Tungsten hexachloride supplier

Name
TUNGSTEN(VI) CHLORIDE
EINECS 236-293-9
CAS No. 13283-01-7
Article Data78
CAS DataBase
Density 3.52 g/cm³
Solubility soluble organic solvents such as ethanol [HAW93]
Melting Point 275 °C(lit.)
Formula WCl₆
Boiling Point 347 °C(lit.)
Molecular Weight 396.568
Flash Point 346°C
Transport Information UN 3260
Appearance dark grey-violet crystalline powder
Safety 26-36/37/39-45
Risk Codes 34
Molecular Structure
Hazard Symbols C
Synonyms Tungstenchloride (WCl6) (6CI,8CI);Hexachlorotungsten;Hexachlorotungsten (Cl6W);Tungsten chloride;Tungsten hexachloride;Tungsten(VI) chloride;Wolframhexachloride;
PSA 0.00000
LogP 4.13700

Synthetic route

: 37823-96-4
pentacarbonyl(methoxyphenylmethylene)tungsten(0)

A: 93-58-3
benzoic acid methyl ester

B: 22550-09-0
tungsten(IV) oxychloride

C: 67-72-1
hexachloroethane

D: 201230-82-2
carbon monoxide

E: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
In tetrachloromethane byproducts: HCl, Cl2; further products; N2; stirred; gas-chromy., MAS; elem. anal.;	A 4.1% B n/a C 28% D 70% E n/a

...Expand

: 7440-33-7
tungsten

: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
With chlorine dry chlorine free of oxygen, 250-300°C;
With chlorine dry chlorine free of oxygen, 250-300°C;

: 10025-67-9
disulfur dichloride

: 7440-33-7
tungsten

: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
With chlorine In not given

: 10025-67-9
disulfur dichloride

: 7782-50-5
chlorine

: 7440-33-7
tungsten

: 13283-01-7
tungsten(VI) chloride

...Expand

: 7782-50-5
chlorine

: 7440-33-7
tungsten

: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
heating in dry H2-stream, then removal of hydrogen by air-free chlorine, red heat, explosion-like react.; repeated sublimation in Cl2-stream;
heating in dry H2-stream, then removal of hydrogen by air-free chlorine, red heat, explosion-like react.;
increasing of reaction rate by 0.1% platinum black in case of pure metal;

: WCl4*PCl5

: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
heating;
heating;

: tungsten(VI) oxide

: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
With chlorine In tetrachloromethane 280°C;

: 75-44-5
phosgene

: tungsten(VI) oxide

: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
In neat (no solvent) passing stream of COCl2 over WO3 at 350 °C;;

: 10025-67-9
disulfur dichloride

: tungsten(VI) oxide

A: tungsten(VI) oxychloride

B: 13283-01-7
tungsten(VI) chloride

C: 13520-76-8
tungsten dioxydichloride

Conditions

Conditions	Yield
In neat (no solvent) below 500°C;;	A n/a B 0% C n/a
In neat (no solvent) below 500°C;;	A n/a B 0% C n/a

...Expand

: 56-23-5
tetrachloromethane

: tungsten(VI) oxide

A: tungsten(VI) oxychloride

B: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
In neat (no solvent) reaction of WO3 with CCl4 at 250°C formation of WOCl4, at 400°C formation of WCl6;;
heating for 3-4 h in a closed tube at 280°C; washing with CCl4, exhausting of CCl4 by suction, heating at 150°C, drying in vac.;
heating for 3-4 h in a closed tube at 280°C; washing with CCl4, exhausting of CCl4 by suction, heating at 150°C, drying in vac.;
In neat (no solvent) reaction of WO3 with CCl4 at 250°C formation of WOCl4, at 400°C formation of WCl6;;

...Expand

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: tungsten(VI) oxide

A: 13470-14-9
tungsten(V) chloride

B: 13283-01-7
tungsten(VI) chloride

C: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

Conditions

Conditions	Yield
heating in CO2 atm.;

...Expand

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: tungsten(VI) oxide

A: 13283-01-7
tungsten(VI) chloride

B: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

Conditions

Conditions	Yield
170°C; inclusion tube;

...Expand

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: tungsten(VI) oxide

A: 13470-14-9
tungsten(V) chloride

B: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
In carbon disulfide heating for several d at 30-40°C then for 8-10 d at 80-90°C under pressure, evapn. of CS2 in CO2-stream;
heating of equiv. amts. of educts in CO2-athmosphere;
In carbon disulfide under pressure;

...Expand

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: tungsten(VI) oxide

: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
byproducts: POCl3; heating of a homogeneous mixt. of educts (molar ratio 1:3) in a closed glass tube by melting, at 170-200°C; distn. of POCl3, heating in CO2-stream at 120°C;
byproducts: POCl3; heating of a homogeneous mixt. of educts (molar ratio 1:3) in a closed glass tube by melting, at 170-200°C; distn. of POCl3, heating in CO2-stream at 120°C;

: 56-23-5
tetrachloromethane

: tungsten tritaoctoxide

A: 13470-14-9
tungsten(V) chloride

B: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
heating chlorine-free CCl4, in a closed tube at 240°C;
heating chlorine-free CCl4, in a closed tube at 240°C;

...Expand

: 56-23-5
tetrachloromethane

: tungsten(IV) oxide

A: tungsten(VI) oxychloride

B: 13283-01-7
tungsten(VI) chloride

C: 13470-13-8
tungsten(IV) chloride

D: 13520-76-8
tungsten dioxydichloride

Conditions

Conditions	Yield
In neat (no solvent) reaction on heating WO2 with CCl4 to 250°C in a closed tube for 8h;;
In neat (no solvent) reaction on heating WO2 with CCl4 to 250°C in a closed tube for 8h;;

...Expand

: 13470-14-9
tungsten(V) chloride

: 10241-05-1
molybdenum(V) chloride

A: 13283-01-7
tungsten(VI) chloride

B: 13320-71-3
molybdenum(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent)

...Expand

: tungsten(VI) oxychloride

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
byproducts: chlorine, WCl5; heating of equimolar amts. of educts in a closed tube at 170°C;
heating in closed tube at 170°C;
heating in closed tube at 170°C;
byproducts: chlorine, WCl5; heating of equimolar amts. of educts in a closed tube at 170°C;

: 14040-11-0
tungsten hexacarbonyl

: 7782-50-5
chlorine

: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
In neat (no solvent) treatment (200 K), warming to 320 K (Cl2 atmosphere); elem. anal.;

: tungsten(IV) sulfide

: 7782-50-5
chlorine

A: 10025-67-9
disulfur dichloride

B: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
heating with dry chlorine, under red heat; heating to melting;
heating with dry chlorine, under red heat; heating to melting;

...Expand

: tungsten(IV) sulfide

: 7782-50-5
chlorine

: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
only oxychloride formation;	0%
400°C;
only oxychloride formation;	0%
400°C;

: tungsten silicide

A: 10026-04-7, 53609-55-5
tetrachlorosilane

B: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
With Cl2 dry Cl2 at 200-300°C;

: W2(15)NCl9

A: W(15)NCl3

B: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
heated at 130 °C;

: tungsten(IV) oxide

: 75-71-8
Dichlorodifluoromethane

A: tungsten(VI) oxofluoride

B: tungsten(VI) oxychloride

C: 124-38-9
carbon dioxide

D: 201230-82-2
carbon monoxide

E: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
In neat (no solvent) reaction below 525°C; further products;;

...Expand

: tungsten monophosphide

A: 13283-01-7
tungsten(VI) chloride

B: 7719-12-2, 52843-90-0
phosphorus trichloride

Conditions

Conditions	Yield
With Cl2 at red heat;

: tungsten carbide

: 14700-96-0, 14835-24-6, 15723-23-6, 16547-50-5, 16885-04-4, 16887-00-6, 16904-11-3, 16904-12-4, 16999-02-3, 20337-89-7, 20499-73-4, 22537-15-1, 22537-27-5, 22541-73-7, 22541-74-8, 24203-47-2, 33944-49-9, 34937-26-3, 37352-90-2
chlorine

: graphite

B: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
400°C;
400°C;

...Expand

: 75-44-5
phosgene

: 7440-33-7
tungsten

A: 13470-14-9
tungsten(V) chloride

B: tungsten(VI) oxychloride

C: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
trace formation;
trace formation;

...Expand

: 7782-50-5
chlorine

: 7440-33-7
tungsten

A: 13470-14-9
tungsten(V) chloride

B: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
red heat;
red heat;

...Expand

: tungsten chlorobromide

: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
With chlorine byproducts: Br2; below m.p.;
With Cl2 byproducts: Br2; below m.p.;

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: tungsten(VI) oxide

A: 13470-14-9
tungsten(V) chloride

B: tungsten(VI) oxychloride

C: 13283-01-7
tungsten(VI) chloride

Conditions

Conditions	Yield
heating of equiv. amts. of educts in a CO2-atmosphere;
heating of equiv. amts. of educts in a CO2-atmosphere;

...Expand

: tellurium

: 7553-56-2
iodine

: 13283-01-7
tungsten(VI) chloride

: 1,4-diiodo-cyclo-hexatellurium(2+) bis(hexachlorotungstate(-))

Conditions

Conditions	Yield
In neat (no solvent) Ar atmosphere, sealed ampoule, formation of black melt at 300°C, tube furnace (150°C), crystn. (3 months);	100%

...Expand

: 34838-48-7
1,2-dihydro-3,3,5,5,7,7-hexaphenyl-1,2,4,6,3λ5,5λ5,7λ5-tetraazatriphosphepinium chloride

: 13283-01-7
tungsten(VI) chloride

: 126085-30-1
diphenyl-bis(chlorodiphenylphosphoranylideneamino)phosphonium hexachlorotungstate (V)

Conditions

Conditions	Yield
With chlorine In dichloromethane byproducts: nitrogen; To the soln. obtained from the reaction of the tetraazatriphosphepinium chloride chlorine was added at 0°C.; removal of the volatile components, recrystn. at -25°C from CH2Cl2;	100%

: 107-46-0
Hexamethyldisiloxane

: 13283-01-7
tungsten(VI) chloride

: tungsten(VI) oxychloride

Conditions

Conditions	Yield
In dichloromethane byproducts: (CH3)3SiCl; under N2, dropwise addn. of a CH2Cl2 soln. of (Me3Si)2O to WCl6 in CH2Cl2 at room temp. over a period of 15 min, stirred for 60 min; filtered, washed with petroleum ether, dried in vac.; elem. anal.;	99%

: 107-46-0
Hexamethyldisiloxane

: 13283-01-7
tungsten(VI) chloride

: 160797-03-5, 13520-78-0
tungsten oxytetrachloride

Conditions

Conditions	Yield
In dichloromethane byproducts: Me3SiCl; under inert atm.; soln. of Si-compd. added dropwise to a stirred suspension of W-compd. at room temp. over a period of 15 min, deposition of crystals, mixt. stirred at room temp. for 60 min; supernatant decanted, solid collected, washed (petroleum ether), dried (vac.); elem. anal.;	99%
In octane byproducts: M3SiCl; yielding amorphous powder;

: 109-99-9
tetrahydrofuran

: 13283-01-7
tungsten(VI) chloride

: 34445-14-2
{WCl4(thf)2}

Conditions

Conditions	Yield
With 1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene at -78 - 20℃; for 1h; Inert atmosphere;	99%
With cyclopentene In dichloromethane under Ar: addn. of 306 mmol cyclopentene to a stirred suspension of 29.8 mmol WCl6; filtration of the soln. after 15 min at room temperature; addn. of tetrahydrofuran after cooling to ice-bath temperature; pptn. after a few minutes at room temperature;; filtration after 1 h; washing with dichloromethyne; drying under vac.; elem. anal.;;	36%

: 13283-01-7
tungsten(VI) chloride

: WOCl3(C5H5N)3*0.33C5H5N

Conditions

Conditions	Yield
With pyridine In pyridine 1 d stirring; filtration, elem. anal.;	99%

: tungsten(IV) oxide

: 13283-01-7
tungsten(VI) chloride

A: tungsten(VI) oxychloride

B: 20193-56-0
tungsten(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) mixt. of educts held at 300-350°C for 2-3 h; WOCl4 sepd. by sublimation at 250°C; the residue held at 450-470°C for 3-4 h; WOCl4 sepd. once more by sublimation at 350-370°C; cooled; elem.anal., XRD;	A n/a B 98.1%

...Expand

: 13283-01-7
tungsten(VI) chloride

: 13470-13-8
tungsten(IV) chloride

Conditions

Conditions	Yield
With Sn In 1,2-dichloro-ethane byproducts: SnCl4; absence of air and moisture; stirring with Sn-powder at room temp. for 17 h, then at 80-90°C for 2 d; centrifugation, washing (CH2Cl2), drying (vac., room temp.); elem. anal.;	98%
With Sb In neat (no solvent) byproducts: SbCl3, WOCl4, WCl5; absence of air and moisture; sealed evacuated glass tube, 75-80°C(12 h), 105°C (12 h), 130°C (12 h); distn. off of byproducts (130°C, 1d; then 160°C, 1 d; then215°C, 1 d); elem. anal.;	97%
With red phosphorus In neat (no solvent) byproducts: PCl3, WOCl4, WCl5; absence of air and moisture; sealed evacuated glass tube, slow heating to 200°C (over 12 h), then to 300°C (over further 12 h); sublimation off of byproducts (230-240°C, 1 d, trap at liquid N2-temp.; further byproduct: POCl3); elem. anal.;	94%

: 55-21-0
benzamide

: 13283-01-7
tungsten(VI) chloride

: trans-[WOCl4(benzonitrile)]

Conditions

Conditions	Yield
In benzene byproducts: HCl; under N2; WCl6 and PhCONH2 in benzene heated under reflux for 16 h; solvent removed; washed with hexane; dried in vac.; elem. anal.;	98%

: 13465-84-4
silicon tetraiodide

: 13283-01-7
tungsten(VI) chloride

: W3I12

Conditions

Conditions	Yield
at 120℃; for 16h; Inert atmosphere; Glovebox; Schlenk technique;	98%
at 120℃; for 16h;

: 7732-18-5
water

: 13283-01-7
tungsten(VI) chloride

: 2129-89-7
diphenyl(methyl)phosphine oxide

: WCl2(O)2(methyl(diphenyl)phosphine oxide)2

Conditions

Conditions	Yield
With H2O2 In dichloromethane; water WCl6 and methyl(diphenyl)phosphine oxide dissolved in CH2Cl2 together with H2O, stirred, treated with H2O2 soln., stirred for ca 1 h; concd. (vac.), pptd. (hexanes), filtered off, dissolved in CH2Cl2, stirred for ca 1-2 h, concd., pptd. (hexanes), dried (vac.); elem. anal.;	96%

...Expand

: 76-06-2
chloropicrin

: 13283-01-7
tungsten(VI) chloride

: 13520-78-0, 160797-03-5
tungsten(VI) oxychloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: NOCl, CCl4; under exclusion of moisture, refluxed for 10 min, cooled quickly to 0°C; filtered; dried under vac.; elem. anal.;	95.3%

: 7732-18-5
water

: 13283-01-7
tungsten(VI) chloride

: tungsten(VI) oxide

Conditions

Conditions	Yield
With carbon In N,N-dimethyl-formamide Sonication; a soln. of WCl6 in DMF was added to a dispersed carbon microspheres in DMF at a speed of 20 s per drop while being ultrasonicated, after 30 min and small amounts H2O was added dropwise, ultrasonication for 1 h, aged at room temp. for 1 d; filtered, washed with alcohol and distilled water, dried in vac. at 80°C for 12 h, the carbon spheres were removed in a conventional muffle furnace, calcination at 450°C for 2 h in air, cooled to room temp.;	95%
In ethanol deposited on SnO2; EtOH soln. of WCl6, heated at 373 K for 20 h in the absence of moistute, washed with water, dried at 393 K; SEM, XRD;
With pluronic F127 In water WCl6 added to a soln. of pluronic F127 in water, mixt. stirred for 3 h, heated at 120 °C for 24 h in autoclave, cooled to 25°C, residue centrifugated, washed with water/EtOH, dried at 80 °C for 12 h, heated at 550 °C, for 3 h;
Stage #1: water; tungsten(VI) chloride With Pluronic P-127 In ethanol at 40℃; Stage #2: With air at 450℃; for 6h; Calcination;

: 624-74-8
diiodoacetylene

: 13283-01-7
tungsten(VI) chloride

: 103055-81-8
[WCl4(ICCI)]2

Conditions

Conditions	Yield
In tetrachloromethane (under exclusion of moisture); dropwise addn. of the acetylene in CCl4 to WCl6 in CCl4, reflux for 12 h; filtn., ppt. is washed, dried in vac., elem. anal.;	95%

: 4526-07-2
1,4-bis(trimethylsilyl)-1,3-butadiyne

: 13283-01-7
tungsten(VI) chloride

: octachloro-1,4-bis(trimethylsilyl)butadiine-ditungsten

Conditions

Conditions	Yield
With 1,1,2,2-tetrachloroethylene In tetrachloromethane byproducts: C2Cl6, C4Cl2(SiMe3)2; under Ar; WCl6 suspensed in CCl4; the butadiyne added; refluxed for 12 h; filtered; washed with CCl4 and CH2Cl2; dried in vacuo for 3 h; elem. anal.;	95%

: 107-46-0
Hexamethyldisiloxane

: 13283-01-7
tungsten(VI) chloride

: W2O3Cl6

Conditions

Conditions	Yield
In dichloromethane at 0℃; for 1.5h;	95%
In dichloromethane (Ar); dropwise addn. of a soln. of silicon compd. in CH2Cl2 to a suspn. of WCl4 in CH2Cl2 at room temp. over 15 min, stirring for 60 min; sepn., washing with hexane, drying in vac.;

: 676-96-0
Trimethylphosphine oxide

: 107-46-0
Hexamethyldisiloxane

: 13283-01-7
tungsten(VI) chloride

: [WO2Cl2(OP(CH3)3)2]

Conditions

Conditions	Yield
In dichloromethane N2, W compd. stirred with Si compd. (2 equiv.) for 2 h, P compd. (light excess) added, stirred for ca. 2 h; filtered, solvent removed (vac.), ppt. washed (hexane), dried (vac.); elem. anal.;	95%

...Expand

: phosphorous

: 13283-01-7
tungsten(VI) chloride

A: W4PCl11

B: 13470-13-8
tungsten(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: PCl3; WCl6 and red P (1:1.34) mixed (Ar), sealed (vac.) in silica tube, heatedat 500°C for 24 h; sublimated, XRD;	A 95% B 5%

...Expand

: phosphorous

: 13283-01-7
tungsten(VI) chloride

: W6PCl17

Conditions

Conditions	Yield
In neat (no solvent) byproducts: PCl3; WCl6 and red P (1:1.34) mixed (Ar), sealed (vac.) in silica tube, heatedat 370°C for 24 h; sublimated, XRD;	95%

: 13465-84-4
silicon tetraiodide

: 13283-01-7
tungsten(VI) chloride

: W4I13

Conditions

Conditions	Yield
at 150℃; for 16h; Inert atmosphere; Schlenk technique;	95%

: 38177-56-9
trimethyl(4-phenylbuta-1,3-diyn-1-yl)silane

: 13283-01-7
tungsten(VI) chloride

: [WCl4(C6H5CCCCSi(CH3)3)]2

Conditions

Conditions	Yield
With tetrachloroethylene In tetrachloromethane byproducts: Cl3CCCl3, PhC4Cl2SiMe3; under Ar; dissolving PhCCCCSiMe3 in CCl4 and C2Cl4, refluxing (95°C), adding WCl6 by boiling CCl4 via an extraction frit (4.5 h), heating (12 h); filtering, washing (CCl4 and CH2Cl2), drying (high vac.); elem. anal.;	94%

: 13283-01-7
tungsten(VI) chloride

: 70-55-3
toluene-4-sulfonamide

: 204396-51-0
dichlorobis(tosylimido)tungsten(VI)

Conditions

Conditions	Yield
In toluene byproducts: HCl; Ar atm.; refluxing (2 h); filtn. (hot), washing (hot toluene, 3 times), drying (vac.); elem. anal.;	94%

: 507-28-8, 14842-08-1
tetraphenylarsonium chloride

: 13283-01-7
tungsten(VI) chloride

: 19453-44-2
tetraphenylarsonium hexachlorotungstate(V)

Conditions

Conditions	Yield
With C2Cl4 In dichloromethane byproducts: C2Cl6; addn. of CCl4 and CH2Cl2 to WCl6 and arsonium compd. under Ar; heating slowly to 40°C; foaming of soln.; pptn.; refluxing, 2h; cooling ato 20°C; addn. of dry CH2Cl2; heating with stirring, 30 min; cooling; pptn.; filtration; further crystn. of mother liquor at -5°C; elem. anal.;	93%

: 16940-66-2
sodium tetrahydroborate

: 13283-01-7
tungsten(VI) chloride

: lithium methylcyclopentadienide

: 61112-90-1
WH2(C5H4CH3)2

Conditions

Conditions	Yield
In tetrahydrofuran; pentane oxygen exclusion; mixing solns. (-78 to 0°C), warming to room temp., reflux, 2 h; sublimation (ca. 80°C, 1E-4 Torr);	93%

...Expand

: 3457-48-5
1,2-di(4-methylphenyl)-1,2-ethanedione

: 13283-01-7
tungsten(VI) chloride

: C32H28Cl2O4W

Conditions

Conditions	Yield
With 1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene In toluene at -78 - 20℃; for 1h; Inert atmosphere;	93%

: 13283-01-7
tungsten(VI) chloride

: 7440-33-7
tungsten

: 13470-13-8
tungsten(IV) chloride

Conditions

Conditions	Yield
In 1,2-dichloro-ethane at 20℃; for 17h;	93%

: 132724-39-1
tetraselendinitride

: 13283-01-7
tungsten(VI) chloride

: (tungsten(Cl4)(chlorselenonitrene))2

Conditions

Conditions	Yield
In dichloromethane Se4N2 is suspended in CH2Cl2, WCl6 is added under stirring, stirring at room temp. under exclusion of moisture for 24 h; filtn., washing (CH2Cl2), drying (vac.);	92%

: 39232-92-3
N-methyl-N-phenylhydrazine hydrochloride

: 13283-01-7
tungsten(VI) chloride

: 182283-31-4
[WCl4(NNCH3C6H5)]

Conditions

Conditions	Yield
In dichloromethane (N2); stirring (-78°C, 0.08 h); warming to room temp., solvent removal (vac.), drying (vac., 0.5 h), pentane addn., stirring (0.2 h), filtn., washing (pentane), drying (vac.);	92%

: C36H42N2

: 13283-01-7
tungsten(VI) chloride

: 1430073-48-5
C36H40Cl4N2W

Conditions

Conditions	Yield
Stage #1: tungsten(VI) chloride With 1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene In toluene at -78 - 20℃; for 1h; Inert atmosphere; Stage #2: C36H42N2 In toluene at 20℃; for 16h; Inert atmosphere;	92%

: 366-18-7
[2,2]bipyridinyl

: 110-71-4
1,2-dimethoxyethane

: 13283-01-7
tungsten(VI) chloride

: 124509-54-2, 18252-71-6
W(O)2Cl2(2,2′-bipyridine)

Conditions

Conditions	Yield
Stage #1: 1,2-dimethoxyethane; tungsten(VI) chloride With Hexamethyldisiloxane In dichloromethane at 20℃; for 2h; Stage #2: [2,2]bipyridinyl In dichloromethane for 0.5h;	92%

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Tungsten hexachloride Specification

The Tungsten hexachloride, with CAS registry number 13283-01-7, has the systematic name of tungsten(+2) cation hexachloride. And its IUPAC name is hexachlorotungsten. Its other registry number is 18715-53-2. What's more, it is a kind of dark grey-violet crystalline powder.

Physical properties about this chemical are: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: Å².

When you are using this chemical, please be cautious about it as the following:
The Tungsten hexachloride may cause burns. When use it, wear suitable protective clothing, gloves and eye/face protection. If contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

You can still convert the following datas into molecular structure:
(1)SMILES: [W+2].[W+2].[W+2].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-]
(2)InChI: InChI=1/6ClH.3W/h6*1H;;;/q;;;;;;3*+2/p-6
(3)InChIKey: IHZJZUWBRYPYFX-CYFPFDDLAE
(4)Std. InChI: InChI=1S/6ClH.3W/h6*1H;;;/q;;;;;;3*+2/p-6
(5)Std. InChIKey: IHZJZUWBRYPYFX-UHFFFAOYSA-H

Product Name

TUNGSTEN(VI) CHLORIDE

Synthetic route

Tungsten hexachloride Specification

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