Hexafluoropropylene supplier

Name
Perfluoro-1 -propene
EINECS 204-127-4
CAS No. 116-15-4
Article Data136
CAS DataBase
Density 1.442 g/cm³
Solubility

Stability

Stable. Incompatible with alkali metals, powdered metals.

Toxicology

Harmful if inhaled - may cause suffocation. Respiratory irritant.

Toxicity data
(T

Melting Point -153 ºC
Formula C₃F₆
Boiling Point -28 ºC
Molecular Weight 150.023
Flash Point °C
Transport Information UN 1858
Appearance colourless gas
Safety Mildly toxic by inhalation. Explosive reaction with Grignard reagents (e.g., phenylmagnesium bromide). Reacts with tetrafluorethylene + air to form explosive peroxides. When heated to decomposition it emits toxic fumes of F⁻.
Risk Codes R20;R37
Molecular Structure
Hazard Symbols
Synonyms Propene,hexafluoro- (8CI);1,1,2,3,3,3-Hexafluoro-1-propene;1,1,2,3,3,3-Hexafluoropropene;Esafluoropropene;F 1216;HFC 1216;Hexafluoro-1-propene;Hexafluoropropene;Hexafluoropropylene;PFC 1216;Perfluoro-1-propene;Perfluoropropene;Perfluoropropylene;Propylene hexafluoride;R 1216;
PSA 0.00000
LogP 2.62630

Synthetic route

: 116-14-3
polytetrafluoroethylene

: 116-15-4
perfluoropropylene

Conditions

Conditions	Yield
With silicon carbide at 450 - 850℃; for 3.33333E-05h;	96.5%
at 760 - 860℃; unter vermindertem Druck;
at 700℃; bei der thermischen Zersetzung;

: 423-25-6
(heptafluoro n-propyl) magnesiumiodide

A: 2252-84-8
HFC-227ca

B: 116-15-4
perfluoropropylene

Conditions

Conditions	Yield
In further solvent(s) decomposition on boiling in dibutyl ether;;	A 76% B 6%
In further solvent(s) decomposition on boiling in dibutyl ether;;	A 76% B 6%

: 662-13-5
(heptafluoro i-propyl) magnesiumbromide

: 116-15-4
perfluoropropylene

Conditions

Conditions	Yield
In diethyl ether warming from -78 to 20°C and heating under reflux, 1 hour;;	70.5%
In diethyl ether warming from -78 to 20°C and heating under reflux, 1 hour;;	70.5%

: 756-13-8
perfluoro-2-methylpentan-3-one

A: 116-15-4
perfluoropropylene

B: 422-61-7
perfluoropropanoyl fluoride

Conditions

Conditions	Yield
With cesium fluoride at 250℃; for 2h; Product distribution;	A 68% B n/a

: 1526-49-4
ethyl heptafluoroisobutyrate

: 591-51-5
phenyllithium

A: 116-15-4
perfluoropropylene

B: 93-89-0
benzoic acid ethyl ester

C: 56112-35-7
perfluoroisopropyl phenyl ketone

Conditions

Conditions	Yield
In diethyl ether at -110℃; for 0.166667h; C6H5Li added to ester;	A n/a B n/a C 65%

...Expand

: 355-49-7
perfluorocetane

A: 116-14-3
polytetrafluoroethylene

B: 116-15-4
perfluoropropylene

C: 357-26-6
octafluoro-1-butene

Conditions

Conditions	Yield
at 195 - 500℃; under 75.7576 Torr; Temperature; Pressure; Pyrolysis;	A 62.4% B 24.3% C 6.2%

...Expand

: 661-95-0
1,2-dibromohexafluoropropane

A: 2252-78-0
1-bromo-1,1,2,3,3,3-hexafluoro-propane

B: 116-15-4
perfluoropropylene

C: 431-63-0
1,1,1,2,3,3-hexafluoropropane

D: 2252-80-4
2-bromo-1,1,1,2,3,3-hexafluoro-propane

Conditions

Conditions	Yield
With tri-n-butyl-tin hydride for 1.5h; Product distribution; Heating;	A 53% B 3% C 14% D 21%

...Expand

: 355-49-7
perfluorocetane

A: 116-14-3
polytetrafluoroethylene

B: 116-15-4
perfluoropropylene

Conditions

Conditions	Yield
at 195 - 600℃; under 75.7576 Torr; Temperature; Pressure; Pyrolysis;	A 50.3% B 28.9%

: 34557-54-5
methane

: 115-25-3
Octafluorocyclobutane

A: 116-14-3
polytetrafluoroethylene

B: 116-15-4
perfluoropropylene

C: 75-38-7
Vinylidene fluoride

D: 754-12-1
2,3,3,3-tetrafluoro-propene

E: 359-11-5
1,1,2-trifluoroethylene

Conditions

Conditions	Yield
at 250 - 800℃; under 150.015 Torr; for 0.000175h; Temperature;	A 45.8% B 7.4% C 10.4% D 8.4% E 9.5%

...Expand

: 355-49-7
perfluorocetane

A: 116-14-3
polytetrafluoroethylene

B: 116-15-4
perfluoropropylene

C: 115-25-3
Octafluorocyclobutane

Conditions

Conditions	Yield
at 195 - 550℃; under 75.7576 Torr; Temperature; Pressure; Pyrolysis;	A 36.1% B 42.7% C 6.1%

...Expand

: 83714-48-1
2-chloroundecafluoro-2-methyl-3-pentanone

A: 116-15-4
perfluoropropylene

B: 422-61-7
perfluoropropanoyl fluoride

C: 756-13-8
perfluoro-2-methylpentan-3-one

Conditions

Conditions	Yield
With cesium fluoride In diethylene glycol dimethyl ether for 1h; Product distribution; Heating;	A n/a B n/a C 38%

...Expand

: 377-51-5
heptafluoro-butyric acid iodoamide

A: 2252-84-8
HFC-227ca

B: 116-15-4
perfluoropropylene

C: 931-91-9
1,1,2,2,3,3-Hexafluoro-cyclopropane

Conditions

Conditions	Yield
With sodium hydroxide byproducts: NH3; boiled in 30% NaOH for 5h;	A 38% B n/a C n/a
With NaOH byproducts: NH3; boiled in 30% NaOH for 5h;	A 38% B n/a C n/a

...Expand

: 355-49-7
perfluorocetane

A: 116-14-3
polytetrafluoroethylene

B: 116-15-4
perfluoropropylene

C: 357-26-6
octafluoro-1-butene

D: 115-25-3
Octafluorocyclobutane

Conditions

Conditions	Yield
at 195 - 450℃; under 75.7576 Torr; Temperature; Pressure; Pyrolysis;	A 32.5% B 16.5% C 9.2% D 8.2%

...Expand

: 67641-28-5
perfluoroallylfluorosulphate

: 116-15-4
perfluoropropylene

Conditions

Conditions	Yield
With Trimethyl borate; sulfur trioxide at 25℃; for 168h;	30%
With cesium fluoride In 1,2-dimethoxyethane at 20℃;	25.5%

: 773837-37-9
sodium cyanide

: 67641-28-5
perfluoroallylfluorosulphate

A: 640723-20-2, 2699-79-8, 12769-73-2
fluorosulfonyl fluoride

B: 116-15-4
perfluoropropylene

C: 558-25-8
methyl fluorosulfonate

D: 7792-66-7
2,2,3,4,4-pentafluorobut-3-ene nitrile

E: 667-49-2
2,3,3-trifluoroacryloyl fluoride

F: 7446-09-5
sulfur dioxide

Conditions

Conditions	Yield
In acetonitrile at -10 - 4.4℃; for 4.5h; Temperature; Inert atmosphere;	A n/a B n/a C n/a D 27% E n/a F n/a

...Expand

: 67641-28-5
perfluoroallylfluorosulphate

: 10442-39-4
tetra-n-butylammonium cyanide

A: 640723-20-2, 2699-79-8, 12769-73-2
fluorosulfonyl fluoride

B: 353-50-4
Carbonyl fluoride

C: 116-15-4
perfluoropropylene

D: 7792-66-7
2,2,3,4,4-pentafluorobut-3-ene nitrile

E: 7783-61-1
silicon tetrafluoride

Conditions

Conditions	Yield
In dichloromethane at -20 - 20℃; for 4h; Solvent; Inert atmosphere;	A n/a B n/a C n/a D 22% E n/a

...Expand

: 76-18-6
2-Chloro-F-propane

: 116-15-4
perfluoropropylene

Conditions

Conditions	Yield
With hydrogen; NiCl2 on activated carbon at 250 - 300℃; for 0.00161111 - 0.00305556h;	21.6%

: 773837-37-9
sodium cyanide

: 112-49-2
Triethylene glycol dimethyl ether

: 67641-28-5
perfluoroallylfluorosulphate

A: 640723-20-2, 2699-79-8, 12769-73-2
fluorosulfonyl fluoride

B: 116-15-4
perfluoropropylene

C: 74-90-8
hydrogen cyanide

D: 115-10-6
Dimethyl ether

E: 460-19-5
ethanedinitrile

F: 558-25-8
methyl fluorosulfonate

G: 380-29-0
methyl-pentafluoroallyl ether

H: 7792-66-7
2,2,3,4,4-pentafluorobut-3-ene nitrile

I: 667-49-2
2,3,3-trifluoroacryloyl fluoride

J: 7446-09-5
sulfur dioxide

K: 7789-21-1
fluorosulphonic acid

L: 7783-61-1
silicon tetrafluoride

Conditions

Conditions	Yield
at -10 - 60℃; for 2.5h; Temperature; Inert atmosphere;	A n/a B n/a C n/a D n/a E n/a F n/a G n/a H 18% I n/a J n/a K n/a L n/a

...Expand

: 75-46-7
trifluoromethan

A: 116-14-3
polytetrafluoroethylene

B: 75-73-0
carbon tetrafluoride

C: 76-19-7
freon-218

D: 116-15-4
perfluoropropylene

E: 76-16-4
Hexafluoroethane

Conditions

Conditions	Yield
With activated carbon supported potassium at 799.84℃; under 750.075 Torr; Pyrolysis; Inert atmosphere;	A 16.1% B n/a C n/a D 14.4% E n/a

...Expand

: 375-22-4
heptafluorobutyric Acid

: 116-15-4
perfluoropropylene

Conditions

Conditions	Yield
at 300℃; Reaktion des Natrium-Salzes;
at 235℃; Reaktion des Kalium-Salzes;
at 275℃; Reaktion des Barium-Salzes;

: 375-22-4
heptafluorobutyric Acid

A: 116-15-4
perfluoropropylene

B: 355-42-0
tetradecafluorohexane

Conditions

Conditions	Yield
at 300 - 320℃; Reaktion des Silber-Salzes.Pyrolysis;

: 375-22-4
heptafluorobutyric Acid

A: 116-15-4
perfluoropropylene

B: 335-42-2
perfluorobutyryl fluoride

C: 336-59-4
heptafluorobutyric anhydride

Conditions

Conditions	Yield
Pyrolyse von Lithium-, Calcium-, Strontium-, Blei- und Aluminium-Salz.Pyrolysis;

...Expand

: 60-29-7
diethyl ether

: 422-89-9
heptafluoro-propyl lithium

: 116-15-4
perfluoropropylene

Conditions

Conditions	Yield
at 25℃;

: 661-95-0
1,2-dibromohexafluoropropane

: 116-15-4
perfluoropropylene

Conditions

Conditions	Yield
With acetic acid; zinc at 25℃;
With ethanol; zinc

: 75-45-6
Chlorodifluoromethane

: 116-15-4
perfluoropropylene

Conditions

Conditions	Yield
at 700℃; Pyrolysis;

: 116-14-3
polytetrafluoroethylene

A: 116-15-4
perfluoropropylene

B: 76-16-4
Hexafluoroethane

C: 382-21-8
perfluoroisobutylene

D: 115-25-3
Octafluorocyclobutane

Conditions

Conditions	Yield
at 600℃; Dimerisierung.Pyrolysis;
at 650℃; Dimerisierung.Pyrolysis;

...Expand

: 116-14-3
polytetrafluoroethylene

A: 116-15-4
perfluoropropylene

B: 360-89-4, 172368-67-1
octafluoro-2-butene

Conditions

Conditions	Yield
at 700℃;
at 700℃;

: 661-97-2
1,2-dichlorohexafluoropropane

: 116-15-4
perfluoropropylene

Conditions

Conditions	Yield
With ethanol; zinc at 40℃;
With ethanol; zinc at 100℃; unter Druck;

: 116-15-4
perfluoropropylene

: 39269-10-8
adamantane-1,3-dicarboxylic acid

: 86302-01-4
5-(1,1,2,3,3,3-Hexafluoro-propyl)-adamantane-1,3-dicarboxylic acid

Conditions

Conditions	Yield
In acetic acid at 20℃; for 20h; Product distribution; Irradiation; var. time, var. temp., var. solvents, var. absorbed dose;	100%
In acetic acid at 70℃; for 20h; Irradiation;	100%

: 116-15-4
perfluoropropylene

: 95-54-5
1,2-diamino-benzene

: 41185-74-4
2-(α-hydro-tetrafluoroethyl)benzimidazole

Conditions

Conditions	Yield
With potassium fluoride In N,N-dimethyl-formamide	100%
With diethylamine In ethyl acetate at 7 - 12℃; for 1.25 - 2.5h;	85%
In ethyl acetate at 75℃; under 3000.3 - 9750.98 Torr; for 18h; Solvent; Autoclave;	75%

: 116-14-3
polytetrafluoroethylene

: 116-15-4
perfluoropropylene

copolymer; monomers: tetrafluoroethylene; hexafluoropropylene: copolymer; monomers: tetrafluoroethylene; hexafluoropropylene

Conditions

Conditions	Yield
With ozone at -33.15 - 16.85℃;	100%

: 33309-88-5
palladium(0)bis(tricyclohexylphosphine)

: 116-15-4
perfluoropropylene

: (η2-CF2=CFCF3)Pd(PCy3)2

Conditions

Conditions	Yield
In toluene at 20℃; under 2660.18 Torr; for 0.5h; Inert atmosphere; Autoclave; regioselective reaction;	100%

: 116-15-4
perfluoropropylene

: 431-63-0
1,1,1,2,3,3-hexafluoropropane

Conditions

Conditions	Yield
With palladium/alumina; hydrogen at 59 - 121℃; under 1125.11 Torr; Pressure; Temperature;	99.9%
With hydrogen; Pd on alumina; corundum at 105 - 140℃; under 750.075 Torr; Product distribution / selectivity;	95.2%
With palladium Hydrogenation;

: 116-15-4
perfluoropropylene

: 76-37-9
2,2,3,3-tetrafluoropropanol

: 65064-78-0
1,1,1,2,3,3-hexafluoro-3-(2,2,3,3-tetrafluoropropoxy)propane

Conditions

Conditions	Yield
With potassium hydroxide In water at 50 - 60℃; under 3000.3 - 3750.38 Torr; Inert atmosphere; Autoclave;	99.8%
With potassium hydroxide at 20 - 40℃;	87%
With potassium hydroxide
With potassium hydroxide In acetonitrile cooling;

: 116-15-4
perfluoropropylene

A: 756-12-7
trifluoromethyl(perfluoroisopropyl)ketone

B CF(CF3)2-1,1,1,3,4,4,4-heptafluoro-3-trifluoromethylbutan-2-one: CF(CF3)2-1,1,1,3,4,4,4-heptafluoro-3-trifluoromethylbutan-2-one

Conditions

Conditions	Yield
With potassium fluoride; trifluoroacetic anhydride In diethylene glycol dimethyl ether	A 99.6% B n/a

: 116-15-4
perfluoropropylene

: 661-95-0
1,2-dibromohexafluoropropane

Conditions

Conditions	Yield
With bromine at 100℃; Cooling with acetone-dry ice;	99.41%
With bromine at 20℃; for 19h;	95%
With bromine for 19h;	95%

: 116-15-4
perfluoropropylene

: 64-17-5
ethanol

: 380-34-7
1,1,2,3,3,3-hexafluoropropyl ethyl ether

Conditions

Conditions	Yield
With potassium hydroxide at 20 - 40℃;	99%
With potassium hydroxide
(i) NaN3, (ii) Br2, aq. NaBr, (iii) Hg; Multistep reaction;

: 1256935-40-6
porassium hydrogen difluoride

: 116-15-4
perfluoropropylene

: 375-62-2
Perfluoro pentanoyl fluoride

A CF(CF3)2-1,1,1,2,4,4,5,5,6,6,7,7,7-tridecafluoro-2-trifluoromethylheptan-3-one: CF(CF3)2-1,1,1,2,4,4,5,5,6,6,7,7,7-tridecafluoro-2-trifluoromethylheptan-3-one

B: 87383-08-2
1,1,1,2,4,4,5,5,6,6,7,7,7-tridecafluoro-2-trifluoromethyl-heptan-3-one

Conditions

Conditions	Yield
With potassium fluoride In diethylene glycol dimethyl ether	A n/a B 99%

...Expand

: 116-15-4
perfluoropropylene

: 754-12-1
2,3,3,3-tetrafluoro-propene

Conditions

Conditions	Yield
Stage #1: perfluoropropylene With trimethylaminealane In benzene-d6 at 20℃; under 760.051 Torr; for 0.0833333h; Inert atmosphere; Schlenk technique; Stage #2: With trimethylaminealane In benzene-d6 at 40℃; for 72h; Inert atmosphere; Schlenk technique;	98.7%
With trimethylamin alane In benzene-d6 at 40℃; for 90h;	98%
With diisobutylaluminium hydride In diethylene glycol dimethyl ether at 20℃; for 19h;	94.5%
With palladium on activated charcoal; hydrogen at 120℃; Catalytic behavior; Reagent/catalyst;
With palladium on activated charcoal; hydrogen In neat (no solvent) at 120℃; under 750.075 Torr;

: 116-15-4
perfluoropropylene

: 2070-70-4
perfluoro-4-methyl-2-pentene

Conditions

Conditions	Yield
With potassium fluoride; 18-crown-6 ether In acetonitrile at 130℃; under 11026.1 Torr; for 4h; Temperature; Reagent/catalyst; Pressure; Flow reactor; Industrial scale;	98.43%
cesium fluoride In acetonitrile at 0℃;	95%
With Tetrakis(dimethylamino)ethylen for 24h; Ambient temperature;	88%

: 116-15-4
perfluoropropylene

: 422-61-7
perfluoropropanoyl fluoride

: 756-13-8
perfluoro-2-methylpentan-3-one

Conditions

Conditions	Yield
With iron(III) trifluoride; 18-crown-6 ether In acetonitrile at 90℃; for 10h; Autoclave;	98.2%
With activated carbon BAU-A-2 supported 20 wtpercent CsF In neat (no solvent) at 95℃; under 1875.19 Torr;
at 160℃; under 750.075 Torr; for 10h; Gas phase;

: 67-56-1
methanol

: 116-15-4
perfluoropropylene

: 382-34-3
1,1,1,2,3,3-hexafluoro-3-methoxypropane

Conditions

Conditions	Yield
With sodium for 1.5h;	98%
With 1,4-diaza-bicyclo[2.2.2]octane; dmap; DBN; 1,8-diazabicyclo[5.4.0]undec-7-ene In 1-methyl-pyrrolidin-2-one at 50℃; for 0.00277778h;	95.9%
With potassium hydroxide

: 353-50-4
Carbonyl fluoride

: 116-15-4
perfluoropropylene

: 677-84-9
perfluoroisobutyryl fluoride

Conditions

Conditions	Yield
cesium fluoride on NaF at 250℃; for 5h;	98%
cesium fluoride on NaF at 190℃;	95%
cesium fluoride on NaF at 190℃;	95%

: 116-15-4
perfluoropropylene

: C3F7IO3S

Conditions

Conditions	Yield
With IOSO2F Ambient temperature;	98%

: 116-15-4
perfluoropropylene

: 35771-41-6
5-Hydroxy-2-(4-nitrophenylazo)pyridine

: 110861-11-5
[5-(1,1,2,3,3,3-Hexafluoro-propoxy)-pyridin-2-yl]-(4-nitro-phenyl)-diazene

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile at 22 - 36℃; for 0.5h;	98%

: (N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II)

: 116-15-4
perfluoropropylene

: 6476-36-4
tris(1-methylethyl)phosphine

: (η2-CF2=CFCF3)Pd(PiPr3)2

Conditions

Conditions	Yield
In toluene at 20℃; under 2660.18 Torr; for 0.5h; Inert atmosphere; Autoclave; regioselective reaction;	98%

...Expand

: 116-15-4
perfluoropropylene

: 258278-28-3
1,3-bis(2,6-diisopropylphenyl)dihydroimidazol-2-ylidene

: C30H38F6N2

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; under 1277.21 Torr; Glovebox; Schlenk technique; Sealed tube;	98%

: 116-15-4
perfluoropropylene

: 360-58-7
1-ethoxy-1,3,3,3-tetrafluoro-2-trifluoromethyl-propene

: C7H5F9O

Conditions

Conditions	Yield
at 50℃; for 5h;	98%

: 116-15-4
perfluoropropylene

: 355-42-0
tetradecafluorohexane

Conditions

Conditions	Yield
With oxygen at 60℃; Temperature;	98%

: 116-15-4
perfluoropropylene

: 74-85-1
ethene

: 49852-57-5
1,1,2-trifluoro-2-(trifluoromethyl)cyclobutane

Conditions

Conditions	Yield
With 4-tert-Butylcatechol at 320 - 350℃; for 5h; Inert atmosphere;	97.9%
at 250℃; for 18h;

: 116-15-4
perfluoropropylene

: 583-78-8
2,5-dichlorophenol

: 1026364-35-1
1,1,2,3,3,3-hexafluoropropoxy-2,5-dichlorobenzene

Conditions

Conditions	Yield
With sodium hydroxide In dimethyl sulfoxide at 25℃; under 2250.23 Torr; Solvent; Reagent/catalyst; Temperature; Pressure;	97.7%

: 67-56-1
methanol

: 116-15-4
perfluoropropylene

: 568550-25-4
1,1,2,3,3,3-hexafluoroisopropyl methyl ether

Conditions

Conditions	Yield
With 1,3-bis-(diphenylphosphino)propane In acetonitrile at 80℃; under 1500.15 - 6000.6 Torr; for 20h; Reagent/catalyst; Solvent; Pressure; Temperature; Autoclave;	97.7%

: 116-15-4
perfluoropropylene

: 354-34-7
trifluoroacetyl fluoride

: 756-12-7
trifluoromethyl(perfluoroisopropyl)ketone

Conditions

Conditions	Yield
With 15-crown-5; cobalt(II) fuoride In acetonitrile at 80℃; for 10h; Reagent/catalyst; Autoclave;	97.5%
With liquid phase catalyst Cat15 at 60℃; for 3h; Reagent/catalyst; Autoclave; Inert atmosphere;	95.3%
With potassium fluoride In diethylene glycol dimethyl ether at 100 - 110℃; for 8h; Autoclave;	70%
potassium fluoride In N,N-dimethyl-formamide at 80℃; for 11.17h; Product distribution / selectivity;	54 - 84 %Chromat.
With activated carbon BAU-A-2 supported 20 wtpercent CsF In neat (no solvent) at 65 - 130℃; under 1875.19 Torr;

: 353-50-4
Carbonyl fluoride

: 116-15-4
perfluoropropylene

: 813-44-5
1,1,1,2,4,5,5,5-octafluoro-2,4-bis(trifluoromethyl)pentan-3-one

Conditions

Conditions	Yield
With nickel(II) fluoride; 18-crown-6 ether In acetonitrile at 90℃; for 10h; Autoclave;	97.2%
With cesium fluoride In acetonitrile

: 116-15-4
perfluoropropylene

: 382-31-0
2,2,3,4,4,4-hexafluoro-1-butanol

: 928617-03-2
CF3CFHCF2CH2OCF2CFHCF3

Conditions

Conditions	Yield
Stage #1: perfluoropropylene; 2,2,3,4,4,4-hexafluoro-1-butanol With potassium carbonate In acetonitrile at 40℃; Stage #2: With potassium hydrogen difluoride; adogen 464 In diethylene glycol dimethyl ether at 110℃; for 24h;	97%

: 616-47-7
1-methyl-1H-imidazole

: 116-15-4
perfluoropropylene

: 1-methyl-3-(1,1,2,3,3,3-hexafluoropropyl)imidazolium chloride

Conditions

Conditions	Yield
With hydrogenchloride In diethyl ether; acetonitrile at 20℃; under 3863.02 Torr;	97%

: 116-15-4
perfluoropropylene

: 4286-23-1
4-isopropenylphenol

: p-(perfluorononenyloxy)isopropenylbenzene

Conditions

Conditions	Yield
Stage #1: perfluoropropylene; 4-isopropenylphenol With triethylamine at 40℃; for 3h; Stage #2: With calcium carbonate at 40℃; for 2h;	96.7%

Hexafluoropropylene Consensus Reports

Reported in EPA TSCA Inventory.

Hexafluoropropylene Standards and Recommendations

DOT Classification: 2.2; Label: Nonflammable Gas

Hexafluoropropylene Specification

The Hexafluoropropene, with the cas registry number 116-15-4, has the systematic name of 1,1,2,3,3,3-hexafluoroprop-1-ene. This is a kind of colorless nonflammable air with no odour.

The characteristics of this chemical are as follows: (1)ACD/LogP: 1.88; (2)ACD/LogD (pH 5.5): 1.88; (3)ACD/LogD (pH 7.4): 1.88; (4)ACD/BCF (pH 5.5): 15.8; (5)ACD/BCF (pH 7.4): 15.8; (6)ACD/KOC (pH 5.5): 251.01; (7)ACD/KOC (pH 7.4): 251.01; (8)Index of Refraction: 1.253; (9)Molar Refractivity: 16.63 cm³; (10)Molar Volume: 104 cm³; (11)Polarizability: 6.59× 10^-24cm³; (12)Surface Tension: 9.6 dyne/cm ; (13)Density: 1.442 g/cm³; (14)Enthalpy of Vaporization: 21.51 kJ/mol; (15)Vapour Pressure: 4770 mmHg at 25°C; (16)Exact Mass: 149.990419 ; (17)MonoIsotopic Mass: 149.990419 ; (18)Heavy Atom Count: 9 ; (19)Complexity: 126.

Use of Hexafluoropropene: Hexafluoropropene reacts to produce 1,2-dibromo-1,1,2,3,3,3-hexafluoro-propane, with the following condition: solvent: bromine; other condition: im Licht.

As to its usage, it is widely applied in many ways. It could be used in producing fluro fined chemistry, pharmaceutic intermediate, extinguishant and fluoropolymer material; It could also be used in the material for the PSAIM, fluorocarbon oil, HFPO and so on.

While dealing with this chemical, you should be very cautious. This is irritant to respiratory system and may cause inflammation to the skin or other mucous membranes; Then it may cause damage to health, and if in case of fire and/or explosion, do not breathe fumes.

Additionally, the following datas could be converted into the molecular structure:
(1)SMILES:F/C(F)=C(/F)C(F)(F)F
(2)InChI:InChI=1/C3F6/c4-1(2(5)6)3(7,8)9

Below are the toxicity information of this chemical:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LC50	inhalation	750ppm/4H (750ppm)		Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 27, Pg. 509, 1966.
rat	LC50	inhalation	11200mg/m3/4H (11200mg/m3)	BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)	Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 15(2), Pg. 38, 1971.

Product Name

Perfluoro-1 -propene

Stability

Toxicology

Synthetic route

Hexafluoropropylene Consensus Reports

Hexafluoropropylene Standards and Recommendations

Hexafluoropropylene Specification

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