Vinyl isopropyl ether supplier

Name
Vinyl isopropyl ether
EINECS 213-142-5
CAS No. 926-65-8
Article Data17
CAS DataBase
Density 0.762 g/cm³
Solubility
Melting Point -140oC
Formula C₅H₁₀O
Boiling Point 57.5 °C at 760 mmHg
Molecular Weight 86.1338
Flash Point °C
Transport Information
Appearance colorless and transparent liquid
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Ether,isopropyl vinyl (6CI,8CI);Isopropoxyethene;Isopropoxyethylene;Isopropylvinyl ether;Vinyl isopropyl ether;
PSA 9.23000
LogP 1.55490

Synthetic route

: 67-63-0
isopropyl alcohol

: 74-86-2
acetylene

: 926-65-8
vinyl isopropyl ether

Conditions

Conditions	Yield
With sodium hydroxide; cesium fluoride In dimethyl sulfoxide at 100℃; for 5.5h; atmospheric pressure;	86%
With potassium hydroxide In dimethyl sulfoxide at 120℃; for 2h;	53%
With potassium hydroxide at 150 - 155℃;

: 80857-63-2
β-isopropoxyethyl vinyl sulfoxide

A: 926-65-8
vinyl isopropyl ether

B: 2492-74-2
ethenesulfenic acid

Conditions

Conditions	Yield
With potassium hydroxide at 280 - 290℃;	A 65% B n/a

: 80857-63-2
β-isopropoxyethyl vinyl sulfoxide

: 926-65-8
vinyl isopropyl ether

Conditions

Conditions	Yield
With potassium hydroxide at 60 - 70℃; for 1h;	62%
With potassium hydroxide at 60 - 70℃; under 1 Torr; for 1h; Product distribution;	62%

: 109-53-5
isobutyl vinyl ether

: 67-63-0
isopropyl alcohol

: 926-65-8
vinyl isopropyl ether

Conditions

Conditions	Yield
With mercury(II) diacetate at 55 - 56℃;	30%

: 4285-59-0
1,1-diisopropoxy-ethane

: 926-65-8
vinyl isopropyl ether

Conditions

Conditions	Yield
With sodium hydrogen sulfate

: 84607-80-7
1-chloro-1-(1-methyletoxy)ethane

: 926-65-8
vinyl isopropyl ether

Conditions

Conditions	Yield
With pyridine

: 54149-16-5
2-isopropyloxyethyl bromide

: 926-65-8
vinyl isopropyl ether

Conditions

Conditions	Yield
With potassium hydroxide at 130℃;
With potassium tert-butylate In dimethyl sulfoxide at 90℃;

: 111-34-2
-butyl vinyl ether

: 67-63-0
isopropyl alcohol

: 926-65-8
vinyl isopropyl ether

Conditions

Conditions	Yield
With mercury(II) diacetate

: 683-60-3
sodium isopropylate

: 74-86-2
acetylene

: 926-65-8
vinyl isopropyl ether

Conditions

Conditions	Yield
at 150 - 155℃;

: 109-59-1
2-(1-methylethoxy)-ethanol

: 926-65-8
vinyl isopropyl ether

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: pyridine; phosphorus tribromoide 2: KOH / 130 °C View Scheme

: 926-65-8
vinyl isopropyl ether

: 61367-62-2
(4-bromo-3,5-dimethoxyphenyl)methanol

: 1144100-25-3
2-bromo-5-[(1-isopropoxyethoxy)methyl]-1,3-dimethoxybenzene

Conditions

Conditions	Yield
With pyridinium p-toluenesulfonate In tetrahydrofuran at 20℃; for 2.5h;	99.6%

: 926-65-8
vinyl isopropyl ether

: 96530-26-6
(3E)-1-Phenylsulfonyl-2-oxo-3-pentene

: 161420-34-4
(2R,4R)-6-Benzenesulfonylmethyl-2-isopropoxy-4-methyl-3,4-dihydro-2H-pyran

Conditions

Conditions	Yield
With diisopropoxytitanium(IV) dibromide; 4 A molecular sieve; (R,R)-TADDOL In dichloromethane at -78℃; for 24h;	92%
Stage #1: (3E)-1-Phenylsulfonyl-2-oxo-3-pentene With titanium((4R,5R)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethylate)Br2 In dichloromethane at -78℃; Hetero Diels-Alder cycloaddition; Molecular sieve; Inert atmosphere; Stage #2: vinyl isopropyl ether In dichloromethane Hetero Diels-Alder cycloaddition; Inert atmosphere; optical yield given as %ee; enantioselective reaction;

: 926-65-8
vinyl isopropyl ether

: 110945-43-2
2-((E)-4,4,4-Trichloro-3-oxo-but-1-enyl)-isoindole-1,3-dione

: 142362-49-0, 142362-50-3
2-isopropyloxy-4-phthalimido-6-trichloromethyl-3,4-dihydro-2H-pyran

Conditions

Conditions	Yield
With 2-tert-Butyl-4-methylphenol In toluene at 120℃; for 24h;	91%

: 75-15-0
carbon disulfide

: 926-65-8
vinyl isopropyl ether

: 109-89-7
diethylamine

: 112165-06-7
Diethyl-dithiocarbamic acid 1-isopropoxy-ethyl ester

Conditions

Conditions	Yield
	89%

...Expand

: 926-65-8
vinyl isopropyl ether

: 2977-45-9
2,2-dimethyl-3,4-dihydro-2H-naphthalen-1-one

: C17H24O2

Conditions

Conditions	Yield
With Fe(PMe3)4 at 50℃; for 40h; Inert atmosphere; regioselective reaction;	89%

: 1680-44-0
4-phenyl-1H-1,2,3-triazole

: 926-65-8
vinyl isopropyl ether

: 2-(1-isopropoxyethyl)-4-phenyl-2H-1,2,3-triazole

Conditions

Conditions	Yield
With triphenylphosphine gold(I)chloride; silver(I) triflimide In 1,2-dichloro-ethane at 80℃; for 6h; Inert atmosphere; Schlenk technique; regioselective reaction;	88%

: 926-65-8
vinyl isopropyl ether

: 67257-30-1
diethyl 2-oxo-3-butenylphosphonate

: (6-Isopropoxy-5,6-dihydro-4H-pyran-2-ylmethyl)-phosphonic acid diethyl ester

Conditions

Conditions	Yield
zinc(II) chloride In dichloromethane for 3h; Ambient temperature;	87%

: 926-65-8
vinyl isopropyl ether

: 1490-33-1
hexafluorothioacetone

A: 1206485-04-2
C8H10F6OS

B: 1258730-51-6
C8H10F6OS2

Conditions

Conditions	Yield
With cesium fluoride In N,N-dimethyl-formamide at 25℃; for 48h; Inert atmosphere;	A 85% B n/a
With sulfur; cesium fluoride In N,N-dimethyl-formamide at 25 - 35℃; Inert atmosphere;	A n/a B 20%

...Expand

: 926-65-8
vinyl isopropyl ether

: 58288-30-5
N,N,N’,N’-tetrabenzylmethanediamine

: 67-63-0
isopropyl alcohol

: 1493780-01-0
N,N-dibenzyl-3,3-diisopropoxypropan-1-amine

Conditions

Conditions	Yield
With Pd(xantphos)(CH3CN)2(OTf)2 In toluene at 110℃; for 12h; Inert atmosphere; Schlenk technique;	84%
With C39H32OP22C2H3N2CF3O3S(1-)*Pd(2+) In toluene at 110℃; for 12h; Reagent/catalyst; Inert atmosphere;	84%

...Expand

: 926-65-8
vinyl isopropyl ether

: methyl 2-romo-2-(4,5-dihydrooxazol-2-yl)-3,3,3-trifluoropropanoate

: methyl 1-(2-bromoethyl)-5-isopropoxy-2-oxo-3-(trifluoromethyl)-pyrrolidine-3-carboxylate

Conditions

Conditions	Yield
With Ir(dF(CF3)ppy)2(dtbbpy)(PF6) In N,N-dimethyl-formamide at 20℃; for 1h; Schlenk technique; Inert atmosphere; Irradiation;	83%

: 926-65-8
vinyl isopropyl ether

: 182740-91-6
dibenzyl 2-vinylcyclopropane-1,1-dicarboxylate

: C26H30O5

Conditions

Conditions	Yield
With (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; toluene-4-sulfonic acid isopropylidenehydrazide; potassium carbonate In acetonitrile at 20℃; Irradiation; Inert atmosphere;	83%

: 926-65-8
vinyl isopropyl ether

: 1490-33-1
hexafluorothioacetone

: 1206485-04-2
C8H10F6OS

Conditions

Conditions	Yield
With potassium fluoride In N,N-dimethyl-formamide at 25℃; for 48h; Inert atmosphere;	82%

: 926-65-8
vinyl isopropyl ether

: C24H34O5

: C29H43IO6

Conditions

Conditions	Yield
With N-iodo-succinimide In dichloromethane	79%

: 926-65-8
vinyl isopropyl ether

: 32117-28-5
(E)-4-phenyl-1-phenylsulfonyl-3-buten-2-one

: 161420-36-6
(2R,4R)-6-Benzenesulfonylmethyl-2-isopropoxy-4-phenyl-3,4-dihydro-2H-pyran

Conditions

Conditions	Yield
With diisopropoxytitanium(IV) dibromide; 4 A molecular sieve; (R,R)-TADDOL In dichloromethane at -70℃; for 20h;	77%

: 926-65-8
vinyl isopropyl ether

: 38576-60-2
senecioyl cyanide

: 83379-78-6
6-Isopropoxy-4,4-dimethyl-5,6-dihydro-4H-pyran-2-carbonitrile

Conditions

Conditions	Yield
at 160℃; for 10h;	76%

: 926-65-8
vinyl isopropyl ether

: C16H17NO5

: 9-(tert-butyl) 4-methyl (2R,4R)-2-isopropoxy-3,4-dihydropyrano[2,3-b]indole-4,9(2H)-dicarboxylate

Conditions

Conditions	Yield
Stage #1: C16H17NO5 With nickel(II) tetrafluoroborate hexahydrate; C33H48N4O4 In dichloromethane at 30℃; for 0.5h; Stage #2: vinyl isopropyl ether In dichloromethane at 0℃; for 12h; Diels-Alder Cycloaddition; enantioselective reaction;	75%

: 67-66-3
chloroform

: 926-65-8
vinyl isopropyl ether

: 13764-05-1
2,2-dichlorocyclopropyl isopropyl ether

Conditions

Conditions	Yield
With potassium hydroxide; triethylamine; N-benzyl-N,N,N-triethylammonium chloride	73.5%

: 926-65-8
vinyl isopropyl ether

: 5813-57-0
2-acetyl-1,4-naphthoquinone

: 1452153-50-2
1-(5-hydroxy-2-isobutoxy-2,3-dihydronaphtho[1,2-b]furan-4-yl)ethanone

Conditions

Conditions	Yield
With ammonium cerium (IV) nitrate In acetonitrile at 20℃; for 0.333333h;	70%

: 926-65-8
vinyl isopropyl ether

: 126690-80-0
N-(p-toluenesulfonyl)-2-vinylaziridine

: C16H23NO3S

Conditions

Conditions	Yield
With (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; toluene-4-sulfonic acid isopropylidenehydrazide; potassium carbonate In acetonitrile at 20℃; Irradiation; Inert atmosphere;	67%

: 75-91-2
tert.-butylhydroperoxide

: 926-65-8
vinyl isopropyl ether

: 5883-82-9
2-((4-methoxyphenyl)amino)-1-phenylethanone

: 4-tert-butoxy-3-isopropoxy-2-(4-methoxyphenylamino)-1-phenylbutan-1-one

Conditions

Conditions	Yield
With copper(l) chloride In hexane at 50℃; for 12h; Inert atmosphere; regioselective reaction;	51%

...Expand

: 926-65-8
vinyl isopropyl ether

: 158362-24-4
((1-butoxy-2-methylprop-1-en-1-yl)oxy)trimethylsilane

: butyl 2,2-dimethyl-3-butenoate

Conditions

Conditions	Yield
With gallium(III) bromide In 1,2-dichloro-ethane at 80℃; for 2h; regioselective reaction;	50%
In 1,2-dichloro-ethane at 80℃;	50 %Chromat.

: 926-65-8
vinyl isopropyl ether

: 762-04-9
phosphonic acid diethyl ester

: 50350-99-7
isopropyl diethylphosphonoacetate

Conditions

Conditions	Yield
With pyridine; manganese(III) acetylacetonate In acetonitrile at 20℃; for 24h;	50%

: 2637-34-5
pyridine-2-thione

: 926-65-8
vinyl isopropyl ether

A: 114193-80-5
2-<1-isopropoxy-2-(2-isopropoxyethylthio)ethyl>pyridine

B: 114193-85-0
bis<2-isopropoxy-2-(2-pyridyl)ethyl>disulfide

Conditions

Conditions	Yield
In acetonitrile for 4h; Irradiation;	A 46% B 3%

...Expand

: 597-52-4
Triethylsilanol

: 926-65-8
vinyl isopropyl ether

: 18048-18-5
et3Si(Oet-1-Oi-pr)

Conditions

Conditions	Yield
In hydrogenchloride (C2H5)3Si(OH) and CH2CHOCH(CH3)2 in presence of 30% HCl soln. at 50-90°C;;	42%

: 926-65-8
vinyl isopropyl ether

: 122-51-0
orthoformic acid triethyl ester

A: 122-31-6
malondialdehyde bis(diethyl acetal)

B: 603151-68-4
1,3,3-triethoxy-1-(isopropoxy)propane

Conditions

Conditions	Yield
iron(III) chloride at -30℃; for 6h; Product distribution / selectivity;	A 6.5% B 42%
iron(III) chloride at 0℃; for 6h; Product distribution / selectivity;	A 13.6% B 27%

...Expand

: 926-65-8
vinyl isopropyl ether

: 55991-67-8
5-phenylfuran-2,3-dione

A: 2397-79-7
2-phenyl-4H-pyran-4-one

B: 14895-21-7
3-benzoyl-4-hydroxy-6-phenyl-2H-pyran-2-one

Conditions

Conditions	Yield
In benzene for 3h; Heating;	A 30% B n/a

...Expand

Vinyl isopropyl ether Chemical Properties

IUPAC Name: 2-Ethenoxypropane
Synonyms of Isopropyl vinyl ether (CAS NO.926-65-8): 2-(Ethenyloxy)propane ; EINECS 213-142-5 ; 2-(Vinyloxy)propane ; Propane, 2-(ethenyloxy)- ; Vinyl isopropyl ether
CAS NO: 926-65-8
Molecular Formula of Isopropyl vinyl ether (CAS NO.926-65-8): C₅H₁₀O
Molecular Weight: 86.1323
Molecular Structure:

Polar Surface Area: 9.23 Å²
Index of Refraction: 1.388
Molar Refractivity: 26.64 cm³
Molar Volume: 112.9 cm³
Surface Tension: 19.4 dyne/cm
Density of Isopropyl vinyl ether (CAS NO.926-65-8): 0.762 g/cm³
Enthalpy of Vaporization: 28.78 kJ/mol
Boiling Point: 57.5 °C at 760 mmHg
Vapour Pressure: 230 mmHg at 25°C

Vinyl isopropyl ether Safety Profile

RIDADR: 3271
HazardClass: 3.1
PackingGroup: II
A very dangerous fire hazard when exposed to heat, spark, or flame. When heated to decomposition it emits acrid smoke and fumes. See also ETHERS.

Product Name

Vinyl isopropyl ether

Synthetic route

Vinyl isopropyl ether Chemical Properties

Vinyl isopropyl ether Safety Profile

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