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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Vanadium(III) chloride

Cas:7718-98-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Vanadium trichloride

Cas:7718-98-1

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Vanadium trichloride

Cas:7718-98-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

VANADIUM(III) CHLORIDE

Cas:7718-98-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High Purity vanadium trichloride

Cas:7718-98-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance: white powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceut

Vanadium chloride (VCl<sub>3</sub>)

Cas:7718-98-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Ocean Chemical Co., Ltd.

Ocean inorganic department is a professional supplier and exporter engaging in inorganic chemical materials and metal organic compounds. Over the past years, our company is committed to improving the product quality and developing new products, in

Vanadium chloride

Cas:7718-98-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Vanadium(III) chloride

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Other

inquiry

DB BIOTECH CO., LTD

Q1: Are you a manufacturer Answer: Yes, we are factory founded on 2012.Q2: How to contact with us Click "contact supplier" And then send us message the product you interest in, you will get reply within 12 hours.Q3:Which kind of payment terms do you

VANADIUM(III) CHLORIDE

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

VANADIUM(III) CHLORIDE

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description &amp; Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 7718-98-1 with competitive price

Cas:7718-98-1

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Vanadium chloride (VCl<sub>3</sub>)

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Beantown Chemical

in stock Application:7718-98-1

Vanadium(III) chloride, 99% trace metals basis

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Trading Company

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HWRK Chem

in store Package:10g Application:Organic Chemicals

VANADIUM(III) CHLORIDE

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

VANADIUM(III) CHLORIDE

Cas:7718-98-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Xi'an Harmonious Natural Bio-Technology Co., Ltd.

Before-Sale Service:---Any inquiries will be replied within 12 hours.---Golden Manufactory under?ISO/GMP?with?large stock.---Dedication to quality,We?have?strict?quality?control?system.?---OEM/ODM Available.---Sample is available for your evaluation

Gmp factory supply vanadium trichloride in high quality

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Ruishun Trade Co.,Ltd

Hebei ruishun trade co.,ltd, registered capital one million,have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&amp;d center,seek development by credit reputation.our products have a large price advanta

Vanadium(III) chloride

Cas:7718-98-1

Min.Order:10 Gram

FOB Price: $0.9 / 1.2

Type:Trading Company

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

sub/micron to mesh powders (near/spheres, whiskers, flake, fiber, porous) and grain/ball, thin/ thick metal / alloys pieces / parts, thin and thick (particle) film materials /target, and custom-made crystals, substrates/parts. In the industries and a

Vanadium trichloride

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of &ldquo;Excellent Quality at a Reasonable Price&rdquo;. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

VanadiuM(III) chloride, 99% (Metals b

Cas:7718-98-1

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Henan Fine Chemicals Co., Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & CommercialHenan Fine Chemicals Co., LTD. is a diversified technology - oriented integrated company, which mainly concentrates on fine chemicals. Our company is committed to becom

Vanadium(III) chloride

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Vanadium chloride (VCl<sub>3</sub>)

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai AngewChem Co., Ltd.

Shanghai AngewChemCo., Ltd. is an innovative enterprise on fine chemicals and pharmaceuticals. Based on Shanghai R&D center and Hunan chemical manufacturing plant, we offer chemical research, process development, and large-scale production. Complete

Vanadium chloride (VCl<sub>3</sub>)

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Strem Chemicals, Inc.

1.High Quality Specialty Chemicals2.Expertise and Experience in Manufacturing High Purity, High Quality Chemicals3.Long Term Focus in Inorganics, Organometallics and Metals4.ISO 9001 CertifiedAppearance:purple pwdr.

Vanadium(III) chloride, anhydrous, min. 95%

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Other

inquiry

Springchem New Material Technology Co.,Limited

≥99%, stockAppearance:dark blue to violet to black powder Storage:water-free area Package:1kg/bag;25kg/cardboard drum Application:OLED Transportation:by air, by sea

VCl3

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuxi Morality Chemical Co., Ltd

Do best quality products, erect the morality model Application:Please email us, thanks

Vanadium chloride (VCl<sub>3</sub>)

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Yanchu chemicals Co., Ltd

low price and good quality Application:It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and D

Vanadium chloride (VCl<sub>3</sub>)

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Skyrun Industrial Co.,Ltd

Adequate stocks available,prompt shipment,Strictly control on quality,Timely after-sales Application:API

VanadiuM(III) chloride, 99% (Metals basis)

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemical Co.Ltd

Vanadium chloride (VCl3) Application:for chemcial

Vanadium chloride (VCl<sub>3</sub>)

Cas:7718-98-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

vanadium hexacarbonyl
14024-00-1

vanadium hexacarbonyl

triphenyllead(IV) chloride
1153-06-6

triphenyllead(IV) chloride

A

(C6H5)3PbV(CO)6
89669-25-0

(C6H5)3PbV(CO)6

B

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In n-heptane byproducts: CO; under N2 or Ar, exclusion of light, stirred for 24 h at room temp.; filtered (VCl3), partial evapn. in vac. at room temp., cooled to -30°C overnight; elem. anal.;A 60%
B 99%
hydrogenchloride
7647-01-0

hydrogenchloride

bis(mesitylene)vanadium(0)
1272-71-5

bis(mesitylene)vanadium(0)

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In n-heptane byproducts: 1,3,5-trimethylbenzene, H2; under purified Ar atm.; soln. of V(η6-Me3C6H3)2 in heptane was treated with dry HCl; after 2 hs suspn. filtered; solid dried (vac.) at room temp.; elem. anal.;98%
vanadiumtetrachloride
7632-51-1

vanadiumtetrachloride

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
With hydrogen sulfide In benzene treatment with H2S about 20 min at ambiente temp.;; washing pptn. with CCl4 and drying in vacuum at 2 torr and 150°C;;98%
With HI In n-heptane treating a heptane soln. of VCl4 with dry HI; stirring, room temp., 15 h;; filtration; washing solid with heptane; heating, 50°C, 0.05mmHg, 4h; elem. anal.;;97%
In neat (no solvent) decompn. about 50 h;; purifn. in vac.;;90%
vanadium hexacarbonyl
14024-00-1

vanadium hexacarbonyl

trityl chloride
76-83-5

trityl chloride

A

hexaphenylethane
17854-07-8

hexaphenylethane

B

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In n-heptane byproducts: CO; under Ar or N2, exclusion of light, stirred for 10 min at room temp.; observed by IR, removal of solvent in vac., extn. (toluene), VCl3 sepd. by filtration, soln. evapd. to dryness in vac. at room temp., washed with n-heptane (C2Ph6);A 92%
B 98%
vanadium hexacarbonyl
14024-00-1

vanadium hexacarbonyl

triphenyltin chloride
639-58-7

triphenyltin chloride

A

(C6H5)3SnV(CO)6
27323-98-4

(C6H5)3SnV(CO)6

B

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In n-heptane byproducts: CO; under N2 or Ar, exclusion of light, stirred for 24 h at room temp.; filtered (VCl3), partial evapn. in vac. at room temp., cooled to -30°C overnight;A 76%
B 97%
vanadium hexacarbonyl
14024-00-1

vanadium hexacarbonyl

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
With hydrogen chloride In n-heptane byproducts: carbon monoxide, dihydrogen; under Ar or N2, exclusion of light, at -78°C, warmed to -40°C; pptn. filtered off at room temp.;96%
(CO)4V(μ-PPh2)2V(CO)4

(CO)4V(μ-PPh2)2V(CO)4

chloro-diphenylphosphine
1079-66-9

chloro-diphenylphosphine

A

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

B

Tetraphenyldiphosphin
1101-41-3

Tetraphenyldiphosphin

Conditions
ConditionsYield
In n-heptane byproducts: CO; under Ar or N2, exclusion of light, refluxed for 4 h; filtered hot (VCl3), partial evapn. of solvent, cooled at -78°C (P2Ph4);A 86%
B 91%
thionyl chloride
7719-09-7

thionyl chloride

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
With N2H5Cl In tetrachloromethane heating 10 - 15 h under N2 at reflux;; heating with CS2; pptn. washing with CHCl3 and ether;;90%
With N2H5Cl In tetrachloromethane heating 10 - 15 h under N2 at reflux;; heating with CS2; pptn. washing with CHCl3 and ether;;90%
With toluene In neat (no solvent) heating SOCl2;;
triethylsilane
617-86-7

triethylsilane

vanadiumtetrachloride
7632-51-1

vanadiumtetrachloride

A

triethylsilyl chloride
994-30-9

triethylsilyl chloride

B

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

C

vanadium(II) chloride

vanadium(II) chloride

Conditions
ConditionsYield
In neat (no solvent) in heating triethylsilane in 5 min;;A 87%
B n/a
C n/a
In neat (no solvent) in heating triethylsilane in 5 min;;A 87%
B n/a
C n/a
vanadium hexacarbonyl
14024-00-1

vanadium hexacarbonyl

chloro-diphenylphosphine
1079-66-9

chloro-diphenylphosphine

A

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

B

Tetraphenyldiphosphin
1101-41-3

Tetraphenyldiphosphin

Conditions
ConditionsYield
In n-heptane byproducts: CO; under Ar or N2, exclusion of light, stirred for 15 h at room temp.; observed by IR, removal of solvent in vac., extn. (toluene), VCl3 sepd. by filtration, soln. evapd. to dryness in vac. at room temp., washed with n-heptane (P2Ph4);A n/a
B 87%
vanadium hexacarbonyl
14024-00-1

vanadium hexacarbonyl

benzyl chloride
100-44-7

benzyl chloride

A

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

B

benzil
134-81-6

benzil

Conditions
ConditionsYield
In n-heptane byproducts: CO; under Ar or N2, exclusion of light, stirred for 12 h at room temp.; observed by IR, removal of solvent in vac., extn. (toluene), VCl3 sepd. by filtration, soln. evapd. to dryness in vac. at room temp., washed with n-heptane (dibenzyl);A n/a
B 81%
thionyl chloride
7719-09-7

thionyl chloride

vanadia

vanadia

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) in 24 h in sealed tube at 200°C;; removal of by-products on heating under N2;;80%
In neat (no solvent) in 24 h in sealed tube at 200°C;; distn. SOCl2 in vac.; pptn. washed with CS2 and dried at 80°C in vac.;;>99
vanadium hexacarbonyl
14024-00-1

vanadium hexacarbonyl

chlorobenzene
108-90-7

chlorobenzene

A

biphenyl
92-52-4

biphenyl

B

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In n-heptane byproducts: CO; under Ar or N2, exclusion of light, stirred for 48 h at room temp.; observed by IR, removal of solvent in vac., extn. (toluene), VCl3 sepd. by filtration, soln. evapd. to dryness in vac. at room temp., washed with n-heptane (diphenyl);A 80%
B n/a
vanadium
7440-62-2

vanadium

chlorine
7782-50-5

chlorine

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In gas vaporized V reacted with Cl2;40%
In tetrachloromethane slow heating of V (purity 93%) with Cl2 in CCl4 at 100°C;;
In neat (no solvent) react. of V powder with gaseous Cl2 on strong heating;;
vanadium
7440-62-2

vanadium

Iodine monochloride
7790-99-0

Iodine monochloride

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) heating under exclusion of moisture at reflux; extraction with freshly distd. CCl4 (over P2O5); filtration under N2;; pptn. washed with CCl4 and dried in vacuum;;
In melt byproducts: I2; melting of fine V-powder with an excess of ICl, react. starts even on slight warming;;>99
sulfur dioxide
7446-09-5

sulfur dioxide

vanadiumtetrachloride
7632-51-1

vanadiumtetrachloride

A

thionyl chloride
7719-09-7

thionyl chloride

B

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
byproducts: VOCl3; 2 month;
byproducts: VOCl3; 2 month;
vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

sulfur
7704-34-9

sulfur

A

sulfur dioxide
7446-09-5

sulfur dioxide

B

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) at 150°C;;
In neat (no solvent) at 150°C;;
disulfur dichloride
10025-67-9

disulfur dichloride

vanadium
7440-62-2

vanadium

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) heating 8 h at 400°C in tube; washing with CS2 and heating at 150°C in vacuum;;>99
In neat (no solvent) quant. react. of V-powder with S2Cl2 in a shooting tube at 400°C within 8 h;; solid VCl3 obtained;;>99
vanadium
7440-62-2

vanadium

tin(IV) chloride
7646-78-8

tin(IV) chloride

tin(ll) chloride

tin(ll) chloride

A

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

B

vanadium(II) chloride

vanadium(II) chloride

Conditions
ConditionsYield
In neat (no solvent) heating under back flow, 600°C;; mixture of VCl2 and VCl3 obtained;;
hydrogenchloride
7647-01-0

hydrogenchloride

vanadium
7440-62-2

vanadium

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) at 300 - 400°C;;
In neat (no solvent) react. of V-powder with sharply dried, streaming HCl-gas at 300 to 400°C;; partially sublimating VCl3 obtained;;
hydrogenchloride
7647-01-0

hydrogenchloride

vanadium iron powder

vanadium iron powder

A

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

B

vanadium(II) chloride

vanadium(II) chloride

Conditions
ConditionsYield
In neat (no solvent) reaction at 300-400 °C;;
thionyl chloride
7719-09-7

thionyl chloride

vanadia

vanadia

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) heating 8 h under reflux;; washing with CS2 and drying in vac. at 120°C;;
In neat (no solvent) heating 8 h under reflux;; extraction with CS2;;
thionyl chloride
7719-09-7

thionyl chloride

vanadium(IV) oxide

vanadium(IV) oxide

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) heating under reflux;;
In neat (no solvent)
In neat (no solvent)
thionyl chloride
7719-09-7

thionyl chloride

vanadium(IV) oxide

vanadium(IV) oxide

A

chlorine
7782-50-5

chlorine

B

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) heating;;
In neat (no solvent) heating;;
thionyl chloride
7719-09-7

thionyl chloride

vanadia

vanadia

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) 200°C, 24 h; further byproducts: higher chlorides;;
In neat (no solvent) 200°C, 24 h; further byproducts: higher chlorides;;
perchloropropene
1888-71-7

perchloropropene

vanadia

vanadia

A

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

B

vanadiumtetrachloride
7632-51-1

vanadiumtetrachloride

Conditions
ConditionsYield
In not given heating under reflux;;
In not given heating under reflux;;
disulfur dichloride
10025-67-9

disulfur dichloride

vanadia

vanadia

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) pure;;
heated; washed (CS2);
With sulfur In not given at 138°C; equimolar amounts;;
disulfur dichloride
10025-67-9

disulfur dichloride

vanadia

vanadia

A

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

B

vanadiumtetrachloride
7632-51-1

vanadiumtetrachloride

C

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In not given heating;;
vanadium(III) sulphide

vanadium(III) sulphide

chlorine
7782-50-5

chlorine

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

C

vanadiumtetrachloride
7632-51-1

vanadiumtetrachloride

Conditions
ConditionsYield
In neat (no solvent) at higher temp.;;
In neat (no solvent) at higher temp.;;
disulfur dichloride
10025-67-9

disulfur dichloride

vanadiumtetrachloride
7632-51-1

vanadiumtetrachloride

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Conditions
ConditionsYield
With carbon dioxide In neat (no solvent) heating under reflux in CO2 stream at 140 - 150°C;; drying under CO2;;
With chlorine In neat (no solvent) distn. of mixt. in Cl2 stream;; washing with ether;;
With CO2 In neat (no solvent) heating under reflux in CO2 stream at 140 - 150°C;; drying under CO2;;
methyl methylphenylphosphinate
6389-79-3

methyl methylphenylphosphinate

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

poly(vanadium methylphenylphosphinate)

poly(vanadium methylphenylphosphinate)

Conditions
ConditionsYield
In further solvent(s) byproducts: MeCl; slow heating in neat Ph(Me)P(O)OMe until complete pptn.; particle size and polymerization degree depending on heating rate;100%
1,4,7-trithiacyclononane
6573-11-1

1,4,7-trithiacyclononane

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

V(III)(1,4,7-trithiacyclononane)Cl3

V(III)(1,4,7-trithiacyclononane)Cl3

Conditions
ConditionsYield
In tetrahydrofuran; dichloromethane N2-atmosphere; pptn. on addn. of VCl3 (in THF) to slight excess of ligand (in CH2Cl2); filtration, washing (CH2Cl2); elem. anal.;100%
tetrahydrofuran
109-99-9

tetrahydrofuran

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

lithium chloride

lithium chloride

(THF)2LiCl2VCl2(THF)2 C16H32Cl4LiO4V, monocline
372099-04-2

(THF)2LiCl2VCl2(THF)2 C16H32Cl4LiO4V, monocline

Conditions
ConditionsYield
In tetrahydrofuran 1 equiv. of LiCl and VCl3 were mixed in THF, reflux for 10 h, under Ar; crystn. at 20 °C for 3 days, elem. anal.;99%
tetrahydrofuran
109-99-9

tetrahydrofuran

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

Vanadium (III) chloride-(tris-tetrahydrofuran)
131063-11-1, 16997-51-6, 19559-06-9

Vanadium (III) chloride-(tris-tetrahydrofuran)

Conditions
ConditionsYield
In tetrahydrofuran heating overnight; hot filtration, crystn. at room temp.;99%
With magnesium boiling for 8 hours in presence of Mg; exclusion of moisture (reaction under N2);; extraction with THF, evaporation and cooling to -10°C; washing with cold THF and recrystallization from THF;;
With Mg boiling for 8 hours in presence of Mg; exclusion of moisture (reaction under N2);; extraction with THF, evaporation and cooling to -10°C; washing with cold THF and recrystallization from THF;;
In tetrahydrofuran continuous extrn. with THF;
3,4-dicyanoaniline
56765-79-8

3,4-dicyanoaniline

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

vanadyl tetra-4-ureidophthalocyanine

vanadyl tetra-4-ureidophthalocyanine

Conditions
ConditionsYield
With urea In quinoline stirred (205-210°C); elem.anal.;98%
ammonium thiocyanate

ammonium thiocyanate

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

vanadium (III)-thiocyanate
7231-02-9

vanadium (III)-thiocyanate

Conditions
ConditionsYield
In hydrogenchloride extraction from 0.5n-HCl with 6M-NH4SCN with methyl isobutyl ketone;;96%
In water soln. of V(SCN)3 obtained;;
vanadium(III) chloride
7718-98-1

vanadium(III) chloride

VCl2(C4OH8)2
21729-44-2

VCl2(C4OH8)2

Conditions
ConditionsYield
With tetrahydrofuran; zinc In tetrahydrofuran a complexes was extracted twice in Soxhlet extractor for 3-4 days onto zinc, Ar atm.; filtration, washing a ppt. with THF, drying in vac.; elem. anal.;96%
vanadium(III) chloride
7718-98-1

vanadium(III) chloride

tripotassium 1,4,7-tris-(5-t-butyl-2-hydroxylatobenzyl)-1,4,7-triazacyclononane
129865-73-2

tripotassium 1,4,7-tris-(5-t-butyl-2-hydroxylatobenzyl)-1,4,7-triazacyclononane

V((C2H4)3(NCH2C6H3(O)C(CH3)3)3)
129681-97-6

V((C2H4)3(NCH2C6H3(O)C(CH3)3)3)

Conditions
ConditionsYield
With triethyl amine In acetonitrile refluxing of VCl3 in MeCN (Ar atmosphere), addn. of org. compds.; pptn. on addn. of H2O; elem. anal.;96%
5,10,15,20-tetrakis(4-methylphenyl)porphyrin

5,10,15,20-tetrakis(4-methylphenyl)porphyrin

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

oxo-5,10,15,20-tetrakis(4-methylphenyl)porphyrinatovanadium(IV)

oxo-5,10,15,20-tetrakis(4-methylphenyl)porphyrinatovanadium(IV)

Conditions
ConditionsYield
With H2O; O2 In further solvent(s) byproducts: HCl; refluxed in water-free 1,2,4-trichlorobenzene for 2 h (under Ar); 1,2,4-trichlorobenzene removed in vac.; residue dissolved in dichloromethane; filtered; chromd. (Al2O3); solvent removed from single fraction obtained; dried in vac.;96%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

vanadium(III) triflate

vanadium(III) triflate

Conditions
ConditionsYield
In neat (no solvent) (Ar); to VCl3 was added CF3SO3H and refluxed for 3 h, green solid formed; solid sepd. and dried in vac.; elem. anal.;95%
With water byproducts: HCl; reaction of VCl3 with CF3SO3H in an O2-free glove box; treatment of the reaction mixt. with H2O distilled onto the mixt., removal of formed HCl and final vacuum drying, elem. anal.;
In trifluoroacetic acid mixt. of VCl3 in neat triflic acid heated at reflux under Ar; cooled to room temp., ppt. collected;
vanadium(III) chloride
7718-98-1

vanadium(III) chloride

vanadium
7440-62-2

vanadium

Conditions
ConditionsYield
With magnesium hydride In tetrahydrofuran byproducts: H2; (argon); grinding VCl3 and MgH2 in a mill, addn. of -70°C cold THF, then slow addn. of TiCl4, heating to reflux temp. under further grinding (5 h); washing (THF), drying (vac.);94.4%
With sodium In neat (no solvent) reaction by redn. of solid VCl3 with Na in presence of CaCl2 in a bomb (vacuum or inert gas atmosphere), heating at light red heat for a period up to 3 hours;; 95% metallic V;;93%
With hydrogen In neat (no solvent) reaction by redn. of VCl3 with H2 in a stepwise procedure;; metallic V obtained;;90%
benzoin oxime
441-38-3

benzoin oxime

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

V2O4(H2O)2(C6H5C(O)C(O)C6H5)4

V2O4(H2O)2(C6H5C(O)C(O)C6H5)4

Conditions
ConditionsYield
With aq. NaOH In ethanol; water pH 2.5; heating (60-80°C, 10 min); elem. anal.;92.7%
vanadium(III) chloride
7718-98-1

vanadium(III) chloride

vanadium(II) chloride

vanadium(II) chloride

Conditions
ConditionsYield
With H2 In neat (no solvent) at 750°C;; 99.6% VCl2 unpured with 0.25% VCl3 and <0.1% Fe;;92%
With tin byproducts: SnCl2; reaction at 16.2 and 58°C;;
With hydrogen In neat (no solvent) reaction started at 480°C;;
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

V(2,2`-bipyridine)3
14376-05-7

V(2,2`-bipyridine)3

Conditions
ConditionsYield
With sodium amalgam In tetrahydrofuran under oxygen-free nitrogen or argon or vac.; 2,2'-bpyridin was added toa suspn. of VCl3 and sodium amalgam in THF; after stirring for 24 h at room temp. and filtering, the soln. was reduced under vac.; diethyletherwas slowly added; ppt. was collected, washed with petroleum (b.p.40-60°C) and recrystd. from THF-diethylether;92%
vanadium(III) chloride
7718-98-1

vanadium(III) chloride

N,N',N''-trimethyl-1,4,7-triazacyclononane
96556-05-7

N,N',N''-trimethyl-1,4,7-triazacyclononane

trichloro(1,4,7-trimethyl-1,4,7-triazacyclononane)vanadium(III)
112087-96-4

trichloro(1,4,7-trimethyl-1,4,7-triazacyclononane)vanadium(III)

Conditions
ConditionsYield
In acetonitrile heating of a soln. of VCl3 in dry acetonitrile to reflux for 10 min; precipitation on cooling of the soln.; addn. of a CH3CN soln. of the organic compound to the mixture; heating to reflux for 30 min; precipitation;;92%
4,4,5,5-tetramethyl-2-thioxo-2λ5-[1,3,2]dioxaphospholane-2-thiol
699-36-5

4,4,5,5-tetramethyl-2-thioxo-2λ5-[1,3,2]dioxaphospholane-2-thiol

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

V[S2PO(C(CH3)2)2O]3
532987-23-8

V[S2PO(C(CH3)2)2O]3

Conditions
ConditionsYield
In benzene byproducts: HCl; exclusion of moisture; soln. of alkylene dithiophosphoric acid in C6H6 added dropwise with constant stirring to VCl3 in C6H6, molar ratio 3:1, refluxed for ca. 6 h; evapd. in vac., washed with n-hexane (several times), dried in vac.; elem. anal.;92%
N,N,N,N,N,N-hexamethylphosphoric triamide
680-31-9

N,N,N,N,N,N-hexamethylphosphoric triamide

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

VCl3(((CH3)2N)3PO)3
76077-70-8

VCl3(((CH3)2N)3PO)3

Conditions
ConditionsYield
In tetrahydrofuran (N2), VCl3 extracted into dry THF, organic compound added; collected, washed with n-hexane, pumped in vac. at room temp. for several hours; elem. anal.;91%
2,2':6,2''-terpyridine
1148-79-4

2,2':6,2''-terpyridine

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

V(III)(2,2':6',2''-terpyridine)Cl3
64347-78-0

V(III)(2,2':6',2''-terpyridine)Cl3

Conditions
ConditionsYield
In acetonitrile (Ar); to soln. of VCl3 was added ligand, soln. stirred for 4 h, color then had charged from purple to brown; brown ppt. was sepd., washed with diethylether and dried in vac.; elem. anal.;91%
vanadium(III) chloride
7718-98-1

vanadium(III) chloride

1,4,7-tri(iso-propyl)-1,4,7-triazacyclononane
110076-36-3

1,4,7-tri(iso-propyl)-1,4,7-triazacyclononane

{V(C15H33N3)Cl3}
147185-97-5

{V(C15H33N3)Cl3}

Conditions
ConditionsYield
In acetonitrile refluxing a suspension of VCl3 in dry CH3CN under argon; addn. of C15H33N3 in CH3CN; refluxing for 0.5 h;; pptn. on cooling to 20°C; elem. anal.;;91%
vanadium(III) chloride
7718-98-1

vanadium(III) chloride

1,4,7-triazacyclononane
4730-54-5

1,4,7-triazacyclononane

(1,4,7-triazacyclononane)VCl3
127133-03-3

(1,4,7-triazacyclononane)VCl3

Conditions
ConditionsYield
In acetonitrile Ar-atmosphere; refluxing VCl3 to dissoln., addn. of ligand at 40°C, refluxing for 1 h; pptn. on cooling to 10°C, collection (filtration);91%
In N,N-dimethyl-formamide addn. of ligand to soln. of VCl3, refluxing (1 h); pptn. on cooling (room temp.), filtration, washing (Et2O), drying (air); elem. anal.;23%
niobium

niobium

rubidium chloride

rubidium chloride

niobium pentachloride
10026-12-7

niobium pentachloride

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

RbVNb3Cl11

RbVNb3Cl11

Conditions
ConditionsYield
In neat (no solvent) (Ar); sealed in a silica tube under vac., heated at 740°C for 1 wk followed by slow cooling to 550°C in 48 h; radiative cooling to room temp.;90%
vanadium(III) chloride
7718-98-1

vanadium(III) chloride

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

bis(mesitylene)vanadium(0)
1272-71-5

bis(mesitylene)vanadium(0)

Conditions
ConditionsYield
With Al; AlCl3 In 1,3,5-trimethyl-benzene heating suspension of VCl3, Al powder and AlCl3 in mesitylene at 120-130°C for 2 h, under purified Ar atmosphere; addn. of heptane and THF at 20-25°C under vigorous stirring; mechanism discussed;; filtration after 3 h; removal of volatiles in vac. at 50°C; treating residue with heptane; filtration; washing carefully with heptane; cooling to -78°C;;90%
With Al; AlCl3 In 1,3,5-trimethyl-benzene heating suspension of VCl3, Al powder and AlCl3 in mesitylene at 120-130°C for 2 h, under purified Ar atmosphere; addn. of heptane and DMF at 20-25°C under vigorous stirring; mechanism discussed;; filtration after 3 h; removal of volatiles in vac. at 50°C; treating residue with heptane; filtration; washing carefully with heptane; cooling to -78°C;;70%
With AlBr3; Al In 1,3,5-trimethyl-benzene sublimation, recrystn. from pentane;14%
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