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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 50488-34-1 2-Bromo-4-(tert-butyl)pyridine Manufacturer

Cas:50488-34-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company engages in Sodium Tripolyphosphate (STPP) and Sodium Hexametabphosphate (SHMP) production; development of noble metal catalysts, synthesis of electronic chemical materials and general chemicals Imp&Exp trading business. The company

TIANFU-CHEM - 2-Bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Pyridine, 2-bromo-4-(1,1-dimethylethyl)-

Cas:50488-34-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

2-Bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:1 Gram

FOB Price: $1951.0

Type:Trading Company

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Pyridine, 2-bromo-4-(1,1-dimethylethyl)-

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: 2-Bromo-4-(Tert-Butyl)Pyridine CAS No.:50488-34-1 Molecule Formula:C9H12BrN Molecule Weight:214.10 Purity: 98% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS

High Quality 2-Bromo-4-(Tert-Butyl)Pyridine in stock

Cas:50488-34-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Huarong Pharm Co., Ltd.

We Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O

2-Bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2-Bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Pyridine, 2-bromo-4-(1,1-dimethylethyl)-

Cas:50488-34-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

2-bromo-4-tertbutylpyridine

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Antimex Chemical Limied

hight degree of purity Application:Fine chemical intermediates, used as the main raw material for he synthesis of various pesticides, medicines, surfactants, polymer monomers, end entifungal agents

Pyridine, 2-bromo-4-(1,1-dimethylethyl)-

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white to yellow crystal powder Storage:Room temperature with sealed well Package:according to the clients requirement Applicatio

2-Bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Trading Company

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Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-bromo-4-tert-butylpyridine

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Other

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Shanghai Scochem Technology Co., Ltd.

High quality suppliers Application:healing drugs

2-Bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-Bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Trading Company

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LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

2-Bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Trading Company

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

2-Bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

WUHAN YING YUAN BEI TECHNOLOGY CO., LTD

in stock Assay:99% white powder dentification(HPLC) :The retention time of the major peak in the chromatogram of the assay preparation corresponds to that in the chromatogram of the Conformal standard preparation, as obtained in the ass

2-Bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:1 Kilogram

FOB Price: $160.0

Type:Trading Company

inquiry

ENAO Chemical Co, Limited

For quick quotation, please send us the inquiry include CAS#, Structure, Chemical Name, quantity, purity, as well as any additional specifications you require, we will try to get back to you within 24 hours. Our Services Besides manufacturing,

2-Bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xi'an Kaixiang Photoelectric Technology Co., Ltd

Superiority 1.Powerful & d team 2.Capacity for mass production,from grams to tons; 3.Various kinds of advanced equipment in the laboratory and factory; 4.Strict QC standard to meet the demand of customers,advanced equipment for anal

2-bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:1 Gram

FOB Price: $1.0

Type:Manufacturers

inquiry

Chemical Technology Co.,LTD

1. Production capacity: we have three production base with high-tech production equipment and instruments, equipped with professional production personnel, meet your requirements.2. Quality assurance: we have a first-class testing equipment and testi

2-Bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Other

inquiry

Changzhou Hopschain Chemical Co.,Ltd

We did before and have a mature technology.If you need NMR/HPLC,please contact with us Package:As your requrement Application:Intermediate Transportation:By Express

4-tert-butyl-2-bromopyridine

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Springchem New Material Technology Co.,Limited

≥99%, stock Application:OLED Transportation:by air, by sea

2-Bromo-4-(tert-butyl)pyridine

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Borun Chemical Co.,Ltd.

2-Bromo-4-(2-methyl-2-propanyl)pyridine

Cas:50488-34-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2-chloro-4-(1,1-dimethylethyl)pyridine
81167-60-4

2-chloro-4-(1,1-dimethylethyl)pyridine

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

Conditions
ConditionsYield
With trimethylsilyl bromide; propiononitrile for 21h; Reflux;100%
With trimethylsilyl bromide for 48h; Reflux;80%
C12H12F6LiNO

C12H12F6LiNO

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

Conditions
ConditionsYield
With 1,2-dibromo-1,1,2,2-tetrachloroethane In tetrahydrofuran; diethyl ether at -107℃;50%
4-tert-butylpyridine
3978-81-2

4-tert-butylpyridine

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

Conditions
ConditionsYield
Stage #1: 4-tert-butylpyridine With n-butyllithium; 2-(N,N-dimethylamino)ethanol at -5℃; for 1h; Inert atmosphere;
Stage #2: With carbon tetrabromide at -78 - 20℃; Inert atmosphere;
45%
Multi-step reaction with 3 steps
1: -78 °C
2: lithium 2,2,6,6-tetramethylpiperidide / tetrahydrofuran; diethyl ether / 1 h / -107 °C
3: 50 percent / (Cl2CBr)2 / tetrahydrofuran; diethyl ether / -107 °C
View Scheme
4-tert-butylpyridine N-oxide
23569-17-7

4-tert-butylpyridine N-oxide

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

Conditions
ConditionsYield
Stage #1: 4-tert-butylpyridine N-oxide With phosphorus(V) oxybromide In 1,2-dichloro-ethane at 20 - 70℃;
Stage #2: With water; sodium hydroxide In 1,2-dichloro-ethane pH=10; Cooling;
14%
Multi-step reaction with 2 steps
1: trichlorophosphate / 24 h / Reflux
2: trimethylsilyl bromide / 48 h / Reflux
View Scheme
Multi-step reaction with 2 steps
1: trichlorophosphate / 20 h / Cooling with ice; Reflux
2: trimethylsilyl bromide; propiononitrile / 21 h / Reflux
View Scheme
C12H13F6NO
87432-73-3

C12H13F6NO

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: lithium 2,2,6,6-tetramethylpiperidide / tetrahydrofuran; diethyl ether / 1 h / -107 °C
2: 50 percent / (Cl2CBr)2 / tetrahydrofuran; diethyl ether / -107 °C
View Scheme
2-bromo-9H-carbazole
3652-90-2

2-bromo-9H-carbazole

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

2-bromo-9-(4-(tert-butyl)pyridin-2-yl)-9H-carbazole

2-bromo-9-(4-(tert-butyl)pyridin-2-yl)-9H-carbazole

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 24h; Inert atmosphere;99%
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 130℃; for 24h; Inert atmosphere;99%
With 1-methyl-1H-imidazole; copper(l) iodide; lithium tert-butoxide In toluene at 20 - 130℃; for 48h; Inert atmosphere;99%
With 1-methyl-1H-imidazole; copper(l) iodide; potassium carbonate In toluene at 115 - 125℃; for 96h; Inert atmosphere;96%
With copper(l) iodide; potassium carbonate In toluene at 115 - 125℃; for 96h; Inert atmosphere;96%
6-bromo-2-methoxy-9H-carbazole

6-bromo-2-methoxy-9H-carbazole

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

C22H21BrN2O

C22H21BrN2O

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; trans-1,2-cyclohexanediamine In 1,4-dioxane at 120℃; for 12h;95%
2-(3-(3,5-dimethyl-1H-pyrazol-1-yl)phenoxy)-9H-carbazole
1393812-51-5

2-(3-(3,5-dimethyl-1H-pyrazol-1-yl)phenoxy)-9H-carbazole

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

2-(3-(3,5-dimethyl-1H-pyrazol-1-yl)phenoxy)-9-(4-tert-butylpyridin-2-yl)-9H-carbazole

2-(3-(3,5-dimethyl-1H-pyrazol-1-yl)phenoxy)-9-(4-tert-butylpyridin-2-yl)-9H-carbazole

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); johnphos; sodium t-butanolate In 1,4-dioxane; toluene at 95 - 105℃; for 48h; Inert atmosphere;94%
With tris-(dibenzylideneacetone)dipalladium(0); johnphos; sodium t-butanolate In 1,4-dioxane; toluene at 95 - 105℃; for 48h; Schlenk technique; Inert atmosphere; Sealed tube;94%
6-tert-butyl-2-methoxycarbazole

6-tert-butyl-2-methoxycarbazole

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

C26H30N2O

C26H30N2O

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 42h; Inert atmosphere;93%
3-methoxy-N-phenylaniline
101-16-6

3-methoxy-N-phenylaniline

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

4-(tert-butyl)-N-(3-methoxyphenyl)-N-phenylpyridin-2-amine

4-(tert-butyl)-N-(3-methoxyphenyl)-N-phenylpyridin-2-amine

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate In toluene for 18h; Reflux;89%
2'-(1H-pyrazol-1-yl)-9H-2,9'-bicarbazole

2'-(1H-pyrazol-1-yl)-9H-2,9'-bicarbazole

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

9-(4-tert-butylpyridin-2-yl)-2'-(1H-pyrazol-1-yl)-9H-2,9'-bicarbazole

9-(4-tert-butylpyridin-2-yl)-2'-(1H-pyrazol-1-yl)-9H-2,9'-bicarbazole

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); johnphos; sodium t-butanolate In 1,4-dioxane; toluene at 95 - 105℃; for 48h; Inert atmosphere;88%
2-(3-(4-phenyl-1H-pyrazol-1-yl)phenoxy)-9H-carbazole

2-(3-(4-phenyl-1H-pyrazol-1-yl)phenoxy)-9H-carbazole

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

9-(4-tert-butylpyridin-2-yl)-2-(3-(4-phenyl-1H-pyrazol-1-yl)phenoxy)-9H-carbazole

9-(4-tert-butylpyridin-2-yl)-2-(3-(4-phenyl-1H-pyrazol-1-yl)phenoxy)-9H-carbazole

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); johnphos; sodium t-butanolate In 1,4-dioxane; toluene at 100 - 110℃; for 39h; Inert atmosphere; Sealed tube;86%
With tris-(dibenzylideneacetone)dipalladium(0); johnphos In 1,4-dioxane; toluene at 100 - 110℃; for 39h; Schlenk technique; Inert atmosphere; Sealed tube;
2-methoxy-9H-carbazole
6933-49-9

2-methoxy-9H-carbazole

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

C22H22N2O

C22H22N2O

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; trans-1,2-cyclohexanediamine In 1,4-dioxane at 120℃; for 12h;85%
With potassium phosphate; copper(l) iodide; rac-diaminocyclohexane In 1,4-dioxane at 120℃; for 18h;80%
2-methoxy-6-methyl-(9H)-carbazole
32550-53-1

2-methoxy-6-methyl-(9H)-carbazole

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

C23H24N2O

C23H24N2O

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; copper(l) chloride; lithium tert-butoxide In toluene at 130℃; for 24h; Inert atmosphere;80%
2-amino-N-(2-(2-methyl-1H-indol-3-yl)ethyl)pyrimidine-5-carboxamide

2-amino-N-(2-(2-methyl-1H-indol-3-yl)ethyl)pyrimidine-5-carboxamide

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

2-((4-(tert-butyl)pyridin-2-yl)amino)-N-(2-(2-methyl-1H-indol-3-yl)ethyl)pyrimidine-5-carboxamide

2-((4-(tert-butyl)pyridin-2-yl)amino)-N-(2-(2-methyl-1H-indol-3-yl)ethyl)pyrimidine-5-carboxamide

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; Inert atmosphere;80%
tert-butyl (4S)-4-[(3Z)-3-tert-butylsulfinyliminopropyl]-2,2-dimethylpyrrolidine-1-carboxylate

tert-butyl (4S)-4-[(3Z)-3-tert-butylsulfinyliminopropyl]-2,2-dimethylpyrrolidine-1-carboxylate

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

tert-butyl (4S)-4-[3-(4-tert-butyl-2-pyridyl)-3-(tert-butylsulfinylamino)propyl]-2,2-dimethylpyrrolidine-1-carboxylate

tert-butyl (4S)-4-[3-(4-tert-butyl-2-pyridyl)-3-(tert-butylsulfinylamino)propyl]-2,2-dimethylpyrrolidine-1-carboxylate

Conditions
ConditionsYield
Stage #1: 4-(tert-butyl)-2-bromopyridine With n-butyllithium In diethyl ether; hexane at -70℃; for 0.666667h; Inert atmosphere;
Stage #2: tert-butyl (4S)-4-[(3Z)-3-tert-butylsulfinyliminopropyl]-2,2-dimethylpyrrolidine-1-carboxylate In tetrahydrofuran; diethyl ether; hexane at -78 - -40℃; for 0.75h; Inert atmosphere;
79%
4-ethoxycarbonyl-2-(pyridin-2-yl)pyridine N-oxide
1286763-08-3

4-ethoxycarbonyl-2-(pyridin-2-yl)pyridine N-oxide

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

4-tert-butyl-4'-ethoxycarbonyl-2,2':6',2''-terpyridine N'-oxide

4-tert-butyl-4'-ethoxycarbonyl-2,2':6',2''-terpyridine N'-oxide

Conditions
ConditionsYield
With potassium phosphate; methyldi-t-butylphosphine; palladium diacetate In toluene at 120℃; for 24h; Inert atmosphere; Glovebox;71%
4-ethoxycarbonyl-2-(4-methoxypyridin-2-yl)pyridine N-oxide
1286763-32-3

4-ethoxycarbonyl-2-(4-methoxypyridin-2-yl)pyridine N-oxide

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

4''-(tert-butyl)-4'-ethoxycarbonyl-4-methoxy-2,2':6',2''-terpyridine N'-oxide

4''-(tert-butyl)-4'-ethoxycarbonyl-4-methoxy-2,2':6',2''-terpyridine N'-oxide

Conditions
ConditionsYield
With potassium phosphate; methyldi-t-butylphosphine; palladium diacetate In toluene at 120℃; for 24h; Inert atmosphere; Glovebox;67%
4-ethoxycarbonyl-2-(6-methoxypyridin-2-yl)pyridine N-oxide
1286763-24-3

4-ethoxycarbonyl-2-(6-methoxypyridin-2-yl)pyridine N-oxide

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

4''-(tert-butyl)-4'-ethoxycarbonyl-6-methoxy-2,2':6',2''-terpyridine N'-oxide

4''-(tert-butyl)-4'-ethoxycarbonyl-6-methoxy-2,2':6',2''-terpyridine N'-oxide

Conditions
ConditionsYield
With potassium phosphate; methyldi-t-butylphosphine; palladium diacetate In toluene at 120℃; for 24h; Inert atmosphere; Glovebox;64%
2,2'-(oxybis(3,1-phenylene))bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)

2,2'-(oxybis(3,1-phenylene))bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

C30H32N2O

C30H32N2O

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water at 80℃; for 24h;64%
2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

4-(tert-butyl)-2-(4-(tert-butyl)phenyl)pyridine
808142-68-9

4-(tert-butyl)-2-(4-(tert-butyl)phenyl)pyridine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); ethanol; sodium carbonate In benzene at 70℃; for 48h; Suzuki coupling;61%
4'-tert-butyl-4-ethoxycarbonyl-2,2'-bipyridine N-oxide

4'-tert-butyl-4-ethoxycarbonyl-2,2'-bipyridine N-oxide

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

4,4''-bis(tert-butyl)-4'-ethoxycarbonyl-2,2':6′,2''-terpyridine N'-oxide

4,4''-bis(tert-butyl)-4'-ethoxycarbonyl-2,2':6′,2''-terpyridine N'-oxide

Conditions
ConditionsYield
With potassium phosphate; methyldi-t-butylphosphine; palladium diacetate In toluene at 120℃; for 24h; Inert atmosphere; Glovebox;59%
C15H22BF3N2O3

C15H22BF3N2O3

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

4-(tert-butyl)-2-(3-(trifluoromethyl)-1H-pyrazol-5-yl)pyridine
1026999-80-3

4-(tert-butyl)-2-(3-(trifluoromethyl)-1H-pyrazol-5-yl)pyridine

Conditions
ConditionsYield
Stage #1: C15H22BF3N2O3; 4-(tert-butyl)-2-bromopyridine With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 70℃;
Stage #2: With hydrogenchloride In 1,4-dioxane; water at 60℃;
58%
1H-imidazole
288-32-4

1H-imidazole

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

4-tert-butyl-2-(1H-imidazol-1-yl)pyridine
1261616-69-6

4-tert-butyl-2-(1H-imidazol-1-yl)pyridine

Conditions
ConditionsYield
With copper(l) iodide; potassium carbonate; L-proline In dimethyl sulfoxide at 75℃; for 47h; Ullmann coupling; Inert atmosphere;57%
ethyl isonicotinate N-oxide
14906-37-7

ethyl isonicotinate N-oxide

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

A

4'-tert-butyl-4-ethoxycarbonyl-2,2'-bipyridine N-oxide

4'-tert-butyl-4-ethoxycarbonyl-2,2'-bipyridine N-oxide

B

4,4''-bis(tert-butyl)-4'-ethoxycarbonyl-2,2':6′,2''-terpyridine N'-oxide

4,4''-bis(tert-butyl)-4'-ethoxycarbonyl-2,2':6′,2''-terpyridine N'-oxide

Conditions
ConditionsYield
With potassium phosphate; tri-tert-butyl phosphine; palladium diacetate In toluene at 120℃; for 24h; Concentration; Inert atmosphere; Glovebox;A 57%
B 7%
tert-butyl (3R)-3-[(3E)-3-tert-butylsulfinyliminopropyl]piperidine-1-carboxylate

tert-butyl (3R)-3-[(3E)-3-tert-butylsulfinyliminopropyl]piperidine-1-carboxylate

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

tert-butyl (3R)-3-[3-(4-tert-butyl-2-pyridyl)-3-(tert-butylsulfinylamino)propyl]piperidine-1-carboxylate

tert-butyl (3R)-3-[3-(4-tert-butyl-2-pyridyl)-3-(tert-butylsulfinylamino)propyl]piperidine-1-carboxylate

Conditions
ConditionsYield
Stage #1: 4-(tert-butyl)-2-bromopyridine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.75h;
Stage #2: tert-butyl (3R)-3-[(3E)-3-tert-butylsulfinyliminopropyl]piperidine-1-carboxylate In tetrahydrofuran; hexane at 20℃; for 4h;
57%
6-(methylsulfanyl)-2-(propan-2-yl)-1H,2H,3H-pyrazolo[3,4-d]pyrimidin-3-one
955368-93-1

6-(methylsulfanyl)-2-(propan-2-yl)-1H,2H,3H-pyrazolo[3,4-d]pyrimidin-3-one

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

1-(4-(tert-butyl)pyridin-2-yl)-2-isopropyl-6-(methylthio)-1,2-dihydro-3H-pyrazolo[3,4-d]pyrimidin-3-one

1-(4-(tert-butyl)pyridin-2-yl)-2-isopropyl-6-(methylthio)-1,2-dihydro-3H-pyrazolo[3,4-d]pyrimidin-3-one

Conditions
ConditionsYield
With copper(l) iodide; potassium carbonate; N,N`-dimethylethylenediamine In 1,4-dioxane at 90℃;56.5%
2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

phenylboronic acid
98-80-6

phenylboronic acid

4-(tert-butyl)-2-phenylpyridine
53911-36-7

4-(tert-butyl)-2-phenylpyridine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene Inert atmosphere; Reflux;55%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 70℃; for 16h; Inert atmosphere;
2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

2-bromo-4-(tert-butyl)-6-fluoropyridine

2-bromo-4-(tert-butyl)-6-fluoropyridine

Conditions
ConditionsYield
With silver(II) fluoride In acetonitrile at 20℃; Inert atmosphere; Autoclave;51%
2,2'-(4,6-difluoro-1,3-phenylene)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
1136948-11-2

2,2'-(4,6-difluoro-1,3-phenylene)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)

2-bromo-4-(tert-butyl)pyridine
50488-34-1

2-bromo-4-(tert-butyl)pyridine

1,5-bis(4-tert-butylpyridine-2-yl)-2,4-difluorobenzene

1,5-bis(4-tert-butylpyridine-2-yl)-2,4-difluorobenzene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate In 1,2-dimethoxyethane for 48h; Suzuki-Miyaura Coupling; Inert atmosphere; Reflux;50%
With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate In 1,2-dimethoxyethane for 48h; Reflux;50%

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