Product Name

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  • Name

    Sodium

  • EINECS 231-132-9
  • CAS No. 7440-23-5
  • Article Data592
  • CAS DataBase
  • Density 1.04 g/mL at 20 °C
  • Solubility soluble in water
  • Melting Point 97.8 °C(lit.)
  • Formula Na
  • Boiling Point 883 °C(lit.)
  • Molecular Weight 22.9898
  • Flash Point 128°F
  • Transport Information
  • Appearance light, soft silver metal
  • Safety 26-8-6A-45-43D-43-53
  • Risk Codes 34-14/15-45
  • Molecular Structure Molecular Structure of 7440-23-5 (Sodium)
  • Hazard Symbols CorrosiveC,FlammableF,ToxicT
  • Synonyms Atomicsodium;Natrium;Sodium atom;Sodium metal;Sodium-23;
  • PSA 0.00000
  • LogP 0.11250

Synthetic route

sodium azide

sodium azide

sodium
7440-23-5

sodium

Conditions
ConditionsYield
In neat (no solvent) heating NaN3 to 275°C;;100%
In neat (no solvent) heating NaN3 to 275°C;;100%
In neat (no solvent) carbon support was impregnated with NaN3 following with drying procedureunder UHV and at 450°C; carbon support was used;
sodium carbonate
497-19-8

sodium carbonate

sodium
7440-23-5

sodium

Conditions
ConditionsYield
With pyrographite; calcium oxide In neat (no solvent) 110°C, 1-2 Torr;;94%
With coal; CaO In neat (no solvent) 110°C, 1-2 Torr;;94%
With pyrographite In neat (no solvent) 110°C, 1-2 Torr;;92%
sodium chloride
7647-14-5

sodium chloride

sodium
7440-23-5

sodium

Conditions
ConditionsYield
With calcium carbide In neat (no solvent) byproducts: CaCl2, C; at 900°C, diminshed yield with increase of pressure (1-10 Torr);;92%
With calcium carbide; sodium fluoride In neat (no solvent) byproducts: CaCl2, C; powdered and pressed, 0.5 Torr, 6% NaF, 875°C;;82%
With calcium carbide In neat (no solvent) reduction at 900°C;;63%
sodium sulfate
7757-82-6

sodium sulfate

sodium
7440-23-5

sodium

Conditions
ConditionsYield
With pyrographite In neat (no solvent) 110°C, 1-2 Torr;;54%
With coal In neat (no solvent) 110°C, 1-2 Torr;;54%
With pyrographite; calcium oxide In neat (no solvent) 110°C, 1-2 Torr;;83-95
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

A

boron

boron

B

hydrogen
1333-74-0

hydrogen

C

sodium
7440-23-5

sodium

Conditions
ConditionsYield
decompn. at 500°C, heating in N2- or H2-atm.;A n/a
B 45%
C n/a
decompn. at 500°C, heating in N2- or H2-atm.;A n/a
B 45%
C n/a
sodium bromide
7647-15-6

sodium bromide

A

bromine
7726-95-6

bromine

B

sodium
7440-23-5

sodium

Conditions
ConditionsYield
Electrolysis;
dolomite

dolomite

sodium chloride
7647-14-5

sodium chloride

A

sodium
7440-23-5

sodium

B

magnesium
7439-95-4

magnesium

Conditions
ConditionsYield
In neat (no solvent) 1200°C;; simultaneous preparation of Na and Mg;;
borax

borax

magnesium
7439-95-4

magnesium

A

magnesium diboride

magnesium diboride

B

sodium
7440-23-5

sodium

Conditions
ConditionsYield
In gaseous matrix slow reaction with small amounts; vigorous reaction with greater amounts and at a certain temperature;;
In gaseous matrix slow reaction with small amounts; vigorous reaction with greater amounts and at a certain temperature;;
iron acetylide

iron acetylide

sodium hydroxide
1310-73-2

sodium hydroxide

sodium
7440-23-5

sodium

Conditions
ConditionsYield
In neat (no solvent) byproducts: iron, carbon dioxide, carbon monoxide; reaction of FeC2 (70 parts metal, 30 parts carbon) with 3 parts NaOH in a cast iron crucible; passing in of CO is of advantage; further byproduct: hydrogene;;
sodium monoxide

sodium monoxide

sodium
7440-23-5

sodium

Conditions
ConditionsYield
In gas Kinetics; byproducts: O2; carrier gas (He); fast flow reactor; not isolated, detected by fluorescence;
iron(III) oxide

iron(III) oxide

sodium carbonate
497-19-8

sodium carbonate

sodium
7440-23-5

sodium

Conditions
ConditionsYield
With iron In neat (no solvent) preparation of NaFeO2 by heating powdered Fe2O3 and Na2CO3 (stoechiometric mixture) to 900°C in an alundum-vessel, mixing with Fe-powder, heating at 2 torr to 1250°C;;
iron(III) oxide

iron(III) oxide

sodium carbonate
497-19-8

sodium carbonate

calcium hydroxide

calcium hydroxide

sodium
7440-23-5

sodium

Conditions
ConditionsYield
With pyrographite In neat (no solvent) a mixture of dry Na2CO3, Ca(OH)2, Fe2O3 is heated;;
aluminum oxide
1333-84-2, 1344-28-1

aluminum oxide

sodium carbonate
497-19-8

sodium carbonate

sodium sulfate
7757-82-6

sodium sulfate

A

sodium oxide

sodium oxide

B

carbon dioxide
124-38-9

carbon dioxide

C

sodium
7440-23-5

sodium

D

sulfur
7704-34-9

sulfur

E

aluminium
7429-90-5

aluminium

Conditions
ConditionsYield
In melt Kinetics; byproducts: O2, CO; Electrolysis; solid, granular sodium salts placed in alumina crucible and tube, purgedwith argon for 3 h, heated at 840.+-.20°C; detd. by IR gas analyzer, electrochemical cell analyzer, capillary ion electrophoresis, inductively coupled plasma anal., acid titration;
sodium sulfide

sodium sulfide

aluminum oxide
1333-84-2, 1344-28-1

aluminum oxide

sodium carbonate
497-19-8

sodium carbonate

sodium sulfate
7757-82-6

sodium sulfate

A

sodium oxide

sodium oxide

B

carbon dioxide
124-38-9

carbon dioxide

C

sodium
7440-23-5

sodium

D

sulfur
7704-34-9

sulfur

E

aluminium
7429-90-5

aluminium

Conditions
ConditionsYield
In melt Kinetics; byproducts: O2, CO; Electrolysis; solid, granular sodium salts placed in alumina crucible and tube, purgedwith argon for 3 h, heated at 840.+-.20°C; detn. by IR gas analyzer, electrochemical cell analyzer, capillary ion electrophoresis, inductively coupled plasma anal., acid titration;
aluminum oxide
1333-84-2, 1344-28-1

aluminum oxide

cryolite

cryolite

A

sodium
7440-23-5

sodium

B

aluminium
7429-90-5

aluminium

Conditions
ConditionsYield
In melt Electrolysis; Al2O3-cryolite melt;; Na permeates through the carbon-bottom-plate of the bath and can be periodically removed;;
In melt Electrolysis; Al2O3-cryolite melt;; Na permeates through the carbon-bottom-plate of the bath and can be periodically removed;;
sodium nitride

sodium nitride

A

sodium azide

sodium azide

B

sodium
7440-23-5

sodium

Conditions
ConditionsYield
In neat (no solvent) decompn. upon heating;
sodium azide

sodium azide

A

nitrogen
7727-37-9

nitrogen

B

sodium
7440-23-5

sodium

Conditions
ConditionsYield
In solid Irradiation (UV/VIS); photolysis of up to 5.0 GPa compressed solid NaN3;
In neat (no solvent) Irradiation (UV/VIS); λ=2537 Å; -268.93°C, next heating to 600 K;
In neat (no solvent) decompn. in vac. at 275°C;
bismuth
7440-69-9

bismuth

sodium
7440-23-5

sodium

sodium bismuthide

sodium bismuthide

Conditions
ConditionsYield
In neat (no solvent) heating a mixture of Na and Bi (molar ratio 3 : 1) at 775°C under Ar;;100%
determined by thermal analysis;;
determined by chemical methods;;
tellurium

tellurium

sodium
7440-23-5

sodium

disodium telluride

disodium telluride

Conditions
ConditionsYield
In neat (no solvent) Na was warmed in high vacuum and added to liquid Te in N2 atmosphere, NH3 was condensed over the mixture, the NH3 was slowly evaporated;; tempered at 400-500°C, stored under N2;;100%
In neat (no solvent) Na was warmed in high vacuum and added to liquid Te in N2 atmosphere, NH3 was condensed over the mixture, the NH3 was slowly evaporated;; tempered at 400-500°C, stored under N2;;100%
In neat (no solvent) Te heated to 620 .-+. 20°C was added in small portions to 300°C hot Na, excess of Na was distilled off;;80%
Conditions
ConditionsYield
In neat (no solvent, solid phase) (inert gas), mixed, heated to 500°C for 24 h, stayed at 500°C for 2 days, heated to 800°C for 2 days, held at 800°C for 10 days; slowly cooled to room temp., elem. anal., XRD;100%
manganese
7439-96-5

manganese

tellurium

tellurium

silver
7440-22-4

silver

sodium
7440-23-5

sodium

Na1.03Mn0.96Ag1.02Te2

Na1.03Mn0.96Ag1.02Te2

Conditions
ConditionsYield
In neat (no solvent, solid phase) (inert gas), mixed, heated to 500°C for 24 h, stayed at 500°C for 2 days, heated to 800°C for 2 days, held at 800°C for 10 days; slowly cooled to room temp., elem. anal., XRD;100%
antimony
7440-36-0

antimony

sodium
7440-23-5

sodium

rubidium

rubidium

Na16(RbRb6)Sb7

Na16(RbRb6)Sb7

Conditions
ConditionsYield
In neat (no solvent) byproducts: RbSb; molar ratio Na:Rb:Sb stoichiometric to 2:1:1; heating (12 h to 873 K; 120 h, 873 K), cooling (48 h, room temp.); XRD;100%
triiron dodecarbonyl
17685-52-8

triiron dodecarbonyl

sodium
7440-23-5

sodium

disodium tetracarbonylferrate

disodium tetracarbonylferrate

Conditions
ConditionsYield
In N,N,N,N,N,N-hexamethylphosphoric triamide (Ar); react. metal carbonyl with Na in HMPA for 1 h at 20°C;99%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

sodium
7440-23-5

sodium

sodium tetracarbonylruthenate(II)

sodium tetracarbonylruthenate(II)

Conditions
ConditionsYield
In N,N,N,N,N,N-hexamethylphosphoric triamide (Ar); react. metal carbonyl with Na in HMPA for 1 h at 20°C;99%
In ammonia NH3 (liquid); NH3 distilled onto Na/Ru mixture (acetone/dry ice bath) under vac., slowly warmed to 235 K, vigorously stirred for ca. 60 min, warmed to 260 K; dried (vac., 260 K, 3.5 h);

Sodium History

In medieval Europe a compound of Sodium (CAS NO.7440-23-5) with the Latin name of sodanum was used as a headache remedy. The name sodium probably originates from the Arabic word suda meaning headache as the headache-alleviating properties of sodium carbonate or soda were well known in early times.
 Sodium's chemical abbreviation Na was first published by J?ns Jakob Berzelius in his system of atomic symbols (Thomas Thomson, Annals of Philosophy) and is a contraction of the element's new Latin name natrium which refers to the Egyptian natron, the word for a natural mineral salt whose primary ingredient is hydrated sodium carbonate. Hydrated sodium carbonate historically had several important industrial and household uses later eclipsed by soda ash, baking soda and other sodium compounds.
Although Sodium (sometimes called "soda" in English) has long been recognized in compounds, it was not isolated until 1807 by Sir Humphry Davy through the electrolysis of caustic soda.
 Sodium imparts an intense yellow color to flames. As early as 1860, Kirchhoff and Bunsen noted the high sensitivity that a flame test for sodium could give.

Sodium Specification

The Sodium is an organic compound with the formula Na. The IUPAC name of this chemical is sodium. With the CAS registry number 7440-23-5, it is also named as Sodium metal. The product's categories are Inorganics; ACS Grade Synthetic Reagents; Essential Chemicals; Routine Reagents; Alkali Metals Metal and Ceramic Science; Metals; Reduction; Synthetic Reagents. Besides, it is light, soft silver metal.It is  an element that is a member of the alkali group of metals. It has the atomic symbol Na, atomic number 11, and atomic weight 23. With a valence of 1, it has a strong affinity for oxygen and other nonmetallic elements. Sodium provides the chief cation of the extracellular body fluids. Its salts are the most widely used in medicine. (From Dorland, 27th ed) Physiologically the sodium ion plays a major role in blood pressure regulation, maintenance of fluid volume, and electrolyte balance.

Preparation of Sodium:
this chemical was first produced commercially in 1855 by thermal reduction of sodium carbonate with carbon at 1100 °C, in what is known as the Deville process.
Na2CO3 (l) + 2 C (s) → 2 Na (g) + 3 CO (g)

Uses of Sodium:
Sodium in its metallic form can be used to refine some reactive metals, such as zirconium and potassium, from their compounds. In certain alloys to improve their structure. It is used to descale metal (make its surface smooth) and purify molten metals. In sodium vapor lamps, an efficient means of producing light from electricity, often used for street lighting in cities. Low-pressure sodium lamps give a distinctive yellow-orange light which consists primarily of the twin sodium D lines. High-pressure sodium lamps give a more natural peach-colored light, composed of wavelengths spread much more widely across the spectrum. It is used as a heat transfer fluid in some types of nuclear reactors and inside the hollow valves of high-performance internal combustion engines. In organic synthesis, sodium is used as a reducing agent, for example in the Birch reduction. In chemistry, sodium is often used either alone or with potassium in an alloy, NaK as a desiccant for drying solvents. Used with benzophenone, it forms an intense blue coloration when the solvent is dry and oxygen-free. The sodium fusion test uses sodium's high reactivity, low melting point, and the near-universal solubility of its compounds, to qualitatively analyze compounds.

When you are using Sodium, please be cautious about it as the following:
It reacts violently with water, liberating extremely flammable gases. Please keep container tightly closed. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical can cause burns and may cause cancer. When you are using it, avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: [Na]
(2)InChI: InChI=1/Na CopyCopied
(3)InChIKey: KEAYESYHFKHZAL-UHFFFAOYAO
(4)Std. InChI: InChI=1S/Na
(5)Std. InChIKey: KEAYESYHFKHZAL-UHFFFAOYSA-N

The toxicity data of Sodium is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 4gm/kg (4000mg/kg)   "Structure et Activite Pharmacodyanmique des Medicaments du Systeme Nerveux Vegetatif," Bovet, D., and F. Bovet-Nitti, New York, S. Karger, 1948Vol. -, Pg. 704, 1948.

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