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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesis.

professional supplier 2-Bromocarbazole on sale reasonable price

Cas:3652-90-2

Min.Order:100 Gram

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Bromocarbazole

Cas:3652-90-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Bromocarbazole supplier in China

Cas:3652-90-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/304.html Product Name 2-Bromocarbazole CAS No. 3652-90-2

2-Bromocarbazole

Cas:3652-90-2

Min.Order:1 Gram

FOB Price: $352.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production 2-phenylacetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carbon environ

2-Bromo-9H-carbazole CAS NO.3652-90-2

Cas:3652-90-2

Min.Order:100 Gram

FOB Price: $2.0

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

Unique advantages for 2-Bromocarbazole Cas 3652-90-2 Guaranteed the purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Powder Storage:Store at room Package:25kg/drum Application:OLED Transport

OLED Materials 2-Bromocarbazole Cas 3652-90-2 with top purity low price

Cas:3652-90-2

Min.Order:1 Kilogram

FOB Price: $10.0 / 135.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

T he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality service 2-BROM

2-BROMOCARBAZOLE 3652-90-2

Cas:3652-90-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Bromo-9H-carbazole

Cas:3652-90-2

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 3652-90-2 9H-Carbazole, 2-bromo- Manufacturer

Cas:3652-90-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Bromocarbazole

Cas:3652-90-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Product Name: 2-BROMOCARBAZOLE Synonyms: 2-Bromocarbazole, 2-Bromo-9-azafluorene;2-broMo-9H-carbazole (2BC);2-broMidecarbazole;9H-Carbazole, 2-bromo-;2-BROMOCARBAZOLE;2-BroMocarbazo;factory sell EG-2201 powder;Buy EG-2201 CAS: 36

3652-90-2 2-broMo-9H-carbazole (2BC);

Cas:3652-90-2

Min.Order:1 Gram

FOB Price: $8900.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

2-Bromocarbazole CAS 3652-90-2

Cas:3652-90-2

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 3652-90-2 with best quality

Cas:3652-90-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS 3652-90-2 EG-2201

Cas:3652-90-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Chemical Name: 2-Bromocarbazole Molecular Fomula: C12H8BrN Molecular weight: 246.106 Appearance: White powder Assay: 99%min Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:drum Application:oled

2-Bromocarbazole

Cas:3652-90-2

Min.Order:1 Kilogram

FOB Price: $3652902.0

Type:Other

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Hangzhou Think Chemical Co. Ltd

2-Bromocarbazole CAS NO.:3652-90-2 HANGZHOU THINK CHEMICAL CO., LTD. (THINKCHEM) is an integrative corporation of trade, research and contract manufacture. With about ten years of business experiences on the marketing & distrib

High purity 2-Bromocarbazole CAS NO.:3652-90-2 Supplier from China

Cas:3652-90-2

Min.Order:1 Kilogram

FOB Price: $10.0 / 20.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Bromo-9H-carbazole 3652-90-2

Cas:3652-90-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

Beluga chemical professional supply China's high-quality 2-Bromocarbazole manufact CAS 3652-90-2urer 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabi

China's high-quality 2-Bromocarbazole manufact CAS 3652-90-2urer

Cas:3652-90-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Bromo-9H-carbazole

Cas:3652-90-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Wuhan Kemi-Works Chemical Co., Ltd

ISO9001 Exporting Japan, Korea regularly. Appearance:white powder Package:25kg/ fibre drum Application:OLED intermediate Port:Chinese port

2-Bromocarbazole

Cas:3652-90-2

Min.Order:1 Gram

Negotiable

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Bromo-9H-carbazole

Cas:3652-90-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

2-broMocarbazole

Cas:3652-90-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou ZeErRui Chemical Co., Ltd.

Product Name 2-bromo-9H-carbazole CAS No. 3652-90-2 Appearance Off-white powder Purity 98%

2-Bromocarbazole manufacture

Cas:3652-90-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hefei Zhaobo Technology Co., Ltd.

Our Advantages Production: Advanced chemical equipment with years of experience Staffs for producing various extract products. Quality Control:A complete set of Testing Professional and Analysis Equipment ensures the Quality Requirements and Specif

2-broMidecarbazole CAS NO.3652-90-2

Cas:3652-90-2

Min.Order:1 Kilogram

FOB Price: $75.0 / 150.0

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Bromocarbazole

Cas:3652-90-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

2-Bromocarbazole

Cas:3652-90-2

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Bromo-9H-carbazole

Cas:3652-90-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 2-bromo-9H-carbazole

Cas:3652-90-2

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2-BROMOCARBAZOLE/High quality/Best price

Cas:3652-90-2

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-Bromocarbazole manufacturer/best price

Cas:3652-90-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Synthetic route

2-bromo-9-(pyrimidin-2-yl)-9H-carbazole

2-bromo-9-(pyrimidin-2-yl)-9H-carbazole

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
With N1-(4-hydroxy-2,6-dimethylphenyl)-N2-(4-hydroxy-3,5-dimethylphenyl)oxalamide; water; copper(l) chloride; sodium t-butanolate In dimethyl sulfoxide at 110℃; for 24h; Schlenk technique; Inert atmosphere;99%
4'-bromo-2-nitrobiphenyl
35450-34-1

4'-bromo-2-nitrobiphenyl

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
With triphenylphosphine In 1,2-dichloro-benzene at 170℃; for 12h; Inert atmosphere;89%
With triethyl phosphite In 1,2-dichloro-benzene at 80 - 150℃; Inert atmosphere;75%
Stage #1: 4'-bromo-2-nitrobiphenyl With triethyl phosphite at 160℃; for 2h;
Stage #2: With hydrogenchloride In water for 1h; Reflux;
67.6%

2-bromo-9H-carbazole

2-bromo-9H-carbazole

Conditions
ConditionsYield
With potassium fluoride; tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; potassium bromide In 1,4-dioxane at 130℃; for 16h; Inert atmosphere;83%

Conditions
ConditionsYield
With triethylphosphine for 12h; Reflux;82.4%
With triphenylphosphine In 1,2-dichloro-benzene at 200℃;77%
With triphenylphosphine In 1,2-dichloro-benzene Inert atmosphere; Reflux;77%
1-bromo-3-nitrosobenzene

1-bromo-3-nitrosobenzene

2-(trimethylsilyl)phenyl trifluoromethanesulfonate
88284-48-4

2-(trimethylsilyl)phenyl trifluoromethanesulfonate

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
With cesium fluoride In acetonitrile at 20℃; regioselective reaction;80%
2-azido-4'-bromo-1,1'-biphenyl

2-azido-4'-bromo-1,1'-biphenyl

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
In tetrahydrofuran for 4h; Solvent; Inert atmosphere; Irradiation;80%
2-bromo-9-(pyrimidin-2-yl)-9H-carbazole

2-bromo-9-(pyrimidin-2-yl)-9H-carbazole

A

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

B

2-hydroxy-9-(2-pyrimidinyl)carbazole

2-hydroxy-9-(2-pyrimidinyl)carbazole

Conditions
ConditionsYield
With N1-(4-hydroxy-2,6-dimethylphenyl)-N2-(4-hydroxy-3,5-dimethylphenyl)oxalamide; water; copper(l) chloride; sodium hydroxide In dimethyl sulfoxide at 110℃; for 24h; Schlenk technique; Inert atmosphere;A 74%
B 26%
3-bromodibenzo[b,d]iodol-5-ium trifluoromethanesulfonate

3-bromodibenzo[b,d]iodol-5-ium trifluoromethanesulfonate

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
With sodium azide; copper(I) thiophene-2-carboxylate; sodium hydrogencarbonate; triphenylphosphine In N,N-dimethyl acetamide at 100℃; for 12h; Inert atmosphere; Schlenk technique;63%
With sodium azide; copper(I) thiophene-2-carboxylate; sodium hydrogencarbonate; triphenylphosphine In N,N-dimethyl acetamide at 100℃; for 12h; Inert atmosphere; Schlenk technique;63%
4'-bromo-[1,1'-biphenyl]-2-amine
62532-98-3

4'-bromo-[1,1'-biphenyl]-2-amine

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; copper diacetate; Trimethylacetic acid In 1-methyl-pyrrolidin-2-one at 120℃; for 12h;33%
Multi-step reaction with 2 steps
1.1: acetic acid; sodium nitrite / water / 1 h / 0 °C
1.2: Sandmeyer Reaction / 1 h / 0 - 20 °C / Inert atmosphere
2.1: tetrahydrofuran / 4 h / Inert atmosphere; Irradiation
View Scheme
Multi-step reaction with 3 steps
1.1: hydrogenchloride; sodium nitrite / water; tetrahydrofuran / 1 h / 0 - 5 °C
1.2: 20 °C
2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 0 - 20 °C
3.1: copper(I) thiophene-2-carboxylate; triphenylphosphine; sodium azide; sodium hydrogencarbonate / N,N-dimethyl acetamide / 12 h / 100 °C / Inert atmosphere; Schlenk technique
View Scheme
7-bromo-2,3,4,9-tetrahydro-1H-carbazole
78863-99-7

7-bromo-2,3,4,9-tetrahydro-1H-carbazole

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
With chloranil; xylene
4-Brom-2-azidobiphenyl
91330-90-4

4-Brom-2-azidobiphenyl

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
With (thermal decomposition) In decalin at 148 - 163.6℃; Kinetics;
1,4-dibromo-2-nitrobenzene
3460-18-2

1,4-dibromo-2-nitrobenzene

phenylboronic acid
98-80-6

phenylboronic acid

A

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

B

Conditions
ConditionsYield
Stage #1: 1,4-dibromo-2-nitrobenzene; phenylboronic acid With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In toluene at 90℃; for 5.5h; Suzuki-Miyaura coupling;
Stage #2: With triethyl phosphite for 10h; Heating; Title compound not separated from byproducts;

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 37 percent / Br2; FeCl3 / CH2Cl2 / Heating
2: 39 percent / triethyl phosphite / 12 h / Heating
View Scheme
Multi-step reaction with 2 steps
1: iron(III) chloride; bromine / water
2: triethyl phosphite / 160 °C
View Scheme
Multi-step reaction with 2 steps
1.1: iron(III) chloride / water / 0.5 h / 60 °C / Inert atmosphere
1.2: Reflux
2.1: triethyl phosphite / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 2 steps
1: iron(III) chloride; bromine / tetrachloromethane / 12 h / 0 - 20 °C
2: triethyl phosphate / 7 h / 150 °C
View Scheme
Multi-step reaction with 2 steps
1: iron(III) chloride / water / 4 h / Inert atmosphere; Reflux
2: triethyl phosphite / Inert atmosphere; Reflux
View Scheme
cyclohexanone
108-94-1

cyclohexanone

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous sulfuric acid
2: tetrachloro-<1,4>benzoquinone; xylene
View Scheme
3-bromophenylhydrazine
40887-80-7

3-bromophenylhydrazine

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous sulfuric acid
2: tetrachloro-<1,4>benzoquinone; xylene
View Scheme
2-hydroxycarbazole
86-79-3

2-hydroxycarbazole

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 2h;
4-Bromophenylboronic acid
5467-74-3

4-Bromophenylboronic acid

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
With potassium carbonate; Pd(PPh3)4 In 1,2-dimethoxyethane; hexane; water; ethyl acetate
Multi-step reaction with 2 steps
1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene / 4 h / 100 °C
2: triethyl phosphite / 6 h / 150 °C
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine)palladium (0) / water; ethyl acetate; 1,2-dimethoxyethane
2: nitrogen; triphenylphosphine / ethyl acetate; 1,2-dichloro-benzene; methanol
View Scheme
1-iodo-4-bromo-2-nitrobenzene
112671-42-8

1-iodo-4-bromo-2-nitrobenzene

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: palladium diacetate; potassium carbonate; triphenylphosphine / water; toluene / 8 h / 70 °C
2: triethyl phosphite / 5 h / Reflux
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
2: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
2: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
View Scheme
phenylboronic acid
98-80-6

phenylboronic acid

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: palladium diacetate; potassium carbonate; triphenylphosphine / water; toluene / 8 h / 70 °C
2: triethyl phosphite / 5 h / Reflux
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene / 6 h / 90 °C
2: triethyl phosphite / 18 h / 160 °C
View Scheme
Multi-step reaction with 2 steps
1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 8 h / Inert atmosphere; Reflux
2: triphenylphosphine / 1,2-dichloro-benzene / 8 h / 180 °C / Inert atmosphere
View Scheme
1,4-dibromo-2-nitrobenzene
3460-18-2

1,4-dibromo-2-nitrobenzene

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene / 6 h / 90 °C
2: triethyl phosphite / 18 h / 160 °C
View Scheme
Multi-step reaction with 2 steps
1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 8 h / Inert atmosphere; Reflux
2: triphenylphosphine / 1,2-dichloro-benzene / 8 h / 180 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / water; toluene / 5.5 h / 90 °C / Inert atmosphere
2: triethyl phosphite / 10 h / Reflux; Inert atmosphere
View Scheme
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: nitric acid; acetic acid / 5 h / Reflux
2: triphenylphosphine / 1,2-dichloro-benzene / 12 h / 180 °C
View Scheme
Multi-step reaction with 2 steps
1: nitric acid; acetic acid / water
2: triethyl phosphite / 24 h / Reflux
View Scheme
o-nitroiodobenzene
609-73-4

o-nitroiodobenzene

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene / 4 h / 100 °C
2: triethyl phosphite / 6 h / 150 °C
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine)palladium (0) / water; ethyl acetate; 1,2-dimethoxyethane
2: nitrogen; triphenylphosphine / ethyl acetate; 1,2-dichloro-benzene; methanol
View Scheme
Multi-step reaction with 2 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / 1,2-dimethoxyethane; water / 16 h / Inert atmosphere; Reflux
2.1: triethyl phosphite / Inert atmosphere; Reflux
2.2: 3 h / 80 °C
View Scheme
triethyl phosphate
78-40-0

triethyl phosphate

4'-bromo-2-nitrobiphenyl
35450-34-1

4'-bromo-2-nitrobiphenyl

A

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

B

2-bromo-9-ethyl-9H-carbazole
56166-63-3

2-bromo-9-ethyl-9H-carbazole

Conditions
ConditionsYield
for 5h; Inert atmosphere; Reflux;A 7.2 g
B 4.26 g
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / ethanol; toluene / 5 h / Reflux
2: iron(III) chloride; bromine / tetrachloromethane / 12 h / 0 - 20 °C
3: triethyl phosphate / 7 h / 150 °C
View Scheme
Multi-step reaction with 2 steps
1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran; water / 12 h / 90 °C / Inert atmosphere
2: triphenylphosphine / 1,2-dichloro-benzene / 12 h / 170 °C / Inert atmosphere
View Scheme
4-Bromophenylboronic acid
5467-74-3

4-Bromophenylboronic acid

2-bromoaniline
615-36-1

2-bromoaniline

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: bis-triphenylphosphine-palladium(II) chloride; potassium carbonate / N,N-dimethyl-formamide; water / 24 h / 80 °C / Inert atmosphere
2: bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; Trimethylacetic acid; copper diacetate / 1-methyl-pyrrolidin-2-one / 12 h / 120 °C
View Scheme
1,4-dibromo-2-nitrobenzene
3460-18-2

1,4-dibromo-2-nitrobenzene

phenylboronic acid
98-80-6

phenylboronic acid

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene; water / 8 h / Reflux; Inert atmosphere
2: triphenylphosphine / 1,2-dichloro-benzene / 8 h / 180 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; 1,4-dioxane / 12 h / Reflux
2: triethylphosphine / 12 h / Reflux
View Scheme
2-iodophenylamine
615-43-0

2-iodophenylamine

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: potassium carbonate; bis-triphenylphosphine-palladium(II) chloride / 1,2-dimethoxyethane; water / 18 h / 80 °C / Inert atmosphere; Sealed tube
2.1: acetic acid; sodium nitrite / water / 1 h / 0 °C
2.2: Sandmeyer Reaction / 1 h / 0 - 20 °C / Inert atmosphere
3.1: tetrahydrofuran / 4 h / Inert atmosphere; Irradiation
View Scheme
Multi-step reaction with 4 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium phosphate / ethanol / 100 °C
2.1: hydrogenchloride; sodium nitrite / water; tetrahydrofuran / 1 h / 0 - 5 °C
2.2: 20 °C
3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 0 - 20 °C
4.1: copper(I) thiophene-2-carboxylate; triphenylphosphine; sodium azide; sodium hydrogencarbonate / N,N-dimethyl acetamide / 12 h / 100 °C / Inert atmosphere; Schlenk technique
View Scheme
4'-bromo-2-iodo-1,1'-biphenyl

4'-bromo-2-iodo-1,1'-biphenyl

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 0 - 20 °C
2: copper(I) thiophene-2-carboxylate; triphenylphosphine; sodium azide; sodium hydrogencarbonate / N,N-dimethyl acetamide / 12 h / 100 °C / Inert atmosphere; Schlenk technique
View Scheme
3,4-dihydro-2H-pyran
110-87-2

3,4-dihydro-2H-pyran

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-9-(tetrahydro-2H-pyran-2-yl)-9H-carbazole
183012-41-1

2-bromo-9-(tetrahydro-2H-pyran-2-yl)-9H-carbazole

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In dichloromethane Reflux;99%
pyridinium p-toluenesulfonate In dichloromethane at 20 - 50℃; for 4h;90%
With camphor-10-sulfonic acid In dichloromethane
2-bromo-pyridine
109-04-6

2-bromo-pyridine

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-9-(pyridin-2-yl)-9H-carbazole 3-Br
1352932-32-1

2-bromo-9-(pyridin-2-yl)-9H-carbazole 3-Br

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 24h; Concentration; Reagent/catalyst; Inert atmosphere;99%
With 1-methyl-1H-imidazole; copper(l) iodide; potassium carbonate In toluene at 120℃; Inert atmosphere;99%
With 1-methyl-1H-imidazole; copper(l) iodide; potassium carbonate In toluene at 120℃; for 144h; Glovebox; Sealed tube;99%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

2-bromo-9-(4-(tert-butyl)pyridin-2-yl)-9H-carbazole

2-bromo-9-(4-(tert-butyl)pyridin-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 24h; Inert atmosphere;99%
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 24h; Inert atmosphere;99%
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 20 - 130℃; for 48h; Inert atmosphere;99%
With 1-methyl-1H-imidazole; copper(l) iodide; potassium carbonate In toluene at 115 - 125℃; for 96h; Inert atmosphere;96%
With copper(l) iodide; potassium carbonate In toluene at 115 - 125℃; for 96h; Inert atmosphere;96%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

diphenylamine
122-39-4

diphenylamine

N,N-diphenyl-(9H-carbazol-2-yl)amine
929099-71-8

N,N-diphenyl-(9H-carbazol-2-yl)amine

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; lithium hexamethyldisilazane; tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran at 65℃; for 12h; Inert atmosphere;99%
2,5-dibromopyridine
624-28-2

2,5-dibromopyridine

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-9-(5-bromopyridin-2-yl)-9H-carbazole

2-bromo-9-(5-bromopyridin-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 5h; Inert atmosphere;98%
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 5h; Ullmann Condensation; chemoselective reaction;80%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

phenylhydrazine
100-63-0

phenylhydrazine

9-(phenyl)-2-bromo-9H-carbazole
94994-62-4

9-(phenyl)-2-bromo-9H-carbazole

Conditions
ConditionsYield
With cobalt(II) phthalocyanine; N,N,N,N,-tetramethylethylenediamine In acetonitrile at 60℃; for 12h; Schlenk technique;98%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

phenylboronic acid
98-80-6

phenylboronic acid

2-phenyl-9H-carbazole
88590-00-5

2-phenyl-9H-carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; toluene at 120℃; for 5h;97%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 5h; Reflux;86%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 5h; Reflux;86%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-chloro-4,6-diphenylpyrimidine
2915-16-4

2-chloro-4,6-diphenylpyrimidine

C28H18BrN3

C28H18BrN3

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl acetamide at 70℃; for 16.5h; Inert atmosphere;97%
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 8h; Inert atmosphere;90%
2-bromonicotinic acid methyl ester
52718-95-3

2-bromonicotinic acid methyl ester

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

methyl 2-(2-bromo-9H-carbazol-9-yl)pyridine-3-carboxylate

methyl 2-(2-bromo-9H-carbazol-9-yl)pyridine-3-carboxylate

Conditions
ConditionsYield
With copper(l) iodide; potassium carbonate; L-proline In toluene at 105 - 115℃; for 24h; Inert atmosphere;97%
With copper(l) iodide; potassium carbonate; L-proline In toluene at 120℃; for 24h; Inert atmosphere; Sealed tube;
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-4-(trifluoromethyl)pyridine
175205-81-9

2-bromo-4-(trifluoromethyl)pyridine

2-bromo-9-(4-(trifluoromethyl)pyridin-2-yl)-9H-carbazole

2-bromo-9-(4-(trifluoromethyl)pyridin-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 24h; Inert atmosphere;97%
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 12h; Schlenk technique; Inert atmosphere;88%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-4-methoxypyridine
89488-29-9

2-bromo-4-methoxypyridine

2-bromo-9-(4-methoxypyridin-2-yl)-9H-carbazole

2-bromo-9-(4-methoxypyridin-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 15h; Ullmann Condensation; Inert atmosphere;97%
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide for 15h;95%
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 120℃; for 15h; Inert atmosphere;95%
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 12h; Schlenk technique; Inert atmosphere;94%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromopyrimidine
4595-60-2

2-bromopyrimidine

2-bromo-9-(pyrimidin-2-yl)-9H-carbazole

2-bromo-9-(pyrimidin-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 7h; Inert atmosphere;96%
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 7h; Ullmann Condensation; chemoselective reaction;96%
2-Bromo-4-picoline
4926-28-7

2-Bromo-4-picoline

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-9-(4-methylpyridine-2-yl)-9H-carbazole
1404169-08-9

2-bromo-9-(4-methylpyridine-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 2.5h; Inert atmosphere;95%
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 2.5h; Ullmann Condensation; chemoselective reaction;95%
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 20 - 130℃; for 48h; Inert atmosphere;95%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

1,3-dihexyl-5-iodobenzene

1,3-dihexyl-5-iodobenzene

2-bromo-9-(3,5-dihexylphenyl)-9H-carbazole

2-bromo-9-(3,5-dihexylphenyl)-9H-carbazole

Conditions
ConditionsYield
With 1,10-Phenanthroline; copper(l) chloride; potassium hydroxide In o-xylene at 100 - 140℃; for 21h; Inert atmosphere;95%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-4-chloropyridine
22918-01-0

2-bromo-4-chloropyridine

2-bromo-9-(4-chloropyridin-2-yl)-9H-carbazole

2-bromo-9-(4-chloropyridin-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 24h; Inert atmosphere;95%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-3,6-diiodo-9H-carbazole

2-bromo-3,6-diiodo-9H-carbazole

Conditions
ConditionsYield
With diphenyliodonium tetrafluoroborate; copper(II) sulfate In acetonitrile for 0.666667h; Inert atmosphere; Reflux;95%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

1-bromo-hexane
111-25-1

1-bromo-hexane

2-bromo-9-hexylcarbazole
864550-95-8

2-bromo-9-hexylcarbazole

Conditions
ConditionsYield
Stage #1: 2-bromo-9H-carbazole With tetrabutylammomium bromide; sodium hydroxide at 20℃; for 0.0833333h;
Stage #2: 1-bromo-hexane for 12h;
94%
Stage #1: 2-bromo-9H-carbazole With potassium tert-butylate In N,N-dimethyl-formamide at 20℃;
Stage #2: 1-bromo-hexane In N,N-dimethyl-formamide at 130℃;
2-bromoquinoline
2005-43-8

2-bromoquinoline

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-9-(quinolin-2-yl)-9H-carbazole

2-bromo-9-(quinolin-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 3h; Inert atmosphere;94%
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 3h; Ullmann Condensation; chemoselective reaction;94%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

1-bromo-octane
111-83-1

1-bromo-octane

2-bromo-9-n-octyl-9H-carbazole

2-bromo-9-n-octyl-9H-carbazole

Conditions
ConditionsYield
Stage #1: 2-bromo-9H-carbazole With tetrabutylammomium bromide; sodium hydroxide In dimethyl sulfoxide at 20℃;
Stage #2: 1-bromo-octane In dimethyl sulfoxide at 20℃; for 8h;
93%
In toluene at 80℃; for 16h; Inert atmosphere; Alkaline conditions;68.6%
With N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide In dimethyl sulfoxide for 8.5h;65%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

tert-butyl 2-bromo-9H-carbazole-9-carboxylate
1247868-53-6

tert-butyl 2-bromo-9H-carbazole-9-carboxylate

Conditions
ConditionsYield
With dmap In tetrahydrofuran at 20℃; for 3h; Inert atmosphere;93%
With dmap In tetrahydrofuran at 20℃; for 12h; Inert atmosphere;84%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-4-fluoro-pyridine
357927-50-5

2-bromo-4-fluoro-pyridine

2-bromo-9-(4-fluoropyridin-2-yl)-9H-carbazole

2-bromo-9-(4-fluoropyridin-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 4h; Inert atmosphere;93%
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 4h; Ullmann Condensation; chemoselective reaction;93%
2-bromopyrazine
56423-63-3

2-bromopyrazine

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-9-(pyrazin-2-yl)-9H-carbazole

2-bromo-9-(pyrazin-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 7h; Inert atmosphere;93%
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 7h; Ullmann Condensation; chemoselective reaction;93%
2-bromo-1,3-thiazole
3034-53-5

2-bromo-1,3-thiazole

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-9-(thiazol-2-yl)-9H-carbazole

2-bromo-9-(thiazol-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 11h; Ullmann Condensation; chemoselective reaction;93%
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 8h; Inert atmosphere;92%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

iodobenzene
591-50-4

iodobenzene

9-(phenyl)-2-bromo-9H-carbazole
94994-62-4

9-(phenyl)-2-bromo-9H-carbazole

Conditions
ConditionsYield
With copper(l) iodide; caesium carbonate; ethylenediamine In toluene for 12h; Reflux;92.4%
With potassium phosphate; ethylenediamine for 12h; Reflux;91.65%
With copper(l) iodide; 1,10-Phenanthroline; potassium hydroxide In para-xylene at 140℃; for 48h; Ullmann condensation; Inert atmosphere;90%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

4,4,5,5-tetramethyl-2-(5'-phenyl-[1,1’:3' ,1"-terphenyl]-4-yl)-1,3,2-dioxaborolane

4,4,5,5-tetramethyl-2-(5'-phenyl-[1,1’:3' ,1"-terphenyl]-4-yl)-1,3,2-dioxaborolane

2-(3-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-carbazole

2-(3-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 12h; Inert atmosphere; Reflux;92%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 12h; Reflux;60%
2-Bromo-5-methylpyridine
3510-66-5

2-Bromo-5-methylpyridine

2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-9-(5-methylpyridin-2-yl)-9H-carbazole

2-bromo-9-(5-methylpyridin-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 3h; Inert atmosphere;92%
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 2h; Ullmann Condensation; chemoselective reaction;92%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole
1242412-60-7

2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In N,N-dimethyl-formamide at 85℃; for 4h; Sealed tube; Inert atmosphere;92%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In N,N-dimethyl-formamide at 130℃; for 3h;38%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

methyl iodide
74-88-4

methyl iodide

2-bromo-9-methyl-9H-carbazole
108793-89-1

2-bromo-9-methyl-9H-carbazole

Conditions
ConditionsYield
Stage #1: 2-bromo-9H-carbazole With sodium hydride In tetrahydrofuran at 0 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;
92%
Stage #1: 2-bromo-9H-carbazole With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 1h; Inert atmosphere;
Stage #2: methyl iodide In N,N-dimethyl-formamide; mineral oil at 20℃; Inert atmosphere;
72%
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

biphenyl-4-yl-hydrazine
2217-77-8

biphenyl-4-yl-hydrazine

9-[1,1’-biphenyl]-4-yl-2-bromo-9H-carbazole
1393835-87-4

9-[1,1’-biphenyl]-4-yl-2-bromo-9H-carbazole

Conditions
ConditionsYield
With potassium carbonate; copper(II) nitrate In acetonitrile at 0℃; for 4h;92%

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