2aα,8bα-1,1,2,2-tetrachloro-2,2a-dihydro-8-methyl-1H-cyclobuta[c][2]benzothiopyran-4-one

2aα,8bα-1,1,2,2-tetrachloro-2,2a-dihydro-8-methyl-1H-cyclobuta[c][2]benzothiopyran-4-one

Conditions
ConditionsYield
In acetonitrile for 12h; Irradiation;97%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Pd(CN(2,6-(2,6-(i-Pr)2C6H3)2C6H3))2
1182649-23-5

Pd(CN(2,6-(2,6-(i-Pr)2C6H3)2C6H3))2

Pd(η2-C2Cl4)(CN(2,6-(2,6-(i-Pr)2C6H3)2C6H3))2

Pd(η2-C2Cl4)(CN(2,6-(2,6-(i-Pr)2C6H3)2C6H3))2

Conditions
ConditionsYield
In toluene; pentane for 0.25h; Inert atmosphere; Schlenk technique; Glovebox;97%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

A

1,1,1-trifluoro-2,2-dichloroethane
306-83-2

1,1,1-trifluoro-2,2-dichloroethane

B

1,1,2-trichloro-2,2-difluoroethane
354-21-2

1,1,2-trichloro-2,2-difluoroethane

C

freon-121
354-14-3

freon-121

D

1,1,1,2-tetrafluoro-2-chloroethane
2837-89-0

1,1,1,2-tetrafluoro-2-chloroethane

Conditions
ConditionsYield
With hydrogen fluoride; antimony(III) fluoride; antimony pentafluoride at 125 - 139℃; under 16351.6 - 18376.8 Torr; for 3.7h;A 92.4%
B 0.9%
C 0.01%
D 0.4%
With hydrogen fluoride; antimony(III) fluoride; antimony pentafluoride at 122 - 140℃; under 17926.8 - 20252 Torr; for 3.6h;A 89.8%
B 0.3%
C 0.08%
D 3.1%
With hydrogen fluoride; antimony(III) fluoride; antimony pentafluoride at 124 - 140℃; under 18001.8 - 19201.9 Torr; for 3.1h;A 87.2%
B 1.1%
C 0.01%
D 0.5%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

copper hydroxide
20427-59-2

copper hydroxide

Trimethylenediamine
109-76-2

Trimethylenediamine

Cu2(C10H16N4Cl4)(H2O)4(4+)*4Cl(1-)*8H2O = [Cu2(C10H16N4Cl4)(H2O)4]Cl4*8H2O

Cu2(C10H16N4Cl4)(H2O)4(4+)*4Cl(1-)*8H2O = [Cu2(C10H16N4Cl4)(H2O)4]Cl4*8H2O

Conditions
ConditionsYield
In water; butan-1-ol refluxing in butanol (10 h), extraction (water); pptn. from aq. phase (concn., cooling); elem. anal.;92%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

(E)-tert-butyldimethyl[3-(tributylstannyl)prop-2-enyloxy]silane
90838-72-5, 110410-38-3, 134435-95-3, 86633-16-1, 81925-28-2, 86646-19-7

(E)-tert-butyldimethyl[3-(tributylstannyl)prop-2-enyloxy]silane

(6E,10E)-8,9-Bis((E)-3-((tert-butyldimethylsilyl)oxy)prop-1-en-1-yl)-2,2,3,3,14,14,15,15-octamethyl-4,13-dioxa-3,14-disilahexadeca-6,8,10-triene
1638292-74-6

(6E,10E)-8,9-Bis((E)-3-((tert-butyldimethylsilyl)oxy)prop-1-en-1-yl)-2,2,3,3,14,14,15,15-octamethyl-4,13-dioxa-3,14-disilahexadeca-6,8,10-triene

Conditions
ConditionsYield
With palladium diacetate; XPhos at 60℃; Stille Cross Coupling; Inert atmosphere;90%
With palladium diacetate; XPhos at 60℃; Stille Cross Coupling; Inert atmosphere;90%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

tributyl[(E)-2-trimethylsilylethenyl]stannane
58207-97-9

tributyl[(E)-2-trimethylsilylethenyl]stannane

((1E,5E)-3,4-bis((E)-2-(trimethylsilyl)vinyl)hexa-1,3,5-triene-1,6-diyl)bis(trimethylsilane)
1638178-58-1

((1E,5E)-3,4-bis((E)-2-(trimethylsilyl)vinyl)hexa-1,3,5-triene-1,6-diyl)bis(trimethylsilane)

Conditions
ConditionsYield
With palladium diacetate; XPhos at 60℃; Stille Cross Coupling; Inert atmosphere;89%
With palladium diacetate; XPhos at 60℃; Stille Cross Coupling; Inert atmosphere;89%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

sodium isopropanethiolate
20607-43-6

sodium isopropanethiolate

tetrakis-isopropylsulfanyl-ethene
39137-72-9

tetrakis-isopropylsulfanyl-ethene

Conditions
ConditionsYield
In N,N,N,N,N,N-hexamethylphosphoric triamide for 1h; Ambient temperature;85%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

hypofluorous acid trifluoromethyl ester
373-91-1

hypofluorous acid trifluoromethyl ester

A

CFC-112a
76-12-0

CFC-112a

B

dichloro-fluoro-acetyl chloride
354-17-6

dichloro-fluoro-acetyl chloride

C

1,1,2,2-tetrachloro-1-fluoro-2-trifluoromethoxyethane
136649-69-9

1,1,2,2-tetrachloro-1-fluoro-2-trifluoromethoxyethane

D

Trichloroacetyl chloride
76-02-8

Trichloroacetyl chloride

E

Dichloro-trifluoromethoxy-acetyl chloride

Dichloro-trifluoromethoxy-acetyl chloride

F

COCl2

COCl2

Conditions
ConditionsYield
With oxygen at 40.9℃; under 420.8 Torr; for 1.97833h; Product distribution; Mechanism; Rate constant; var. of partial pressure, temp.;A n/a
B n/a
C n/a
D 85%
E n/a
F n/a
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

fac-tricarbonyl(bis(diphenylphosphino)ethane)(η1-methyldithiobenzoate)tungsten
118050-71-8, 118050-81-0

fac-tricarbonyl(bis(diphenylphosphino)ethane)(η1-methyldithiobenzoate)tungsten

mer-tricarbonyl(bis(diphenylphosphino)ethane)(η2-methyldithiobenzoate)tungsten * tetrachloroethene

mer-tricarbonyl(bis(diphenylphosphino)ethane)(η2-methyldithiobenzoate)tungsten * tetrachloroethene

Conditions
ConditionsYield
In tetrahydrofuran isomerization in THF within about 48 h;; concn.; pptn. with tetrachloroethene; elem. anal.;;85%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

tetrabutyl-ammonium chloride
1112-67-0

tetrabutyl-ammonium chloride

C2Cl12Si4(2-)*2C16H36N(1+)

C2Cl12Si4(2-)*2C16H36N(1+)

Conditions
ConditionsYield
With hexachlorodisilane In dichloromethane at -10 - 20℃; for 12h; Inert atmosphere;85%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Octanethiol
111-88-6

Octanethiol

A

Octyl-<1.2.2-trichlor-vinyl>-sulfid
36061-42-4

Octyl-<1.2.2-trichlor-vinyl>-sulfid

B

1-((E)-1,2-Dichloro-2-octylsulfanyl-vinylsulfanyl)-octane
130920-00-2

1-((E)-1,2-Dichloro-2-octylsulfanyl-vinylsulfanyl)-octane

Conditions
ConditionsYield
With potassium hydroxide In ethanol; N,N-dimethyl-formamide at 60 - 70℃;A n/a
B 83%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

diamantane-3-spiro-3'-diazirine
105522-49-4

diamantane-3-spiro-3'-diazirine

3-chlorodiamantane
30651-01-5

3-chlorodiamantane

Conditions
ConditionsYield
Irradiation;83%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

A

1,1,1-trifluoro-2,2-dichloroethane
306-83-2

1,1,1-trifluoro-2,2-dichloroethane

B

1,1,2-trichloro-2,2-difluoroethane
354-21-2

1,1,2-trichloro-2,2-difluoroethane

C

1,1,1,2-tetrafluoro-2-chloroethane
2837-89-0

1,1,1,2-tetrafluoro-2-chloroethane

Conditions
ConditionsYield
With hydrogen fluoride; antimony(III) fluoride; antimony pentafluoride at 129 - 143℃; under 17626.8 - 19502 Torr; for 4.1h;A 80.5%
B 0.3%
C 5.1%
With hydrogen fluoride; antimony pentafluoride at 135 - 143℃; under 18751.9 Torr; for 2.7h;A 26%
B 0.6%
C 25.8%

Tetrachloroethylene Specification

The IUPAC name of Perchlorethylene is 1,1,2,2-tetrachloroethene. With the CAS registry number 127-18-4, it is also named as Tetrachloroethylene. The product's categories are Organics; Analytical Chemistry; Standard Solution of Volatile Organic Compounds for Water & Soil Analysis; Standard Solutions (VOC). Besides, it is colourless liquid with ether-like odour, which should be stored in a cool, dry, ventilated warehouse at 0-6 °C. It is stable, but incompatible with strong oxidizing agents, alkali metals, aluminium, strong bases. In addition, its molecular formula is C2Cl4 and molecular weight is 165.83.

The other characteristics of this product can be summarized as: (1)EINECS: 204-825-9; (2)ACD/LogP: 2.95; (3)# of Rule of 5 Violations: 0; (4)ACD/LogD (pH 5.5): 2.95; (5)ACD/LogD (pH 7.4): 2.95; (6)ACD/BCF (pH 5.5): 102.96; (7)ACD/BCF (pH 7.4): 102.96; (8)ACD/KOC (pH 5.5): 960.03; (9)ACD/KOC (pH 7.4): 960.03; (10)#H bond acceptors: 0; (11)#H bond donors: 0; (12)#Freely Rotating Bonds: 0; (13)Index of Refraction: 1.519; (14)Molar Refractivity: 30.45 cm3; (15)Molar Volume: 100.3 cm3; (16)Surface Tension: 35.6 dyne/cm; (17)Density: 1.653 g/cm3; (18)Flash Point: 27.4 °C; (19)Melting Point: -22 °C; (20)FreezingPoint: -22.0 °C; (21)Solubility in water: 0.015 g/100 mL (20 °C); (22)Enthalpy of Vaporization: 34.68 kJ/mol; (23)Boiling Point: 119.1 °C at 760 mmHg; (24)Vapour Pressure: 19.3 mmHg at 25 °C.

Preparation of Perchlorethylene: this chemical can be prepared by the reaction of 1,2-Dichloroethane with Chlorine. This reaction can be catalyzed by a mixture of potassium chloride and aluminium chloride at temperature of 400 °C.
ClCH2CH2Cl + 3 Cl2 → Cl2C=CCl2 + 4 HCl

Uses of Perchlorethylene: thos chemical is an excellent solvent for organic materials. It is often used in dry cleaning. And it is also used as a mixture with other chlorocarbons to degrease metal parts in the automotive and other metalworking industries. Additionally, it can be used as paint stripper and spot remover. It has been used for the treatment for hookworm infestation. Furthermore, it can be used as an intermediate in the manufacture of HFC-134a and related refrigerants.

When you are using this chemical, please be cautious about it as the following: it may cause damage to health which is reflected in some aspects. It is toxic by inhalation and if swallowed or in contact with skin, and may even have very serious irreversible effect. Then it has limited evidence of a carcinogenic effect to our health. It is not only harmful to our health but also to our environment. This is dangerous for the environment  for it  may present an immediate or delayed danger to one or more components of the environment; Then it is toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment. What's more, it is highly flammable because it may catch fire in contact with air, only needing brief contact with an ignition source, and it has a very low flash point or evolve highly flammable gases in contact with water.

People can use the following data to convert to the molecule structure.
(1)Canonical SMILES: C(=C(Cl)Cl)(Cl)Cl
(2)InChI: InChI=1S/C2Cl4/c3-1(4)2(5)6
(3)InChIKey: CYTYCFOTNPOANT-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LDLo oral 4gm/kg (4000mg/kg) BEHAVIORAL: SLEEP

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
American Journal of Hygiene. Vol. 9, Pg. 430, 1929.
child TDLo oral 545mg/kg (545mg/kg) BEHAVIORAL: COMA Journal of Toxicology, Clinical Toxicology. Vol. 23, Pg. 103, 1985.
dog LD50 intraperitoneal 2100mg/kg (2100mg/kg) LIVER: LIVER FUNCTION TESTS IMPAIRED Toxicology and Applied Pharmacology. Vol. 10, Pg. 119, 1967.
dog LDLo intravenous 85mg/kg (85mg/kg)   Quarterly Journal of Pharmacy & Pharmacology. Vol. 7, Pg. 205, 1934.
dog LDLo oral 4gm/kg (4000mg/kg) BEHAVIORAL: SLEEP

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
American Journal of Hygiene. Vol. 9, Pg. 430, 1929.
human TCLo inhalation 96ppm/7H (96ppm) PERIPHERAL NERVE AND SENSATION: LOCAL ANESTHETIC

SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE

BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS"
National Technical Information Service. Vol. PB257-185,
man TCLo inhalation 600ppm/10M (600ppm) SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE

BEHAVIORAL: GENERAL ANESTHETIC
AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 5, Pg. 566, 1952.
mouse LC50 inhalation 5200ppm/4H (5200ppm)   Acta Pharmacologica et Toxicologica. Vol. 9, Pg. 303, 1953.
mouse LD intraperitoneal > 500mg/kg (500mg/kg)   "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 4, Pg. 378, 1952.
mouse LD50 oral 8100mg/kg (8100mg/kg) BEHAVIORAL: GENERAL ANESTHETIC National Technical Information Service. Vol. PB257-185,
mouse LD50 subcutaneous 65gm/kg (65000mg/kg) BEHAVIORAL: SLEEP

BEHAVIORAL: ATAXIA
Journal of Pharmacology and Experimental Therapeutics. Vol. 123, Pg. 224, 1958.
rabbit LD skin > 3228mg/kg (3228mg/kg)   National Technical Information Service. Vol. AD-A180-198,
rabbit LDLo oral 5gm/kg (5000mg/kg) BEHAVIORAL: SLEEP

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
American Journal of Hygiene. Vol. 9, Pg. 430, 1929.
rabbit LDLo subcutaneous 2200mg/kg (2200mg/kg)   Quarterly Journal of Pharmacy & Pharmacology. Vol. 7, Pg. 205, 1934.
rat LC50 inhalation 34200mg/m3/8H (34200mg/m3)   American Industrial Hygiene Association Journal. Vol. 20, Pg. 364, 1959.
rat LD50 intraperitoneal 4678mg/kg (4678mg/kg)   Environmental Research. Vol. 40, Pg. 411, 1986.
rat LD50 oral 2629mg/kg (2629mg/kg)   American Industrial Hygiene Association Journal. Vol. 20, Pg. 364, 1959.
rat LDLo intratracheal 450mg/kg (450mg/kg)   National Technical Information Service. Vol. OTS0520615,

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