Triallyl isocyanurate supplier

Name
1,3,5-Tri-2-propenyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione
EINECS 213-834-7
CAS No. 1025-15-6
Article Data38
CAS DataBase
Density 1.15 g/cm³
Solubility > 1 g/L in water at 20 °C
Melting Point 23.5 - 25oC
Formula C₁₂H₁₅N₃O₃
Boiling Point 315.2 °C at 760 mmHg
Molecular Weight 249.269
Flash Point 153.4 °C
Transport Information UN 2811
Appearance colourless viscous liquid or white powder
Safety 36/37/39
Risk Codes 22
Molecular Structure
Hazard Symbols Xn
Synonyms 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione,1,3,5-tri-2-propenyl- (9CI);s-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-triallyl-(8CI);s-Triazine-2,4,6(1H,3H,5H)-trione, triallyl- (6CI,7CI);1,3,5-Tri-2-propenyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione;1,3,5-Triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione;1,3,5-Triallylisocyanurate;1,3,5-Triallylisocyanuric acid;1,3,5-Tris-2'-propenylisocyanuric acid;Drimix TAIC;Isocyanuricacid triallyl ester;NSC11692;Nor-TAIC KS;Perkalink 301;Perkalink 301-50;SR 533;1,3,5-triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-tri-2-propen-1-yl-;
PSA 66.00000
LogP -0.27030

Synthetic route

: 108-80-5
cyanuric acid

: 107-18-6
allyl alcohol

: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With triphenylphosphine In 5,5-dimethyl-1,3-cyclohexadiene at 95℃; for 22h; Reagent/catalyst; Inert atmosphere;	98.6%

: 1476-23-9
allylisocyanate

: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With 1,3-bis(2,6-diisopropylphenyl)dihydroimidazol-2-ylidene at 20℃; for 1h;	98%
With tetraethylammonium 2-(carbamoyl)benzoate at 50℃; for 6h; Neat (no solvent);	95%
With 1,3-dimethyl-4,5-diphenyl-2-(propan-2-ylidene)-2,3-dihydro-1H-imidazole; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 20℃; for 48h; Inert atmosphere; Glovebox;	89%

: 106-95-6
allyl bromide

: 108-80-5
isocyanuric acid

: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
Stage #1: isocyanuric acid With tetrabutylammomium bromide; triethylamine; copper(l) chloride In 1,2-dichloro-ethane at 80℃; Large scale; Stage #2: allyl bromide In 1,2-dichloro-ethane at 80℃; for 6.5h; Temperature; Large scale;	93.2%

: 4873-09-0
allyl tosylate

: 917-61-3
sodium isocyanate

: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With triethylamine In N,N-dimethyl-formamide at 20 - 60℃; for 4.17h; Solvent; Reagent/catalyst; Green chemistry;	93%

: 101-37-1
triallyl cyanurate

A: 2916-14-5
allyl chloroacetate

B: 6294-79-7
1,3-diallyl-[1,3,5]triazinane-2,4,6-trione

C: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With chloroacetic acid In toluene for 2h; Heating; Yields of byproduct given;	A n/a B 91.5% C n/a
With chloroacetic acid In toluene for 2h; Heating; Yield given. Yields of byproduct given;

...Expand

: 542-75-6
E/Z-1,3-Dichloropropene

: 917-61-3
sodium isocyanate

: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With calcium chloride; potassium bromide In N,N-dimethyl-formamide at 120℃;	91%
With calcium chloride; potassium bromide In N,N-dimethyl-formamide at 120℃; Product distribution / selectivity;

: 101-37-1
triallyl cyanurate

: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
copper(II) chloride hydrate In xylene at 120℃; for 2h;	90%
With copper(II) choride dihydrate In 5,5-dimethyl-1,3-cyclohexadiene at 65 - 75℃; Inert atmosphere;	90%
copper dichloride In toluene at 113 - 140℃; under 1.50015 - 2.25023 Torr; Product distribution / selectivity;

: 101-37-1
triallyl cyanurate

A: 591-87-7
Allyl acetate

B: 6294-79-7
1,3-diallyl-[1,3,5]triazinane-2,4,6-trione

C: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With acetic acid In toluene for 2h; Heating; Yields of byproduct given;	A n/a B 85% C n/a
With acetic acid In toluene for 2h; Heating; Yield given. Yields of byproduct given;

...Expand

: 101-37-1
triallyl cyanurate

A: 557-40-4
Allyl ether

B: 6294-79-7
1,3-diallyl-[1,3,5]triazinane-2,4,6-trione

C: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With allyl alcohol In toluene for 2h; Heating; Yields of byproduct given;	A n/a B 81.5% C n/a
With allyl alcohol In toluene for 2h; Heating; Yield given. Yields of byproduct given;

...Expand

: 1,3,5-Triallyl-[1,3,5]triazinane-2,4,6-triylidenetriamine

: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With hydrogenchloride In water for 5h; Heating;	77%

: 108-80-5
cyanuric acid

: 107-18-6
allyl alcohol

A: 6294-79-7
1,3-diallyl-[1,3,5]triazinane-2,4,6-trione

B: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With triphenylphosphine In 5,5-dimethyl-1,3-cyclohexadiene at 95℃; for 8h; Time; Reagent/catalyst; Solvent; Inert atmosphere;	A 13% B 68.1%

...Expand

: 108-80-5
cyanuric acid

: 6728-21-8
allyl mesylate

: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With sodium carbonate; potassium bromide In dimethyl sulfoxide at 65℃; for 1.5h;	68%

: 101-37-1
triallyl cyanurate

: 16715-84-7
2,4,6-tris(methallyloxy)-1,3,5-triazine

A: 1025-15-6
triallyl isocyanurate

B: 118361-38-9
1-(allyl)-3,5-bis(2-methylprop2-en-1-yl)isocyanurate

C: 73669-73-5
1-(2-methylprop-2-en-1-yl)-3,5-bis(3-propenyl)isocyanurate

D: 6291-95-8
tris-2-methylprop-2-en-1-ylisocyanurate

Conditions

Conditions	Yield
With CuCl2.2H2O In toluene for 4h; Heating;	A 18.5% B 31.7% C 40.4% D 9.4%
at 190 - 200℃; for 5h;	A 23.3% B 31.6% C 24% D 21.1%
at 190 - 200℃; for 5h;	A 23.3% B 31.6% C 24% D 21.1%

...Expand

: 590-28-3
potassium cyanate

: 107-05-1
3-chloroprop-1-ene

: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With acetonitrile at 150℃;

: 590-28-3
potassium cyanate

: 107-05-1
3-chloroprop-1-ene

: 75-05-8
acetonitrile

A: 1801-72-5
1,3-diallylurea

B: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
at 150℃;

...Expand

: 108-80-5
cyanuric acid

: 107-05-1
3-chloroprop-1-ene

: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With sodium hydride 1.) HMPA, 100 deg C, 3 h, 2.) HMPA, 100 deg C, 3 h; Yield given. Multistep reaction;

: 1,3,5-Triallyl-[1,3,5]triazinane-2,4-dione

A: 1,3,5-triallyl-6-hydroperoxy-[1,3,5]triazinane-2,4-dione

B: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With oxygen In chlorobenzene at 70℃;

: 108-80-5
cyanuric acid

: 106-95-6
allyl bromide

: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With potassium carbonate In dimethyl sulfoxide at 20 - 80℃;
With magnesium sulfate; potassium carbonate In dimethyl sulfoxide; ethyl acetate

: 917-61-3
sodium isocyanate

: 107-05-1
3-chloroprop-1-ene

: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
With sodium hydrogen sulfate In dimethyl sulfoxide at 95℃; Temperature;

: 3047-33-4
sodium cyanurate

: 106-95-6
allyl bromide

: 1025-15-6
triallyl isocyanurate

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 120 - 125℃; for 6h;	154.6 g

: 4420-74-0
3-(trimethoxysilyl)-1-propanethiol

: 1025-15-6
triallyl isocyanurate

: 1,3,5-tris [3-[[3-(trimethoxysilyl)propyl]thio]propyl]isocyanurate

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) at 110℃; for 5h;	100%

: 1025-15-6
triallyl isocyanurate

: 52434-90-9
1,3,5-tris(β,γ-dibromopropyl)-2,4,6-trioxo-1,3,5-triazine

Conditions

Conditions	Yield
With tetraethylammonium bromide; bromine In dichloromethane at 60℃; for 20h; Reagent/catalyst; Solvent; Temperature;	99.5%

: 1025-15-6
triallyl isocyanurate

: 60-24-2
2-hydroxyethanethiol

: 1,3,5-tris[3-(2-hydroxyethylsulfanyl)propyl]-1,3,5-triazinane-2,4,6-trione

Conditions

Conditions	Yield
With bis(1-methyl-1-phenylethyl)peroxide at 105℃; for 8h; Temperature; Reagent/catalyst; Inert atmosphere; Schlenk technique;	97%

: 1191-08-8
1,4-Butanedithiol

: 1025-15-6
triallyl isocyanurate

: 1,3,5-tris[3-(4-mercaptobutylsulfanyl)propyl]isocyanurate

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) at 70℃; for 4h;	96%

: 998-30-1
Triethoxysilane

: 1025-15-6
triallyl isocyanurate

: C18H31N3O6Si

Conditions

Conditions	Yield
With platinum-containing olefin organic polymer catalyst at 25℃; for 24h;	95%

: 1025-15-6
triallyl isocyanurate

: silver perchlorate

: [Ag(triallyl isocyanurate)(ClO4)]n

Conditions

Conditions	Yield
In acetone	90.4%

: 1025-15-6
triallyl isocyanurate

: 35948-25-5
9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide

: C48H42N3O9P3

Conditions

Conditions	Yield
With dibenzoyl peroxide In 1,4-dioxane at 110℃; under 7500.75 Torr; for 12h; Pressure; Temperature; Solvent; Autoclave; Large scale;	88.5%
In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 10h; Solvent; Temperature;

: 4420-74-0
3-(trimethoxysilyl)-1-propanethiol

: 1025-15-6
triallyl isocyanurate

: C18H31N3O6SSi

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran at 20℃; for 24h; Inert atmosphere; Cooling with ice;	76%

: 240494-25-1
2-mercaptoethyl-3-hydroxy-2-(hydroxymethyl)-2-methylpropanoate

: 1025-15-6
triallyl isocyanurate

: 1228999-35-6
C33H57N3O15S3

Conditions

Conditions	Yield
With 2,2-bis(hydroxymethyl)propionic acid In methanol at 20℃; Inert atmosphere; UV-irradiation;	71%

: 1025-15-6
triallyl isocyanurate

: 507-09-5
thioacetic acid

: 76486-41-4
1,3,5-tris(3-acetylmercaptopropyl)-1,3,5-triazine-2,4,6-trione

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In tetrahydrofuran at 65℃; for 16.5h; Inert atmosphere;	67%
With 2,2'-azobis(isobutyronitrile) In methanol; water

: 1025-15-6
triallyl isocyanurate

: 7787-70-4
copper(I) bromide

: [(triallyl-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione)2hexabromohexacopper(I)](n)

Conditions

Conditions	Yield
In ethanol heated for 3 d at 80-90°C in a sealed tube;	50%

: 1025-15-6
triallyl isocyanurate

: 7787-70-4
copper(I) bromide

: [(triallyl-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione)2tetrabromotetracopper(I)](n)

Conditions

Conditions	Yield
In methanol heated for 3 d at 50-60°C in a sealed tube;	40%

: 1025-15-6
triallyl isocyanurate

: silver nitrate

: [Ag(triallyl isocyanurate)(NO3)]n

Conditions

Conditions	Yield
In water	34%

: 1025-15-6
triallyl isocyanurate

: 1476-23-9
allylisocyanate

Conditions

Conditions	Yield
With hydrogenchloride; toluene dann Erhitzen bis auf 220grad oder beim Behandeln mit Chlorwasserstoff bei 130grad;

Triallyl isocyanurate Specification

The Triallyl isocyanurate, with the CAS registry number 1025-15-6, is also known as 1,3,5-Triallylisocyanurate. It belongs to the product categories of Allyl Monomers; Monomers; Polymer Science. Its EINECS number is 213-834-7. This chemical's molecular formula is C₁₂H₁₅N₃O₃ and molecular weight is 249.27. What's more, its systematic name is 1,3,5-tri(prop-2-en-1-yl)-1,3,5-triazinane-2,4,6-trione. Its classification code is Mutation data. It is stable at common pressure and temperature, and it should be sealed and stored at the temperature of 2 - 8 °C. Moreover, it should be protected from oxides. You should not breathe dust. It is used as an assistant-vulcanizing agent of special rubber and a cross-linking agent of unsaturated polyester fiberglass-reinforced plastics.

Physical properties of Triallyl isocyanurate are: (1)ACD/LogP: -0.43; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.43; (4)ACD/LogD (pH 7.4): -0.43; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 13.87; (8)ACD/KOC (pH 7.4): 13.87; (9)#H bond acceptors: 6; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 6; (12)Polar Surface Area: 60.93 Å²; (13)Index of Refraction: 1.521; (14)Molar Refractivity: 65.98 cm³; (15)Molar Volume: 216.6 cm³; (16)Polarizability: 26.15×10^-24cm³; (17)Surface Tension: 39.4 dyne/cm; (18)Density: 1.15 g/cm³; (19)Flash Point: 153.4 °C; (20)Enthalpy of Vaporization: 55.64 kJ/mol; (21)Boiling Point: 315.2 °C at 760 mmHg; (22)Vapour Pressure: 0.000445 mmHg at 25°C.

Preparation of Triallyl isocyanurate: this chemical can be prepared by 1,3,5-triallyl-[1,3,5]triazinane-2,4,6-triylidenetriamine by heating. This reaction will need reagent conc. HCl and solvent H₂O with the reaction time of 5 hours. The yield is about 77%.

Triallyl isocyanurate can be prepared by 1,3,5-triallyl-[1,3,5]triazinane-2,4,6-triylidenetriamine by heating

You can still convert the following datas into molecular structure:
(1)SMILES: O=C1N(C(=O)N(C(=O)N1C\C=C)C\C=C)C\C=C
(2)Std. InChI: InChI=1S/C12H15N3O3/c1-4-7-13-10(16)14(8-5-2)12(18)15(9-6-3)11(13)17/h4-6H,1-3,7-9H2
(3)Std. InChIKey: KOMNUTZXSVSERR-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD50	oral	1gm/kg (1000mg/kg)		National Technical Information Service. Vol. OTS0536507.

Product Name

1,3,5-Tri-2-propenyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione

Synthetic route

Triallyl isocyanurate Specification

Related Products

Hot Products