Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesis.
Cas:3652-90-2
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inquiryDayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryProduct Description Product website: http://www.finerchem.com/pro01en/id/304.html Product Name 2-Bromocarbazole CAS No. 3652-90-2
Cas:3652-90-2
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inquiryHebei yanxi chemical co., LTD is a professional research, development and production 2-phenylacetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carbon environ
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inquiryUnique advantages for 2-Bromocarbazole Cas 3652-90-2 Guaranteed the purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Powder Storage:Store at room Package:25kg/drum Application:OLED Transport
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inquiryT he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality service 2-BROM
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
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inquiryProduct Name: 2-BROMOCARBAZOLE Synonyms: 2-Bromocarbazole, 2-Bromo-9-azafluorene;2-broMo-9H-carbazole (2BC);2-broMidecarbazole;9H-Carbazole, 2-bromo-;2-BROMOCARBAZOLE;2-BroMocarbazo;factory sell EG-2201 powder;Buy EG-2201 CAS: 36
Cas:3652-90-2
Min.Order:1 Gram
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inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
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inquiryChemical Name: 2-Bromocarbazole Molecular Fomula: C12H8BrN Molecular weight: 246.106 Appearance: White powder Assay: 99%min Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:drum Application:oled
2-Bromocarbazole CAS NO.:3652-90-2 HANGZHOU THINK CHEMICAL CO., LTD. (THINKCHEM) is an integrative corporation of trade, research and contract manufacture. With about ten years of business experiences on the marketing & distrib
Cas:3652-90-2
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inquiryBeluga chemical professional supply China's high-quality 2-Bromocarbazole manufact CAS 3652-90-2urer 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabi
Cas:3652-90-2
Min.Order:1 Gram
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Cas:3652-90-2
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inquiryISO9001 Exporting Japan, Korea regularly. Appearance:white powder Package:25kg/ fibre drum Application:OLED intermediate Port:Chinese port
Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By
Product Name 2-bromo-9H-carbazole CAS No. 3652-90-2 Appearance Off-white powder Purity 98%
Cas:3652-90-2
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inquiryOur Advantages Production: Advanced chemical equipment with years of experience Staffs for producing various extract products. Quality Control:A complete set of Testing Professional and Analysis Equipment ensures the Quality Requirements and Specif
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Cas:3652-90-2
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inquiryA substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
Cas:3652-90-2
Min.Order:4 Kilogram
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
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Cas:3652-90-2
Min.Order:100 Gram
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Cas:3652-90-2
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inquiry2-bromo-9H-carbazole
Conditions | Yield |
---|---|
With N1-(4-hydroxy-2,6-dimethylphenyl)-N2-(4-hydroxy-3,5-dimethylphenyl)oxalamide; water; copper(l) chloride; sodium t-butanolate In dimethyl sulfoxide at 110℃; for 24h; Schlenk technique; Inert atmosphere; | 99% |
4'-bromo-2-nitrobiphenyl
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
With triphenylphosphine In 1,2-dichloro-benzene at 170℃; for 12h; Inert atmosphere; | 89% |
With triethyl phosphite In 1,2-dichloro-benzene at 80 - 150℃; Inert atmosphere; | 75% |
Stage #1: 4'-bromo-2-nitrobiphenyl With triethyl phosphite at 160℃; for 2h; Stage #2: With hydrogenchloride In water for 1h; Reflux; | 67.6% |
Conditions | Yield |
---|---|
With potassium fluoride; tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; potassium bromide In 1,4-dioxane at 130℃; for 16h; Inert atmosphere; | 83% |
Conditions | Yield |
---|---|
With triethylphosphine for 12h; Reflux; | 82.4% |
With triphenylphosphine In 1,2-dichloro-benzene at 200℃; | 77% |
With triphenylphosphine In 1,2-dichloro-benzene Inert atmosphere; Reflux; | 77% |
2-(trimethylsilyl)phenyl trifluoromethanesulfonate
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
With cesium fluoride In acetonitrile at 20℃; regioselective reaction; | 80% |
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
In tetrahydrofuran for 4h; Solvent; Inert atmosphere; Irradiation; | 80% |
A
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
With N1-(4-hydroxy-2,6-dimethylphenyl)-N2-(4-hydroxy-3,5-dimethylphenyl)oxalamide; water; copper(l) chloride; sodium hydroxide In dimethyl sulfoxide at 110℃; for 24h; Schlenk technique; Inert atmosphere; | A 74% B 26% |
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
With sodium azide; copper(I) thiophene-2-carboxylate; sodium hydrogencarbonate; triphenylphosphine In N,N-dimethyl acetamide at 100℃; for 12h; Inert atmosphere; Schlenk technique; | 63% |
With sodium azide; copper(I) thiophene-2-carboxylate; sodium hydrogencarbonate; triphenylphosphine In N,N-dimethyl acetamide at 100℃; for 12h; Inert atmosphere; Schlenk technique; | 63% |
4'-bromo-[1,1'-biphenyl]-2-amine
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; copper diacetate; Trimethylacetic acid In 1-methyl-pyrrolidin-2-one at 120℃; for 12h; | 33% |
Multi-step reaction with 2 steps 1.1: acetic acid; sodium nitrite / water / 1 h / 0 °C 1.2: Sandmeyer Reaction / 1 h / 0 - 20 °C / Inert atmosphere 2.1: tetrahydrofuran / 4 h / Inert atmosphere; Irradiation View Scheme | |
Multi-step reaction with 3 steps 1.1: hydrogenchloride; sodium nitrite / water; tetrahydrofuran / 1 h / 0 - 5 °C 1.2: 20 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 0 - 20 °C 3.1: copper(I) thiophene-2-carboxylate; triphenylphosphine; sodium azide; sodium hydrogencarbonate / N,N-dimethyl acetamide / 12 h / 100 °C / Inert atmosphere; Schlenk technique View Scheme |
7-bromo-2,3,4,9-tetrahydro-1H-carbazole
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
With chloranil; xylene |
4-Brom-2-azidobiphenyl
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
With (thermal decomposition) In decalin at 148 - 163.6℃; Kinetics; |
Conditions | Yield |
---|---|
Stage #1: 1,4-dibromo-2-nitrobenzene; phenylboronic acid With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In toluene at 90℃; for 5.5h; Suzuki-Miyaura coupling; Stage #2: With triethyl phosphite for 10h; Heating; Title compound not separated from byproducts; |
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 37 percent / Br2; FeCl3 / CH2Cl2 / Heating 2: 39 percent / triethyl phosphite / 12 h / Heating View Scheme | |
Multi-step reaction with 2 steps 1: iron(III) chloride; bromine / water 2: triethyl phosphite / 160 °C View Scheme | |
Multi-step reaction with 2 steps 1.1: iron(III) chloride / water / 0.5 h / 60 °C / Inert atmosphere 1.2: Reflux 2.1: triethyl phosphite / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 2 steps 1: iron(III) chloride; bromine / tetrachloromethane / 12 h / 0 - 20 °C 2: triethyl phosphate / 7 h / 150 °C View Scheme | |
Multi-step reaction with 2 steps 1: iron(III) chloride / water / 4 h / Inert atmosphere; Reflux 2: triethyl phosphite / Inert atmosphere; Reflux View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: aqueous sulfuric acid 2: tetrachloro-<1,4>benzoquinone; xylene View Scheme |
3-bromophenylhydrazine
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: aqueous sulfuric acid 2: tetrachloro-<1,4>benzoquinone; xylene View Scheme |
Conditions | Yield |
---|---|
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 2h; |
Conditions | Yield |
---|---|
With potassium carbonate; Pd(PPh3)4 In 1,2-dimethoxyethane; hexane; water; ethyl acetate | |
Multi-step reaction with 2 steps 1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene / 4 h / 100 °C 2: triethyl phosphite / 6 h / 150 °C View Scheme | |
Multi-step reaction with 2 steps 1: tetrakis(triphenylphosphine)palladium (0) / water; ethyl acetate; 1,2-dimethoxyethane 2: nitrogen; triphenylphosphine / ethyl acetate; 1,2-dichloro-benzene; methanol View Scheme |
1-iodo-4-bromo-2-nitrobenzene
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: palladium diacetate; potassium carbonate; triphenylphosphine / water; toluene / 8 h / 70 °C 2: triethyl phosphite / 5 h / Reflux View Scheme | |
Multi-step reaction with 2 steps 1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C 2: triphenylphosphine / 1,2-dichloro-benzene / 200 °C View Scheme | |
Multi-step reaction with 2 steps 1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C 2: triphenylphosphine / 1,2-dichloro-benzene / 200 °C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: palladium diacetate; potassium carbonate; triphenylphosphine / water; toluene / 8 h / 70 °C 2: triethyl phosphite / 5 h / Reflux View Scheme | |
Multi-step reaction with 2 steps 1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene / 6 h / 90 °C 2: triethyl phosphite / 18 h / 160 °C View Scheme | |
Multi-step reaction with 2 steps 1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 8 h / Inert atmosphere; Reflux 2: triphenylphosphine / 1,2-dichloro-benzene / 8 h / 180 °C / Inert atmosphere View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene / 6 h / 90 °C 2: triethyl phosphite / 18 h / 160 °C View Scheme | |
Multi-step reaction with 2 steps 1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 8 h / Inert atmosphere; Reflux 2: triphenylphosphine / 1,2-dichloro-benzene / 8 h / 180 °C / Inert atmosphere View Scheme | |
Multi-step reaction with 2 steps 1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / water; toluene / 5.5 h / 90 °C / Inert atmosphere 2: triethyl phosphite / 10 h / Reflux; Inert atmosphere View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: nitric acid; acetic acid / 5 h / Reflux 2: triphenylphosphine / 1,2-dichloro-benzene / 12 h / 180 °C View Scheme | |
Multi-step reaction with 2 steps 1: nitric acid; acetic acid / water 2: triethyl phosphite / 24 h / Reflux View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene / 4 h / 100 °C 2: triethyl phosphite / 6 h / 150 °C View Scheme | |
Multi-step reaction with 2 steps 1: tetrakis(triphenylphosphine)palladium (0) / water; ethyl acetate; 1,2-dimethoxyethane 2: nitrogen; triphenylphosphine / ethyl acetate; 1,2-dichloro-benzene; methanol View Scheme | |
Multi-step reaction with 2 steps 1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / 1,2-dimethoxyethane; water / 16 h / Inert atmosphere; Reflux 2.1: triethyl phosphite / Inert atmosphere; Reflux 2.2: 3 h / 80 °C View Scheme |
triethyl phosphate
4'-bromo-2-nitrobiphenyl
A
2-bromo-9H-carbazole
B
2-bromo-9-ethyl-9H-carbazole
Conditions | Yield |
---|---|
for 5h; Inert atmosphere; Reflux; | A 7.2 g B 4.26 g |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / ethanol; toluene / 5 h / Reflux 2: iron(III) chloride; bromine / tetrachloromethane / 12 h / 0 - 20 °C 3: triethyl phosphate / 7 h / 150 °C View Scheme | |
Multi-step reaction with 2 steps 1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran; water / 12 h / 90 °C / Inert atmosphere 2: triphenylphosphine / 1,2-dichloro-benzene / 12 h / 170 °C / Inert atmosphere View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: bis-triphenylphosphine-palladium(II) chloride; potassium carbonate / N,N-dimethyl-formamide; water / 24 h / 80 °C / Inert atmosphere 2: bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; Trimethylacetic acid; copper diacetate / 1-methyl-pyrrolidin-2-one / 12 h / 120 °C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene; water / 8 h / Reflux; Inert atmosphere 2: triphenylphosphine / 1,2-dichloro-benzene / 8 h / 180 °C / Inert atmosphere View Scheme | |
Multi-step reaction with 2 steps 1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; 1,4-dioxane / 12 h / Reflux 2: triethylphosphine / 12 h / Reflux View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1.1: potassium carbonate; bis-triphenylphosphine-palladium(II) chloride / 1,2-dimethoxyethane; water / 18 h / 80 °C / Inert atmosphere; Sealed tube 2.1: acetic acid; sodium nitrite / water / 1 h / 0 °C 2.2: Sandmeyer Reaction / 1 h / 0 - 20 °C / Inert atmosphere 3.1: tetrahydrofuran / 4 h / Inert atmosphere; Irradiation View Scheme | |
Multi-step reaction with 4 steps 1.1: tetrakis(triphenylphosphine) palladium(0); potassium phosphate / ethanol / 100 °C 2.1: hydrogenchloride; sodium nitrite / water; tetrahydrofuran / 1 h / 0 - 5 °C 2.2: 20 °C 3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 0 - 20 °C 4.1: copper(I) thiophene-2-carboxylate; triphenylphosphine; sodium azide; sodium hydrogencarbonate / N,N-dimethyl acetamide / 12 h / 100 °C / Inert atmosphere; Schlenk technique View Scheme |
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 0 - 20 °C 2: copper(I) thiophene-2-carboxylate; triphenylphosphine; sodium azide; sodium hydrogencarbonate / N,N-dimethyl acetamide / 12 h / 100 °C / Inert atmosphere; Schlenk technique View Scheme |
3,4-dihydro-2H-pyran
2-bromo-9H-carbazole
2-bromo-9-(tetrahydro-2H-pyran-2-yl)-9H-carbazole
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In dichloromethane Reflux; | 99% |
pyridinium p-toluenesulfonate In dichloromethane at 20 - 50℃; for 4h; | 90% |
With camphor-10-sulfonic acid In dichloromethane |
2-bromo-pyridine
2-bromo-9H-carbazole
2-bromo-9-(pyridin-2-yl)-9H-carbazole 3-Br
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 24h; Concentration; Reagent/catalyst; Inert atmosphere; | 99% |
With 1-methyl-1H-imidazole; copper(l) iodide; potassium carbonate In toluene at 120℃; Inert atmosphere; | 99% |
With 1-methyl-1H-imidazole; copper(l) iodide; potassium carbonate In toluene at 120℃; for 144h; Glovebox; Sealed tube; | 99% |
2-bromo-9H-carbazole
2-bromo-4-(tert-butyl)pyridine
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 24h; Inert atmosphere; | 99% |
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 24h; Inert atmosphere; | 99% |
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 20 - 130℃; for 48h; Inert atmosphere; | 99% |
With 1-methyl-1H-imidazole; copper(l) iodide; potassium carbonate In toluene at 115 - 125℃; for 96h; Inert atmosphere; | 96% |
With copper(l) iodide; potassium carbonate In toluene at 115 - 125℃; for 96h; Inert atmosphere; | 96% |
2-bromo-9H-carbazole
diphenylamine
N,N-diphenyl-(9H-carbazol-2-yl)amine
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; lithium hexamethyldisilazane; tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran at 65℃; for 12h; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 5h; Inert atmosphere; | 98% |
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 5h; Ullmann Condensation; chemoselective reaction; | 80% |
Conditions | Yield |
---|---|
With cobalt(II) phthalocyanine; N,N,N,N,-tetramethylethylenediamine In acetonitrile at 60℃; for 12h; Schlenk technique; | 98% |
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; toluene at 120℃; for 5h; | 97% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 5h; Reflux; | 86% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 5h; Reflux; | 86% |
Conditions | Yield |
---|---|
With caesium carbonate In N,N-dimethyl acetamide at 70℃; for 16.5h; Inert atmosphere; | 97% |
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 8h; Inert atmosphere; | 90% |
2-bromonicotinic acid methyl ester
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
With copper(l) iodide; potassium carbonate; L-proline In toluene at 105 - 115℃; for 24h; Inert atmosphere; | 97% |
With copper(l) iodide; potassium carbonate; L-proline In toluene at 120℃; for 24h; Inert atmosphere; Sealed tube; |
2-bromo-9H-carbazole
2-bromo-4-(trifluoromethyl)pyridine
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 24h; Inert atmosphere; | 97% |
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 12h; Schlenk technique; Inert atmosphere; | 88% |
2-bromo-9H-carbazole
2-bromo-4-methoxypyridine
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 15h; Ullmann Condensation; Inert atmosphere; | 97% |
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide for 15h; | 95% |
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 120℃; for 15h; Inert atmosphere; | 95% |
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 12h; Schlenk technique; Inert atmosphere; | 94% |
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 7h; Inert atmosphere; | 96% |
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 7h; Ullmann Condensation; chemoselective reaction; | 96% |
2-Bromo-4-picoline
2-bromo-9H-carbazole
2-bromo-9-(4-methylpyridine-2-yl)-9H-carbazole
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 2.5h; Inert atmosphere; | 95% |
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 2.5h; Ullmann Condensation; chemoselective reaction; | 95% |
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 20 - 130℃; for 48h; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
With 1,10-Phenanthroline; copper(l) chloride; potassium hydroxide In o-xylene at 100 - 140℃; for 21h; Inert atmosphere; | 95% |
2-bromo-9H-carbazole
2-bromo-4-chloropyridine
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 24h; Inert atmosphere; | 95% |
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
With diphenyliodonium tetrafluoroborate; copper(II) sulfate In acetonitrile for 0.666667h; Inert atmosphere; Reflux; | 95% |
Conditions | Yield |
---|---|
Stage #1: 2-bromo-9H-carbazole With tetrabutylammomium bromide; sodium hydroxide at 20℃; for 0.0833333h; Stage #2: 1-bromo-hexane for 12h; | 94% |
Stage #1: 2-bromo-9H-carbazole With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; Stage #2: 1-bromo-hexane In N,N-dimethyl-formamide at 130℃; |
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 3h; Inert atmosphere; | 94% |
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 3h; Ullmann Condensation; chemoselective reaction; | 94% |
Conditions | Yield |
---|---|
Stage #1: 2-bromo-9H-carbazole With tetrabutylammomium bromide; sodium hydroxide In dimethyl sulfoxide at 20℃; Stage #2: 1-bromo-octane In dimethyl sulfoxide at 20℃; for 8h; | 93% |
In toluene at 80℃; for 16h; Inert atmosphere; Alkaline conditions; | 68.6% |
With N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide In dimethyl sulfoxide for 8.5h; | 65% |
2-bromo-9H-carbazole
di-tert-butyl dicarbonate
tert-butyl 2-bromo-9H-carbazole-9-carboxylate
Conditions | Yield |
---|---|
With dmap In tetrahydrofuran at 20℃; for 3h; Inert atmosphere; | 93% |
With dmap In tetrahydrofuran at 20℃; for 12h; Inert atmosphere; | 84% |
2-bromo-9H-carbazole
2-bromo-4-fluoro-pyridine
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 4h; Inert atmosphere; | 93% |
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 4h; Ullmann Condensation; chemoselective reaction; | 93% |
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 7h; Inert atmosphere; | 93% |
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 7h; Ullmann Condensation; chemoselective reaction; | 93% |
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 11h; Ullmann Condensation; chemoselective reaction; | 93% |
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 8h; Inert atmosphere; | 92% |
Conditions | Yield |
---|---|
With copper(l) iodide; caesium carbonate; ethylenediamine In toluene for 12h; Reflux; | 92.4% |
With potassium phosphate; ethylenediamine for 12h; Reflux; | 91.65% |
With copper(l) iodide; 1,10-Phenanthroline; potassium hydroxide In para-xylene at 140℃; for 48h; Ullmann condensation; Inert atmosphere; | 90% |
2-bromo-9H-carbazole
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 12h; Inert atmosphere; Reflux; | 92% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 12h; Reflux; | 60% |
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 3h; Inert atmosphere; | 92% |
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 2h; Ullmann Condensation; chemoselective reaction; | 92% |
2-bromo-9H-carbazole
bis(pinacol)diborane
2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole
Conditions | Yield |
---|---|
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In N,N-dimethyl-formamide at 85℃; for 4h; Sealed tube; Inert atmosphere; | 92% |
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In N,N-dimethyl-formamide at 130℃; for 3h; | 38% |
Conditions | Yield |
---|---|
Stage #1: 2-bromo-9H-carbazole With sodium hydride In tetrahydrofuran at 0 - 20℃; for 0.5h; Inert atmosphere; Stage #2: methyl iodide In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; | 92% |
Stage #1: 2-bromo-9H-carbazole With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: methyl iodide In N,N-dimethyl-formamide; mineral oil at 20℃; Inert atmosphere; | 72% |
2-bromo-9H-carbazole
biphenyl-4-yl-hydrazine
9-[1,1’-biphenyl]-4-yl-2-bromo-9H-carbazole
Conditions | Yield |
---|---|
With potassium carbonate; copper(II) nitrate In acetonitrile at 0℃; for 4h; | 92% |
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