3-Methoxybenzyl alcohol supplier

Name
m-Anisyl alcohol
EINECS 230-200-5
CAS No. 6971-51-3
Article Data187
CAS DataBase
Density 1.085 g/cm³
Solubility Immiscible with water
Melting Point 29 - 30oC
Formula C₈H₁₀O₂
Boiling Point 247.4 °C at 760 mmHg
Molecular Weight 138.166
Flash Point 109.9 °C
Transport Information
Appearance Colorless to light yellow liquid
Safety 23-24/25-37/39-26-36
Risk Codes 36/37/38-22
Molecular Structure
Hazard Symbols Xn, Xi
Synonyms 3-methoxy benzylalcohol;Benzylalcohol, m-methoxy- (6CI,7CI,8CI);(3-Methoxyphenyl)methanol;1-(Hydroxymethyl)-3-methoxybenzene;3-Methoxybenzenemethanol;NSC 66559;[3-(Methyloxy)phenyl]methanol;m-Anisalcohol;m-Methoxybenzyl alcohol;Benzenemethanol,3-methoxy-;
PSA 29.46000
LogP 1.18750

Synthetic route

: 591-31-1
3-methoxy-benzaldehyde

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With hydrogen; Pd as electrode electrochemical reaction;	100%
With sodium tetrahydroborate In methanol at 20℃; for 1h;	100%
With sodium tetrahydroborate; Dowex1-x8 In tetrahydrofuran at 20℃; for 0.5h;	99%

: 5368-81-0
methyl 3-methoxybenzoate

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
Stage #1: methyl 3-methoxybenzoate With diethylzinc; lithium chloride In tetrahydrofuran; hexane at 20℃; for 6h; Inert atmosphere; Stage #2: With sodium hydroxide In tetrahydrofuran; hexane; water at 20℃; for 8h; Inert atmosphere; chemoselective reaction;	98%
With HN(CH2CH2C3H3N2Mes)2Cl2; potassium tert-butylate; hydrogen; cobalt(II) chloride In tetrahydrofuran at 100℃; under 22502.3 Torr; for 16h; Autoclave; Glovebox;	91%
With methanol; sodium tetrahydroborate In tetrahydrofuran at 65℃; for 4h;	90%

: 132816-03-6
(3-Methoxy-benzyloxy)-trimethyl-silane

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With Oxone In methanol for 0.4h; Heating;	98%
With bismuth(lll) trifluoromethanesulfonate In methanol at 20℃; for 0.0333333h;	97%
With poly (ethylene glycol)-sulfonated sodium montmorillonite nanocomposite In methanol at 20℃; for 0.00833333h;	96%

: 18483-97-1
2-(3-methoxybenzyloxy)tetrahydro-2H-pyran

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With bismuth(lll) trifluoromethanesulfonate In methanol for 0.05h;	97%
With sulfuric acid; silica gel In methanol at 20℃; for 0.5h;	95%
With Oxone In methanol for 1.5h; Heating;	80%

: 10259-22-0
ethyl 3-methoxybenzoate

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With lithium borohydride In diethyl ether; toluene at 100℃; for 0.5h;	95%

: 1026136-92-4
2-tert-butylsulfinyl-3-methoxyphenylmethanol

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With nickel In ethanol for 3h; Reflux;	94%

: 19693-78-8
2-(3-methoxyphenyl)-1,3-dioxolane

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With sulfuric acid; zinc at 38℃; for 2h; Temperature;	93.5%

: 1058648-97-7
3-methoxy-1-[(ethoxymethoxy)methyl]benzene

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
phosphotungstic acid In ethanol for 3h; Heating;	93%
With 1-methylimidazole hydrogen sulfate at 50℃; for 1.25h; chemoselective reaction;	92%

: 161358-52-7
3-methoxy-1-(methoxymethoxy)methyl benzene

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With 1-methylimidazole hydrogen sulfate at 120℃; for 0.05h; Microwave irradiation; chemoselective reaction;	93%
phosphotungstic acid In ethanol for 3h; Heating;	89%

: 591-31-1
3-methoxy-benzaldehyde

: 766-97-2
4-n-methylphenylacetylene

A: 6971-51-3
3-methoxybenzyl alcohol

B: 1-(3-methoxyphenyl)-3-(p-tolyl)prop-2-yn-1-one

Conditions

Conditions	Yield
With triethylamine; zinc(II) iodide In toluene at 80℃; for 12h; Schlenk technique; Inert atmosphere;	A n/a B 93%

...Expand

: 874-98-6
1-bromomethyl-3-methoxybenzene

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With water; dimethyl sulfoxide at 50℃; for 24h; Schlenk technique; Sealed tube;	90%
With potassium hydroxide In ethanol for 2h; Ambient temperature; Yield given;

: C14H16O2Si

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With sodium hydroxide In water Schlenk technique; Inert atmosphere;	90%
With sodium hydroxide In water

: 591-31-1
3-methoxy-benzaldehyde

A: 6971-51-3
3-methoxybenzyl alcohol

B: 586-38-9
3-Methoxybenzoic acid

Conditions

Conditions	Yield
With sodium hydroxide In water at 15℃; for 2.5h; Cannizzaro Reaction;	A n/a B 87%
With Ximenia american In aq. phosphate buffer; water at 30℃; for 72h; pH=7; Enzymatic reaction;	A 75% B n/a

: 498-00-0
4-hydroxymethyl-2-methoxyphenol

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
Stage #1: 4-hydroxymethyl-2-methoxyphenol With TentaGel-N(R)C(O)CH2C2F4OC2F4SO2F; potassium carbonate In N,N-dimethyl-formamide at 20℃; Stage #2: With formic acid; 1,3-bis-(diphenylphosphino)propane; triethylamine; palladium diacetate In N,N-dimethyl-formamide at 85℃; for 2h; Further stages.;	86%

: 2-((3-methoxybenzyl)oxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With hydrogenchloride In tetrahydrofuran; methanol; water at 50℃; for 1h; Inert atmosphere; Glovebox; Schlenk technique;	84%
With water; sodium hydroxide In tetrahydrofuran at 25℃; for 1h; Inert atmosphere; Schlenk technique; Sealed tube;	0.12 g

: 5813-86-5
m-methoxybenzamide

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With C24H20ClN2OPRu; potassium tert-butylate; hydrogen In tetrahydrofuran at 110℃; under 10640.7 Torr; for 36h; Inert atmosphere; Schlenk technique;	83%

: 625-81-0
diisopropyl zinc

: 591-31-1
3-methoxy-benzaldehyde

A: 6971-51-3
3-methoxybenzyl alcohol

B: 1-(3-methoxyphenyl)-2-methylpropan-1-ol

Conditions

Conditions	Yield
With C35H47N5O4 In toluene at 0 - 20℃; for 12h; Inert atmosphere; enantioselective reaction;	A 11% B 83%

...Expand

: 591-31-1
3-methoxy-benzaldehyde

A: 6971-51-3
3-methoxybenzyl alcohol

B: 24318-46-5
3-methoxybenzyl 3-methoxybenzoate

C: 586-38-9
3-Methoxybenzoic acid

Conditions

Conditions	Yield
With aluminum (III) chloride; triethylamine In dichloromethane at 20℃; for 48h; Cannizzaro Reaction;	A 9% B 81% C 9%
With aluminum (III) chloride; triethylamine In dichloromethane at 20℃; for 48h; Cannizzaro Reaction;	A 74% B 12% C 74%

...Expand

: 586-38-9
3-Methoxybenzoic acid

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
Stage #1: 3-Methoxybenzoic acid With sodium aminodiboranate In tetrahydrofuran at 20℃; Stage #2: With water	78%
With lithium aluminium tetrahydride; diethyl ether; benzene
With lithium aluminium tetrahydride

: 620-24-6
3-Hydroxybenzyl alcohol

: 75-57-0
tetramethlyammonium chloride

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With caesium carbonate In 1,2-dimethoxyethane at 145℃; for 1h; Microwave irradiation; Inert atmosphere; Sealed vessel;	72%

: 150192-39-5
2-Bromo-5-methoxybenzyl alcohol

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With palladium diacetate; caesium carbonate; triphenylphosphine In N,N-dimethyl-formamide at 120℃; for 24h; Inert atmosphere;	72%

: 5071-96-5
3-METHOXYBENZYLAMINE

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With [Ir(κ2O,O-CH3COO)(I)2{κC,C'-methylenebis(N-methyl)imidazole-2-ylidene}]; water; glycerol; potassium hydroxide at 120℃; for 16h;	70%

: 51755-56-7
(3-methoxybenzyl)trimethylsilane

A: 6971-51-3
3-methoxybenzyl alcohol

B: 36707-27-4
1,2-bis(3-methoxyphenyl)ethane

Conditions

Conditions	Yield
With titanium(IV) oxide; silver sulfate In water; acetonitrile for 0.5h; Oxidation; desilylation; dimerization; coupling; Irradiation;	A 27% B 68%

: 1026136-90-2
2-tert-butylsulfinyl-3-methoxybenzaldehyde

: 6971-51-3
3-methoxybenzyl alcohol

Conditions

Conditions	Yield
With nickel In methanol for 3h; Reflux;	44%

: 194018-68-3
vanillin triflate

A: 6971-51-3
3-methoxybenzyl alcohol

B: 100-84-5
1-methoxy-3-methyl-benzene

Conditions

Conditions	Yield
With palladium 10% on activated carbon; hydrogen In ethyl acetate at 20℃; under 760.051 Torr; for 40h;	A 30% B 42%

: 556-56-9
allyl iodid

: 591-31-1
3-methoxy-benzaldehyde

A: 24165-65-9
1-(3-methoxyphenyl)but-3-en-1-ol

B: 6971-51-3
3-methoxybenzyl alcohol

C: 156091-01-9
1,2-bis(3-methoxyphenyl)-1,2-ethanediol

Conditions

Conditions	Yield
With ammonium chloride; magnesium for 12h; Ambient temperature;	A 40% B 18 % Spectr. C 37 % Spectr.

...Expand

: 591-31-1
3-methoxy-benzaldehyde

: 870-63-3
prenyl bromide

A: 6971-51-3
3-methoxybenzyl alcohol

B: 133480-24-7
2,2-dimethyl-1-(3-methoxy phenyl)-3-butene-1-one

C: 1-(3-methoxy-phenyl)-2,2-dimethyl-but-3-en-1-ol

D: 3-methoxy-benzoic acid 1-(3-methoxy-phenyl)-2,2-dimethyl-but-3-enyl ester

Conditions

Conditions	Yield
With chromium dichloride; lithium iodide In tetrahydrofuran at 55℃; for 3h; Hiyama-Nozaki reaction;	A n/a B n/a C 33% D n/a

...Expand

: 107325-75-7
(3-methoxybenzoyl)trimethylsilane

A: 6971-51-3
3-methoxybenzyl alcohol

B: 586-38-9
3-Methoxybenzoic acid

C: (R)-(3-Methoxy-phenyl)-trimethylsilanyl-methanol

D: (S)-(-)-3-Methoxy-α-(trimethylsilyl)benzenemethanol

Conditions

Conditions	Yield
With baker's yeast on montmorillonite K10; potassium chloride; Sucrose at 35℃; for 48h; Reduction; Bioreduction; Enzymatic reaction; Title compound not separated from byproducts;	A 25% B n/a C n/a D n/a

...Expand

: 591-31-1
3-methoxy-benzaldehyde

A: 6971-51-3
3-methoxybenzyl alcohol

: 156091-01-9
(1RS,2RS)-1,2-Bis(3-methoxyphenyl)ethane-1,2-diol

C: (S,R)-1,2-bis(3-methoxyphenyl)ethane-1,2-diol

Conditions

Conditions	Yield
With zinc In water at 70℃; for 2h; Green chemistry;	A 12% B n/a C n/a
With ammonium chloride; zinc In water at 45℃; for 2h;	A 7% B n/a C n/a
With sodium hydroxide for 1.66667h; Ambient temperature; Yield given. Yields of byproduct given;
Stage #1: 3-methoxy-benzaldehyde With chloro-trimethyl-silane; samarium diiodide; tert-butylammonium hexafluorophosphate(V) In tetrahydrofuran at 20℃; Electrochemical reaction; Stage #2: Acidic conditions; Overall yield = 42 %; diastereoselective reaction;

...Expand

: 6971-51-3
3-methoxybenzyl alcohol

: 591-31-1
3-methoxy-benzaldehyde

Conditions

Conditions	Yield
With oxygen; perruthenate modified mesoporous silicate MCM-41 In toluene at 80℃; for 3h; Oxidation;	100%
With Oxone; [Mn(NO3)2(2,3,5,6-tetra(2-pyridyl)pyrazine)(H2O)]; tetrabutylammomium bromide In dichloromethane at 20℃; Catalytic behavior; Reagent/catalyst;	100%
With 1-benzyl-1-aza-4-azoniabicyclo<2.2.2>octane periodate In acetonitrile for 10h; Heating;	99%

: 6971-51-3
3-methoxybenzyl alcohol

: 824-98-6
m-methoxybenzyl chloride

Conditions

Conditions	Yield
With thionyl chloride; triethylamine In dichloromethane at 20℃; for 1h;	100%
With hydrogenchloride at 120℃; under 7500.75 Torr; Flow reactor;	99%
With pyridine; thionyl chloride In benzene at 0℃; for 2h;	96%

: 6971-51-3
3-methoxybenzyl alcohol

: 874-98-6
1-bromomethyl-3-methoxybenzene

Conditions

Conditions	Yield
With phosphorus tribromide In benzene at 20℃;	100%
With chloro-trimethyl-silane; lithium bromide In acetonitrile for 22h; Bromination; Heating;	98%
With 1H-imidazole; iodine In dichloromethane at 20℃; for 0.25h;	96%

: 6971-51-3
3-methoxybenzyl alcohol

: 108-24-7
acetic anhydride

: 35480-26-3
m-(acetoxymethyl)anisole

Conditions

Conditions	Yield
With pyridine at 21℃; for 12h;	100%
With pyridine 1.) 0 degC, 15 min 2.) room temperature, 12 h;	99%
With tin(IV) tetraphenylporphyrin perchlorate at 20℃; for 0.0833333h;	99%

: 6971-51-3
3-methoxybenzyl alcohol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 153974-48-2
3-methoxy-O-tert-butyldimethylsilylbenzyl alcohol

Conditions

Conditions	Yield
With 1H-imidazole at 25℃;	100%
With 1H-imidazole In N,N-dimethyl-formamide at 25℃;	100%
With 1H-imidazole In dichloromethane	94%
With 1H-imidazole In dichloromethane at 15 - 42.9℃; for 17h; Inert atmosphere; Large scale;	94%
With 1H-imidazole In dichloromethane at 15 - 42.9℃; for 17.15h; Inert atmosphere; Large scale;	94%

: 6971-51-3
3-methoxybenzyl alcohol

: 98-88-4
benzoyl chloride

: 24318-44-3
3-methoxylbenzyl benzoate

Conditions

Conditions	Yield
With pyridine at 0℃; for 1.5h;	100%

: 6971-51-3
3-methoxybenzyl alcohol

: 100-84-5
1-methoxy-3-methyl-benzene

Conditions

Conditions	Yield
With palladium dichloride In methanol at 40℃; for 18h; Inert atmosphere; Green chemistry; chemoselective reaction;	99%
With chlorocarbonylbis(triphenylphosphine)iridium(I); hydrazine hydrate; potassium hydroxide In methanol at 160℃; for 3h; Wolff-Kishner Reduction; Sealed tube;	86%
With chlorocarbonylbis(triphenylphosphine)iridium(I); hydrazine hydrate; potassium hydroxide In methanol at 160℃; for 3h; Sealed tube;	86%
With carbon monoxide; hydrogen; benzene unter Zusatz von Octacarbonyldikobalt und CoCO3 auf 190grad/238 at;
Multi-step reaction with 3 steps 1: 78 percent / sodium iodide; sodium hydride / tetrahydrofuran / 0 - 20 °C 2: sulfuryl chloride / CH2Cl2 / -78 °C 3: lithium; 4,4'-di-tert-butylbiphenyl / tetrahydrofuran / 1 h / 0 °C View Scheme

: 6971-51-3
3-methoxybenzyl alcohol

: 93-97-0
benzoic acid anhydride

: 24318-44-3
3-methoxylbenzyl benzoate

Conditions

Conditions	Yield
With bismuth(lll) trifluoromethanesulfonate In acetonitrile for 0.5h; Heating;	99%

: 6971-51-3
3-methoxybenzyl alcohol

: 109-94-4
formic acid ethyl ester

: 3-methoxybenzyl formate

Conditions

Conditions	Yield
With bismuth(lll) trifluoromethanesulfonate for 0.666667h; Heating;	99%
With K5 for 1.25h; Heating;	97%
(NH4)8[CeW10O36]*20H2O for 9h; Heating;	85%

: 6971-51-3
3-methoxybenzyl alcohol

: 62-53-3
aniline

: 81308-21-6
N-(3-methoxybenzyl)aniline

Conditions

Conditions	Yield
With zinc(II) nitrate hexahydrate; potassium tert-butylate In toluene at 140℃; for 36h; Sealed tube; Inert atmosphere; Schlenk technique;	99%
With sodium hydrogencarbonate; bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] In toluene at 110℃; for 17h;	97%
With cesiumhydroxide monohydrate at 130℃; for 24h; Schlenk technique;	96%

: 6971-51-3
3-methoxybenzyl alcohol

: 17100-64-0
(4-bromo-3-methoxyphenyl)methanol

Conditions

Conditions	Yield
With N-Bromosuccinimide In tetrahydrofuran at 20℃; for 8h;	99%
With sodium bromate; sodium hydrogensulfite In water; acetonitrile at 20℃; for 1.5h;	88%
With sodium bromate; sodium hydrogensulfite In water; acetonitrile at 20℃; for 1.5h;	88%

: 6971-51-3
3-methoxybenzyl alcohol

: 141-97-9
ethyl acetoacetate

: 63965-31-1
ethyl 2-(3-methoxybenzyl)-3-oxobutanoate

Conditions

Conditions	Yield
With rice husk ash nano silica supported 12-tungstophosphoric acid at 80℃; for 0.0333333h; Neat (no solvent);	99%
With ferric hydrogen sulphate In 1,2-dichloro-ethane at 86℃; for 5h;	65%

: 6971-51-3
3-methoxybenzyl alcohol

: 105-45-3
acetoacetic acid methyl ester

: 1350653-48-3
methyl 2-[(3-methoxyphenyl)methyl]-3-oxobutanoate

Conditions

Conditions	Yield
With rice husk ash nano silica supported 12-tungstophosphoric acid at 80℃; for 0.0333333h; Neat (no solvent);	99%
With cesium 12-tungstophosphate at 80℃; for 1h; Neat (no solvent);	92%

: 6971-51-3
3-methoxybenzyl alcohol

: 1527-89-5
3-methoxybenzonitrile

Conditions

Conditions	Yield
With ammonia; oxygen In tert-Amyl alcohol; water at 100℃; under 3750.38 Torr; for 10h; Autoclave; High pressure;	99%
With ammonium hydroxide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [{(MeOH)Cu(OAc)}(μ-k2:k1-2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)acetic acid(-H))]2*0.5H2O; tetraethylammonium iodide; oxygen; potassium carbonate In water at 60℃; under 760.051 Torr; for 24h;	93%
With ammonia; oxygen In tert-Amyl alcohol; water at 130℃; under 3750.38 Torr; for 24h;	92%

: 108-05-4
vinyl acetate

: 6971-51-3
3-methoxybenzyl alcohol

: 35480-26-3
m-(acetoxymethyl)anisole

Conditions

Conditions	Yield
With Ximenia american In hexane at 30℃; for 24h; pH=5; Enzymatic reaction;	99%

: 86-73-7
9H-fluorene

: 6971-51-3
3-methoxybenzyl alcohol

: 9-(3-methoxybenzyl)-9H-fluorene

Conditions

Conditions	Yield
With potassium tert-butylate In toluene at 120℃; for 3h; Inert atmosphere;	99%
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; potassium tert-butylate In toluene at 120℃; for 18h; Inert atmosphere; Sealed tube;	87%

: 6971-51-3
3-methoxybenzyl alcohol

: 64-19-7
acetic acid

: 35480-26-3
m-(acetoxymethyl)anisole

Conditions

Conditions	Yield
With bismuth(lll) trifluoromethanesulfonate at 20℃; for 0.333333h;	98%
With K5 for 0.75h; Heating;	97%
In neat (no solvent) at 70℃; for 0.416667h; Catalytic behavior;	92 %Chromat.

: 33647-88-0
(R)-5-oxo-5,6-dihydro-2H-pyran-2-yl acetate

: 6971-51-3
3-methoxybenzyl alcohol

: 581782-83-4
(S)-(-)-6-(3-methoxybenzyl)oxy-2H-pyran-3(6H)-one

Conditions

Conditions	Yield
Stage #1: 3-methoxybenzyl alcohol With triphenyl phosphite; palladium diacetate In dichloromethane Stage #2: (R)-5-oxo-5,6-dihydro-2H-pyran-2-yl acetate In dichloromethane	98%

: 6971-51-3
3-methoxybenzyl alcohol

: 999-97-3
1,1,1,3,3,3-hexamethyl-disilazane

: 132816-03-6
(3-Methoxy-benzyloxy)-trimethyl-silane

Conditions

Conditions	Yield
With poly(4-vinylpyridine) In acetonitrile at 20℃; for 0.0166667h;	98%
With copper(II) sulfate In acetonitrile at 20℃; for 4h;	95%
With iron(III) chloride In acetonitrile at 20℃;	95%

: 6971-51-3
3-methoxybenzyl alcohol

: 70-55-3
toluene-4-sulfonamide

: 191085-63-9
N-(3-methoxybenzyl)-4-methylbenzenesulfonamide

Conditions

Conditions	Yield
With Ru/Fe3O4; potassium carbonate at 150℃; for 12h; Inert atmosphere;	98%
With air; copper diacetate; potassium carbonate at 150℃; for 12h;	91%
With copper diacetate; potassium carbonate at 150℃; for 12h;	91%

: 1450-14-2
1,1,1,2,2,2-hexamethyldisilane

: 6971-51-3
3-methoxybenzyl alcohol

: 132816-03-6
(3-Methoxy-benzyloxy)-trimethyl-silane

Conditions

Conditions	Yield
With lanthanum(III) nitrate hexahydrate In acetonitrile at 20℃;	98%

: 6971-51-3
3-methoxybenzyl alcohol

: 123-54-6
acetylacetone

: 791809-44-4
3-(3-methoxybenzyl)pentane-2,4-dione

Conditions

Conditions	Yield
With rice husk ash nano silica supported 12-tungstophosphoric acid at 80℃; for 0.0333333h; Neat (no solvent);	98%

: 6971-51-3
3-methoxybenzyl alcohol

: 95-55-6
2-amino-phenol

: 32959-59-4
2-(3-methoxyphenyl)benzoxazole

Conditions

Conditions	Yield
Stage #1: 3-methoxybenzyl alcohol With oxygen at 106℃; under 3800.26 Torr; for 0.216667h; Flow reactor; Green chemistry; Stage #2: 2-amino-phenol at 106℃; Flow reactor; Green chemistry; Stage #3: at 106℃; for 0.666667h; Flow reactor; Green chemistry;	98%

: 110-87-2
3,4-dihydro-2H-pyran

: 6971-51-3
3-methoxybenzyl alcohol

: 18483-97-1
2-(3-methoxybenzyloxy)tetrahydro-2H-pyran

Conditions

Conditions	Yield
With H7[PMo8V4O40] In acetonitrile at 20℃; for 0.0833333h;	97.5%
With C10H10N2O6S2(2+)*2HO4S(1-) at 20℃; for 0.116667h;	91%
With P-benzyltriphenylphosphonium tribromide In dichloromethane at 20℃; for 0.116667h;	90%

: 109-09-1
2-chloropyridine

: 6971-51-3
3-methoxybenzyl alcohol

: 1044501-34-9
2-(3-methoxybenzyloxy)pyridine

Conditions

Conditions	Yield
With potassium tert-butylate In 1,4-dioxane at 98℃; for 18h;	97%
With potassium tert-butylate In 1,4-dioxane at 98℃; for 19h;	97%

: 6971-51-3
3-methoxybenzyl alcohol

: 55-21-0
benzamide

: N-(3'-methoxybenzyl)benzamide

Conditions

Conditions	Yield
With potassium carbonate at 160℃; for 12h;	97%
With C44H39IrN2P(1+)*C32H12BF24(1-); caesium carbonate In toluene at 120℃; for 12h; Inert atmosphere;	91%
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; sodium acetate at 130℃; for 17h; Inert atmosphere;	59%

3-Methoxybenzyl alcohol Specification

1. Introduction of 3-Methoxybenzyl alcohol
3-Methoxybenzyl alcohol is clear colorless liquid for API intermediartes, the IUPAC Name of it is (3-Methoxyphenyl)methanol.

2. Properties of 3-Methoxybenzyl alcohol
Melting Point: 89-91 °C
Product Categories: Benzhydrols, Benzyl & Special Alcohols ; Alcohol
Polar Surface Area: 18.46 Å²
Index of Refraction: 1.531
Molar Refractivity: 39.38 cm³
Molar Volume: 127.2 cm³
Surface Tension: 38.7 dyne/cm
Density of Benzenemethanol,3-methoxy-: 1.085 g/cm³
Flash Point: 109.9 °C
Enthalpy of Vaporization: 51.2 kJ/mol
Boiling Point: 247.4 °C at 760 mmHg
Vapour Pressure: 0.0136 mmHg at 25°C

3. Structure Descriptors of 3-Methoxybenzyl alcohol
InChI=1S/C8H10O2/c1-10-8-4-2-3-7(5-8)6-9/h2-5,9H,6H2,1H3
InChIKey: IIGNZLVHOZEOPV-UHFFFAOYSA-N

4. Safety Information of 3-Methoxybenzyl alcohol

Hazard Codes : Harmful Xn,Xi
Risk Statements: 36/37/38-22
R36/37/38: Irritating to eyes, respiratory system and skin.
R22:Harmful if swallowed.
Safety Statements: 23-24/25-37/39-26-36
S23: Do not breathe vapour.
S24/25: Avoid contact with skin and eyes.
S37/39: Wear suitable gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36: Wear suitable protective clothing.
WGK Germany: 3
HS Code: 29094990

Product Name

m-Anisyl alcohol

Synthetic route

3-Methoxybenzyl alcohol Specification

Related Products

Hot Products