9-(4-Bromophenyl)carbazole supplier

: 589-87-7
1,4-bromoiodobenzene

: 86-74-8
9H-carbazole

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
With copper(l) iodide; 1,10-Phenanthroline; potassium hydroxide In 1,2-dimethoxyethane; water at 95℃; for 20h; Catalytic behavior; Solvent; Schlenk technique; Inert atmosphere; Sealed tube;	99%
With copper; potassium carbonate In N,N-dimethyl acetamide at 180℃; for 40h; Schlenk technique; Inert atmosphere;	99%
With copper; potassium carbonate In N,N-dimethyl-formamide at 130℃; for 42h; Inert atmosphere;	96%

: 189999-35-7
[1,1'-biphenyl]-2,2'-iodonium trifluoromethanesulfonate

: 106-40-1
4-bromo-aniline

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
With copper diacetate; sodium carbonate In ethylene glycol; isopropyl alcohol at 90℃; for 16h;	98.46%
With copper diacetate; sodium carbonate; ethylene glycol In isopropyl alcohol at 85℃; for 16h; Ullmann Condensation; Inert atmosphere;	65%
With copper diacetate; sodium carbonate In ethylene glycol; isopropyl alcohol for 16h; Inert atmosphere; Reflux; Green chemistry;

: 86-74-8
9H-carbazole

: 589-21-9
(4-bromophenyl)hydrazine

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
With palladium diacetate; cesium fluoride In acetonitrile at 60℃; for 12h; Schlenk technique;	96%

: 86-74-8
9H-carbazole

: 460-00-4
1-Bromo-4-fluorobenzene

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
With caesium carbonate In N,N-dimethyl-formamide at 150℃; for 24h;	95%
With potassium phosphate In N,N-dimethyl-formamide at 190℃; for 1h; Microwave irradiation;	91%
With caesium carbonate In dimethyl sulfoxide at 160℃; for 48h; Inert atmosphere;	80%
With potassium fluoride; 18-crown-6 ether In dimethyl sulfoxide for 24h; Reflux;	68.3%
With caesium carbonate In N,N-dimethyl-formamide at 20℃; for 16h; Inert atmosphere;	66%

: 603-34-9
N,N-diphenylaminobenzene

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
With N-Bromosuccinimide In chloroform at 20℃; for 24h;	91%
Multi-step reaction with 2 steps 1: N-Bromosuccinimide / N,N-dimethyl-formamide / 16 h / 0 °C / Inert atmosphere 2: 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; tetrakis(acetonitrile)copper(I)tetrafluoroborate; 2.9-dimethyl-1,10-phenanthroline; iodine; methyloxirane / tetrahydrofuran / 21 h / 21 °C / Flow reactor; Irradiation View Scheme

: 106-37-6
1.4-dibromobenzene

: 86-74-8
9H-carbazole

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
With copper(l) iodide; potassium carbonate; L-proline In dimethyl sulfoxide at 140℃; Ullmann reaction; Inert atmosphere;	85%
With copper; potassium carbonate; nitrobenzene at 120 - 160℃; Inert atmosphere;	85%
With potassium phosphate; copper(l) iodide; trans-1,2-Diaminocyclohexane In toluene at 110℃; for 24h; Inert atmosphere; sealed tube;	83%

: 589-87-7
1,4-bromoiodobenzene

: 86-74-8
9H-carbazole

A: 57102-42-8
N-(4-bromophenyl)carbazole

B: 19287-68-4
9-(4-(9H-carbazol-9-yl)phenyl)-9H-carbazole

Conditions

Conditions	Yield
With copper; potassium carbonate In Triethylene glycol dimethyl ether at 180 - 200℃; for 24h; Ullmann condensation;	A 71% B 28%
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tri-tert-butyl phosphine; sodium t-butanolate In toluene at 111℃; for 26h; Schlenk technique; Inert atmosphere; chemoselective reaction;	A 49% B 13%

...Expand

: 2101-88-4
1-azido-4-bromobenzene

: 4688-76-0
2-Biphenylboronic acid

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver(I) acetate; sodium carbonate In 1,4-dioxane at 80℃; for 12h; Schlenk technique;	70%

: 2113-51-1
2-iodobiphenyl

: 106-40-1
4-bromo-aniline

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
With copper diacetate; palladium diacetate; caesium carbonate; triphenylphosphine In N,N-dimethyl-formamide at 120℃; for 12h; Sealed tube;	48%

N-N'-dimetylpropyleneurea: N-N'-dimetylpropyleneurea

: 106-37-6
1.4-dibromobenzene

: 7681-65-4
copper(I) iodide

: 86-74-8
9H-carbazole

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
With potassium carbonate; 18-crown-6 ether	35%

...Expand

: 24044-24-4
1,3,4-trimethylimidazolidin-2-one

: 106-37-6
1.4-dibromobenzene

: 86-74-8
9H-carbazole

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
With potassium carbonate; 18-crown-6 ether; copper(I) iodide	35%

...Expand

: 86-74-8
9H-carbazole

: 583-53-9
1,2-dibromobenzene

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
With potassium carbonate; copper(II) sulfate at 210℃; Inert atmosphere;	31%

: 36809-26-4
4-N,N-diphenylamino-1-bromobenzene

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
With tetrakis(acetonitrile)copper(I)tetrafluoroborate; 2.9-dimethyl-1,10-phenanthroline; iodine; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; methyloxirane In tetrahydrofuran at 21℃; for 21h; Reagent/catalyst; Flow reactor; Irradiation;	19%

: 589-87-7
1,4-bromoiodobenzene

: 86-74-8
9H-carbazole

A: 57102-42-8
N-(4-bromophenyl)carbazole

B: 19287-68-4
9-(4-(9H-carbazol-9-yl)phenyl)-9H-carbazole

C: 57103-15-8
9-(4-iodophenyl)carbazole

Conditions

Conditions	Yield
With copper(l) iodide; 18-crown-6 ether; potassium carbonate at 175℃; for 24h; Schlenk technique; Inert atmosphere;	A 20 %Spectr. B 9% C 33 %Spectr.

...Expand

: 7226-23-5
1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone

: 106-37-6
1.4-dibromobenzene

: 7681-65-4
copper(I) iodide

: 86-74-8
9H-carbazole

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
With potassium carbonate; 18-crown-6 ether

...Expand

: 98-80-6
phenylboronic acid

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
Multi-step reaction with 5 steps 1.1: potassium phosphate; tetrakis(triphenylphosphine) palladium(0) / ethanol / 6 h / Reflux; Inert atmosphere 2.1: hydrazine hydrate / methanol / 2 h / 20 °C 3.1: hydrogenchloride; sodium nitrite / tetrahydrofuran; water / 0.33 h / Cooling with ice 3.2: 20 °C / Cooling with ice 4.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 20 °C 5.1: copper diacetate; sodium carbonate; ethylene glycol / isopropyl alcohol / 16 h / 85 °C / Inert atmosphere View Scheme
Multi-step reaction with 4 steps 1.1: tetrakis(triphenylphosphine) palladium(0); potassium phosphate / ethanol / 6 h / Reflux 2.1: sodium nitrite; hydrogenchloride / water; tetrahydrofuran / 0 °C 2.2: Sandmeyer Reaction / 20 °C 3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 20 °C 4.1: sodium carbonate; copper diacetate / isopropyl alcohol; ethylene glycol / 16 h / Inert atmosphere; Reflux; Green chemistry View Scheme

Yield

Multi-step reaction with 5 steps
1.1: potassium phosphate; tetrakis(triphenylphosphine) palladium(0) / ethanol / 6 h / Reflux; Inert atmosphere
2.1: hydrazine hydrate / methanol / 2 h / 20 °C
3.1: hydrogenchloride; sodium nitrite / tetrahydrofuran; water / 0.33 h / Cooling with ice
3.2: 20 °C / Cooling with ice
4.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 20 °C
5.1: copper diacetate; sodium carbonate; ethylene glycol / isopropyl alcohol / 16 h / 85 °C / Inert atmosphere
View Scheme

Multi-step reaction with 4 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium phosphate / ethanol / 6 h / Reflux
2.1: sodium nitrite; hydrogenchloride / water; tetrahydrofuran / 0 °C
2.2: Sandmeyer Reaction / 20 °C
3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 20 °C
4.1: sodium carbonate; copper diacetate / isopropyl alcohol; ethylene glycol / 16 h / Inert atmosphere; Reflux; Green chemistry
View Scheme

: 609-73-4
o-nitroiodobenzene

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
Multi-step reaction with 5 steps 1.1: potassium phosphate; tetrakis(triphenylphosphine) palladium(0) / ethanol / 6 h / Reflux; Inert atmosphere 2.1: hydrazine hydrate / methanol / 2 h / 20 °C 3.1: hydrogenchloride; sodium nitrite / tetrahydrofuran; water / 0.33 h / Cooling with ice 3.2: 20 °C / Cooling with ice 4.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 20 °C 5.1: copper diacetate; sodium carbonate; ethylene glycol / isopropyl alcohol / 16 h / 85 °C / Inert atmosphere View Scheme

Yield

Multi-step reaction with 5 steps
1.1: potassium phosphate; tetrakis(triphenylphosphine) palladium(0) / ethanol / 6 h / Reflux; Inert atmosphere
2.1: hydrazine hydrate / methanol / 2 h / 20 °C
3.1: hydrogenchloride; sodium nitrite / tetrahydrofuran; water / 0.33 h / Cooling with ice
3.2: 20 °C / Cooling with ice
4.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 20 °C
5.1: copper diacetate; sodium carbonate; ethylene glycol / isopropyl alcohol / 16 h / 85 °C / Inert atmosphere
View Scheme

: 86-00-0
2-nitrobiphenyl

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1.1: hydrazine hydrate / methanol / 2 h / 20 °C 2.1: hydrogenchloride; sodium nitrite / tetrahydrofuran; water / 0.33 h / Cooling with ice 2.2: 20 °C / Cooling with ice 3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 20 °C 4.1: copper diacetate; sodium carbonate; ethylene glycol / isopropyl alcohol / 16 h / 85 °C / Inert atmosphere View Scheme

Yield

Multi-step reaction with 4 steps
1.1: hydrazine hydrate / methanol / 2 h / 20 °C
2.1: hydrogenchloride; sodium nitrite / tetrahydrofuran; water / 0.33 h / Cooling with ice
2.2: 20 °C / Cooling with ice
3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 20 °C
4.1: copper diacetate; sodium carbonate; ethylene glycol / isopropyl alcohol / 16 h / 85 °C / Inert atmosphere
View Scheme

: 90-41-5
2-phenylaniline

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1.1: hydrogenchloride; sodium nitrite / tetrahydrofuran; water / 0.33 h / Cooling with ice 1.2: 20 °C / Cooling with ice 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 20 °C 3.1: copper diacetate; sodium carbonate; ethylene glycol / isopropyl alcohol / 16 h / 85 °C / Inert atmosphere View Scheme
Multi-step reaction with 3 steps 1.1: sodium nitrite; hydrogenchloride / water; tetrahydrofuran / 0 °C 1.2: Sandmeyer Reaction / 20 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 20 °C 3.1: sodium carbonate; copper diacetate / isopropyl alcohol; ethylene glycol / 16 h / Inert atmosphere; Reflux; Green chemistry View Scheme

: 2113-51-1
2-iodobiphenyl

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 20 °C 2: copper diacetate; sodium carbonate; ethylene glycol / isopropyl alcohol / 16 h / 85 °C / Inert atmosphere View Scheme
Multi-step reaction with 2 steps 1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 20 °C 2: sodium carbonate; copper diacetate / isopropyl alcohol; ethylene glycol / 16 h / Inert atmosphere; Reflux; Green chemistry View Scheme

: 615-43-0
2-iodophenylamine

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1.1: tetrakis(triphenylphosphine) palladium(0); potassium phosphate / ethanol / 6 h / Reflux 2.1: sodium nitrite; hydrogenchloride / water; tetrahydrofuran / 0 °C 2.2: Sandmeyer Reaction / 20 °C 3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 20 °C 4.1: sodium carbonate; copper diacetate / isopropyl alcohol; ethylene glycol / 16 h / Inert atmosphere; Reflux; Green chemistry View Scheme

Yield

Multi-step reaction with 4 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium phosphate / ethanol / 6 h / Reflux
2.1: sodium nitrite; hydrogenchloride / water; tetrahydrofuran / 0 °C
2.2: Sandmeyer Reaction / 20 °C
3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 20 °C
4.1: sodium carbonate; copper diacetate / isopropyl alcohol; ethylene glycol / 16 h / Inert atmosphere; Reflux; Green chemistry
View Scheme

: 2052-07-5
2-Bromobiphenyl

: 57102-42-8
N-(4-bromophenyl)carbazole

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1.1: n-butyllithium / tetrahydrofuran / 2 h / -78 °C / Schlenk technique 1.2: 10 h / -78 - 20 °C / Schlenk technique 1.3: 1 h / 20 °C / pH 6 - 7 / Schlenk technique 2.1: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver(I) acetate; sodium carbonate / 1,4-dioxane / 12 h / 80 °C / Schlenk technique View Scheme

: 57102-42-8
N-(4-bromophenyl)carbazole

: 1226860-66-7
3-bromo-9-(4-bromophenyl)-9H-carbazole

Conditions

Conditions	Yield
With N-Bromosuccinimide at 20℃; for 12h; Inert atmosphere;	100%
With N-Bromosuccinimide at 20℃;	98%
With N-Bromosuccinimide In N,N-dimethyl-formamide at 20℃; for 12.5h;	92%

: 57102-42-8
N-(4-bromophenyl)carbazole

: 9,9′-bis(4-bromophenyl)-9H,9′H-3,3′-bicarbazole

Conditions

Conditions	Yield
Stage #1: N-(4-bromophenyl)carbazole With methanesulfonic acid In dichloromethane at 0℃; Inert atmosphere; Stage #2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane at 20℃; for 0.0166667h; Reagent/catalyst; Inert atmosphere; regioselective reaction;	99%
With iron(III) chloride In chloroform at 20℃; for 40h; Inert atmosphere;

: 57102-42-8
N-(4-bromophenyl)carbazole

: 601454-29-9
9‐(4‐bromophenyl)‐3,6‐diiodocarbazole

Conditions

Conditions	Yield
With potassium iodate; potassium iodide In acetic acid at 80℃; for 4h;	98%
With potassium iodate; acetic acid; potassium iodide for 4h; Reflux; Inert atmosphere;	85%
With potassium iodate; acetic acid; potassium iodide at 135℃; for 18h;	82.22%

: 57102-42-8
N-(4-bromophenyl)carbazole

: 73087-83-9
3,6-dibromo-9-(4-bromophenyl)-9H-carbazole

Conditions

Conditions	Yield
With N-Bromosuccinimide In dichloromethane at 0℃; for 16h; Schlenk technique; Darkness; Inert atmosphere;	98%
With N-Bromosuccinimide In N,N-dimethyl-formamide at 20℃; for 3h;	88%
With N-Bromosuccinimide at 0℃; for 8h; Darkness;	87%

: 56017-36-8
5-(phenylthio)quinolin-8-amine

: 57102-42-8
N-(4-bromophenyl)carbazole

: N,N-bis(4-(9H-carbazol-9-yl)phenyl)-5-(phenylthio)quinolin‐8‐amine

Conditions

Conditions	Yield
With potassium carbonate; nickel dichloride In tetrahydrofuran at 100℃; for 24h; Inert atmosphere;	97%

: 57102-42-8
N-(4-bromophenyl)carbazole

: 73183-34-3
bis(pinacol)diborane

: 785051-54-9
9-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole

Conditions

Conditions	Yield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; palladium diacetate In dimethyl sulfoxide at 80℃; for 8h; Inert atmosphere;	96.8%
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In 1,4-dioxane at 85℃; for 48h;	87%
Stage #1: N-(4-bromophenyl)carbazole; bis(pinacol)diborane With potassium acetate In dimethyl sulfoxide at 60℃; for 0.25h; Stage #2: With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In dichloromethane; dimethyl sulfoxide at 80℃; for 6h;	86%

: 667-27-6
Ethyl bromodifluoroacetate

: 57102-42-8
N-(4-bromophenyl)carbazole

: C22H17F2NO2

Conditions

Conditions	Yield
With bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; tetrabutylammomium bromide; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; zinc In tetrahydrofuran at 60℃; for 24h; Inert atmosphere;	96%

: 578-66-5
8-amino quinoline

: 57102-42-8
N-(4-bromophenyl)carbazole

: N,N-bis(4-(9H-carbazol-9-yl)phenyl)quinolin‐8‐amine

Conditions

Conditions	Yield
With sodium hydroxide; nickel dichloride In N,N-dimethyl-formamide at 150℃; for 16h; Reagent/catalyst; Inert atmosphere; Glovebox; Sealed tube; Schlenk technique;	96%
With potassium carbonate; nickel dibromide In tetrahydrofuran at 100℃; for 24h; Reagent/catalyst; Temperature; Solvent; Inert atmosphere;	95%

: 9,9-diphenyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

: 57102-42-8
N-(4-bromophenyl)carbazole

: N-(4-(9H-carbazol-9-yl)phenyl)-9,9-diphenyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

Conditions

Conditions	Yield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 120℃; for 24h; Inert atmosphere;	95%

: 57102-42-8
N-(4-bromophenyl)carbazole

: 222620-05-5
N-(4-hydroxyphenyl)carbazole

Conditions

Conditions	Yield
With tris(6,6'-diamino-2,2'-bipyridine); 4,4-diphenyl-1,3,5,7,8-pentamethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene; Br2Ni*3H2O; water; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide; acetonitrile at 20℃; for 36h; Glovebox; Irradiation; Inert atmosphere;	95%
With oxygen; triethylamine; sodium iodide In acetonitrile at 32℃; for 24h; Schlenk technique; UV-irradiation;	40%

: 55484-55-4
4-phenyl-8-aminoquinoline

: 57102-42-8
N-(4-bromophenyl)carbazole

: N,N-bis(4-(9H-carbazol-9-yl)phenyl)-4-phenylquinolin‐8‐amine

Conditions

Conditions	Yield
With nickel dichloride; sodium t-butanolate In water; N,N-dimethyl-formamide at 150℃; for 16h; Inert atmosphere; Glovebox; Sealed tube; Schlenk technique;	95%
With nickel(II) sulphate; caesium carbonate In acetonitrile at 100℃; for 24h; Inert atmosphere;	86%

: 57102-42-8
N-(4-bromophenyl)carbazole

: C34H36Cl2Si3Zn2

: C70H60N2Si3

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0) In toluene at 120℃; for 12h; Inert atmosphere;	94%

: 57102-42-8
N-(4-bromophenyl)carbazole

: 58328-31-7
4,4'-bis(9H-carbazol-9-yl)biphenyl

Conditions

Conditions	Yield
Stage #1: N-(4-bromophenyl)carbazole With tert.-butyl lithium In tetrahydrofuran; pentane at -78℃; for 1h; Inert atmosphere; Stage #2: With copper(l) cyanide In tetrahydrofuran; pentane at -78 - 25℃; Inert atmosphere; Stage #3: In tetrahydrofuran; pentane at 25℃; for 3h; Inert atmosphere;	93%

: 4028-23-3
Allylchlorodimethylsilane

: 57102-42-8
N-(4-bromophenyl)carbazole

: 9-(4-(allyldimethylsilyl)phenyl)-9H-carbazole

Conditions

Conditions	Yield
Stage #1: N-(4-bromophenyl)carbazole With n-butyllithium In tetrahydrofuran; acetone at -78℃; for 3h; Inert atmosphere; Stage #2: Allylchlorodimethylsilane In tetrahydrofuran at 20℃;	93%

: 90-52-8
6-methoxyquinolin-8-amine

: 57102-42-8
N-(4-bromophenyl)carbazole

: N,N-bis(4-(9H-carbazol-9-yl)phenyl)-6-(methoxy)quinolin‐8‐amine

Conditions

Conditions	Yield
With nickel(II) fluoride; potassium carbonate In tetrahydrofuran at 100℃; for 24h; Inert atmosphere;	93%
With nickel dichloride; sodium t-butanolate In water; N,N-dimethyl-formamide at 150℃; for 16h; Catalytic behavior; Reagent/catalyst; Solvent; Inert atmosphere; Glovebox; Sealed tube; Schlenk technique;	83%

: 104711-51-5
5-phenylquinoline-8-amine

: 57102-42-8
N-(4-bromophenyl)carbazole

: N,N-bis(4-(9H-carbazol-9-yl)phenyl)-5-(phenyl)quinolin‐8‐amine

Conditions

Conditions	Yield
With nickel dichloride; sodium t-butanolate In water; N,N-dimethyl-formamide at 150℃; for 16h; Catalytic behavior; Reagent/catalyst; Solvent; Inert atmosphere; Glovebox; Sealed tube; Schlenk technique;	93%
With nickel(II) fluoride; potassium carbonate In tetrahydrofuran at 100℃; for 24h; Inert atmosphere;	91%

: 76-09-5
2,3-dimethyl-2,3-butane diol

: 5419-55-6
Triisopropyl borate

: 57102-42-8
N-(4-bromophenyl)carbazole

: 785051-54-9
9-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole

Conditions

Conditions	Yield
Stage #1: N-(4-bromophenyl)carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Schlenk technique; Inert atmosphere; Stage #2: Triisopropyl borate In tetrahydrofuran; hexane at -78℃; for 0.166667h; Schlenk technique; Inert atmosphere; Stage #3: 2,3-dimethyl-2,3-butane diol In tetrahydrofuran; hexane at 20℃; for 69h; Schlenk technique; Inert atmosphere;	93%
Stage #1: N-(4-bromophenyl)carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere; Schlenk technique; Sealed tube; Stage #2: Triisopropyl borate In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere; Schlenk technique; Sealed tube; Stage #3: 2,3-dimethyl-2,3-butane diol In tetrahydrofuran at 20℃; for 69h; Inert atmosphere; Schlenk technique;	67%

...Expand

: 57102-42-8
N-(4-bromophenyl)carbazole

: 1432666-69-7
C22H17N3

: N,N-bis[3-(pyridin-2-yl)phenyl]4-(9H-carbazole-9-yl)aniline

Conditions

Conditions	Yield
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene for 24h; Buchwald-Hartwig Coupling; Inert atmosphere; Reflux;	92%

: 1060735-19-4
9,9″-diphenyl-9H,9′H,9″H-3,3':6′,3″-tercarbazole

: 57102-42-8
N-(4-bromophenyl)carbazole

: C66H42N4

Conditions

Conditions	Yield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene for 10h; Inert atmosphere; Reflux;	92%

: 57102-42-8
N-(4-bromophenyl)carbazole

: 106-49-0
p-toluidine

: 908139-14-0
9-[4-(4-methylphenylamino)phenyl]-9H-carbazole

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; XPhos In toluene at 108℃; for 2h; Inert atmosphere;	92%

: 57102-42-8
N-(4-bromophenyl)carbazole

: 5-(naphthalen-1-yl)quinolin-8-amine

: N,N-bis(4-(9H-carbazol-9-yl)phenyl)-5-(naphthalen-1-yl)quinolin-8-amine

Conditions

Conditions	Yield
With nickel dichloride; sodium t-butanolate In water; N,N-dimethyl-formamide at 150℃; for 16h; Inert atmosphere; Glovebox; Sealed tube; Schlenk technique;	92%

: 57102-42-8
N-(4-bromophenyl)carbazole

: 63503-60-6
3-chlorophenylboronic acid

: C24H16ClN

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere;	92%

: 1072194-21-8
N-phenyl-N-[4-(9-phenylcarbazole-3-yl)phenyl]amine

: 57102-42-8
N-(4-bromophenyl)carbazole

: 1246637-79-5
4-(9H-carbazol-9-yl)-4'-(9-phenyl-9H-carbazol-3-yl)triphenylamine

Conditions

Conditions	Yield
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In hexane; toluene at 80℃; for 5h; Inert atmosphere;	91%

: 57102-42-8
N-(4-bromophenyl)carbazole

: 90-41-5
2-phenylaniline

: N-(4-(9H-carbazol-9-yl)phenyl)-[1,1'-biphenyl]-2-amine

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene for 6h; Inert atmosphere; Reflux;	91%

: 57102-42-8
N-(4-bromophenyl)carbazole

: 403-43-0
4-fluorobenzoyl chloride

: (9-(4-bromophenyl)-9H-carbazol-3-yl)(4-fluorophenyl)methanone

Conditions

Conditions	Yield
With aluminum (III) chloride In dichloromethane at 0 - 20℃; for 12h; Friedel-Crafts Acylation;	91%

Product Name

(9-(4-BROMOPHENYL))-9H-CARBAZOLE

Synthetic route

9-(4-Bromophenyl)carbazole Specification

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