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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4-Methoxytriphenylamine Manufacturer/High quality/Best price/In stock

Cas:4316-51-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Wuhan Kemi-Works Chemical Co., Ltd

ISO9001 Exporting Japan, Korea regularly. Appearance:white powder Package:25kg/ fibre drum Application:OLED intermediate Port:Chinese port

4-Methoxytriphenylamine

Cas:4316-51-2

Min.Order:1 Gram

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 4316-51-2 4-METHOXYTRIPHENYLAMINE 97 Manufacturer

Cas:4316-51-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

4-Methoxytriphenylamine CAS No. 4316-51-2

Cas:4316-51-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

4-Methoxytriphenylamine

Cas:4316-51-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 4316-51-2 with best quality

Cas:4316-51-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

4-Methoxytriphenylamine 97

Cas:4316-51-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Methoxytriphenylamine 97

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Name 4-Methoxytriphenylamine Cas 4316-51-2 Appearance white powder Capacity:200MT/year Application: Oled intermediate Assay: min99% Standard: enterprise Package: 25kg/drum Molecular Formula C19H17NO Molecular Weight 275.34

4-Methoxytriphenylamine

Cas:4316-51-2

Min.Order:1 Gram

FOB Price: $34.0

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

4-MethoxytriphenylamineCAS NO.: 4316-51-2

Cas:4316-51-2

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4-Methoxytriphenylamine 97

Cas:4316-51-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Cas no.4316-51-2 98% 4-METHOXYTRIPHENYLAMINE 97

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:OLED Intermediate Transportation:by air or by sea Port:Shanghai, Qingdao

4-METHOXYTRIPHENYLAMINE 97

Cas:4316-51-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

4-Methoxytriphenylamine

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 4-Methoxytriphenylamine 25g

Cas:4316-51-2

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

High quality 4-Methoxytriphenylamine cas NO.: 4316-51-2

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Other

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Antimex Chemical Limied

4316-51-2 C19H17NO 4-METHOXYTRIPHENYLAMINE 97Appearance:As detailed Storage:room temperature Package:As required Application:4316-51-2 Transportation:By air/sea/express

4316-51-2 C19H17NO 4-METHOXYTRIPHENYLAMINE 97

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

4-Methoxytriphenylamine

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:25kg,50kg,180kg,200kg,250kg,1000kg,customization Application:Pharma;Industry;Agricultural;chemical reaserch Tran

4-methoxy-N,N-diphenylaniline

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white to yellow powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as

4-Methoxytriphenylamine

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

4-Methoxytriphenylamine cas 4316-51-2Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

4-Methoxytriphenylamine cas 4316-51-2

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Other

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

4-Methoxytriphenylamine 97

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

4316-51-2

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

4-Methoxytriphenylamine 97

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

4-Methoxytriphenylamine

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

factory 4316-51-2 In China4-Methoxytriphenylamine on hot selling

Cas:4316-51-2

Min.Order:10 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Sunwise Chemical Co., Ltd

ISO 9001 Certified We implement ISO management throughout our day to day operation. Since we started ISO system in Year 2008, we improve each year to implement the management system in details of each supplying process. This helps us to provi

4-Methoxytriphenylamine

Cas:4316-51-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

4316-51-2 C19H17NO 4-METHOXYTRIPHENYLAMINE 97

Cas:4316-51-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hebei youze Biotechnology Co.,Ltd

What's our company advantages 1.Government support guarantees good company credibility and finance safe. 2.Place of Origin China with Super quality by reasonable price. 3.Fast delivery by safe express way to all the country. 4.We

4-Methoxytriphenylamine CAS NO.4316-51-2 high purity best price spot goods

Cas:4316-51-2

Min.Order:1 Kilogram

FOB Price: $16.0

Type:Trading Company

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Watson International Ltd

Watson International Ltd' has a very strong R&D and technical capacity supported by FCAD's platform. The subsidiaries under FCAD Group have accumulated much know-how of different fine chemical branches. For example, Apnoke Scientific L

4-Methoxytriphenylamine

Cas:4316-51-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

diphenylamine
122-39-4

diphenylamine

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 80℃; for 12h;99%
With bis(η3-allyl-μ-chloropalladium(II)); 2,6-bis(2,4,6-triisopropylphenyl)phenyl(dicyclohexylphosphine); sodium t-butanolate In dodecane; toluene at 100℃; for 6h; Catalytic behavior; Reagent/catalyst; Glovebox;99%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 70℃; for 16h;97%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

diphenylamine
122-39-4

diphenylamine

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With potassium hydroxide; bis(tri-tert-butylphosphine)palladium(0); cetyltrimethylammonim bromide In water; toluene at 90℃; for 6h;99%
With palladium diacetate; sodium t-butanolate; ruphos In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Green chemistry;99%
With sodium t-butanolate; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane In toluene at 50℃;97%
para-iodoanisole
696-62-8

para-iodoanisole

diphenylamine
122-39-4

diphenylamine

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With copper(l) iodide; 5,6,9,10-tetrahydro-4H,8H-pyrido[3,2,1-ij][1,6]naphthyridine; sodium t-butanolate In toluene at 110℃; for 40h; post-Ullmann reaction;96%
With [Pd{C6H4(CH2N(CH2Ph)2)}(μ-Br)]2; potassium hydroxide In dimethyl sulfoxide at 120℃; for 3h;96%
With sodium t-butanolate; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane In toluene at 30℃;93%
bromobenzene
108-86-1

bromobenzene

4-methoxy-aniline
104-94-9

4-methoxy-aniline

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With dichloro{1,10-[di-(2-diizopropylaminoethyl)]-3,3'-o-xylyldibenzimidazolidin-2,2'-diylidene}palladium (II); potassium tert-butylate In 1,2-dimethoxyethane at 80℃; for 15h; Buchwald-Hartwig amination; Inert atmosphere;95%
With (6-Dipp)PdCl2-SPhos; sodium t-butanolate In neat (no solvent) at 110℃; for 24h; Reagent/catalyst; Buchwald-Hartwig Coupling; Inert atmosphere;90%
With potassium hydroxide In water for 24h; Buchwald-Hartwig reaction; Reflux; Inert atmosphere;85%
iodobenzene
591-50-4

iodobenzene

4-methoxy-aniline
104-94-9

4-methoxy-aniline

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With [2,2]bipyridinyl; potassium tert-butylate; copper(l) iodide In toluene at 115℃; for 3.5h;94%
With tetraethoxy orthosilicate; caesium carbonate; copper(l) iodide at 145℃; for 38h; Ullmann coupling reaction;85%
With C39H33CuF3N2P2(1+)*ClO4(1-); potassium tert-butylate In toluene at 90℃; for 12h; Inert atmosphere;80%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

N-(trimethylsilyl)-diphenylamine
17425-91-1

N-(trimethylsilyl)-diphenylamine

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With cesium fluoride; bis(dibenzylideneacetone)-palladium(0); XPhos at 100℃; for 1h; Inert atmosphere;94%
With cesium fluoride; bis(dibenzylideneacetone)-palladium(0); XPhos at 100℃; for 1h; Time; Reagent/catalyst; Inert atmosphere;94%
With bis(1,5-cyclooctadiene)nickel (0); 1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene hydrochloride; potassium tert-butylate; cesium fluoride at 100℃; for 36h; Inert atmosphere;67%
4-methoxy-aniline
104-94-9

4-methoxy-aniline

2-(trimethylsilyl)phenyl trifluoromethanesulfonate
88284-48-4

2-(trimethylsilyl)phenyl trifluoromethanesulfonate

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With cesium fluoride In acetonitrile at 20℃; for 72h;90%
bromobenzene
108-86-1

bromobenzene

4-methoxy-aniline
104-94-9

4-methoxy-aniline

A

N-(4-methoxyphenyl)phenylamine
1208-86-2

N-(4-methoxyphenyl)phenylamine

B

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With C46H58Br2N4O10Pd; potassium tert-butylate In 1,2-dimethoxyethane at 80℃; for 15h; Inert atmosphere; Buchwald-Hartwig amination;A 11%
B 89%
With potassium tert-butylate; copper(l) iodide; tributylphosphine In toluene at 135℃; for 10.5h; high pressure;A 2%
B 86%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; palladium 10% on activated carbon; sodium t-butanolate In 1,3,5-trimethyl-benzene for 24h; Inert atmosphere; Reflux;A 41%
B 45%
4-methoxy-aniline
104-94-9

4-methoxy-aniline

2-(trimethylsilyl)phenyl trifluoromethanesulfonate
88284-48-4

2-(trimethylsilyl)phenyl trifluoromethanesulfonate

A

N-(4-methoxyphenyl)phenylamine
1208-86-2

N-(4-methoxyphenyl)phenylamine

B

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With cesium fluoride In acetonitrile at 20℃; for 10h;A 89%
B 4%
4-methoxy-aniline
104-94-9

4-methoxy-aniline

chlorobenzene
108-90-7

chlorobenzene

A

N-(4-methoxyphenyl)phenylamine
1208-86-2

N-(4-methoxyphenyl)phenylamine

B

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With potassium tert-butylate; copper(l) iodide; tributylphosphine In toluene at 135℃; for 10.5h; high pressure;A 3%
B 85%
4-methoxy-aniline
104-94-9

4-methoxy-aniline

chlorobenzene
108-90-7

chlorobenzene

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; (E)-2-(((2,5-bis(trifluoromethyl)phenyl)imino)methyl)phenol; sodium t-butanolate In o-xylene at 145℃; for 12h; Schlenk technique; Inert atmosphere;85%
iodobenzene
591-50-4

iodobenzene

4-methoxy-aniline
104-94-9

4-methoxy-aniline

A

N-(4-methoxyphenyl)phenylamine
1208-86-2

N-(4-methoxyphenyl)phenylamine

B

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With potassium tert-butylate; copper(l) iodide In toluene at 135℃; for 14h;A 12%
B 82%
With copper(l) iodide; cesium fluoride In dimethyl sulfoxide at 130℃; for 24h; Ullmann Condensation; Inert atmosphere; Glovebox;A 37 %Chromat.
B 15%
para-iodoanisole
696-62-8

para-iodoanisole

N-phenyl-1-naphthylamine
90-30-2

N-phenyl-1-naphthylamine

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
potassium hydroxide; copper In various solvent(s) at 160℃; for 5h;79%
bromobenzene
108-86-1

bromobenzene

N-(4-methoxyphenyl)phenylamine
1208-86-2

N-(4-methoxyphenyl)phenylamine

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
Stage #1: bromobenzene With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0) In toluene at 20℃; for 0.166667h; Inert atmosphere;
Stage #2: N-(4-methoxyphenyl)phenylamine With sodium t-butanolate In toluene at 90℃; for 20h; Hartwig-Buchwald coupling;
79%
With C37H50BrO3PPd In 1,4-dioxane at 80℃; Kinetics; Inert atmosphere; Glovebox; Sealed tube;
N-(4-methoxyphenyl)phenylamine
1208-86-2

N-(4-methoxyphenyl)phenylamine

triphenylbismuth(V) diacetate
28899-97-0

triphenylbismuth(V) diacetate

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
copper In dichloromethane for 72h; Ambient temperature;78%
triphenylbismuth(V) diacetate
28899-97-0

triphenylbismuth(V) diacetate

4-methoxy-aniline
104-94-9

4-methoxy-aniline

A

N-(4-methoxyphenyl)phenylamine
1208-86-2

N-(4-methoxyphenyl)phenylamine

B

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
copper In dichloromethane for 24h; Ambient temperature;A 28%
B 68%
para-methoxynitrobenzene
100-17-4

para-methoxynitrobenzene

diphenylamine
122-39-4

diphenylamine

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With potassium phosphate; bis(acetylacetonato)palladium(II); dicyclohexyl-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine In n-heptane at 130℃; for 24h; Buchwald-Hartwig Coupling; Sealed tube; Inert atmosphere;66%
With potassium phosphate; bis(acetylacetonato)palladium(II); BrettPhos In n-heptane at 130℃; for 24h;66%
With bis(acetylacetonato)palladium(II); tripotassium phosphate "n" hydrate; dicyclohexyl-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine In n-heptane at 130℃; for 24h; Inert atmosphere;61%
4-Methoxyphenyl isocyanate
5416-93-3

4-Methoxyphenyl isocyanate

2-(trimethylsilyl)phenyl trifluoromethanesulfonate
88284-48-4

2-(trimethylsilyl)phenyl trifluoromethanesulfonate

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With cesium fluoride In acetonitrile at 100℃; for 14h; Inert atmosphere;46%
Diphenyliodonium triflate
66003-76-7

Diphenyliodonium triflate

4-methoxy-aniline
104-94-9

4-methoxy-aniline

A

N-(4-methoxyphenyl)phenylamine
1208-86-2

N-(4-methoxyphenyl)phenylamine

B

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
Stage #1: Diphenyliodonium triflate; 4-methoxy-aniline With copper(l) iodide; 2,6-di-tert-butyl-pyridine In toluene at 20℃; for 12h; Schlenk technique; Inert atmosphere;
Stage #2: With copper(l) iodide; 1,10-Phenanthroline; potassium tert-butylate In toluene at 120℃; for 24h; Schlenk technique; Inert atmosphere;
A 5%
B 44%
1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

4-methoxy-aniline
104-94-9

4-methoxy-aniline

A

N-(4-methoxyphenyl)phenylamine
1208-86-2

N-(4-methoxyphenyl)phenylamine

B

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate In toluene at 110℃; Hartwig-Buchwald coupling; Inert atmosphere;A 42%
B 9%
4-methoxy-aniline
104-94-9

4-methoxy-aniline

A

N-(4-methoxyphenyl)phenylamine
1208-86-2

N-(4-methoxyphenyl)phenylamine

B

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
Product distribution; effect of amount of Ph3Bi(OAc)2 and reaction time;
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

diphenylamine
122-39-4

diphenylamine

A

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

B

N-(3-methoxyphenyl)-diphenylamine
20588-62-9

N-(3-methoxyphenyl)-diphenylamine

Conditions
ConditionsYield
With potassium hydroxide; PEGDM-400 In toluene at 158 - 161℃; for 8h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With iron(III) oxide; potassium tert-butylate In dimethyl sulfoxide at 130℃; for 36h; regioselective reaction;
iodobenzene
591-50-4

iodobenzene

para-iodoanisole
696-62-8

para-iodoanisole

diphenylamine
122-39-4

diphenylamine

A

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

B

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
potassium hydroxide; copper at 160℃; Rate constant; Mechanism; competitive reaction, var. catalysts;
iodobenzene
591-50-4

iodobenzene

para-methoxynitrobenzene
100-17-4

para-methoxynitrobenzene

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
With copper at 195℃;
bromobenzene
108-86-1

bromobenzene

ς-[2,4,6-(CH3)3C6H2]Ni(2,2'-bipyridyl)Br

ς-[2,4,6-(CH3)3C6H2]Ni(2,2'-bipyridyl)Br

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 94 percent / KOH; Pd[P(t-Bu3)]2; cetyltrimethylammonium bromide / toluene; H2O / 3 h / 90 °C
2: 99 percent / KOH; Pd[P(t-Bu3)]2; cetyltrimethylammonium bromide / toluene; H2O / 6 h / 90 °C
View Scheme
aniline
62-53-3

aniline

5-(4-formyl-3,5-dimethoxyphenoxy)valeric aldehyde linker on a polyethylene glycol resin

5-(4-formyl-3,5-dimethoxyphenoxy)valeric aldehyde linker on a polyethylene glycol resin

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 94 percent / KOH; Pd[P(t-Bu3)]2; cetyltrimethylammonium bromide / toluene; H2O / 3 h / 90 °C
2: 99 percent / KOH; Pd[P(t-Bu3)]2; cetyltrimethylammonium bromide / toluene; H2O / 6 h / 90 °C
View Scheme
bromobenzene
108-86-1

bromobenzene

NO2, Br2

NO2, Br2

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 87 percent / Pd(dba)2, P(t-Bu)3, t-BuONa / toluene / 1 h / Ambient temperature
2: 97 percent / Pd(dba)2, P(t-Bu)3, t-BuONa / toluene / 16 h / 70 °C
View Scheme
aniline
62-53-3

aniline

Wang resin-bound styrene 4

Wang resin-bound styrene 4

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 87 percent / Pd(dba)2, P(t-Bu)3, t-BuONa / toluene / 1 h / Ambient temperature
2: 97 percent / Pd(dba)2, P(t-Bu)3, t-BuONa / toluene / 16 h / 70 °C
View Scheme
Multi-step reaction with 2 steps
1: 75 percent / Pd(dba)2, P(t-Bu)3, t-BuONa / toluene / 25 h / Ambient temperature
2: 97 percent / Pd(dba)2, P(t-Bu)3, t-BuONa / toluene / 16 h / 70 °C
View Scheme
chlorobenzene
108-90-7

chlorobenzene

SOCl2

SOCl2

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 75 percent / Pd(dba)2, P(t-Bu)3, t-BuONa / toluene / 25 h / Ambient temperature
2: 97 percent / Pd(dba)2, P(t-Bu)3, t-BuONa / toluene / 16 h / 70 °C
View Scheme
N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

4-hydroxyltriphenylamine
25069-86-7

4-hydroxyltriphenylamine

Conditions
ConditionsYield
Stage #1: N,N-diphenyl-4-methoxyaniline With boron tribromide In dichloromethane; chloroform at 0 - 20℃; for 6h; Inert atmosphere;
Stage #2: With methanol In dichloromethane; chloroform Inert atmosphere; Cooling with ice;
100%
Stage #1: N,N-diphenyl-4-methoxyaniline With boron tribromide In dichloromethane at 0 - 20℃; for 24.5h;
Stage #2: With water In dichloromethane
99%
With boron tribromide In dichloromethane at 20℃; for 3h;90%
N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

4,4′-dibromo-4′′-methoxytriphenylamine
100308-69-8

4,4′-dibromo-4′′-methoxytriphenylamine

Conditions
ConditionsYield
With N-Bromosuccinimide In N,N-dimethyl-formamide at 0℃; for 3h;95%
With N-Bromosuccinimide
N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

4-[N-phenyl-N-(4-methoxyphenyl)amino]benzaldehyde
87755-82-6

4-[N-phenyl-N-(4-methoxyphenyl)amino]benzaldehyde

Conditions
ConditionsYield
With trichlorophosphate In 1,2-dichloro-ethane for 4h; Vilsmeier formylation; Inert atmosphere; Reflux;94%
With trichlorophosphate at 0 - 80℃; for 1h; Inert atmosphere;94.8%
Stage #1: N,N-dimethyl-formamide With trichlorophosphate at 0℃; for 0.75h; Vilsmeier-Haack Formylation;
Stage #2: N,N-diphenyl-4-methoxyaniline at 60℃; for 2h; Vilsmeier-Haack Formylation;
85%
N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

trimethylaluminum
75-24-1

trimethylaluminum

diphenyl(p-tolyl)amine
4316-53-4

diphenyl(p-tolyl)amine

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); sodium t-butanolate; 1,3-bis(cyclohexyl)imidazolium tetrafluoroborate In toluene at 100℃; for 6h; Sealed tube; Glovebox; Inert atmosphere;87%
N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

C25H28BNO3

C25H28BNO3

Conditions
ConditionsYield
With C26H45OSiY In hexane at 100℃; for 24h; regioselective reaction;83%
N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

4,4-diiodo-4''-methoxytriphenylamine
199297-07-9

4,4-diiodo-4''-methoxytriphenylamine

Conditions
ConditionsYield
With potassium iodate; potassium iodide In water; acetic acid at 80℃; for 3h; Iodination;82%
With potassium iodate; potassium iodide In acetic acid
With potassium iodate; potassium iodide In acetic acid
N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4'-methyl-N,N-diphenyl-[1,1'-biphenyl]-4-amine

4'-methyl-N,N-diphenyl-[1,1'-biphenyl]-4-amine

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); C23H28N4 In tetrahydrofuran; m-xylene at 60℃; for 4h; Kumada Cross-Coupling; Inert atmosphere; Sealed tube;81%
N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

acetyl chloride
75-36-5

acetyl chloride

C21H19NO2

C21H19NO2

Conditions
ConditionsYield
With zinc(II) chloride In dichloromethane80%
1,1-diphenyl-4-(p-di-n-propylaminophenyl)-1,3-butadiene

1,1-diphenyl-4-(p-di-n-propylaminophenyl)-1,3-butadiene

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

4,4’-bisformyl-4’’-methoxytriphenylamine
149676-16-4

4,4’-bisformyl-4’’-methoxytriphenylamine

Conditions
ConditionsYield
76.5%
N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

4,4’-bisformyl-4’’-methoxytriphenylamine
149676-16-4

4,4’-bisformyl-4’’-methoxytriphenylamine

Conditions
ConditionsYield
With trichlorophosphate In 1,2-dichloro-ethane at 0℃; for 15h; Vilsmeier-Haack Formylation; Inert atmosphere; Reflux;75%
With trichlorophosphate at 95℃; for 4h; Inert atmosphere;71%
With trichlorophosphate In 1,2-dichloro-benzene at 85℃; for 24h; Vilsmeyer reaction;67%
With trichlorophosphate In 1,2-dichloro-ethane for 6h; Reflux;36.7%
With trichlorophosphate at 80℃; for 24h; Vilsmeier-Haack Formylation;
1-Methylbenzimidazole
1632-83-3

1-Methylbenzimidazole

N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

4-(1-methyl-1H-benzimidazol-2-yl)-N,N-diphenylbenzenamine
1542275-72-8

4-(1-methyl-1H-benzimidazol-2-yl)-N,N-diphenylbenzenamine

Conditions
ConditionsYield
With ortho-tolylmagnesium bromide; bis(1,5-cyclooctadiene)nickel (0); C23H30N4 In m-xylene at 90℃; for 16h;75%
N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

4-(N-phenyl-N-(4-methoxy)phenylamino)-1-bromobenzene
949910-86-5

4-(N-phenyl-N-(4-methoxy)phenylamino)-1-bromobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide In N,N-dimethyl-formamide at 20℃; for 5h;75%
N,N-diphenyl-4-methoxyaniline
4316-51-2

N,N-diphenyl-4-methoxyaniline

N4,N4'-bis(4-methoxyphenyl)-N4,N4'-diphenyl-4,4'-diaminobiphenyl
20441-07-0

N4,N4'-bis(4-methoxyphenyl)-N4,N4'-diphenyl-4,4'-diaminobiphenyl

Conditions
ConditionsYield
Stage #1: N,N-diphenyl-4-methoxyaniline With methanesulfonic acid In dichloromethane at 0℃;
Stage #2: With chloranil In dichloromethane at 0 - 20℃; for 3h;
66%
With tetrafluoroboric acid diethyl ether; C22H42N12*2BF4(1-)*2H(1+) In acetonitrile at 20℃; Reagent/catalyst; Cooling with ice;90 %Spectr.

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