Conditions | Yield |
---|---|
With water; sodium hydroxide In dimethyl sulfoxide at 25℃; Kinetics; | A 100% B n/a |
Conditions | Yield |
---|---|
With sodium hydroxide In methanol; water | 98.9% |
With sodium In 1,4-dioxane for 4h; Heating; | 92% |
With methanol; sodium |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 100℃; for 24h; | 65% |
Conditions | Yield |
---|---|
With oxygen; bismuth(III) nitrate; palladium on activated charcoal In sodium hydroxide at 90℃; for 6h; Product distribution; also with coactivator and other activators, various times, reaction with other 2-phenoxyethanols; | A n/a B 53% |
methanol
dimethyl phenyl phosphate
sodium methylate
A
trimethyl phosphite
B
sodium phenoxide
Conditions | Yield |
---|---|
at 0℃; Rate constant; | |
at 19℃; Rate constant; | |
at 10℃; Rate constant; |
diethyl ether
ethanol
trichloro-methanesulfenic acid phenyl ester
sodium ethanolate
A
trichloro-methanesulfenic acid ethyl ester
B
sodium phenoxide
ethanol
diphenyldiphenoxysilane
A
1,1,3,3,5,5-hexaphenylcyclotrisiloxane
B
sodium phenoxide
1,3,5-trinitro-2,4,6-triphenoxy-benzene
sodium ethanolate
A
1,3,5-triethoxy-2,4,6-trinitrobenzene
B
sodium phenoxide
diphenyldiphenoxysilane
acetone
A
1,1,3,3,5,5-hexaphenylcyclotrisiloxane
B
sodium phenoxide
Conditions | Yield |
---|---|
at 310 - 360℃; Rate constant; |
N,N'-bis(diphenyloxyphosphonyl)-8-quinolinesulfinamidine
A
sodium phenoxide
B
sodium naphthalene-1-sulfinate
Conditions | Yield |
---|---|
With sodium hydroxide for 3h; Product distribution; Heating; |
Conditions | Yield |
---|---|
With sodium hydroxide In 1,4-dioxane; water at 15℃; Rate constant; Thermodynamic data; Kinetics; var. temperatures, var. ratio of solvents, log A, Ea; |
phenoxy radical
sodium phenoxide
Conditions | Yield |
---|---|
With Sodium borate; sodium azide; oxygen; sodium formate In water Rate constant; Irradiation; combination with superoxid anion radicals; |
phenyl N-methyl-N-m-nitrophenylcarbamate
A
N-methyl-3-nitroaniline
B
sodium phenoxide
Conditions | Yield |
---|---|
With sodium hydroxide; cetyltrimethylammonim bromide In methanol; water at 68.5℃; Rate constant; Mechanism; other N-methyl-N-arylcarbamates; reaction in absence of cetyltrimethylammonium bromide; |
Methyl-(4-nitro-phenyl)-carbamic acid phenyl ester
A
sodium phenoxide
B
N-methyl(p-nitroaniline)
Conditions | Yield |
---|---|
With sodium hydroxide; cetyltrimethylammonim bromide In methanol; water at 68.5℃; Rate constant; |
Conditions | Yield |
---|---|
With sodium cation In water; dimethyl sulfoxide at 25℃; Equilibrium constant; |
Conditions | Yield |
---|---|
With sodium tetrahydroborate; hydrogen; PdCl2 complex on modified silca gel In methanol at 20℃; under 760 Torr; Rate constant; hydrogenolysis of chlorobenzenes in the presence of palladium chloride complex deposited on modified silica gel; effect of the nature of substituents in aromatic ring; |
Conditions | Yield |
---|---|
With sodium hydroxide In methanol; water at 25℃; Rate constant; Mechanism; Thermodynamic data; enegy parameters calculated from kobs in range 25-60 deg C; pH range 12.7, 13.9; |
N',N'-Dimethyl-hydrazinecarboxylic acid phenyl ester
A
sodium phenoxide
Conditions | Yield |
---|---|
With sodium hydroxide In methanol; water at 25℃; Rate constant; Mechanism; Thermodynamic data; energy parameters calculated from kobs in range 25-60 deg C; pH range 12.0, 14.9; |
A
sodium phenoxide
Conditions | Yield |
---|---|
With sodium hydroxide In methanol; water at 25℃; Rate constant; Mechanism; Thermodynamic data; energy parameters calculated from kobs in range 25-60 deg C; pH range 13.0, 13.9; |
A
sodium phenoxide
Conditions | Yield |
---|---|
With sodium hydroxide In methanol; water at 25℃; Rate constant; Mechanism; Thermodynamic data; energy parameters calculated from kobs in range 25-60 deg C; pH range 13.6, 14.1; |
Conditions | Yield |
---|---|
With sodium hydroxide In methanol; water at 25℃; Rate constant; Thermodynamic data; Mechanism; energy parameters calculated from kobs in range 25-60 deg C; pH range 11.9, 14.9; |
Conditions | Yield |
---|---|
at 250 - 260℃; |
Conditions | Yield |
---|---|
at 35℃; Product distribution; | |
at 75℃; Product distribution; |
Conditions | Yield |
---|---|
poly<1-hydroxyethylene-co-1-(2-ethylsulf In 1,4-dioxane at 75℃; for 23h; Product distribution; Rate constant; other catalysts; | 100% |
Sucrose-ethyleneoxide adducts In toluene at 110℃; for 8h; Product distribution; further catalysts: PEG, DB18K6; further objects of study: phase-transfer catalysis; | 100% |
dodecyldimethylsulfonium methyl sulfate In water at 40℃; for 6h; | 25% |
Conditions | Yield |
---|---|
With potassium phosphate In tetrahydrofuran at 115℃; for 18h; | 100% |
With CF3-DPPF; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran; toluene at 120℃; for 20h; | 79.6% |
With CF3-DPPF ligand; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran; toluene at 120℃; for 30h; Product distribution; various DPPF ligands for the Pd-catalyzed formation of diaryl ethers; |
sodium phenoxide
6,7-dimethoxy-4-chloroquinazoline
6,7-dimethoxy-4-phenoxyquinazoline
Conditions | Yield |
---|---|
In dimethyl sulfoxide at 80℃; for 3h; | 100% |
Conditions | Yield |
---|---|
Stage #1: 4-phenyl-butan-1-ol With 1,2-Diiodoethane; N,N-dimethyl-formamide; triphenylphosphine at 20℃; for 0.0166667h; Sealed tube; Inert atmosphere; Stage #2: sodium phenoxide at 20℃; Sealed tube; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 20℃; for 1h; | 99% |
perfluoro(propyl vinyl ether)
sodium phenoxide
(2-Chloro-1,1,2-trifluoro-2-heptafluoropropyloxy-ethoxy)-benzene
Conditions | Yield |
---|---|
With hexachloroethane In N,N-dimethyl-formamide 1) 25 deg C - 29 deg C, 2) r.t., overnight; | 99% |
4-nitro-N-methyl-phthalimide
sodium phenoxide
4-phenoxy-N-methyl phthalimide
Conditions | Yield |
---|---|
N-neopentyl chloride of 4-dibutylaminopyridine In toluene at 110℃; for 1h; | 99% |
In dimethyl sulfoxide at 15 - 120℃; for 24h; Inert atmosphere; | 93% |
sodium phenoxide
Conditions | Yield |
---|---|
In water a mixt. of Fe compd. and C6H5ONa in water is refluxed for 5 min; mixt. is cooled and extd. with ether, extract is washed with ether and dried with sodium sulfate, removal of ether by distillation, recrystn. from heptane; | 99% |
sodium phenoxide
diphenylcarbamic chloride
diphenyl-carbamic acid phenyl ester
Conditions | Yield |
---|---|
at 20℃; for 0.08h; Neat (no solvent); Microwave irradiation; Grinding; | 99% |
tert-butyl (3-bromo-5-chloropyrazolo[1,5-a]pyrimidin-7-yl)(2-morpholinoethyl)carbamate
sodium phenoxide
tert-butyl (3-bromo-5-phenoxypyrazolo[1,5-a]pyrimidin-7-yl)(2-morpholinoethyl)carbamate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 20℃; for 0.5h; | 99% |
2-Amino-6-chlor-3,4,5-pyridintricarbonitril
sodium phenoxide
Conditions | Yield |
---|---|
In acetone for 0.5h; Heating; | 98% |
sodium phenoxide
Conditions | Yield |
---|---|
In tetrahydrofuran; water for 48h; Ambient temperature; | 98% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; | 98% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 100℃; | 98% |
sodium phenoxide
tetrachlorophenoxyphosphorane
Conditions | Yield |
---|---|
With phosphorus pentachloride In tetrachloromethane at -15℃; for 1h; | 98% |
biphenyl-4-yl methanol
sodium phenoxide
1-phenyl-4-phenoxymethylbenzene
Conditions | Yield |
---|---|
Stage #1: biphenyl-4-yl methanol With 1,2-Diiodoethane; N,N-dimethyl-formamide; triphenylphosphine at 20℃; for 0.0166667h; Sealed tube; Inert atmosphere; Stage #2: sodium phenoxide at 20℃; Sealed tube; Inert atmosphere; | 98% |
potassium phenolate
sodium phenoxide
2,2,4,4,6,6-hexaphenoxycyclotriphosphazene
Conditions | Yield |
---|---|
With cesium hydroxide; 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine In 1,2-dichloro-benzene at 175℃; Product distribution / selectivity; | 97.9% |
Conditions | Yield |
---|---|
at 105℃; pH=9 - 10; | 97.6% |
Conditions | Yield |
---|---|
at 120℃; for 6h; Temperature; | 97.5% |
Conditions | Yield |
---|---|
In tetrahydrofuran; diethyl ether for 1h; Ambient temperature; | 97% |
Conditions | Yield |
---|---|
N-2-ethylhexyl chloride of 4(4-methylpiperidinyl)pyridine In toluene at 110℃; for 0.25h; | 97% |
With ammonia at 25℃; Kinetics; Concentration; |
sodium phenoxide
A
1-methoxy-4-phenoxy-benzene
B
4-methoxy-7-iodo[2.2]paracyclophane
Conditions | Yield |
---|---|
In [D3]acetonitrile at 80℃; for 1h; Inert atmosphere; Darkness; regioselective reaction; | A 75% B 97% |
(S)-(1-benzyl-2,5-dihydro-1H-pyrrol-2-yl)methanol
sodium phenoxide
(R)-1-benzyl-3-phenoxy-1,2,3,6-tetrahydropyridine
Conditions | Yield |
---|---|
Stage #1: (S)-(1-benzyl-2,5-dihydro-1H-pyrrol-2-yl)methanol With trifluoromethylsulfonic anhydride In dichloromethane at -15℃; Inert atmosphere; Stage #2: sodium phenoxide In tetrahydrofuran; dichloromethane at -15 - 20℃; Inert atmosphere; optical yield given as %ee; regioselective reaction; | 97% |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 36h; Inert atmosphere; Glovebox; | 97% |
sodium phenoxide
Conditions | Yield |
---|---|
In water; acetone at 20℃; for 12h; Schlenk technique; | 97% |
4,5-dichloro-1-phenylpyridazin-6-one
sodium phenoxide
5-chloro-4-phenoxy-2-phenyl-2H-pyridazin-3-one
Conditions | Yield |
---|---|
In 1,4-dioxane for 16h; Ambient temperature; | 96% |
(2-13C)bromoacetic acid
sodium phenoxide
<2-13C>-2-phenoxyacetic acid
Conditions | Yield |
---|---|
With sodium hydride In tetrahydrofuran for 2h; Heating; | 96% |
bis(4-methylbenzenethiocarbonyl) sulphide
sodium phenoxide
O-phenyl 4-methylbenzenecarbothioate
Conditions | Yield |
---|---|
In tetrahydrofuran; diethyl ether; ethanol for 3h; Ambient temperature; | 96% |
1. | scu-mus LDLo:350 mg/kg | AEXPBL Archiv fuer Experimentelle Pathologie und Pharmakologie. 52 (1905),220. | ||
2. | scu-frg LDLo:100 mg/kg | AEXPBL Archiv fuer Experimentelle Pathologie und Pharmakologie. 52 (1905),220. |
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