• Name

  Trihydroxyboroxine

• EINECS
• CAS No. 13460-51-0
• Article Data23
• CAS DataBase
• Density 1.48 g/cm³
• Solubility
• Melting Point
• Formula H₃B₃O₆
• Boiling Point
• Molecular Weight 131.453
• Flash Point
• Transport Information
• Appearance
• Safety
• Risk Codes
• Molecular Structure
• Hazard Symbols
• Synonyms Metaboricacid (H3B3O6) (6CI);Boroxin, trihydroxy-;Trihydroxyboroxin;
• PSA 88.38000
• LogP -3.01860

Synthetic route

boron trioxide

7732-18-5

water

13460-51-0

metaboric acid

Conditions

Conditions	Yield
In neat (no solvent) reaction in steam at 1061 K;;
In neat (no solvent) Kinetics;
In neat (no solvent) Kinetics;
In neat (no solvent) reaction in steam at 1061 K;;

67-56-1

methanol

121-43-7

Trimethyl borate

11113-50-1

boric acid

A

13460-51-0

metaboric acid

B

102-24-9

cyclotriboric acid trimethyl ester

Conditions

Conditions	Yield
In methanol byproducts: H2O; at 100°C, filtration of metaboric acid;;

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11113-50-1

boric acid

13460-51-0

metaboric acid

Conditions

Conditions	Yield
In toluene azeotropic dehydration with toluene;;
In toluene byproducts: H2O; dehydration in boiling toluene by azeotropic distn.;;
In neat (no solvent) 95-100°C, 24h;;

11113-50-1

boric acid

A

13460-51-0

metaboric acid

B

7732-18-5

water

Conditions

Conditions	Yield
In neat (no solvent) heating to temperatures higher than 100°C;;
In neat (no solvent) heating to temperatures higher than 100°C;;

101-36-0

tri-n-butoxyboroxin

10035-10-6, 12258-64-9

hydrogen bromide

13460-51-0

metaboric acid

Conditions

Conditions	Yield
In neat (no solvent) byproducts: C4H9Br; at 20°C;;
In neat (no solvent) byproducts: C4H9Br; at 20°C;;	0%
In neat (no solvent) byproducts: C4H9Br; at 20°C;;	0%
In neat (no solvent) byproducts: C4H9Br; at 20°C;;

64-19-7

acetic acid

A

13460-51-0

metaboric acid

B

7325-11-3

triethoxyboroxine

C

141-78-6

ethyl acetate

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boron trioxide

7732-18-5

water

A

13460-51-0

metaboric acid

B

11113-50-1

boric acid

Conditions

Conditions	Yield
In water heating mixt. of boron oxide and water overnight to melt; different molar ratios of compds. were used; detected by Raman spectroscopy;

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boron

13460-51-0

metaboric acid

hexaboron monoxide

Conditions

Conditions	Yield
In neat (no solvent) heating to 1900 to 2000°C in vacuum at 0.41 kbar;;

13460-51-0

metaboric acid

13460-50-9

metaboric acid

Conditions

Conditions	Yield
In gaseous matrix Irradiation (UV/VIS); pulsed laser evapn. into an Ar stream condensed at 12 K; detd. by IR;

107-10-8

propylamine

13460-51-0

metaboric acid

92274-41-4

(B(OH)O)2OBOHNH2(n-C3H7)

13460-51-0

metaboric acid

75-36-5

acetyl chloride

126755-89-3

triacetyl boroxine

13460-51-0

metaboric acid

111-86-4

n-Octylamine

(B(OH)O)2OBOHNH2(n-C8H17)

13460-51-0

metaboric acid

13460-50-9

BHO2, cubic

Conditions

Conditions	Yield
In neat (no solvent) heatong to 140°C for a longer period of time;;

13460-51-0

metaboric acid

13460-50-9

BHO2, monoclinic

Conditions

Conditions	Yield
In neat (no solvent) at 130-160°C;;
In neat (no solvent) at 130-160°C;;

13460-51-0

metaboric acid

128-39-2

2,6-di-tert-butylphenol

13086-83-4

tris(2.6-di-t-butyl phenyloxy)boroxin

Conditions

Conditions	Yield
excess borane;;
excess borane;;

13460-51-0

metaboric acid

128-37-0

2,6-di-tert-butyl-4-methyl-phenol

53246-53-0

tris(2.6-t-butyl-4-methyl phenyloxy)boroxine

13460-51-0

metaboric acid

59812-98-5, 101186-18-9, 112711-14-5, 1653-31-2

tridecan-2-ol

36375-52-7

tris(2-tridecyloxy)boroxine

13460-51-0

metaboric acid

497-19-8

sodium carbonate

barium carbonate

sodium barium orthoborate

Conditions

Conditions	Yield
In neat (no solvent, solid phase) at 750℃;

...Expand

13460-51-0

metaboric acid

barium carbonate

A

3BaO*B2O3

B

2.5BaO*B2O3

Conditions

Conditions	Yield
With sodium fluoride In neat (no solvent, solid phase) at 800℃; Time;

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Trihydroxy boroxine Specification