Chlorodimethylsilane supplier

Name
Chlorodimethylsilane
EINECS 213-912-0
CAS No. 1066-35-9
Article Data76
CAS DataBase
Density 0.852 g/mL at 25 °C(lit.)
Solubility react with water
Melting Point -111 °C(lit.)
Formula C₂H₇ClSi
Boiling Point 33.1 °C at 760 mmHg
Molecular Weight 94.6161
Flash Point -28 °C
Transport Information UN 2988 4.3/PG 1
Appearance Colorless clear liquid
Safety 16-26-36/37/39-45-9
Risk Codes 11-34-12
Molecular Structure
Hazard Symbols F, C, F+
Synonyms Chlorodimethylhydrosilane;Chlorodimethylsilane;Dimethylchlorohydrosilane;Dimethylchlorosilane;Dimethylhydrosilyl chloride;Dimethylmonochlorosilane;Dimethylsilyl chloride;SID 4070.0;
PSA 0.00000
LogP 1.20860

Synthetic route

: 1111-74-6
dimethylsilane

: 1066-35-9
dimethylmonochlorosilane

Conditions

Conditions	Yield
With hydrogenchloride In diethyl ether at 60℃; for 0.5h; Temperature; Solvent;	100%
With hydrogenchloride In diethylene glycol dimethyl ether at -45 - 15℃; for 12h;	99%

: 992-94-9
methylsilane

: 75-78-5
dimethylsilicon dichloride

: 1066-35-9
dimethylmonochlorosilane

Conditions

Conditions	Yield
	97%

: 75-78-5
dimethylsilicon dichloride

: 1066-35-9
dimethylmonochlorosilane

Conditions

Conditions	Yield
With N,N-diethylaminodimethylsilane Heating;	87%
With sodium tetrahydroborate; tetra-n-butylphosphonium chloride In diethylene glycol dimethyl ether at 80 - 140℃; for 26h;	11%
With Dichloromethylsilane; homogeneous catalyst, preferably pyridinium, phosphonium or imidazolium salt Industry scale;

: 814-98-2
1,1,2,2-tetramethyldisilane

A: 75-77-4
chloro-trimethyl-silane

B: 1066-35-9
dimethylmonochlorosilane

C: 1111-74-6
dimethylsilane

D: 993-07-7
trimethylsilan

Conditions

Conditions	Yield
With tetra-n-butylphosphonium chloride at 180℃; for 17h; Sealed tube;	A 2% B 4% C 87% D 7%

...Expand

: 15933-59-2
1,1,3,3-tetramethyldisilazane

A: 1066-35-9
dimethylmonochlorosilane

B: 135764-59-9
1,1-dimethyl-3,3,3-trichlorosilazane

C: 135764-60-2
1,1,3,3-tetramethyl-(2-trichlorosilyl)disilazane

Conditions

Conditions	Yield
With tetrachlorosilane at 20℃; for 24h;	A n/a B n/a C 78%
With tetrachlorosilane at 20℃; for 24h;	A n/a B 54% C n/a

...Expand

: 3277-26-7
1,1,3,3-Tetramethyldisiloxane

: 75-78-5
dimethylsilicon dichloride

: 1066-35-9
dimethylmonochlorosilane

Conditions

Conditions	Yield
With tetrabutylammomium bromide In water	74.9%

: 75-78-5
dimethylsilicon dichloride

A: 1066-35-9
dimethylmonochlorosilane

B: 1111-74-6
dimethylsilane

Conditions

Conditions	Yield
With sodium tetrahydroborate; N,N,N,N,N,N-hexamethylphosphoric triamide in a glass ampoule under hermetic conditions;	A 62% B 6.1 % Chromat.
With Tetraethylene glycol dimethyl ether; tetra-n-butylphosphonium chloride; lithium hydride In 1,4-dioxane at -196 - 120℃; for 115.5h; Time; Temperature; Reagent/catalyst; Sealed tube;	A 57% B 35%
With lithium hydride; triphenylphosphine In diethylene glycol dimethyl ether at -196 - 160℃; for 62h; Time; Reagent/catalyst; Sealed tube;	A 56% B 11%

: 15933-59-2
1,1,3,3-tetramethyldisilazane

: 1558-33-4
chloromethylmethyldichlorosilane

A: 1066-35-9
dimethylmonochlorosilane

B: 135790-73-7
1-Chloro-1-chloromethyl-1,3,3-trimethyl-disilazane

Conditions

Conditions	Yield
at 20℃; for 24h;	A n/a B 61%

...Expand

: 680-31-9
N,N,N,N,N,N-hexamethylphosphoric triamide

: 3277-26-7
1,1,3,3-Tetramethyldisiloxane

: 75-78-5
dimethylsilicon dichloride

: 1066-35-9
dimethylmonochlorosilane

Conditions

Conditions	Yield
In water	60%

...Expand

: 60-29-7
diethyl ether

: 1111-74-6
dimethylsilane

A: 1066-35-9
dimethylmonochlorosilane

B: 1825-69-0
dimethyl chloro ethoxy silane

Conditions

Conditions	Yield
With hydrogenchloride at 100℃; for 158h;	A 60% B 26%

...Expand

: 4342-61-4
1,2-dichlorotetramethylsilane

A: 75-77-4
chloro-trimethyl-silane

B: 1066-35-9
dimethylmonochlorosilane

C: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
With 2-methylimidazole; tetra-n-butylphosphonium chloride at 175℃; for 89h; Temperature; Reagent/catalyst; Time; Sealed tube;	A 7% B 34% C 57%
With tetra-n-butylphosphonium chloride at 140℃; for 64h; Temperature; Schlenk technique; Inert atmosphere; Sealed tube;

...Expand

: 4342-61-4
1,2-dichlorotetramethylsilane

A: 812-36-2
1,3-dichloro-1,1,2,2,3,3-hexamethyltrisilane

B: 75-77-4
chloro-trimethyl-silane

C: 1066-35-9
dimethylmonochlorosilane

D: 754-75-6
1,4-dichloropermethyltetrasilane

E: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
With 2-methylimidazole; tetra-n-butylphosphonium chloride at 175℃; for 2.5h; Temperature; Time; Sealed tube;	A 14% B 7% C 34% D 8% E 57%

...Expand

: 4342-61-4
1,2-dichlorotetramethylsilane

A: 812-36-2
1,3-dichloro-1,1,2,2,3,3-hexamethyltrisilane

B: 75-77-4
chloro-trimethyl-silane

C: 1066-35-9
dimethylmonochlorosilane

D: 1111-74-6
dimethylsilane

E: 754-75-6
1,4-dichloropermethyltetrasilane

F: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
With tetra-n-butylphosphonium chloride at 220℃; for 21h; Reagent/catalyst; Time; Sealed tube;	A 6% B 15% C 21% D 1% E 1% F 49%

...Expand

: 4342-61-4
1,2-dichlorotetramethylsilane

A: 75-77-4
chloro-trimethyl-silane

B: 1066-35-9
dimethylmonochlorosilane

C: 993-07-7
trimethylsilan

D: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
With tetra-n-butylphosphonium chloride at 220℃; for 24h; Sealed tube;	A 16% B 30% C 5% D 44%

...Expand

: 4342-61-4
1,2-dichlorotetramethylsilane

: 75-78-5
dimethylsilicon dichloride

A: 1066-35-9
dimethylmonochlorosilane

B: 1111-74-6
dimethylsilane

C: 814-98-2
1,1,2,2-tetramethyldisilane

D: 4455-83-8
1-chloro-2-hydro-1,1,2,2-tetramethyldisilane

Conditions

Conditions	Yield
With tetra-n-butylphosphonium chloride; lithium hydride In diethylene glycol dimethyl ether at -196 - 160℃; for 35h; Sealed tube;	A 42% B 35% C 6% D 5%

...Expand

: 4342-61-4
1,2-dichlorotetramethylsilane

A: 75-77-4
chloro-trimethyl-silane

B: 1066-35-9
dimethylmonochlorosilane

C: 1111-74-6
dimethylsilane

D: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
With 2-methylimidazole at 220℃; for 64h; Time;	A 13% B 37% C 10% D 40%

...Expand

: 34557-54-5
methane

A: 75-54-7
Dichloromethylsilane

B: 1066-35-9
dimethylmonochlorosilane

Conditions

Conditions	Yield
With Si-Cu; HCl In neat (no solvent) Si-Cu (10:2) and a mixt. of CH4 and HCl at 350°C;;	A 38.8% B 9.4%
With hydrogenchloride; copper; silicon In neat (no solvent) Si-Cu (10:2) and a mixt. of CH4 and HCl at 350°C;;	A 38.8% B 9.4%

: 4342-61-4
1,2-dichlorotetramethylsilane

A: 75-77-4
chloro-trimethyl-silane

B: 1066-35-9
dimethylmonochlorosilane

C: 1111-74-6
dimethylsilane

D: 993-07-7
trimethylsilan

E: 4519-04-4
dichloro[(chlorodimethylsilyl)methyl]methylsilane

F: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
With n-Butyl chloride; tributylphosphine at 220℃; for 70h; Sealed tube;	A 13% B 30% C 2% D 2% E 18% F 35%

...Expand

: 13683-11-9
trimethylsilyl(dimethylchlorosilyl)methane

: 5357-38-0
bis(chlorodimethylsilyl)methane

: 4519-04-4
dichloro[(chlorodimethylsilyl)methyl]methylsilane

: 4519-03-3
bis(methyldichlorosilyl)methane

: 75-78-5
dimethylsilicon dichloride

A: 75-54-7
Dichloromethylsilane

B: 1066-35-9
dimethylmonochlorosilane

C: 992-94-9
methylsilane

D: 1111-74-6
dimethylsilane

E: 993-00-0
chloro-methyl-silane

Conditions

Conditions	Yield
With tetra-n-butylphosphonium chloride; lithium hydride In diethylene glycol dimethyl ether at -196 - 220℃; for 31h; Sealed tube;	A 7% B 34% C 9% D 5% E 7%

...Expand

: 3277-26-7
1,1,3,3-Tetramethyldisiloxane

: 368-44-5
dichloro(fluoro)(phenyl)silane

A: 1066-35-9
dimethylmonochlorosilane

B: 1344680-26-7
phenyl(dimethylsiloxy)fluorochlorosilane

Conditions

Conditions	Yield
at 20℃; for 14h;	A n/a B 30%

...Expand

: 75-54-7
Dichloromethylsilane

A: 75-79-6
Methyltrichlorosilane

B: 1066-35-9
dimethylmonochlorosilane

C: 993-00-0
chloro-methyl-silane

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate at 150℃; for 4h;	A 25.1% B 3.5% C 2.9%
dihydrogen hexachloroplatinate at 150℃; for 4h;	A 25.1% B 3.5% C 2.9%

...Expand

: 75-79-6
Methyltrichlorosilane

: 75-78-5
dimethylsilicon dichloride

A: 75-54-7
Dichloromethylsilane

B: 1066-35-9
dimethylmonochlorosilane

C: 992-94-9
methylsilane

D: 993-00-0
chloro-methyl-silane

Conditions

Conditions	Yield
With Tetraethylene glycol dimethyl ether; tetra-n-butylphosphonium chloride; lithium hydride at 80 - 120℃; for 86.25h;	A 17% B 19% C 11% D 23%

...Expand

: 1450-14-2
1,1,1,2,2,2-hexamethyldisilane

: 1560-28-7
pentamethylchlorodisilane

: 4342-61-4
1,2-dichlorotetramethylsilane

: 13528-88-6
1,1,2-trichloro-1,2,2-trimethyldisilane

: 4518-98-3
1,1,2,2-tetrachloro-1,2-dimethyldisilane

: 4518-99-4
1,1-dichlorotetramethyldisilane

A: 75-54-7
Dichloromethylsilane

B: 75-77-4
chloro-trimethyl-silane

C: 75-79-6
Methyltrichlorosilane

D: 1066-35-9
dimethylmonochlorosilane

E: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
With hydrogenchloride at 430 - 750℃; for 72h; Conversion of starting material;	A 4 %Chromat. B 12 %Chromat. C 7 %Chromat. D 6 %Chromat. E 21%

...Expand

: 812-15-7
1,1,1,2,2-pentamethyldisilane

A: 75-77-4
chloro-trimethyl-silane

B: 1066-35-9
dimethylmonochlorosilane

C: 993-07-7
trimethylsilan

D: 1560-28-7
pentamethylchlorodisilane

Conditions

Conditions	Yield
With hydrogenchloride In dibutyl ether; water at 70℃; for 24h;	A 5% B 22.8 %Spectr. C 26 %Spectr. D 6.3 %Spectr.
With hydrogenchloride In dibutyl ether; benzene-d6 at 70℃; for 24h; Sealed tube;

...Expand

: 13465-77-5
hexachlorodisilane

: 2304-30-5
tetra-n-butylphosphonium chloride

: 1066-35-9
dimethylmonochlorosilane

Conditions

Conditions	Yield
With 2-methylimidazole at 175℃; for 2.5h; Sealed tube;	5%

: 75-54-7
Dichloromethylsilane

: 75-16-1
methylmagnesium bromide

: 1066-35-9
dimethylmonochlorosilane

: 34557-54-5
methane

: 1066-35-9
dimethylmonochlorosilane

Conditions

Conditions	Yield
With hydrogenchloride; copper(II) hydroxide; silicon at 350℃;

: 14857-34-2
dimethyl(ethoxy)silane

: 98-88-4
benzoyl chloride

: 1066-35-9
dimethylmonochlorosilane

Conditions

Conditions	Yield
at 200℃;

: 14857-34-2
dimethyl(ethoxy)silane

: 1719-58-0
Chlorodimethylvinylsilane

A: 1066-35-9
dimethylmonochlorosilane

B: 5356-83-2
ethoxydimethylvinylsilane

Conditions

Conditions	Yield
at 28.5℃; Equilibrium constant;

...Expand

: 592-41-6
1-hexene

: 1066-35-9
dimethylmonochlorosilane

: 3634-59-1
dimethylhexylsilyl chloride

Conditions

Conditions	Yield
at 90℃; for 5h; Inert atmosphere;	100%
With platinum on carbon nanotubes In neat (no solvent) at 20℃; for 24h;	97%
dihydrogen hexachloroplatinate In diethyl ether for 15h; Heating;	80%

: 1066-35-9
dimethylmonochlorosilane

: 1113-12-8
diallyl(dimethyl)silane

: 55392-19-3
1-(Chloro-dimethyl-silanyl)-3-{[3-(chloro-dimethyl-silanyl)-propyl]-dimethyl-silanyl}-propane

Conditions

Conditions	Yield
With platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane In 5,5-dimethyl-1,3-cyclohexadiene; hexane at 20℃; Inert atmosphere; Reflux;	100%
platinum on activated charcoal In diethyl ether Heating;

: 1066-35-9
dimethylmonochlorosilane

: 7766-49-6
1-iodo-10-undecene

: 139764-33-3
11-(dimethylchlorosilyl)-1-iodoundecane

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate In dichloromethane for 12h;	100%

: 1066-35-9
dimethylmonochlorosilane

: 110661-49-9
10-undecylenic acid N-hydroxysuccinimide ester

: 139764-32-2
N-succinimidyl 11-(dimethylchlorosilyl)undecanoate

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate In dichloromethane for 12h;	100%

: 1066-35-9
dimethylmonochlorosilane

: 139764-38-8
2-Methylene-succinic acid 4-(11-bromo-undecyl) ester 1-[11-((S)-2-dimethylamino-3-phenyl-propoxycarbonyl)-undecyl] ester

: 139764-39-9
2-(Chloro-dimethyl-silanylmethyl)-succinic acid 4-(11-bromo-undecyl) ester 1-[11-((S)-2-dimethylamino-3-phenyl-propoxycarbonyl)-undecyl] ester

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate In dichloromethane for 12h;	100%

: 1066-35-9
dimethylmonochlorosilane

: 95-55-6
2-amino-phenol

: 18245-89-1
2,2-dimethyl-2,3-dihydro-benzo[1,3,2]oxazasilole

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran for 6h; Heating;	100%

: 1066-35-9
dimethylmonochlorosilane

: 146063-23-2
[Methyl-(2-{tris-[2-(methyl-divinyl-silanyl)-ethyl]-silanyl}-ethyl)-vinyl-silanyl]-ethene

: 1-{bis-[2-(chloro-dimethyl-silanyl)-ethyl]-methyl-silanyl}-2-[tris-(2-{bis-[2-(chloro-dimethyl-silanyl)-ethyl]-methyl-silanyl}-ethyl)-silanyl]-ethane

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane (Karstedt's catalyst) In diethyl ether at 50℃; for 20h;	100%

: 1066-35-9
dimethylmonochlorosilane

: 151626-10-7
tetrakis[2-(trivinylsilyl)ethyl]silane

: C56H136Cl12Si17

Conditions

Conditions	Yield
bis(tetrabutylammonium) hexachloroplatinate(IV) In ethanol	100%
chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex Hydrosilation;
platinum Addition;

: 1066-35-9
dimethylmonochlorosilane

: 42403-77-0
(4-(allyloxy)phenyl)(phenyl)methanone

: 4-(3'-chlorodimethylsilyl)propyloxybenzophenone

Conditions

Conditions	Yield
platinum on activated charcoal for 5h; Addition; hydrosilation; Heating;	100%

: 1066-35-9
dimethylmonochlorosilane

: 18269-92-6
bis-allyloxy-dimethyl-silane

: 1-(chloro-dimethyl-silanyl)-3-{[3-(chloro-dimethyl-silanyl)-propoxy]-dimethyl-silanyloxy}-propane

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate at 25℃; for 3.25h;	100%

: 1066-35-9
dimethylmonochlorosilane

: 17984-91-7
tris-allyloxy-methyl-silane

: C16H39Cl3O3Si4

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate at 25℃; for 3.25h;	100%

: 1066-35-9
dimethylmonochlorosilane

: 394737-60-1
3-[allyloxy-(3-{[3-(bis-allyloxy-methyl-silanyl)-propoxy]-dimethyl-silanyloxy}-propyl)-methyl-silanyloxy]-propene

: 1-{bis-[3-(chloro-dimethyl-silanyl)-propoxy]-methyl-silanyl}-3-[(3-{bis-[3-(chloro-dimethyl-silanyl)-propoxy]-methyl-silanyl}-propoxy)-dimethyl-silanyloxy]-propane

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate In diethyl ether at 25℃; for 1.25h;	100%

: 1066-35-9
dimethylmonochlorosilane

: 394737-65-6
C31H60O9Si4

: C43H102Cl6O9Si10

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate at 25℃; for 3.25h;	100%

: 1066-35-9
dimethylmonochlorosilane

: 3-{allyloxy-[3-([3-(bis-allyloxy-methyl-silanyl)-propoxy]-{3-[(3-{bis-[3-(bis-allyloxy-methyl-silanyl)-propoxy]-methyl-silanyl}-propoxy)-dimethyl-silanyloxy]-propyl}-methyl-silanyloxy)-propyl]-methyl-silanyloxy}-propene

: C66H156Cl8O14Si15

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate at 25℃; for 3.25h;	100%

: 1066-35-9
dimethylmonochlorosilane

: C73H144O21Si10

: C97H228Cl12O21Si22

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate at 25℃; for 3.25h;	100%

: 1066-35-9
dimethylmonochlorosilane

: C106H212O30Si15

: C138H324Cl16O30Si31

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate at 25℃; for 3.25h;	100%

: 1066-35-9
dimethylmonochlorosilane

: C108H228Si17

: C132H312Cl12Si29

Conditions

Conditions	Yield
With bis(tetrabutylammonium) hexachloroplatinate(IV) at 20℃;	100%

: 1066-35-9
dimethylmonochlorosilane

: 693-02-7
hex-1-yne

: 79966-86-2
hex-1-yn-1-yldimethylsilane

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; pentane at -78 - 20℃;	100%
Stage #1: hex-1-yne With ethylmagnesium bromide In tetrahydrofuran; diethyl ether at 0 - 20℃; for 0.0833333h; Inert atmosphere; Stage #2: dimethylmonochlorosilane In tetrahydrofuran; diethyl ether at 0 - 20℃; for 4h; Inert atmosphere;	98%
Stage #1: hex-1-yne With n-butyllithium In diethyl ether; hexane at -78℃; for 0.5h; Stage #2: dimethylmonochlorosilane In diethyl ether; hexane at -78 - 20℃; Further stages.;	85%

: 1066-35-9
dimethylmonochlorosilane

: 648930-60-3
4-(pent-4-en-1-yloxy)-1,1'-biphenyl

: 761401-74-5
4-biphenyloxypentyldimethylchlorosilane

Conditions

Conditions	Yield
chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex In xylene at 60℃; for 24h;	100%

: 1066-35-9
dimethylmonochlorosilane

: 70964-99-7
acetic acid 2-allyloxyethyl ester

: 3-(dimethylchlorosilyl)propyloxyethyl acetate

Conditions

Conditions	Yield
divinyltetramethylsiloxaneplatinum(O) In xylene at 30 - 36℃; for 120h;	100%

: 868152-12-9
N-(10'-undecenyl)-12,14-dinitrodehydroabietamide

: 1066-35-9
dimethylmonochlorosilane

: N-[11'-(chlorodimethylsilyl)undecyl]-12,14-dinitrodehydroabietamide

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate In dichloromethane; isopropyl alcohol Heating;	100%

: 868152-15-2
4-(10'-undecenylaminocarbonyl)-1-(friedelan-3α-yl)-benzoate

: 1066-35-9
dimethylmonochlorosilane

: 4-[11'-(chlorodimethylsilyl)undecylaminocarbonyl]-1-(friedelan-3α-yl)-benzoate

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate In dichloromethane; isopropyl alcohol Heating;	100%

: 1066-35-9
dimethylmonochlorosilane

: 1093380-37-0
Zr[Me2Si(η5-C5Me4)(η5-C5H3CMe2CH2CH2CHCH2)]Cl2

: 1093380-62-1
Zr[Me2Si(η5-C5Me4)(η5-C5H3CMe2(CH2)4SiMe2Cl)]Cl2

Conditions

Conditions	Yield
divinyltetramethylsiloxaneplatinum(O) In toluene (N2), 2 drops of catalyst were added to soln. of Zr complex in toluene, stirred at room temp. for 10 min, treated with excess SiHMe2Cl dropwise,stirred for 6 h; filtered, evapd.(vac.), elem. anal.;	100%

: 1066-35-9
dimethylmonochlorosilane

: permethyldecasiloxane-1,19-diol

: 50632-55-8
C24H74O11Si12

Conditions

Conditions	Yield
With pyridine In toluene at 90℃; for 18h;	100%

: 1066-35-9
dimethylmonochlorosilane

: 129750-23-8
Ethyl 3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside

: 1180492-12-9
ethyl 2-O-dimethylsilane-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0℃; Inert atmosphere;	100%
With triethylamine

: 1066-35-9
dimethylmonochlorosilane

: 180187-58-0
ethyl 3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside

: 1180492-09-4
ethyl 2-O-dimethylsilane-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0℃; Inert atmosphere;	100%
With triethylamine

: 1066-35-9
dimethylmonochlorosilane

: 90-11-9
1-Bromonaphthalene

: 38274-80-5
dimethyl(naphthalen-1-yl)silane

Conditions

Conditions	Yield
Stage #1: 1-Bromonaphthalene With diisobutylaluminium hydride; magnesium; lithium chloride In tetrahydrofuran; hexane at 20℃; for 3h; Schlenk technique; Inert atmosphere; Stage #2: dimethylmonochlorosilane In tetrahydrofuran; hexane at 20℃; Schlenk technique; Inert atmosphere;	100%
With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Inert atmosphere;	96.7%
Stage #1: 1-Bromonaphthalene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.333333h; Inert atmosphere; Stage #2: dimethylmonochlorosilane In tetrahydrofuran; hexane at -78 - 20℃; for 0.5h; Inert atmosphere;	91%

: 1066-35-9
dimethylmonochlorosilane

: 1379460-61-3
C74H122O6

: 1379460-55-5
C76H129ClO6Si

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate In dichloromethane for 18h; Reflux;	100%

: 1066-35-9
dimethylmonochlorosilane

: 1379460-62-4
C79H132O6

: 1379460-56-6
2-(ω-(chlorodimethylsilyl)-undecyl)-3,6,7,10,11-penta-decyloxytriphenylene

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate In dichloromethane for 18h; Reflux;	100%

: 1066-35-9
dimethylmonochlorosilane

: 1379460-63-5
C84H142O6

: 1379460-57-7
C86H149ClO6Si

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate In dichloromethane for 18h; Reflux;	100%

Chlorodimethylsilane Specification

The Chlorodimethylsilane with the CAS registry number 1066-35-9, is also known as Dimethylchlorohydrosilane. It belongs to the product categories of Dimethylsilylation (GC Derivatizing Reagents); Analytical Chemistry; GC Derivatizing Reagents; Monochlorosilanes; Reduction; Si (Classes of Silicon Compounds); Si-Cl Compounds; Si-H Compounds;Silylation (GC Derivatizing Reagents); Synthetic Organic Chemistry; Chloro Silanes; Hydrogensilanes Hydrogensiloxanes; Reducing Agents. Its EINECS number is 213-912-0. This chemical's molecular formula is C₂H₇ClSi and molecular weight is 94.62. What's more, its systematic name is chloro(dimethyl)silane. It is a silane, with a silicon atom bonded to two methyl groups, a chlorine atom, and a hydrogen atom. It is stable at common pressure and temperature, and it should be sealed and stored in containers with dry inert gas. Moreover, it should be protected from oxides, alcohol and water.

Physical properties of Chlorodimethylsilane: (1)ACD/LogP: 2.76; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.76; (4)ACD/LogD (pH 7.4): 2.76; (5)ACD/BCF (pH 5.5): 73.5; (6)ACD/BCF (pH 7.4): 73.5; (7)ACD/KOC (pH 5.5): 754.23; (8)ACD/KOC (pH 7.4): 754.23; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 0; (12)Enthalpy of Vaporization: 26.68 kJ/mol; (13)Boiling Point: 33.1 °C at 760 mmHg; (14)Vapour Pressure: 569 mmHg at 25°C.

Preparation of Chlorodimethylsilane: This chemical can be prepared by silica powder and chloromethane at the temperature of 300 °C. This reaction will also need catalyst copper.

Uses of Chlorodimethylsilane: It can be used to produce 2,6-bis-dimethylsilanyl-pyridine by heating. It will need reagent Mg and solvent tetrahydrofuran with the reaction time of 3 hours. The yield is about 61%.

Silane, chlorodimethyl- can be used to produce 2,6-bis-dimethylsilanyl-pyridine by heating

When you are using this chemical, please be cautious about it as the following:
Chlorodimethylsilane is highly flammable, so you should keep it away from sources of ignition - No smoking. It can cause burn. It is irritating to eyes, respiratory system and skin. You should keep the container in a well-ventilated place. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, you must seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)InChI: InChI=1S/C2H6ClSi/c1-4(2)3/h1-2H3
(2)InChIKey: QABCGOSYZHCPGN-UHFFFAOYSA-N
(3)Canonical SMILES: C[Si](C)Cl

Product Name

Chlorodimethylsilane

Synthetic route

Chlorodimethylsilane Specification

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