Tris(2-chloroethyl) phosphate supplier

Name
Tris(2-chloroethyl) phosphate
EINECS 204-118-5
CAS No. 115-96-8
Article Data32
CAS DataBase
Density 1.392 g/cm³
Solubility 7 g/L (20 °C ) in water
Melting Point -51 °C
Formula C₆H₁₂Cl₃O₄P
Boiling Point 347.4 °C at 760 mmHg
Molecular Weight 285.492
Flash Point 232.2 °C
Transport Information UN 2810 6.1/PG 3
Appearance odorless clear liquid
Safety 36/37-61
Risk Codes 22-40-51/53
Molecular Structure
Hazard Symbols Xn,N
Synonyms 3CF;AmgardTCEP;CEF;Celluflex CEF;Disflamoll TCA;Fyrol CEF;Fyrol CF;Genomoll P;NSC 3213;Niax 3CF;Niax Flame Retardant 3CF;Tri(chloroethyl) phosphate;Tri(b-chloroethyl) phosphate;Tris(2-chloroethyl)orthophosphate;
PSA 54.57000
LogP 2.86070

Synthetic route

: 75-21-8
oxirane

: 115-96-8
Tris(2-chloroethyl) phosphate

Conditions

Conditions	Yield
With trichlorophosphate at 10℃; for 2h; Autoclave; Reflux;	99.2%
With titanium tetrachloride; trichlorophosphate at 50 - 65℃; for 9h;	94%
With trichlorophosphate at 100℃;

: 107-07-3
2-chloro-ethanol

: 115-96-8
Tris(2-chloroethyl) phosphate

Conditions

Conditions	Yield
With trichlorophosphate 1.) 25-30 deg C, 3 h, 2.) 50-60 deg C, 6 h;	91%
With trichlorophosphate at 25 - 40℃;
With tetrachloromethane; trichlorophosphate bei Siedetemperatur;

: 140-08-9
tris(2-chloro-ethyl)phosphite

: 115-96-8
Tris(2-chloroethyl) phosphate

Conditions

Conditions	Yield
With potassium permanganate
With chlorine; 2-chloro-ethanol
With phosphoric acid In nitromethane

: 74-85-1
ethene

: 115-96-8
Tris(2-chloroethyl) phosphate

Conditions

Conditions	Yield
With phosphoric acid; chlorine

: 107-07-3
2-chloro-ethanol

: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

: 115-96-8
Tris(2-chloroethyl) phosphate

: 60-29-7
diethyl ether

: 140-08-9
tris(2-chloro-ethyl)phosphite

aqueous potassium permanganate: aqueous potassium permanganate

: 115-96-8
Tris(2-chloroethyl) phosphate

...Expand

: cobalt(II) chloride hexahydrate

: 115-96-8
Tris(2-chloroethyl) phosphate

: tetrakis[tri(2-chloroethyl)phosphate]diaquacobalt(II) tetrachlorocobaltate(II)

Conditions

Conditions	Yield
at 80℃; for 20h;	100%

: 302-17-0
chloral hydrate

: 115-96-8
Tris(2-chloroethyl) phosphate

: 14114-78-4
(2,2,2-trichloro-1-hydroxy-ethyl)-phosphonic acid bis-(2-chloro-ethyl) ester

Conditions

Conditions	Yield
In hexane Heating;	82%

: 115-96-8
Tris(2-chloroethyl) phosphate

: 555-06-6
sodium p-aminobenzoate

: tris[2-(p-aminobenzoyloxy)ethyl] phosphate

Conditions

Conditions	Yield
With 2,6-di-tert-butyl-4-methyl-phenol; N-benzyl-N,N,N-triethylammonium chloride In N,N-dimethyl-formamide 1.) 110 deg C, 2 h, 2.) 130 deg C, 1 h;	46%

: 115-96-8
Tris(2-chloroethyl) phosphate

: 60263-54-9
1-cyclohexylcyclohexane-1-carboxylic acid

: bicyclohexyl-1-carboxylic acid-(2-chloro-ethyl ester)

Conditions

Conditions	Yield
With sodium carbonate

: 115-96-8
Tris(2-chloroethyl) phosphate

: 1892-26-8
phosphoric acid mono-(2-hydroxy-ethyl) ester

Conditions

Conditions	Yield
With barium dihydroxide

: 115-96-8
Tris(2-chloroethyl) phosphate

: phosphoric acid bis-(2-hydroxy-ethyl ester); barium salt

Conditions

Conditions	Yield
With silver(l) oxide nachfolgendes Umsetzen mit Barytwasser;
With water; lead(II) oxide nachfolgendes Umsetzen mit Barytwasser;

: 115-96-8
Tris(2-chloroethyl) phosphate

: 107-06-2
1,2-dichloro-ethane

Conditions

Conditions	Yield
erfolgt Zersetzung;

: 115-96-8
Tris(2-chloroethyl) phosphate

: 75-50-3
trimethylamine

: 38837-96-6
phosphoric acid tris-(2-trimethylammonio-ethyl ester); tris chloride

Conditions

Conditions	Yield
With ethanol at 30 - 33℃;
With benzene at 80℃;

: 115-96-8
Tris(2-chloroethyl) phosphate

: 3156-70-5
1-Nitropropen

: 66833-71-4
isopropenyl-phosphonic acid bis-(2-chloro-ethyl ester)

: 115-96-8
Tris(2-chloroethyl) phosphate

: 82123-74-8
phenylphosphonous acid dichloride; compound with aluminium trichloride (1:1)

A: 644-97-3
Dichlorophenylphosphine

B: complex of tris-2-chloroethyl phosphate with aluminum chloride

Conditions

Conditions	Yield
With phosphorus trichloride at 30℃; for 0.333333h; Product distribution; complexes of various arylphosphonous dichlorides with aluminum chloride;

...Expand

: 115-96-8
Tris(2-chloroethyl) phosphate

: 7732-18-5
water

lead oxide: lead oxide

: 18924-97-5
phosphoric acid bis-(2-hydroxy-ethyl) ester

...Expand

: 115-96-8
Tris(2-chloroethyl) phosphate

silver oxide: silver oxide

: 18924-97-5
phosphoric acid bis-(2-hydroxy-ethyl) ester

: 115-96-8
Tris(2-chloroethyl) phosphate

: tris[2-(p-maleamidobenzoyloxy)ethyl] phosphate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 46 percent / Et3BnNCl, ionol / dimethylformamide / 1.) 110 deg C, 2 h, 2.) 130 deg C, 1 h 2: 91 percent / dioxane / 3 h / 50 - 60 °C View Scheme

: 115-96-8
Tris(2-chloroethyl) phosphate

: 373-02-4, 14998-37-9, 33025-09-1, 94044-50-5, 98268-31-6
nickel diacetate

: bis(2-chloroethoxy)phosphato nickel(II)

Conditions

Conditions	Yield
In neat (no solvent) refluxing nickel(II) acetate and tris(2-chloroethyl)phosphate at 170 - 180°C in vacuo; adding ether, filtering ppt., drying in vacuo; elem. anal.;

: 115-96-8
Tris(2-chloroethyl) phosphate

: 71-48-7, 917-69-1, 5931-89-5, 55881-15-7, 68931-68-0, 68931-69-1, 93029-27-7
cobalt(II) acetate

: bis(2-chloroethoxy)phosphato cobalt(II)

Conditions

Conditions	Yield
In neat (no solvent) refluxing cobalt(II) acetate and tris(2-chloroethyl)phosphate at 170 - 180°C in vacuo; adding ether, filtering ppt., drying in vacuo; elem. anal.;

: 115-96-8
Tris(2-chloroethyl) phosphate

: 7646-79-9
cobalt(II) chloride

: bis(2-chloroethoxy)phosphato cobalt(II)

Conditions

Conditions	Yield
In neat (no solvent) refluxing cobalt(II) chloride and tris(2-chloroethyl)phosphate at 170 - 180°C in vacuo; adding ether, filtering ppt., drying in vacuo; elem. anal.;

: 115-96-8
Tris(2-chloroethyl) phosphate

: nickel dichloride

: bis(2-chloroethoxy)phosphato nickel(II)

Conditions

Conditions	Yield
In neat (no solvent) refluxing nickel(II) chloride and tris(2-chloroethyl)phosphate at 170 - 180°C in vacuo; adding ether, filtering ppt., drying in vacuo; elem. anal.;

: 115-96-8
Tris(2-chloroethyl) phosphate

: 10025-73-7
chromium(III) chloride

: 114802-30-1
(tris(2-chloroethoxy)phosphato)chromium(III)

Conditions

Conditions	Yield
In neat (no solvent) refluxing in vac.; elem. anal.;

: 115-96-8
Tris(2-chloroethyl) phosphate

: 7718-98-1
vanadium(III) chloride

: 114802-29-8
(tris(2-chloroethoxy)phosphato)vanadium(III)

Conditions

Conditions	Yield
In neat (no solvent) refluxing in vac.; elem. anal.;

: vanadyl(IV) chloride

: 115-96-8
Tris(2-chloroethyl) phosphate

: 39923-16-5, 114802-31-2
(bis(2-chloroethoxy)phosphato)oxovanadium(IV)

Conditions

Conditions	Yield
In neat (no solvent) refluxing at 160-180°C; elem. anal.;

Tris(2-chloroethyl) phosphate Consensus Reports

IARC Cancer Review: Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 48 , 1990,p. 109.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 48 , 1990,p. 109.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Tris(2-chloroethyl) phosphate Specification

Tris(2-chloroethyl) phosphate, its cas register number is 115-96-8. It also can be called Phosphoric acid tris(2-chloroethyl)ester; TCEP; Amgard TCEP; Celluflex; Disflamoll TCA; Ethanol, 2-chloro-, phosphate (3:1); Niax Flame Retardant 3CF; Tris(2-chloroethyl) orthophosphate. It is a odorless clear liquid and slightly water soluble.It is incompatible with strong oxidizing agents and strong bases.

Physical properties about this chemical are: (1)ACD/LogP: 1.468; (2)ACD/LogD (pH 5.5): 1.47; (3)ACD/LogD (pH 7.4): 1.47; (4)ACD/BCF (pH 5.5): 7.69; (5)ACD/BCF (pH 7.4): 7.69; (6)ACD/KOC (pH 5.5): 149.89; (7)ACD/KOC (pH 7.4): 149.89; (8)#H bond acceptors: 4; (9)#Freely Rotating Bonds: 9; (10)Index of Refraction: 1.463; (11)Molar Refractivity: 56.503 cm³; (12)Molar Volume: 204.964 cm³; (13)Polarizability: 22.4 10-24cm³; (14)Surface Tension: 40.5740013122559 dyne/cm; (15)Density: 1.393 g/cm³; (16)Flash Point: 232.222 °C; (17)Enthalpy of Vaporization: 56.826 kJ/mol; (18)Boiling Point: 347.374 °C at 760 mmHg

Uses of Tris(2-chloroethyl) phosphate: Tris(2-chloroethyl) phosphate (TCEP) is a chemical compound used as a flame retardant, plasticizer, and viscosity regulator in various types of polymers including polyurethanes, polyester resins, and polyacrylates.

When you are using this chemical, please be cautious about it as the following:
1. Wear suitable protective clothing and gloves;
2. Avoid release to the environment. Refer to special instructions safety data sheet;

You can still convert the following datas into molecular structure:
(1)InChI=1S/C6H12Cl3O4P/c7-1-4-11-14(10,12-5-2-8)13-6-3-9/h1-6H2;
(2)InChIKey=HQUQLFOMPYWACS-UHFFFAOYSA-N;
(3)SmilesP(=O)(OCCCl)(OCCCl)OCCCl;

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	oral	1866mg/kg (1866mg/kg)		National Technical Information Service. Vol. AD-A067-313,
mouse	LDLo	intraperitoneal	250mg/kg (250mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)	"Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 7, Pg. 396, 1955.
rabbit	LDLo	skin	2gm/kg (2000mg/kg)	GASTROINTESTINAL: OTHER CHANGES SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)	National Technical Information Service. Vol. OTS0517716,
rat	LD50	oral	1230mg/kg (1230mg/kg)		Bulletin of Environmental Contamination and Toxicology. Vol. 17, Pg. 720, 1977.

Product Name

Tris(2-chloroethyl) phosphate

Synthetic route

Tris(2-chloroethyl) phosphate Consensus Reports

Tris(2-chloroethyl) phosphate Specification

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