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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesis.

manufacturer best selling of (9-phenyl-9H-carbazol-2-yl)boronic acid

Cas:1001911-63-2

Min.Order:100 Gram

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Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product Name 9-Phenylcarbazole-2-boronic acid CAS No. 1001911-63-2 Appearance White powder Assay ≥99% Capacity 200mt/year Min.packing 100gram

9-Phenylcarbazole-2-boronic acid

Cas:1001911-63-2

Min.Order:1 Gram

FOB Price: $52.0

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high purity Appearance:solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:meet customer's demand Application:auxiliaries Transportation:by sea or by air Port:shanghai

(9-phenyl-9H-carbazol-2-yl)boronic acid

Cas:1001911-63-2

Min.Order:1 Kilogram

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Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply (9-phenyl-9H-carbazol-2-yl)boronic acid

Cas:1001911-63-2

Min.Order:1

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Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 1001911-63-2 Boronicacid,B-(9-phenyl-9H-carbazol-2-yl) Manufacturer

Cas:1001911-63-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

(9-PHENYL-9H-CARBAZOL-2-YL)BORONIC ACID

Cas:1001911-63-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

9-Phenylcarbazole-2-boronic acid CAS 1001911-63-2 In stock

Cas:1001911-63-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

(9-phenyl-9H-carbazol-2-yl)boronic acid ----

Cas:1001911-63-2

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

9-Phenylcarbazole-2-Boronic Acid/2-Bapc CAS 1001911-63-2

Cas:1001911-63-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 1001911-63-2 with best quality

Cas:1001911-63-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

(9-phenyl-9H-carbazol-2-yl)boronic acid

Cas:1001911-63-2

Min.Order:10 Kilogram

FOB Price: $5.0 / 10.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name (9-Phenyl-9H-carbazol-2-yl)boronic acid CAS No. 1001911-63-2 Appearance solid Molecular

(9-Phenyl)carbazole-2-boronic acid

Cas:1001911-63-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers 3.Safe a

9-Phenylcarbazole-2-boronic acid

Cas:1001911-63-2

Min.Order:0 Metric Ton

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Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

(9-phenyl-9H-carbazol-2-yl)boronic acid 1001911-63-2

Cas:1001911-63-2

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: (9-phenyl-9H-carbazol-2-yl)boronic acid Synonyms: 9-Phenylcarbazole-2-boronic acid;B-(9-Phenyl-9H-carbazol-2-yl)-boronic acid;(9-phenyl-9H-carbazol-2-yl)boronic acid (2PCBA);2-BAPC;9-Phenylcarbazole-2-boronic Acid (contains varyin

(9-phenyl-9H-carbazol-2-yl)boronic acid

Cas:1001911-63-2

Min.Order:1 Gram

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Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

(9-phenyl-9H-carbazol-2-yl)boronic acid CAS: 1001911-63-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in hig

(9-phenyl-9H-carbazol-2-yl)boronic acid CAS: 1001911-63-2

Cas:1001911-63-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

(9-phenyl-9H-carbazol-2-yl)boronic acid

Cas:1001911-63-2

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

(9-phenyl-9H-carbazol-2-yl)boronic acid

Cas:1001911-63-2

Min.Order:0

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Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

manufacturer of (9-phenyl-9H-carbazol-2-yl)boronic acid CAS NO.1001911-63-2

Cas:1001911-63-2

Min.Order:10 Gram

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Type:Trading Company

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and qua

(9-phenyl-9H-carbazol-2-yl)boronic acid

Cas:1001911-63-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

(9-phenyl-9H-carbazol-2-yl)boronic acid

Cas:1001911-63-2

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Saiwante (shanghai) New Material Technology Co., Ltd.

ProName: (9-phenyl-9H-carbazol-2-yl)boronic aci... CasNo: 1001911-63-2 Molecular Formula: C18H14BNO2 Appearance: solid Application: auxiliaries DeliveryTime: 20day PackAge: meet customer's demand Port: shanghai ProductionCapacity: 5 Met

(9-phenyl-9H-carbazol-2-yl)boronic acid CAS NO.1001911-63-2

Cas:1001911-63-2

Min.Order:1 Gram

FOB Price: $6.0 / 9.0

Type:Trading Company

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 9-Phenylcarbazole-2-boronic acid

Cas:1001911-63-2

Min.Order:100 Gram

Negotiable

Type:Other

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Wuhan Xinhao Biotechnology Co., Ltd.

High quality with competitive price. 1. Standard bp/usp/ep/enterprise standard. 2. All purity>99%. 3. We are manufacturer and can provide high quality products with factory price. Fast and safe delivery. 1. Parcel can be sent out in 24 hours afte

High Quality (9-phenyl-9H-carbazol-2-yl)boronic acid

Cas:1001911-63-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Trading Company

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

(9-phenyl-9H-carbazol-2-yl)boronic acid

Cas:1001911-63-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

advantage: 1. The best price, satisfactory quality; 2. customers have the right to choose the delivery of parcels (EMS, DHL, FedEx, UPS); 3. customers have the right to choose from the recent effective packaging methods of their products packaging

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

1001911-63-2 (9-phenyl-9H-carbazol-2-yl)boronic acid CAS NO.1001911-63-2

Cas:1001911-63-2

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Hangzhou Johoo Chemical Co., Ltd

High quality products. Always supply highest grade to you. Purity:≥99% Reasonable & Competitive Price. Huge capacity determines the lowest shared cost. The more you buy the more competitive prices you will get. The sincerest and most pro

(9-phenyl-9H-carbazol-2-yl)boronic acid

Cas:1001911-63-2

Min.Order:1 Metric Ton

FOB Price: $5.5 / 10.5

Type:Trading Company

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Siwei Development Group Ltd.

Product name: N-Phenyl-9H-Carbazole-2-Boronic Acid CAS No.:1001911-63-2 Molecule Formula:C18H14BNO2 Molecule Weight:287.12 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard

Best Quality N-Phenyl-9H-Carbazole-2-Boronic Acid

Cas:1001911-63-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

(9-PHENYL-9H-CARBAZOL-2-YL)BORONIC ACID

Cas:1001911-63-2

Min.Order:1 Metric Ton

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Type:Lab/Research institutions

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Synthetic route

Triisopropyl borate
5419-55-6

Triisopropyl borate

9-(phenyl)-2-bromo-9H-carbazole
94994-62-4

9-(phenyl)-2-bromo-9H-carbazole

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Stage #1: 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran at -75 - 0℃; for 1h; Inert atmosphere;
Stage #2: Triisopropyl borate In tetrahydrofuran at -70 - 20℃; for 12h; Inert atmosphere;
Stage #3: With hydrogenchloride In tetrahydrofuran; water for 0.5h; Temperature; Inert atmosphere;
95%
Stage #1: 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran for 1h;
Stage #2: Triisopropyl borate In tetrahydrofuran at 20℃; for 12h;
78.4%
Stage #1: 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium In diethyl ether; hexane at -78℃; for 0.5h;
Stage #2: Triisopropyl borate In diethyl ether; hexane at -78 - 20℃;
Stage #3: With hydrogenchloride In diethyl ether; hexane
78%
Stage #1: 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran at -78℃; for 1h;
Stage #2: Triisopropyl borate In tetrahydrofuran
70%
Stage #1: 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran at -78℃; for 0.666667h;
Stage #2: Triisopropyl borate In tetrahydrofuran at 20℃; for 12h;
Stage #3: With water In tetrahydrofuran; hexane
62.8%
Trimethyl borate
121-43-7

Trimethyl borate

9-(phenyl)-2-bromo-9H-carbazole
94994-62-4

9-(phenyl)-2-bromo-9H-carbazole

water
7732-18-5

water

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Stage #1: 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran at -78 - 0℃; for 1h;
Stage #2: Trimethyl borate In tetrahydrofuran at -78 - 20℃; for 12h;
Stage #3: water With hydrogenchloride In tetrahydrofuran
81%
Trimethyl borate
121-43-7

Trimethyl borate

9-(phenyl)-2-bromo-9H-carbazole
94994-62-4

9-(phenyl)-2-bromo-9H-carbazole

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Stage #1: 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran at -78 - 0℃; for 1h; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran at -78 - 20℃; for 12h;
79%
Stage #1: 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran at -78℃; for 2h; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran at 20℃; for 4h; Inert atmosphere;
72%
Stage #1: 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: Trimethyl borate In tetrahydrofuran; hexane for 12h;
Stage #3: With water
69%
With n-butyllithium
Stage #1: 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium at -78℃;
Stage #2: Trimethyl borate at -78℃;
Stage #3: With hydrogenchloride In water
hydrogenchloride
7647-01-0

hydrogenchloride

Trimethyl borate
121-43-7

Trimethyl borate

9-(phenyl)-2-bromo-9H-carbazole
94994-62-4

9-(phenyl)-2-bromo-9H-carbazole

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Stage #1: Trimethyl borate; 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran at -78 - 20℃;
Stage #2: hydrogenchloride In tetrahydrofuran
76%
9-(phenyl)-2-bromo-9H-carbazole
94994-62-4

9-(phenyl)-2-bromo-9H-carbazole

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Stage #1: 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: With Trimethyl borate In tetrahydrofuran; hexane at 20℃; for 12h;
Stage #3: With water In tetrahydrofuran; hexane
69%
Stage #1: 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: With Triisopropyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 12h;
Stage #3: With water In tetrahydrofuran; hexane at 20℃;
67.33%
With hydrogenchloride; n-butyllithium; Trimethyl borate In water Inert atmosphere;
Triisopropyl borate
5419-55-6

Triisopropyl borate

9-(phenyl)-2-bromo-9H-carbazole
94994-62-4

9-(phenyl)-2-bromo-9H-carbazole

water
7732-18-5

water

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Stage #1: 9-(phenyl)-2-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane for 0.5h;
Stage #2: Triisopropyl borate In tetrahydrofuran; hexane at 20℃; for 5h;
Stage #3: water With hydrogenchloride In tetrahydrofuran; hexane; water for 0.5h;
55%
4-Bromophenylboronic acid
5467-74-3

4-Bromophenylboronic acid

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene / 4 h / 100 °C
2.1: triethyl phosphite / 6 h / 150 °C
3.1: caesium carbonate / copper(l) iodide / toluene / 50 °C
3.2: 14 h / Reflux
4.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C
4.2: 12 h / 20 °C
View Scheme
Multi-step reaction with 4 steps
1.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene / 4 h / 100 °C
2.1: triethyl phosphite / 6 h / 150 °C
3.1: caesium carbonate / copper(l) iodide / toluene / 50 °C
3.2: 14 h / Reflux
4.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C
4.2: 12 h
View Scheme
4'-bromo-2-nitrobiphenyl
35450-34-1

4'-bromo-2-nitrobiphenyl

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: triethyl phosphite / 6 h / 150 °C
2.1: caesium carbonate / copper(l) iodide / toluene / 50 °C
2.2: 14 h / Reflux
3.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C
3.2: 12 h / 20 °C
View Scheme
Multi-step reaction with 3 steps
1.1: triethyl phosphite / 6 h / 150 °C
2.1: caesium carbonate / copper(l) iodide / toluene / 50 °C
2.2: 14 h / Reflux
3.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C
3.2: 12 h
View Scheme
Multi-step reaction with 3 steps
1.1: triethyl phosphate / 7 h / 150 °C
2.1: potassium phosphate; ethylenediamine / 12 h / Reflux
3.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C
3.2: 12 h / -78 - 20 °C
3.3: 20 °C
View Scheme
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: caesium carbonate / copper(l) iodide / toluene / 50 °C
1.2: 14 h / Reflux
2.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C
2.2: 12 h / 20 °C
View Scheme
Multi-step reaction with 2 steps
1.1: caesium carbonate / copper(l) iodide / toluene / 50 °C
1.2: 14 h / Reflux
2.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C
2.2: 12 h
View Scheme
Multi-step reaction with 2 steps
1.1: caesium carbonate; copper(l) iodide; ethylenediamine / toluene / 12 h / Reflux
2.1: n-butyllithium / tetrahydrofuran / 1 h
2.2: 12 h / 20 °C
View Scheme
o-nitroiodobenzene
609-73-4

o-nitroiodobenzene

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene / 4 h / 100 °C
2.1: triethyl phosphite / 6 h / 150 °C
3.1: caesium carbonate / copper(l) iodide / toluene / 50 °C
3.2: 14 h / Reflux
4.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C
4.2: 12 h / 20 °C
View Scheme
Multi-step reaction with 4 steps
1.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene / 4 h / 100 °C
2.1: triethyl phosphite / 6 h / 150 °C
3.1: caesium carbonate / copper(l) iodide / toluene / 50 °C
3.2: 14 h / Reflux
4.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C
4.2: 12 h
View Scheme
1,4-dibromo-2-nitrobenzene
3460-18-2

1,4-dibromo-2-nitrobenzene

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene; ethanol; water / 24 h / Reflux
2.1: triethyl phosphite / 1,2-dichloro-benzene / 24 h / 150 °C
3.1: caesium carbonate; copper(l) iodide; ethylenediamine / toluene / 12 h / Reflux
4.1: n-butyllithium / tetrahydrofuran / 1 h
4.2: 12 h / 20 °C
View Scheme
Multi-step reaction with 4 steps
1.1: sodium carbonate; tetrakis(triphenylphosphine) palladium(0) / toluene; ethanol; water / 24 h / Reflux
2.1: triethyl phosphite / 1,2-dichloro-benzene / 24 h / 150 °C
3.1: copper(l) iodide; ethylenediamine; caesium carbonate / toluene / 4 h / Reflux
4.1: n-butyllithium / tetrahydrofuran / 0.67 h / -78 °C
4.2: 12 h / 20 °C
View Scheme
Multi-step reaction with 4 steps
1.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene / 90 °C
2.1: triethyl phosphite / Reflux
3.1: sodium hydroxide; copper(l) iodide; 1,10-Phenanthroline / para-xylene / 48 h / 140 °C
4.1: n-butyllithium / -78 °C
4.2: -78 °C
View Scheme
Multi-step reaction with 4 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene / Inert atmosphere
2: triethyl phosphite / Inert atmosphere
3: copper(l) iodide; 1,10-Phenanthroline; potassium hydroxide / para-xylene / Inert atmosphere
4: n-butyllithium; hydrogenchloride; Trimethyl borate / water / Inert atmosphere
View Scheme
4-bromo-2-nitro-1-phenylbenzene
70873-41-5

4-bromo-2-nitro-1-phenylbenzene

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: triethyl phosphite / 1,2-dichloro-benzene / 24 h / 150 °C
2.1: caesium carbonate; copper(l) iodide; ethylenediamine / toluene / 12 h / Reflux
3.1: n-butyllithium / tetrahydrofuran / 1 h
3.2: 12 h / 20 °C
View Scheme
Multi-step reaction with 3 steps
1.1: triethyl phosphite / 1,2-dichloro-benzene / 24 h / 150 °C
2.1: copper(l) iodide; ethylenediamine; caesium carbonate / toluene / 4 h / Reflux
3.1: n-butyllithium / tetrahydrofuran / 0.67 h / -78 °C
3.2: 12 h / 20 °C
View Scheme
Multi-step reaction with 3 steps
1.1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
2.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C
3.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C
3.2: 12 h / -78 - 20 °C
View Scheme
phenylboronic acid
98-80-6

phenylboronic acid

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene; ethanol; water / 24 h / Reflux
2.1: triethyl phosphite / 1,2-dichloro-benzene / 24 h / 150 °C
3.1: caesium carbonate; copper(l) iodide; ethylenediamine / toluene / 12 h / Reflux
4.1: n-butyllithium / tetrahydrofuran / 1 h
4.2: 12 h / 20 °C
View Scheme
Multi-step reaction with 5 steps
1.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / ethanol; toluene / 5 h / Reflux
2.1: iron(III) chloride; bromine / tetrachloromethane / 12 h / 0 - 20 °C
3.1: triethyl phosphate / 7 h / 150 °C
4.1: potassium phosphate; ethylenediamine / 12 h / Reflux
5.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C
5.2: 12 h / -78 - 20 °C
5.3: 20 °C
View Scheme
Multi-step reaction with 4 steps
1.1: sodium carbonate; tetrakis(triphenylphosphine) palladium(0) / toluene; ethanol; water / 24 h / Reflux
2.1: triethyl phosphite / 1,2-dichloro-benzene / 24 h / 150 °C
3.1: copper(l) iodide; ethylenediamine; caesium carbonate / toluene / 4 h / Reflux
4.1: n-butyllithium / tetrahydrofuran / 0.67 h / -78 °C
4.2: 12 h / 20 °C
View Scheme
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / ethanol; toluene / 5 h / Reflux
2.1: iron(III) chloride; bromine / tetrachloromethane / 12 h / 0 - 20 °C
3.1: triethyl phosphate / 7 h / 150 °C
4.1: potassium phosphate; ethylenediamine / 12 h / Reflux
5.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C
5.2: 12 h / -78 - 20 °C
5.3: 20 °C
View Scheme
2-nitrobiphenyl
86-00-0

2-nitrobiphenyl

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: iron(III) chloride; bromine / tetrachloromethane / 12 h / 0 - 20 °C
2.1: triethyl phosphate / 7 h / 150 °C
3.1: potassium phosphate; ethylenediamine / 12 h / Reflux
4.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C
4.2: 12 h / -78 - 20 °C
4.3: 20 °C
View Scheme
iodobenzene
591-50-4

iodobenzene

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate / toluene / 100 °C
2.1: n-butyllithium / diethyl ether; hexane / 0.5 h / -78 °C
2.2: -78 - 20 °C
View Scheme
Multi-step reaction with 2 steps
1.1: copper(l) chloride; potassium carbonate / dimethyl sulfoxide / 24 h / Reflux
2.1: n-butyllithium / tetrahydrofuran / 2 h / -78 °C / Inert atmosphere
2.2: 4 h / 20 °C / Inert atmosphere
View Scheme
1-iodo-4-bromo-2-nitrobenzene
112671-42-8

1-iodo-4-bromo-2-nitrobenzene

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 24 h / 80 °C
2.1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
3.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C
4.2: 12 h / -78 - 20 °C
View Scheme
Multi-step reaction with 4 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Reflux
2.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux
3.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
4.2: 12 h / -78 - 20 °C
View Scheme
3-bromo-9H-carbazole
1592-95-6

3-bromo-9H-carbazole

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C30H20N2

C30H20N2

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; toluene at 120℃; for 5h;93%
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium carbonate In 1,4-dioxane; water for 4h; Inert atmosphere; Reflux;80%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 12h; Reflux;80%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 5h; Reflux;58.57%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

3-(4-bromophenyl)-4-naphthyl-5-phenyl-1,2,4-triazole

3-(4-bromophenyl)-4-naphthyl-5-phenyl-1,2,4-triazole

C42H28N4

C42H28N4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; toluene at 70℃; for 24h; Suzuki Coupling; Inert atmosphere;93%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

N-phenyl-2-hydroxycarbazole

N-phenyl-2-hydroxycarbazole

Conditions
ConditionsYield
With 2,5-dimethylfuran; zinc(II) phthalocyanine; oxygen In tetrahydrofuran at 25℃; under 760.051 Torr; for 2h; Time; Irradiation; Sealed tube; Schlenk technique;93%
With oxygen; triethylamine In 2-methyltetrahydrofuran at 20℃; under 760.051 Torr; for 48h; Green chemistry;85%
With oxygen; triethylamine In 2-methyltetrahydrofuran at 20℃; under 760.051 Torr; for 48h; UV-irradiation;85%
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

2-(2-nitrophenyl)-9-phenyl-9H-carbazole
1361125-94-1

2-(2-nitrophenyl)-9-phenyl-9H-carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 100℃; for 12h; Inert atmosphere;92%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 100℃; for 12h; Inert atmosphere;87%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; toluene for 5h; Reflux;81.36%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; toluene for 5h; Reflux;81.36%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 120℃; for 24h; Inert atmosphere;70.6%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

9-phenyl-2-selenocyanato-9H-carbazole

9-phenyl-2-selenocyanato-9H-carbazole

Conditions
ConditionsYield
With selenium In dimethyl sulfoxide at 120℃; Schlenk technique; Green chemistry;91%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C42H31BF2I2N2

C42H31BF2I2N2

C78H55BF2N4

C78H55BF2N4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 12h; Reflux;90%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C37H22ClN

C37H22ClN

C55H34N2

C55H34N2

Conditions
ConditionsYield
With potassium phosphate; bis(tri-t-butylphosphine)palladium(0) In 1,4-dioxane; water for 8h; Reflux;90%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C39H22BrNO2

C39H22BrNO2

C57H34N2O2

C57H34N2O2

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene at 120℃; for 12h;90%
9-[1,1’-biphenyl-4-yl]-3-bromo-9H-carbazole
894791-46-9

9-[1,1’-biphenyl-4-yl]-3-bromo-9H-carbazole

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C42H28N2

C42H28N2

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene for 12h; Reflux;89%
2-bromo-11H-benzo[a]carbazole
103569-04-6

2-bromo-11H-benzo[a]carbazole

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C34H22N2

C34H22N2

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 3h; Inert atmosphere; Heating;88%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C18H8BrClS2

C18H8BrClS2

C36H20ClNS2

C36H20ClNS2

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium hydroxide In tetrahydrofuran; water for 6h;88%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

2-bromo-7-chlorodibenzo[b,d]thiophene

2-bromo-7-chlorodibenzo[b,d]thiophene

C30H18ClNS

C30H18ClNS

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium hydroxide In tetrahydrofuran; water at 80℃; for 12h;88%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C29H20BrN3

C29H20BrN3

C47H32N4

C47H32N4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium hydroxide In tetrahydrofuran; water at 80 - 90℃;86%
3-bromo-2-nitro-1-benzothiophene
17402-78-7

3-bromo-2-nitro-1-benzothiophene

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

2-(2-nitrobenzo[b]thiophen-3-yl)-9-phenyl-9H-carbazole

2-(2-nitrobenzo[b]thiophen-3-yl)-9-phenyl-9H-carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene at 100℃; for 6h; Inert atmosphere;85%
2-bromo-3-nitrobenzo[b]thiophene
100949-37-9

2-bromo-3-nitrobenzo[b]thiophene

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

2-(3-nitrobenzo[b]thiophen-2-yl)-9-phenyl-9H-carbazole

2-(3-nitrobenzo[b]thiophen-2-yl)-9-phenyl-9H-carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene at 100℃; for 6h; Inert atmosphere;85%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C18H9BrClN

C18H9BrClN

C36H21ClN2

C36H21ClN2

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); potassium carbonate In tetrahydrofuran; water for 3h; Reflux;84%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

2-(2-(4-iodophenoxy)-1-phenylethyl)malononitrile

2-(2-(4-iodophenoxy)-1-phenylethyl)malononitrile

2-(1-phenyl-2-(4-(9-phenyl-9H-carbazol-2-yl)phenoxy)ethyl)malononitrile

2-(1-phenyl-2-(4-(9-phenyl-9H-carbazol-2-yl)phenoxy)ethyl)malononitrile

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; triphenylphosphine In ethanol; water; toluene at 100℃; for 24h;83%
With palladium diacetate; potassium carbonate; triphenylphosphine In ethanol; water; toluene at 100℃; for 24h; Suzuki Coupling; Sealed tube; Inert atmosphere;82%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C34H24BrN3

C34H24BrN3

C52H36N4

C52H36N4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 12h; Inert atmosphere; Reflux;82%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C34H19BrO

C34H19BrO

C52H31NO

C52H31NO

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 110℃; for 12h; Inert atmosphere;82%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C18H9BrClN

C18H9BrClN

C36H21ClN2

C36H21ClN2

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); potassium carbonate In tetrahydrofuran; water for 3h; Reflux;81%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C24H14BrN3S

C24H14BrN3S

C42H26N4S

C42H26N4S

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 12h; Reflux; Inert atmosphere;80%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C33H19ClN4

C33H19ClN4

C51H31N5

C51H31N5

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0) In 1,4-dioxane; water for 3h; Reflux;80%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C28H10F18O7S2

C28H10F18O7S2

C56H34N2O

C56H34N2O

Conditions
ConditionsYield
With potassium carbonate; bis(dibenzylideneacetone)-palladium(0); tricyclohexylphosphine In tetrahydrofuran for 5h; Reflux;80%
1,6-dibromonaphthalene
19125-84-9

1,6-dibromonaphthalene

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C28H18BrN

C28H18BrN

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 110℃; Inert atmosphere;79%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C20H8Br2S2

C20H8Br2S2

C56H32N2S2

C56H32N2S2

Conditions
ConditionsYield
With sodium carbonate In toluene at 75 - 90℃; Inert atmosphere;79%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C20H8Br2O2

C20H8Br2O2

C56H32N2O2

C56H32N2O2

Conditions
ConditionsYield
With sodium carbonate In toluene at 75 - 90℃; Inert atmosphere;79%
(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid
1001911-63-2

(9‐phenyl‐9H‐carbazol‐2‐yl)boronic acid

C53H33BrN2

C53H33BrN2

C71H45N3

C71H45N3

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 12h; Inert atmosphere; Reflux;79%

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