Manganese,decacarbonyldi-, (Mn-Mn) supplier

Name
MANGANESE CARBONYL
EINECS 233-445-6
CAS No. 10170-69-1
Article Data218
CAS DataBase
Density 1.75 g/cm³
Solubility Soluble in organic solvents. Insoluble in water
Melting Point 154 ºC
Formula C₁₀Mn₂O₁₀
Boiling Point 80°C/1mm
Molecular Weight 389.98
Flash Point 80°C/1mm subl.
Transport Information
Appearance yellow crystalline powder
Safety 22-26-36/37/39-45
Risk Codes 23/24/25
Molecular Structure
Hazard Symbols T
Synonyms Manganesecarbonyl (6CI);CORM 1;Decacarbonyldimanganese;Decacarbonyldimanganese(0);Dimanganese decacarbonyl;Manganese carbonyl (Mn2(CO)10);Manganesepentacarbonyl dimer;NSC 203018;NSC 22319;
PSA 0.00000
LogP -2.08000

Synthetic route

: 37504-44-2
(acetonitrile)pentacarbonylmanganese(I) hexafluorophosphate

: 13859-41-1
sodium pentacarbonyl manganate

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran Kinetics; byproducts: NaPF6, MeCN; Ar-atmosphere; 0.3 M TBAP, molar ratio Mn-complex cation : Mn-complex anion = 1:1; not isolated, detected by IR spectroscopy;	100%
In tetrahydrofuran byproducts: CH3CN; addn. of 5 mL of 1E-2 M NaMn(CO)5 in THF to 5 mL of 1E-2 M Mn(CO)5(MeCN)PF6 in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR;	88%

: 13859-41-1
sodium pentacarbonyl manganate

: 96412-38-3
pentacarbonyl(pyridine)manganese(I) tetrafluoroborate

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran Kinetics; byproducts: NaBF4, pyridine; Ar-atmosphere; 0.3 M TBAP, molar ratio Mn-complex cation : Mn-complex anion = 1:1; not isolated, detected by IR spectroscopy;	100%
In tetrahydrofuran NaMn(CO)5 (1.2 M, 5 mL) added under Ar to 5 mL of 1E-2 M Mn(CO)5(C5H5N)BF4, 0.3 M tetra-n-butylammonium perchlorate added, react. time approx. 30 min;

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

: 124401-76-9
2-methylisoquinolin-2-ium trifluoromethanesulfonate

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran react. at 20°C;	100%

: 16972-33-1
pentacarbonylhydridomanganese

: 85317-79-9, 89044-05-3
Li(1+)*Mn2(CO)9(CHO)(1-)=Li(Mn2(CO)9(CHO))

: 639-58-7
triphenyltin chloride

A: 10170-69-1
dimanganese decacarbonyl

B: 14405-84-6
triphenyltinmanganesepentacarbonyl

C: 1333-74-0
hydrogen

Conditions

Conditions	Yield
In tetrahydrofuran under N2, soln. of HMn(CO)5 in THF was cooled to -23°C, added tosoln. of formyl-complex in THF (-23°C), warmed slowly to room temp., Ph3SnCl was added, stirred for 1 h; solvent removed by rotary evapn., vac. sublimed at 60°C, residueeluted through silica gel column with ethyl acetate-hexane;	A 69% B 99% C >90

...Expand

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

: 105-39-5
chloroacetic acid ethyl ester

A: 10170-69-1
dimanganese decacarbonyl

B: 14100-30-2
pentacarbonylchloromanganese(I)

C: η1-(CH2COOEt) manganese pentacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran (N2 or Ar); 25°C, rapid mixing; determination by NMR;	A 1% B 0% C 99%
In chloroform-d1 (N2 or Ar); 25°C, rapid mixing; determination by NMR;	A 1% B 0% C 99%

...Expand

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
With N-t-butylbenzaldimine; NOPF6 In tetrahydrofuran soln. of benzaldehyde t-butylimine in THF added dropwise to NOPF6, Mn complex in THF added dropwise, stirred at room temp. for 45 min; not isolated; detected by IR;	98%
With N-t-butylbenzaldimine; NOPF6 In tetrahydrofuran soln. of benzaldehyde t-butylimine in THF added dropwise to NOPF6, Mn complex in THF added dropwise, stirred at -78°C for 45 min; not isolated; detected by IR;	95%
With NOPF6 In not given
With triethylamine; NOPF6 In tetrahydrofuran Et3N in THF added to NOPF6, suspn. of Mn complex in THF added dropwise,stirred at room temp. for 1 h;

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

: 999-54-2
(E)-methyl 4-chlorobut-2-enoate

A: 10170-69-1
dimanganese decacarbonyl

B: 14100-30-2
pentacarbonylchloromanganese(I)

C: η1-4-oxo-4-ethoxy-2-butenyl manganese pentacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran (N2 or Ar), 25°C, stirring for 30 min in a round-bottom flask; solvent is removed under reduced pressure, extd. with pentane, chromy. on silica gel(CH2Cl2), determined by (55)Mn-NMR;	A 2% B 0% C 98%

...Expand

: Mn(CO)5(OC(O)C12H25)

: 201230-82-2
carbon monoxide

: 1333-74-0
hydrogen

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In hexane byproducts: HCOOC12H25, n-C12H25OH; N2-atmosphere; closed vessel, 48 bar CO/H2, 85°C, 11 h; cooling to room temp., solvent removal (vac.), dissoln. in 5% CH2Cl2/hexane, chromy. (SiO2, 5% CH2Cl2/hexane), evapn., drying (vac.);	96%

...Expand

: 159983-78-5
Mn(CO)5(CO(CH2)10CH3)

: 201230-82-2
carbon monoxide

: 1333-74-0
hydrogen

A: 10170-69-1
dimanganese decacarbonyl

B: 16972-33-1
pentacarbonylhydridomanganese

Conditions

Conditions	Yield
In tetrahydrofuran N2-atmosphere; closed vessel, 48 bar CO/H2, 60°C, 8 h; cooling to room temp., solvent removal (vac.), dissoln. in 25% CH2Cl2/pentane, chromy. (SiO2, 5% CH2Cl2/pentane), evapn., drying (vac.);	A 95% B 5%

...Expand

: 600-00-0
ethyl 2-bromoisobutyrate

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

A: 14516-54-2
bromopentacarbonylmanganese(I)

B: 10170-69-1
dimanganese decacarbonyl

C: 16972-33-1
pentacarbonylhydridomanganese

Conditions

Conditions	Yield
In chloroform-d1 (N2 or Ar); 25°C, rapid mixing; determination by NMR;	A 5% B 95% C 0%
In tetrahydrofuran (N2 or Ar); 25°C, rapid mixing; determination by NMR;	A >99 B 0% C 0%

...Expand

: benzylpentacarbonylmanganese

A: 10170-69-1
dimanganese decacarbonyl

B: 14100-30-2
pentacarbonylchloromanganese(I)

C: 122967-79-7
(η3-C6H5CH2)Mn(CO)4

Conditions

Conditions	Yield
With tetrachloromethane In not given byproducts: CO; Irradiation (UV/VIS); irradn. (313 nm, Ar) in alkane solns. (purged with Ar) at 200K; not isolated, IR;	A 0% B 5% C 95%

...Expand

: benzylpentacarbonylmanganese

A: 10170-69-1
dimanganese decacarbonyl

B: 122967-79-7
(η3-C6H5CH2)Mn(CO)4

Conditions

Conditions	Yield
In not given byproducts: CO; Irradiation (UV/VIS); irradn. (313 nm, Ar) in alkane solns. (purged with Ar) at 200K; not isolated, IR;	A 5% B 95%
In methyl cyclohexane byproducts: CO, bibenzyl; Irradiation (UV/VIS); irradn. (Ar) in methylcyclohexane soln. at 295K; bibenzyl is the major org. product (ca 80%); not isolated, IR;
In not given byproducts: CO; Irradiation (UV/VIS); irradn. (313 nm, Ar) in alkane soln. (deoxygenated with Ar) at 295K; the two account for >95% of the η1 complex consumed; prolonged photolysis leads to a buildup of the Mn2(CO)10; not isolated, IR;

: 13859-41-1
sodium pentacarbonyl manganate

: 105-39-5
chloroacetic acid ethyl ester

A: 10170-69-1
dimanganese decacarbonyl

B: 14100-30-2
pentacarbonylchloromanganese(I)

C: η1-(CH2COOEt) manganese pentacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran (N2 or Ar); rapid mixing at room temp.;	A 6% B 0% C 94%

...Expand

: 14516-54-2
bromopentacarbonylmanganese(I)

: 59501-96-1
[C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li

A: 10170-69-1
dimanganese decacarbonyl

B: 1193-82-4
racemic methyl phenyl sulfoxide

C: 882-33-7
diphenyldisulfane

D: 7550-35-8
lithium bromide

Conditions

Conditions	Yield
In tetrahydrofuran mixing reactants in THF at -78°C, slow warming to room temp.; evapn. in vac., extn. with pentane, ether and finally acetone or CH2Cl2, concn., chromy. on Al2O3, purifn. by crystn., distn. or sublimation;	A 87% B 41% C 40% D 93%

...Expand

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

: 99685-96-8, 161105-99-3, 161106-00-9, 111138-12-6, 133318-63-5, 134053-11-5, 134931-35-4, 134931-36-5, 139703-76-7, 145633-27-8, 175414-73-0, 175414-74-1, 175414-75-2, 175519-12-7, 175519-13-8, 175519-14-9, 175519-15-0, 136376-46-0, 144906-37-6, 144906-38-7, 151767-00-9, 152882-97-8, 152882-98-9, 152882-99-0, 153062-34-1, 154171-74-1, 154171-75-2, 154333-99-0, 154334-00-6, 154397-63-4, 154460-59-0, 199456-56-9, 108739-25-9, 120329-57-9, 120329-58-0
fullerene-C60

A: 10170-69-1
dimanganese decacarbonyl

: 241802-79-9
(bis(triphenylphosphoranylidene)ammonium)[Mn(CO)4(η(2)-C60)]

Conditions

Conditions	Yield
In tetrahydrofuran Irradiation (UV/VIS); (Ar); addn. of C60 to a soln. of manganese complex in THF, photolysis atroom temp. for 48 h; cooling, filtration, addn. of hexanes, washing ppt. with toluene and hexanes, drying in vac.;	A n/a B 93%
In tetrahydrofuran (Ar); addn. of C60 to a soln. of manganese complex in THF, refluxing for18 h; cooling, filtration, addn. of hexanes, washing ppt. with toluene and hexanes, drying in vac.;	A n/a B 23%

...Expand

: 14516-54-2
bromopentacarbonylmanganese(I)

: 85320-10-1
(diphenylphosphino)cyclopentadienylthallium

A: 10170-69-1
dimanganese decacarbonyl

B: 62980-80-7
tricarbonyl(η5-diphenylphosphinocyclopentadienyl)manganese

Conditions

Conditions	Yield
In benzene addn. of the Mn compd. to the Tl compd. in benzene in a Ar-flushed Schlenk flask and refluxing for 18 h; cooling to room temp., filtn. through a celite plug on a glas frit, evapn., chromy. of the residue on alumina, elution of the Mn2(CO)10 with pentane, elution with benzene and evapn.; elem. anal.;	A n/a B 92%

...Expand

: 85317-79-9, 89044-05-3
Li(1+)*Mn2(CO)9(CHO)(1-)=Li(Mn2(CO)9(CHO))

: 639-58-7
triphenyltin chloride

A: 10170-69-1
dimanganese decacarbonyl

B: 14405-84-6
triphenyltinmanganesepentacarbonyl

C: 1333-74-0
hydrogen

Conditions

Conditions	Yield
In tetrahydrofuran under N2, soln. of Mn-complex in THF was freeze/thaw degassed, warmed to -40°C for 10 min and then to 24°C for 1 h, Ph3SnCl was added, stirred overnight; solvent removed under vac., chromd. on silica gel in benzene;	A 92% B 70% C >90

...Expand

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

: 86171-13-3
1-methylquinolin-1-ium trifluoromethanesulfonate

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran react. at 20°C;	91%

: 85317-79-9, 89044-05-3
Li(1+)*Mn2(CO)9(CHO)(1-)=Li(Mn2(CO)9(CHO))

: 100-52-7
benzaldehyde

A: 10170-69-1
dimanganese decacarbonyl

B: 100-51-6
benzyl alcohol

Conditions

Conditions	Yield
With water In tetrahydrofuran under N2, soln. of Mn-complex was treated with benzaldehyde;	A 91% B 66%

...Expand

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

: 97801-84-8
N-methylacridinium trifluoromethansulfonate

A: 10170-69-1
dimanganese decacarbonyl

B: 3295-69-0
10,10'-dimethyl-9,10,9',10'-tetrahydro-[9,9']biacridinyl

Conditions

Conditions	Yield
In acetonitrile educts mixed at -30°C, warmed to room temp.;	A 90% B 86%

...Expand

: 35816-56-9, 14971-26-7, 71564-22-2
pentacarbonylmanganate

: 27674-37-9
(acetonitrile)pentacarbonylmanganese(I) cation

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: CH3CN; addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)5(MeCN)(1+) in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR;	88%
In tetrahydrofuran byproducts: pyridine; addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)5(py)(1+) in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR;	84%
In tetrahydrofuran Mn(CO)5(1-) (1.2 M, 5 mL) added under Ar to 5 mL of 1E-2 M Mn(CO)5(NCCH3)(1-), 0.3 M tetra-n-butylammonium perchlorate added, react. time approx. 30 min;
In acetonitrile Mn(CO)5(1-) (1.2 M, 5 mL) added under Ar to 5 mL of 1E-2 M Mn(CO)5(NCCH3)(1+), react. time approx. 500 min;
byproducts: MeCN;

: 16972-33-1
pentacarbonylhydridomanganese

: (trimethylsilyl)manganese pentacarbonyl

: 2206-26-0
[D3]acetonitrile

: 75-07-0
acetaldehyde

A: 10170-69-1
dimanganese decacarbonyl

B: 87682-27-7
CHOCH(CH3)OSi(CH3)3

C: Mn2*9CO*C(2)H3CN=Mn2(CO)9(C(2)H3CN)

Conditions

Conditions	Yield
In [D3]acetonitrile NMR tube charged with Mn complexes and CD3CN, cold acetaldehyde added, allowed to stand at room temp. for 0.5 h; chromd.;	A 8% B 76% C 88%

...Expand

: 13859-41-1
sodium pentacarbonyl manganate

: 999-54-2
(E)-methyl 4-chlorobut-2-enoate

A: 10170-69-1
dimanganese decacarbonyl

B: 14100-30-2
pentacarbonylchloromanganese(I)

C: η1-4-oxo-4-ethoxy-2-butenyl manganese pentacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran (N2 or Ar), 25°C, stirring for 30 min in a round-bottom flask; solvent is removed under reduced pressure, extd. with pentane, chromy. on silica gel(CH2Cl2), determined by (55)Mn-NMR;	A 12% B 0% C 88%

...Expand

: 14516-54-2
bromopentacarbonylmanganese(I)

: sodium acetylide

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: NaBr, C; N2-atmosphere; mixing Mn-complex with excess carbide, THF addn., stirring (room temp., 4 h); extn. (hexanes), solvent removal (vac.); can be sublimed in vac. (50°C);	86%

: 85317-79-9, 89044-05-3
Li(1+)*Mn2(CO)9(CHO)(1-)=Li(Mn2(CO)9(CHO))

: 639-58-7
triphenyltin chloride

A: 10170-69-1
dimanganese decacarbonyl

B: 14405-84-6
triphenyltinmanganesepentacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran under N2, soln. of Mn-complex in THF was stirred for 0.5 h at room temp., solid Ph3SnCl was added, stirred for 0.5 h; solvent removed by rotary evapn., chromd. on silica gel (ethyl acetate-hexane), solvent removed by rotary evaporation, dissolved in hexane, placed in freezer for 2 d, filtered, vac. dried;	A 86% B 82%

...Expand

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

: 623-48-3
ethyl iodoacetae

A: 10170-69-1
dimanganese decacarbonyl

B: 14879-42-6
iodo(pentacarbonyl)manganese(I)

C: η1-(CH2COOEt) manganese pentacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran (N2 or Ar); 25°C, rapid mixing; determination by NMR;	A 0% B 85% C 85%
In chloroform-d1 (N2 or Ar); 25°C, rapid mixing; determination by NMR;	A 16% B 17% C 67%

...Expand

: 15693-51-3
potassium[manganese(pentacarbonyl)]

: 999-54-2
(E)-methyl 4-chlorobut-2-enoate

A: 10170-69-1
dimanganese decacarbonyl

B: 14100-30-2
pentacarbonylchloromanganese(I)

C: 32829-97-3
(2E,6E)-diethyl octa-2,6-dienedioate

D: η1-4-oxo-4-ethoxy-2-butenyl manganese pentacarbonyl

E: ethyl (E)-4-(2'-carbethoxycyclopropyl)-2-butenoate

Conditions

Conditions	Yield
In tetrahydrofuran (N2 or Ar), 25°C, stirring for 30 min in a round-bottom flask; solvent is removed under reduced pressure, extd. with pentane, chromy. on silica gel(CH2Cl2), determined by (55)Mn-NMR;	A 15% B 0% C 14% D 85% E 21%

...Expand

: 82495-39-4
((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylmanganese

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In diethyl ether byproducts: 1,2,4,5-tetraphenylbenzene; soln. of Mn-complex in Et2O was stirred overnight at 20°C, evapd. to dryness; residue was chromd. on silica gel/hexane column, eluted with hexane; detd. by IR;	85%

: 27674-37-9
(acetonitrile)pentacarbonylmanganese(I) cation

: 13859-41-1
sodium pentacarbonyl manganate

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: pyridine; addn. of 5 mL of 1E-2 M NaMn(CO)5 in THF to 5 mL of 1E-2 M Mn(CO)5(py)(1+) in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR;	84%

: 14516-54-2
bromopentacarbonylmanganese(I)

: 13859-41-1
sodium pentacarbonyl manganate

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran (N2 or Ar); 10 min; filtn., evapn., flash chromy.(silica/CH2Cl2), determination by NMR;	84%

: 10170-69-1
dimanganese decacarbonyl

A: 14100-30-2
pentacarbonylchloromanganese(I)

B: 67-72-1
hexachloroethane

Conditions

Conditions	Yield
With tetrachloromethane In tetrachloromethane byproducts: CCl3; Irradiation (UV/VIS); Irradiation λ >350 nm, CCl4, Ar atm.;; detected by IR spectra and GCA;;	A n/a B 100%

: 10170-69-1
dimanganese decacarbonyl

: 62637-93-8
trimethylamine-N-oxide dihydrate

: 108-88-3
toluene

: {{Mn(μ3-OH)(CO)3}4}*2toluene

Conditions

Conditions	Yield
In tetrahydrofuran; toluene stirring Mn2(CO)10 with Me3NO*2H2O in THF (18 h), solvent removal; recrystn. (hot toluene);	100%
In toluene byproducts: trimethylammonium carbonate; treatment of Mn2(CO)10 with 6 equivs. of Me3NO, boiling of product in MePh; hot filtration, crystn. (5°C); second crop from mother liquor; elem. anal.;	98%

...Expand

: 10170-69-1
dimanganese decacarbonyl

: 77938-10-4
bis(N,N-diethylselenocarbamoyl)monoselenide

: 60003-30-7
bis-(N,N-diethylselenocarbamoyl)triselenide

: 78528-81-1
Mn(CO)4((C2H5)2NCSe2)

Conditions

Conditions	Yield
In tetrahydrofuran Irradiation (UV/VIS); slight excess of the org. compounds (1:1), irradiated for 2 h at room temp. under N2; obtained from CH2Cl2/petroleum ether, elem. anal.;	100%

...Expand

: 10170-69-1
dimanganese decacarbonyl

: 77938-11-5
bis(N,N-morpholylselenocarbamoyl)monoselenide

: 77938-12-6
bis(N,N-morpholylselenocarbamoyl)triselenide

: 78537-30-1
Mn(CO)4(OC4H8NCSe2)

Conditions

Conditions	Yield
In tetrahydrofuran Irradiation (UV/VIS); slight excess of the org. compounds (1:1), irradiated for 2 h at room temp. under N2; obtained from CH2Cl2/petroleum ether, elem. anal.;	100%

...Expand

: 10170-69-1
dimanganese decacarbonyl

: 75-09-2
dichloromethane

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 49695-20-7
fac-Mn(CO)3(chloro)(1,2-bis(diphenylphosphino)ethane)

Conditions

Conditions	Yield
In dichloromethane autoclave (N2, 130°C, 2 h); solvent removal, recrystn. (CH2Cl2/hexane);	99%

...Expand

: 10170-69-1
dimanganese decacarbonyl

: 201230-82-2
carbon monoxide

: 7664-39-3
hydrogen fluoride

: 7637-07-2
boron trifluoride

: 15557-71-8
hexacarbonylmanganese(I) tetrafluoroborate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: H2; Mn2(CO)10, BF3, CO (0.6 bar), anhydrous HF were combined and stirred in tetrafluoroethylene-perfluorovinyl ether polymer flask at room temp., 10days; dynamic vac.;	99%

...Expand

: 10170-69-1
dimanganese decacarbonyl

: 251546-77-7, 431896-21-8, 659737-28-7, 166986-33-0, 251546-79-9
(S)-N,N'-bis(2-hydroxy-3,5-di-tert-butylbenzylidene)-1,1'-binaphthyl-2,2'-diamine

: 173099-93-9
Mn(OH)(C20H12(NCHC6H2(C(CH3)3)2O)2)

Conditions

Conditions	Yield
With 1,5-diazabicyclo[4.3.0]non-5-ene In N,N-dimethyl-formamide addn. of Mn2(CO)10 to soln. of ligand and DBN (120°C, stirring), stirring for 6 h; cooling, pptn. on water addn., collection (filtration), washing (cold water, EtOH), dissoln. in CH2Cl2, filtration, solvent removal (vac.); elem. anal.;	99%

: 10170-69-1
dimanganese decacarbonyl

: tricarbonyl(cyclohexadienyl)iron tetrafluoroborate

A: 13755-29-8
sodium tetrafluoroborate

B: 135224-95-2
(OC)3Fe(μ-η4:η1-cyclohexadiene)Mn(CO)5

Conditions

Conditions	Yield
With sodium amalgam In tetrahydrofuran (Ar), reduced Mn-complex (45 min at 0°C, 30 min at 20°C) added at -70°C, stirred for 1 h; solvent removed in vacuo at -30°C, extracted four times with pentane at -25°C (Mn2(CO)10 as by-product), extracted two times with CH2Cl2, solvent removed, dried in high vacuum, (all steps at <-20°C), elem. anal.;	A n/a B 98%

...Expand

: 10170-69-1
dimanganese decacarbonyl

: {Rh2(1,8-diisocyano-p-menthane)4}(PF6)2

: Rh2Mn2(2+)*10CO*4(CN(CH3)C6H9)C(CH3)2NC*2PF6(1-)=(Rh2(CN((CH3)C6H9)C(CH3)2NC)4Mn2(CO)10)(PF6)2

Conditions

Conditions	Yield
In acetone Irradiation (UV/VIS); degassing with N2 for 20 min., Mn:Rh = 20:1, photolyzing for 2.25 h; removing the solvent, washing with hexane;	97%

: 10170-69-1
dimanganese decacarbonyl

: 14243-23-3
(μ-dithio)bis(tricarbonyliron)

: S2Fe2Mn2(CO)14

Conditions

Conditions	Yield
In tetrahydrofuran Irradiation (UV/VIS); under N2, irradiation for 20 h,; chromy. (silicic acid, elution CH2Cl2), elem. anal.;	97%

: 10170-69-1
dimanganese decacarbonyl

: 256509-19-0
(CF3)2PSeC6H5

: (CO)4Mn(P(CF3)2)(SeC6H5)Mn(CO)4

Conditions

Conditions	Yield
In neat (no solvent) byproducts: CO; under inert gas, Mn2(CO)10 contg. ampoule was evacuated under cooling, equimolar amt. of CF3-compd. was condensed into ampoule, heating sealed ampoule at 80 °C for 110 h and at 100 °C for 96 h; fractionated subl. under inert gas, elem. anal.;	97%
In neat (no solvent) heated at 90-130°C in sealed ampoules; fractional sublimation;

: 10170-69-1
dimanganese decacarbonyl

: 14100-30-2
pentacarbonylchloromanganese(I)

Conditions

Conditions	Yield
With thionyl chloride In dichloromethane Product distribution / selectivity; Inert atmosphere;	96%
With sulfuryl dichloride In dichloromethane (N2), soln. of the complex treated with SO2Cl2 at room temp. with stirring, stirred for 30 min at room temp.; solvent and excess SO2Cl2 removed under vacuum, washed with ethanol, dried in vacuo, elem. anal.;	91%
With tetrachloromethane; dimethylglyoxal In tetrachloromethane Irradiation (UV/VIS); under N2, soln. of Mn-complex and biacetyl in CCl4 irradiated (436 nm) at 23.5°C; monitored by UV-vis spectra or IR spectra;

: 10170-69-1
dimanganese decacarbonyl

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

: 148447-53-4
fac-tricarbonyl(1,3-bis(diphenylphosphino)propane)hydridomanganese(I)

Conditions

Conditions	Yield
In propan-1-ol under Ar, refluxed for 6 h; cooled, solvent removed, extd. (benzene), addn. of hexane, filtered, washed with hexane, dried under vac.; elem. anal.;	96%
In propan-1-ol (Ar); using Schlenk techniques; (Organometallics 1993, 12, 1714-1719);

: 10170-69-1
dimanganese decacarbonyl

: {Cp2Fe2(CO)2(μ-CO)(μ-η1:η2-CHCH2)}BF4

: {Cp2Fe2(CO)2(μ-CO)(μ-η1:η1-CHCH2)}2

Conditions

Conditions	Yield
With Na/Hg In tetrahydrofuran under Ar, redn. with Na/Hg, soln. cooled to -70°C, addn. of Fe-compd., slowly warmed to room temp.; centrifuged, washed with H2O, acetone and pentane, dried (vac., 6 h);	96%

: 10170-69-1
dimanganese decacarbonyl

: 13859-41-1
sodium-manganese pentacarbonyl

Conditions

Conditions	Yield
With sodium amalgam In tetrahydrofuran inert atm., 2 h, filtration,; solvent removal (vac., room temp.);	95%
With sodium amalgam In tetrahydrofuran 0.1% sodium amalgam added to soln. Mn2(CO)10 in THF, mixt. stirrred vigorously for 1 h; excess amalgam removed from yellow soln., soln. passed through Celite;
With sodium amalgam In tetrahydrofuran filtration; recrystn. (addn. of n-hexane);

: 10170-69-1
dimanganese decacarbonyl

: C27H57N5Si

: C34H56Mn2N6O8Si

Conditions

Conditions	Yield
In toluene at 0 - 20℃; for 24h; Inert atmosphere; Schlenk technique;	95%

: 10170-69-1
dimanganese decacarbonyl

: potassium tri-sec-butyl-borohydride

: 829-84-5
dicyclohexylphosphane

: dilithium{tetracarbonyl(dicyclohexylphosphido)manganate}

Conditions

Conditions	Yield
With hydrogenchloride; n-butyllithium In tetrahydrofuran; diethyl ether; hexane all steps under Ar and under air and moisture exclusion, addn. of a soln. of BuLi (hexane) to a soln. of phosphane(hydrido)Mn complex (fresh prepd. from Mn2(CO)10, KHB(s-Bu)3, HCl-ether and the phosphane in THF); evapg. of solvent, washing (hexane);	94%

...Expand

: hydrogen perchlorate

: 10170-69-1
dimanganese decacarbonyl

: 66034-78-4
pentacarbonyl(perchlorato)manganese

Conditions

Conditions	Yield
With TFAA In water stirring (0°C, 1.5 h); evapn. (vac.), drying (MgSO4), CH2Cl2 addn., filtering, pptn. on Et2O addn., drying (vac.);	94%

Manganese,decacarbonyldi-, (Mn-Mn) Specification

The Manganese,decacarbonyldi-, (Mn-Mn) , with the CAS registry number 10170-69-1, is also known as Manganese, decacarbonyldi-. Its EINECS number is 233-445-6. This chemical's molecular formula is C₁₀Mn₂O₁₀ and molecular weight is 389.98. What's more, its systematic name is carbon monooxide - manganese (5:1). The product should be sealed and stored in a cool and dry place. It should be ensured that the workshop is well ventilated or equipped with exhaust devices.

When you are using this chemical, please be cautious about it as the following:
It is toxic by inhalation, in contact with skin and if swallowed. You need not breathe dust. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice, besides, in case of accident or if you feel unwell seek medical advice immediately (show the label where possible). When using it, you should wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: [Mn].[Mn].[C-]#[O+].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-]
(2)InChI: InChI=1/10CO.2Mn/c10*1-2;;
(3)InChIKey: QFEOTYVTTQCYAZ-UHFFFAOYAD

Product Name

MANGANESE CARBONYL

Synthetic route

Manganese,decacarbonyldi-, (Mn-Mn) Specification

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