Cyclohexanone peroxide supplier

Name
Cyclohexanone peroxide
EINECS 201-091-1
CAS No. 78-18-2
Article Data24
CAS DataBase
Density 1.2 g/cm³
Solubility
Melting Point 76-77 °C
Formula C12H22 O5
Boiling Point 374.7 °C at 760 mmHg
Molecular Weight 246.304
Flash Point 180.4 °C
Transport Information
Appearance White to colorless solid.
Safety Slightly toxic by parenteral route. A severe eye and skin irritant. When heated to decomposition it emits acrid smoke and irritating vapors.
Risk Codes
Molecular Structure
Hazard Symbols Dangerous fire risk, powerful oxidizer.
Synonyms Peroxide,1-hydroperoxycyclohexyl 1-hydroxycyclohexyl (6CI,7CI);1-Hydroxy-1'-hydroperoxydicyclohexyl peroxide; Perhexa P
PSA 74.60000
LogP 3.05660

Synthetic route

: 108-94-1
cyclohexanone

: 78-93-3
butanone

A: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

B: 126-76-1
3,6-dimethyl-3,6-dihydroperoxy-4,5-dioxaoctane

Conditions

Conditions	Yield
With C14H34N2O6S2(2+)*2HO4S(1-)	A 95.2% B 96.4%

...Expand

: 108-94-1
cyclohexanone

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

Conditions

Conditions	Yield
With dihydrogen peroxide; nitric acid at 18℃; for 2h; Kinetics; Thermodynamic data; Temperature; Time;	96.2%
With dihydrogen peroxide In Petroleum ether at 70 - 80℃; for 4h; Solvent;	88.7%
With sulfuric acid; dihydrogen peroxide at 10℃; for 1h;	84%

: 766-07-4
cyclohexyl hydroperoxide

A: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

B: 2407-94-5
1,1'-dihydroxycyclohexyl peroxide

C: 2699-12-9
bis-(1-hydroperoxycyclohexyl)peroxide

D: 108-94-1
cyclohexanone

Conditions

Conditions	Yield
With ozone In tetrachloromethane at 20℃; Kinetics;

...Expand

: 108-94-1
cyclohexanone

A: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

B: 2407-94-5
1,1'-dihydroxycyclohexyl peroxide

C: 2699-12-9
bis-(1-hydroperoxycyclohexyl)peroxide

Conditions

Conditions	Yield
With dihydrogen peroxide In tetrachloromethane

...Expand

: 7647-01-0
hydrogenchloride

: 7732-18-5
water

: 7722-84-1
dihydrogen peroxide

: 108-94-1
cyclohexanone

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

...Expand

: 7647-01-0
hydrogenchloride

: 60-29-7
diethyl ether

: 7732-18-5
water

: 7722-84-1
dihydrogen peroxide

: 108-94-1
cyclohexanone

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

...Expand

: 108-93-0
cyclohexanol

peroxide: peroxide

oxygen: oxygen

A: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

B bis-<1-hydroxy-cyclohexyl>-peroxide ?: bis-<1-hydroxy-cyclohexyl>-peroxide ?

...Expand

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 2699-12-9
bis-(1-hydroperoxycyclohexyl)peroxide

Conditions

Conditions	Yield
With sulfuric acid; dihydrogen peroxide at 20℃; for 24h;	92%
With dihydrogen peroxide

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 78-94-4
methyl vinyl ketone

A: 73154-83-3
2,12-Tridecanedione

B: 590-90-9
1-Hydroxy-3-butanone

C: 333-60-8
2-oxodecanoic acid

D: 108-94-1
cyclohexanone

Conditions

Conditions	Yield
With titanium(III) chloride; acetic acid for 3h; Ambient temperature; Yields of byproduct given. Title compound not separated from byproducts;	A 26% B n/a C n/a D n/a
With titanium(III) chloride; acetic acid for 3h; Ambient temperature; Yield given. Title compound not separated from byproducts;	A 26% B n/a C n/a D n/a

...Expand

: 110-86-1
pyridine

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 98-88-4
benzoyl chloride

: 13213-29-1
1,1-bis-benzoylperoxy-cyclohexane

Conditions

Conditions	Yield
unter Kuehlung;

...Expand

: 110-86-1
pyridine

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 122-04-3
4-nitro-benzoyl chloride

: 1,1-bis-(4-nitro-benzoylperoxy)-cyclohexane

...Expand

: 56-23-5
tetrachloromethane

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

A: 2699-11-8
1,1-dihydroperoxycyclohexane

B: 108-94-1
cyclohexanone

Conditions

Conditions	Yield
at 30℃; untersucht wurde das Gleichgewicht;

...Expand

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 1147550-11-5
ammonium thiocyanate

: 91468-11-0
6-thiocyanohexanoic acid

Conditions

Conditions	Yield
With water; iron(II) sulfate
With copper(I) thiocyanate; water

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 140-89-6
potassium ethyl xanthogenate

: 51827-49-7
6-ethoxythiocarbonylmercapto-hexanoic acid

Conditions

Conditions	Yield
With water; iron(II) sulfate beim anschliessenden Erhitzen mit Schwefelsaeure;

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 183-84-6
Cyclohexanone diperoxide

Conditions

Conditions	Yield
With diethyl ether; sulfuric acid
With ethanol; sulfuric acid
With diethyl ether; phosphorus pentoxide

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 89534-65-6
6-sulfohexanoic acid

Conditions

Conditions	Yield
With diethyl ether; sulfur dioxide; water; iron(II) sulfate

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 102312-74-3
6-(hydroxy-nitroso-amino)-hexanoic acid

Conditions

Conditions	Yield
With nitrogen(II) oxide; iron(II) sulfate

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 693-23-2
1,12-dodecanedioic acid

Conditions

Conditions	Yield
With sulfuric acid; iron(II) sulfate
With methanol; iron(II) sulfate

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 92038-67-0
6,6’-disulfanediyldihexanoic acid

Conditions

Conditions	Yield
With copper (I)-thiosulfate; water; sodium thiosulfate beim anschliessenden Erhitzen mit wss. Salzsaeure;

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

A: 124-04-9
Adipic acid

B: 693-23-2
1,12-dodecanedioic acid

C: 108-94-1
cyclohexanone

D: 142-62-1
hexanoic acid

Conditions

Conditions	Yield
at 110 - 160℃;

...Expand

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 609-65-4
o-chlorobenzoyl chloride

: 1,1-bis-(2-chloro-benzoylperoxy)-cyclohexane

Conditions

Conditions	Yield
With pyridine

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 98-88-4
benzoyl chloride

: 13213-29-1
1,1-bis-benzoylperoxy-cyclohexane

Conditions

Conditions	Yield
With pyridine

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 106-99-0
buta-1,3-diene

A: 114293-16-2
11-vinyl-octadec-8t-enedioic acid

B: 34990-46-0
7,11-octadecadiene-1,18-dicarboxylic acid

Conditions

Conditions	Yield
With iron (II)-ammonium sulfate; water; urea

...Expand

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 75-36-5
acetyl chloride

: 13213-27-9
cyclohexyl-1,1-diacetylperoxide

Conditions

Conditions	Yield
With pyridine

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 60-29-7
diethyl ether

: 603-35-0
triphenylphosphine

: 2407-94-5
1,1'-dihydroxycyclohexyl peroxide

Conditions

Conditions	Yield
untersucht wurde der zeitliche Verlauf;

...Expand

: 186581-53-3, 908094-01-9
diazomethane

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 28009-71-4
1-Methylperoxycyclohexylhydroperoxid

Conditions

Conditions	Yield
In cyclohexane

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

: 1577-22-6
5-hexenoic acid

Conditions

Conditions	Yield
With copper (I) acetate; iron(II) sulfate In methanol for 1h; ice cooling; Yield given;

: 78-18-2
1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide

carbon monoxide: carbon monoxide

: 111-16-0
heptanedioic acid

Conditions

Conditions	Yield
With iron(II) sulfate; urea at 25℃; under 73550.8 Torr;

Cyclohexanone peroxide Chemical Properties

Molecular Formula: C₁₂H₂₂O₅
Molar mass: 246.3001 g/mol
Nominal Mass: 246 Da
Average Mass: 246.3001 Da
Monoisotopic Mass: 246.146724 Da
Density: 1.2 g/cm³
Flash Point: 180.4 °C
Index of Refraction: 1.518
Boiling Point: 374.7 °C at 760 mmHg
Vapour Pressure: 3.81E-07 mmHg at 25°C
Structure of Cyclohexanone peroxide (78-18-2):

XLogP3-AA: 2.3
H-Bond Donor: 2
H-Bond Acceptor: 5
Systematic Name of Cyclohexanone peroxide (78-18-2): 1-(1-Hydroperoxycyclohexyl)peroxycyclohexan-1-ol
SMILES: O(OC1(OO)CCCCC1)C2(O)CCCCC2
InChI: InChI=1/C12H22O5/c13-11(7-3-1-4-8-11)16-17-12(15-14)9-5-2-6-10-12/h13-14H,1-10H2
InChIKey: UICXTANXZJJIBC-UHFFFAOYAL
Std. InChI: InChI=1S/C12H22O5/c13-11(7-3-1-4-8-11)16-17-12(15-14)9-5-2-6-10-12/h13-14H,1-10H2
Std. InChIKey: UICXTANXZJJIBC-UHFFFAOYSA-N

Cyclohexanone peroxide Toxicity Data With Reference

1.		eye-rbt 80 mg/1M RNS SEV		ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. 8 (1958),25.
2.		par-mus LD50:2 g/kg		NCPBBY National Clearinghouse for Poison Control Centers, Bulletin. U.S. Department of Health, Education, and Welfare (Washington, DC) Jan/Feb ,1969.

Cyclohexanone peroxide Consensus Reports

Reported in EPA TSCA Inventory.

Cyclohexanone peroxide Safety Profile

Slightly toxic by parenteral route. A severe eye and skin irritant. When heated to decomposition it emits acrid smoke and irritating vapors.

Cyclohexanone peroxide Standards and Recommendations

DFG MAK: Strong Skin Effects

Cyclohexanone peroxide Specification

Cyclohexanone peroxide (78-18-2) also can be called Perhexa P ; Cyclohexanol, 1-((1-hydroperoxycyclohexyl)dioxy)- ; 1-Hydroperoxycyclohexyl 1-hydroxycyclohexyl peroxide ;and 1-Hydroxy-1'-hydroperoxydicyclohexyl peroxide .

Product Name

Cyclohexanone peroxide

Synthetic route

Cyclohexanone peroxide Chemical Properties

Cyclohexanone peroxide Toxicity Data With Reference

Cyclohexanone peroxide Consensus Reports

Cyclohexanone peroxide Safety Profile

Cyclohexanone peroxide Standards and Recommendations

Cyclohexanone peroxide Specification

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