The objective of this research is to demonstrate the potential of iridium oxide (IrOx) nanowires based device towards detection of proteins that are disease biomarkers. This device is based on electrical detection of protein biomarkers wherein an immunoassay is built onto the iridium oxide nanow...

The mechanism of thermal destruction of Ir(acac)(CO)2 as one of the most important MOCVD precursors for Ir coatings deposition was proposed on the footing of the in situ mass spectrometry analysis and quantum chemical modeling. Calculated structural parameters and vibrational spectra of Ir(acac)...

Pyrolysis and oxidation reactions of the iridium precursor, (methylcyclopentadienyl)(1,5-cyclooctadiene)iridium (I), were studied to identify the role of O2 in chemical vapor deposition film growth. A toluene solution of (methylcyclopentadienyl)(1,5-cyclooctadiene)iridium (I) was used in a direc...

We studied the interaction of cis-diammine Pt(II)-bridged bis-netropsin, cis-diammine Pt(II)-bridged bis-distamycin and oligomethylene-bridged bis-netropsin with synthetic DNA fragments containing pseudosymmetrical AT-rich nucleotide sequences and compared it with the interaction of the parent c...

A novel method for the one-pot synthesis of 5-substituted 1H-tetrazoles and Benzamide from arylhalide containing in situ CN insertion from inorganic salt source was accomplished in presence of a new magnetically catalyst, palladium on surface-modified Schiff-Base complex. K2[Ni(CN)4] plays a rol...

The pharmacological activity of CR 2039 (4-(1H-tetrazol-5-yl)-N-[4-(1H-tetrazol-5-yl]phenylbenzamide) a newly discovered antiallergic compound is described. CR 2039 administered i.m. or i.v. inhibited rat passive cutaneous anaphylaxis (PCA) with an ED50 of 0.1 mg/kg and a potency about 15 times ...

The synthesis of N-[(dimethylamino)methylidene]-4-[1-(4-nitrophenyl)-1H-tetrazol-5-yl]benzenesulfonamide (3) has been easily approached and the structure has been determined by X-ray crystallography. Tetrazole 3 crystallizes in the monoclinic space group C2/c, with the cell parameters determined...

Trichomoniasis is the most prevalent, non-viral sexually transmitted diseases (STD) caused by amitochondriate protozoan Trichomonas vaginalis. Increased resistance of T. vaginalis to the marketed drug Metronidazole necessitates the development of newer chemical entities. A library of sixty 2-met...

AimsIn the history of the drug discovery there are several tremendous increases are occurring on day by day for the drug resistant pathogens, leading to the drug design and Various novel nitro isoxazole imine imidazole derivatives have been prepared to study on the basis of pharmacological activ...

The rate constants for the Cl atom reaction with three branched ketones have been measured at 298 ± 2 K and 760 Torr using the relative rate method in the absence of NO. The rate constants values obtained (in units of 10− 10 cm3/(molecule·sec)) are: k(2-methyl-3-pentanone) = 1.07 ± 0.26, k(3-...

Open burning of electronic waste (E-waste) produces numerous organochlorine compounds (OCs). Although the presence of unidentified OCs has been suggested, the mass balance of identified and unidentified OCs in E-waste open burning soils (EOBSs) still remains unknown. In this study, the concentra...

In this study, we have synthesized a starch/poly(alginic acid-cl-acrylamide) nanohydrogel (ST/PL(AA-cl-AAm) NHG) by co-polymerization method which was used as an effective adsorbent for the removal of coomassie brilliant (CB) blue R-250 dye from the aqueous solution. The synthesized nanohydrogel...

Halide-containing silver phosphate glasses have been used as model systems for the study of the ionic conductivity of oxide glasses for the past 50 years, mostly due to the massive increase in conductivity observed as the halide concentration is increased, even if the molar ratio of silver is ke...

Combustion behavior, flame structure, and thermal decomposition of bimolecular crystals of hexanitrohexaazaisowurtzitane (CL-20) with glycerol triacetate (GTA), tris[1,2,5]oxadiazolo[3,4-b:3′,4′-d:3″,4″-f]azepine-7-amine (ATFAz), 4,4′′-dinitro-ter-furazan (BNTF), oxepino[2,3-c:4,5-c′:6,7-...

This study provides molecular insights into the initial stages of Cl-induced depassivation of iron passive film by studying the interactions of Cl with pristine and vacancy surfaces of α-Fe2O3 (0001). Subsurface Cl is found to be less stable than adsorbed Cl which contradicts the ion exchange m...

With the aim of understanding the link between excited OH (OH∗) and ground species, we have investigated its distribution and kinetics in steady planar premixed H2-O2-N2 flames. We find that the OH∗ distribution mimics the two-layer chemical structure of the underlying host H2 flame, with a thin...

We designed two stable monolayers of Ca2NOH and Y2C(OH)2 through replacing the anionic electrons with negatively charged hydroxide ions. Calculation results indicate that these two monolayers are dynamic and thermodynamic stable. Ca2NOH is determined as an indirect semiconductor with band gap of...

Herein selective oxidation of glycerol to formic acid catalyzed by Ru(OH)4 nanoparticles decorated on reduced graphite oxide (r-GO) in the presence of FeCl3 was presented. The Ru(OH)4/r-GO catalyst was prepared via refluxing RuCl3 aqueous solution containing graphite oxide (GO), and was characte...

When analyzing the experimental vibrational peak position of heavy light XH stretching vibrations of simple molecules, the local mode model has great success. In addition, the bond dipole approach has helped analyze the experimental intensities, where the transition moment of the XH stretching m...

Tebuconazole (Tbz) and diniconazole (Dnz) were deposited as thin film on quartz plaques. They were submitted to OH-radicals and ozone and their kinetic was measured. OH-radical oxidation was performed relative to a reference whose rate constant is well known. Terbuthylazine (Tbt) and Chlorpyriph...