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Suzhou Sinosun Imp.&Exp. Corporation

We supply good quality 3-(4-Bromophenyl)-9-phenyl-9H-carbazole cas# 1028647-93-9 at competitive price. Our 3-(4-Bromophenyl)-9-phenyl-9H-carbazole cas# 1028647-93-9 has been exported to many countries and regions. If you are looking for 3-(4-Br

3-(4-Bromophenyl)-9-phenyl-9H-carbazole

Cas:1028647-93-9

Min.Order:1 Kilogram

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Puyang Huicheng Electronic Material Co., Ltd

1.Product introduction Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalys

manufacturer of 3-(4-bromophenyl)-N-phenylcarbazole

Cas:1028647-93-9

Min.Order:100 Gram

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

3-(4-Bromophenyl)-9-phenyl-9H-carbazole Manufacturer/High quality/Best price/In stock

Cas:1028647-93-9

Min.Order:1 Kilogram

FOB Price: $3.0

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 3-(4-Bromophenyl)-N-Phenylcarbazole supplier in China

Cas:1028647-93-9

Min.Order:0 Metric Ton

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Jinan Finer Chemical Co., Ltd

Product Description Product Name 3-(4-Bromophenyl)-9-phenyl-9H-carbazole CAS No. 1028647-93-9 Appearance White powder Assay ≥99% Capacity 100mt/year Min.packing 1

3-(4-Bromophenyl)-9-phenyl-9H-carbazole

Cas:1028647-93-9

Min.Order:1 Kilogram

FOB Price: $34.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production 2-phenylacetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carbon environ

3-(4-Bromophenyl)-9-phenyl-9H-carbazole CAS NO.1028647-93-9

Cas:1028647-93-9

Min.Order:100 Gram

FOB Price: $2.0

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Wuhan Fortuna Chemical Co.,Ltd

Unique advantages for 3-(4-Bromophenyl)-9-phenyl-9H-carbazole Cas 1028647-93-9 Guaranteed the purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Powder Storage:Store at room Package:25kg/drum A

Factory supply 3-(4-Bromophenyl)-9-phenyl-9H-carbazole Cas 1028647-93-9 with high purity

Cas:1028647-93-9

Min.Order:1 Kilogram

FOB Price: $20.0 / 200.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:OLED Intermediate Transportation:by air or by sea Port:Shanghai, Qingdao

3-(4-bromophenyl)-N-phenylcarbazole

Cas:1028647-93-9

Min.Order:1 Kilogram

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Type:Manufacturers

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Hangzhou Think Chemical Co. Ltd

3-(4-Bromophenyl)-9-phenyl-9H-carbazole CAS No.:1028647-93-9 Name: 3-(4-Bromophenyl)-9-phenyl-9H-carbazole Molecular Structure: Molecular Formula: C24H16BrN Molecular Weight: 398.29 CAS Regis

High purity 3-(4-Bromophenyl)-9-phenyl-9H-carbazole CAS No.:1028647-93-9

Cas:1028647-93-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Other

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Wuhan Kemi-Works Chemical Co., Ltd

ISO9001 Exporting Japan, Korea regularly. Appearance:Gray powder Storage:-- Package:25kg/ fibre drum Application:OLED intermediates Transportation:--- Port:Chinese port

Dibromo-9-phenylcarbazole

Cas:1028647-93-9

Min.Order:1 Gram

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Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 1028647-93-9 9H-Carbazole, 3-(4-bromophenyl)-9-phenyl- Manufacturer

Cas:1028647-93-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-(4-Bromophenyl)-9-phenyl-9H-carbazole

Cas:1028647-93-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Product Name: 3-(4-bromophenyl)-N-phenylcarbazole Synonyms: 3-(4-bromophenyl)-N-phenylcarbazole;3-(4-Bromophenyl)-9-phenyl-9H-carbazole;3-(4-broMophenyl)-9-phenyl Carbazole;N-phenyl-3-(4-broMophenyl)carbazole;3-(4-broMophenyl)-9-phenyl

1028647-93-9 3-(4-Bromophenyl)-9-phenyl-9H-carbazole

Cas:1028647-93-9

Min.Order:1 Gram

FOB Price: $8900.0

Type:Lab/Research institutions

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Leader Biochemical Group

About Product Details Item Specification Test Results Appearance White crystalline powder Conform

China Biggest factory Supply High Quality 3-(4-bromophenyl)-N-phenylcarbazole CAS 1028647-93-9

Cas:1028647-93-9

Min.Order:1 Kilogram

FOB Price: $1.0 / 5.0

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Ality Chemical Corporation

3-(4-bromophenyl)-N-phenylcarbazole Basic information Product Name: 3-(4-bromophenyl)-N-phenylcarbazole Synonyms: 3-(4-bromophenyl)-N-phenylcarbazole;3-(4-Bromophenyl)-9-phenyl-9H-carbazole;3-(4-broM

Factory Supply BrPPC

Cas:1028647-93-9

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

3-(4-bromophenyl)-N-phenylcarbazole CAS NO 1028647-93-9

Cas:1028647-93-9

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 1028647-93-9 with best quality

Cas:1028647-93-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS 1028647-93-9 ,3-(4-Bromophenyl)-9-phenyl-9H-Carbazole

Cas:1028647-93-9

Min.Order:10 Kilogram

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Henan Sinotech Import&Export Corporation

Name: 3-(4-Bromophenyl)-9-phenyl-carbazole Synonyms: 3-(4-bromophenyl)-9-phenyl-9H-Carbazole CAS:1028647-93-9 MF: C24H16BrN Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:OLED o

3-(4-Bromophenyl)-9-phenyl-carbazole CAS:1028647-93-9

Cas:1028647-93-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:Off-white solid Storage:R.T Package:100G/Bottle, 500G/Bottle, 1KG/Bottle or at customers reqirement. Application:Chemicals Transportation:Express/Sea/Air Port:Any port in China

99% 3-(4-Bromophenyl)-9-phenyl-9H-carbazole cas 1028647-93-9

Cas:1028647-93-9

Min.Order:100 Gram

FOB Price: $2.5 / 4.0

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

3-(4-Bromophenyl)-9-phenyl-9H-Carbazole 1028647-93-9

Cas:1028647-93-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

3-(4-bromophenyl)-N-phenylcarbazole CAS: 1028647-93-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high qu

3-(4-bromophenyl)-N-phenylcarbazole CAS: 1028647-93-9

Cas:1028647-93-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

3-(4-Bromophenyl)-9-phenyl-9H-Carbazole

Cas:1028647-93-9

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

3-(4-Bromophenyl)-9-phenyl-9H-Carbazole

Cas:1028647-93-9

Min.Order:0

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Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

BrPPC

Cas:1028647-93-9

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:As

3-(4-broMophenyl)-N-phenylcarbazole

Cas:1028647-93-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

BrPPC

Cas:1028647-93-9

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-(4-Bromophenyl)-9-phenyl-9H-Carbazole

Cas:1028647-93-9

Min.Order:0

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Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 3-(4-Bromophenyl)-N-phenylcarbazole

Cas:1028647-93-9

Min.Order:100 Gram

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Type:Other

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Hangzhou Lingrui Chemical Co.,Ltd.

Fast Delivery 1028647-93-9 best quality 3-(4-bromophenyl)-9-phenyl-9H-Carbazole in bulk supply 3-(4-bromophenyl)-9-phenylcarbazole is a white solid powder with a melting point of 136.0-140.0 °C, a boiling point of 560.5±32.0 °C(Predi

Synthetic route

N-phenyl-9H-carbazol-3-boronic acid
854952-58-2

N-phenyl-9H-carbazol-3-boronic acid

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 60℃; for 3h;92%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene at 90℃; for 8h; Inert atmosphere;88%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran for 24h; Reflux;78%
N-phenyl-9H-carbazol-3-boronic acid
854952-58-2

N-phenyl-9H-carbazol-3-boronic acid

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; sodium t-butanolate In toluene at 110℃; for 8h; Inert atmosphere;85.6%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

9-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-9H-carbazole
1126522-69-7

9-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 12h; Inert atmosphere; Reflux;81%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 12h; Inert atmosphere; Reflux;81%
With tetrakis(triphenylphosphine) palladium(0); sodium hydroxide In tetrahydrofuran; water at 80℃; Suzuki Coupling;77%
3-bromo-9-phenyl-9H-carbazole
1153-85-1

3-bromo-9-phenyl-9H-carbazole

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Stage #1: 1,4-bromoiodobenzene With iodine; magnesium In tetrahydrofuran for 2h; Inert atmosphere; Reflux;
Stage #2: 3-bromo-9-phenyl-9H-carbazole at 50 - 85℃; for 16h; Inert atmosphere;
77.4%
Stage #1: 3-bromo-9-phenyl-9H-carbazole With iodine; magnesium In tetrahydrofuran for 1h; Inert atmosphere; Reflux;
Stage #2: 1,4-bromoiodobenzene at 50 - 85℃; for 16h; Inert atmosphere;
75.3%
4-Bromophenylboronic acid
5467-74-3

4-Bromophenylboronic acid

3-iodo-9-phenyl-9H-carbazole
502161-03-7

3-iodo-9-phenyl-9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 65℃; for 7h;76%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 65℃; for 7h;76%
With potassium carbonate; palladium diacetate; tris-(o-tolyl)phosphine In 1,2-dimethoxyethane; water at 80℃; for 9.5h; Suzuki Coupling;49%
N-phenyl-9H-carbazol-3-boronic acid
854952-58-2

N-phenyl-9H-carbazol-3-boronic acid

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

A

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

B

1,4-bis(9-phenyl-9H-carbazol-3-yl)benzene

1,4-bis(9-phenyl-9H-carbazol-3-yl)benzene

Conditions
ConditionsYield
With potassium carbonate; palladium diacetate; tris-(o-tolyl)phosphine In ethanol; water; toluene at 80℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere;A 75%
B n/a
With potassium carbonate; palladium diacetate; tris-(o-tolyl)phosphine In ethanol; water; toluene at 80℃; for 6h; Inert atmosphere;
3-iodo-9-phenyl-9H-carbazole
502161-03-7

3-iodo-9-phenyl-9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: n-butyllithium / toluene; hexane; diethyl ether / 1 h / -45 - -5 °C / Inert atmosphere
1.2: 2 h / -45 °C
1.3: 20 °C
2.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Reflux; Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1.1: n-butyllithium / toluene; hexane; diethyl ether / 1 h / -45 - -5 °C / Inert atmosphere
1.2: 2 h / -45 °C / Inert atmosphere
1.3: 20 °C / Inert atmosphere
2.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 2 steps
1.1: n-butyllithium / toluene; hexane / 1 h / -45 - -5 °C / Inert atmosphere
1.2: 2 h / -45 °C
1.3: 20 °C
2.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Inert atmosphere; Reflux
View Scheme
N-phenylcarbazole
1150-62-5

N-phenylcarbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: potassium iodide; sulfuric acid; potassium iodate / ethanol / 2 h / 75 °C
2.1: n-butyllithium / toluene; hexane; diethyl ether / 1 h / -45 - -5 °C / Inert atmosphere
2.2: 2 h / -45 °C
2.3: 20 °C
3.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Reflux; Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1.1: potassium iodide; sulfuric acid; potassium iodate / ethanol / 2 h / 75 °C
2.1: n-butyllithium / toluene; hexane; diethyl ether / 1 h / -45 - -5 °C / Inert atmosphere
2.2: 2 h / -45 °C / Inert atmosphere
2.3: 20 °C / Inert atmosphere
3.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 3 steps
1.1: potassium iodide; sulfuric acid; potassium iodate / ethanol / 2 h / 75 °C
2.1: n-butyllithium / toluene; hexane / 1 h / -45 - -5 °C / Inert atmosphere
2.2: 2 h / -45 °C
2.3: 20 °C
3.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Inert atmosphere; Reflux
View Scheme
3-bromo-9-phenyl-9H-carbazole
1153-85-1

3-bromo-9-phenyl-9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -73 °C / Inert atmosphere
1.2: 4 h / Inert atmosphere
2.1: potassium phosphate; triphenylphosphine; palladium diacetate / toluene; ethanol; water / 2 h / 75 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 24 h
2: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / Reflux
View Scheme
Multi-step reaction with 2 steps
1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 24 h
2: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / Reflux
View Scheme
3-bromo-9-phenyl-9H-carbazole
1153-85-1

3-bromo-9-phenyl-9H-carbazole

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
With potassium carbonate; palladium In toluene at 80℃; for 12h; Inert atmosphere;
5-bromo-2-nitro-biphenyl
105971-15-1

5-bromo-2-nitro-biphenyl

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
2.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C
3.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C
3.2: 12 h / -78 - 20 °C
4.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux
2.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
3.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
3.2: 12 h / -78 - 20 °C / Inert atmosphere
4.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux
2.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
3.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
3.2: 12 h / -78 - 20 °C / Inert atmosphere
4.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 4 steps
1: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / N,N-dimethyl-formamide / 90 °C
2: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
3: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
4: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C
View Scheme
3-bromo-9H-carbazole
1592-95-6

3-bromo-9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C
2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C
2.2: 12 h / -78 - 20 °C
3.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Reflux
View Scheme
Multi-step reaction with 3 steps
1.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
2.2: 12 h / -78 - 20 °C / Inert atmosphere
3.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 3 steps
1.1: tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate / toluene / 24 h / 100 °C
2.1: n-butyllithium / hexane; diethyl ether / 0.5 h / -78 °C
2.2: -78 °C
2.3: 20 °C
3.1: sodium hydroxide; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran; water / 80 - 90 °C
View Scheme
Multi-step reaction with 3 steps
1.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
2.2: 12 h / -78 - 20 °C / Inert atmosphere
3.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 3 steps
1: sodium sulfate; potassium carbonate; copper / nitrobenzene / 195 °C
2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 90 °C
3: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / 80 °C
View Scheme
phenylboronic acid
98-80-6

phenylboronic acid

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 24 h / 80 °C
2.1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
3.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C
4.2: 12 h / -78 - 20 °C
5.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Reflux
View Scheme
Multi-step reaction with 5 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / Inert atmosphere; Reflux
2.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux
3.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
4.2: 12 h / -78 - 20 °C / Inert atmosphere
5.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 5 steps
1.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
2.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux
3.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
4.2: 12 h / -78 - 20 °C / Inert atmosphere
5.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 5 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
2: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / N,N-dimethyl-formamide / 90 °C
3: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
4: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
5: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C
View Scheme
2-iodo-1-nitro-4-bromobenzene
343864-78-8

2-iodo-1-nitro-4-bromobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 24 h / 80 °C
2.1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
3.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C
4.2: 12 h / -78 - 20 °C
5.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Reflux
View Scheme
Multi-step reaction with 5 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / Inert atmosphere; Reflux
2.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux
3.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
4.2: 12 h / -78 - 20 °C / Inert atmosphere
5.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 5 steps
1.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
2.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux
3.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
4.2: 12 h / -78 - 20 °C / Inert atmosphere
5.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 5 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
2: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / N,N-dimethyl-formamide / 90 °C
3: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
4: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
5: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C
View Scheme
iodobenzene
591-50-4

iodobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate / toluene / 24 h / 100 °C
2.1: n-butyllithium / hexane; diethyl ether / 0.5 h / -78 °C
2.2: -78 °C
2.3: 20 °C
3.1: sodium hydroxide; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran; water / 80 - 90 °C
View Scheme
Multi-step reaction with 3 steps
1: sodium sulfate; potassium carbonate; copper / nitrobenzene / 195 °C
2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 90 °C
3: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / 80 °C
View Scheme
9H-carbazole
86-74-8

9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 24 h / 140 °C
2.1: iodine; sulfuric acid / water; methanol / 20 h
3.1: magnesium / tetrahydrofuran / 12 h / 75 - 80 °C
3.2: 5 h / 0 °C
3.3: 2 h / 20 °C / Cooling
4.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / water; toluene / 12 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 24 h / 140 °C
2.1: iodine; sulfuric acid / methanol; water / 20 h / 5 °C / Cooling
3.1: magnesium; water / tetrahydrofuran / 12 h / 75 - 80 °C
3.2: 5 h / -20 - 0 °C
3.3: 2 h / 0 - 20 °C
4.1: potassium carbonate; triethylamine; tetrakis(triphenylphosphine) palladium(0) / toluene; water / 12 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1: sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine / toluene / 24 h / 100 °C
2: N-Bromosuccinimide / dichloromethane / 24 h / 20 °C
3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 24 h
4: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / Reflux
View Scheme
bromobenzene
108-86-1

bromobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 24 h / 140 °C
2.1: iodine; sulfuric acid / water; methanol / 20 h
3.1: magnesium / tetrahydrofuran / 12 h / 75 - 80 °C
3.2: 5 h / 0 °C
3.3: 2 h / 20 °C / Cooling
4.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / water; toluene / 12 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 24 h / 140 °C
2.1: iodine; sulfuric acid / methanol; water / 20 h / 5 °C / Cooling
3.1: magnesium; water / tetrahydrofuran / 12 h / 75 - 80 °C
3.2: 5 h / -20 - 0 °C
3.3: 2 h / 0 - 20 °C
4.1: potassium carbonate; triethylamine; tetrakis(triphenylphosphine) palladium(0) / toluene; water / 12 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1: sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine / toluene / 24 h / 100 °C
2: N-Bromosuccinimide / dichloromethane / 24 h / 20 °C
3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 24 h
4: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / Reflux
View Scheme
C18H20BNO4

C18H20BNO4

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
2: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
3: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C
View Scheme
C18H12BrNO2

C18H12BrNO2

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
2: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C
View Scheme
iodobenzene
591-50-4

iodobenzene

3-(4-bromophenyl)-9H-carbazole

3-(4-bromophenyl)-9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
With copper; potassium carbonate; sodium sulfate In nitrobenzene at 200℃;
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

9-phenyl-3-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole

9-phenyl-3-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In 1,4-dioxane at 100℃; for 12h; Inert atmosphere;99%
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In N,N-dimethyl-formamide for 8h; Inert atmosphere; Reflux;91%
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In N,N-dimethyl-formamide at 80℃; for 8h; Inert atmosphere;91%
dibenzothiophen-2-ylamine
7428-91-3

dibenzothiophen-2-ylamine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)dibenzo[b,d]thiophen-2-amine

N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)dibenzo[b,d]thiophen-2-amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere;96%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

4-Aminobiphenyl
92-67-1

4-Aminobiphenyl

N‐[4‐(9‐phenyl‐9H‐carbazol‐3‐yl)phenyl]‐[1,1'‐biphenyl]‐4‐amine
1160294-96-1

N‐[4‐(9‐phenyl‐9H‐carbazol‐3‐yl)phenyl]‐[1,1'‐biphenyl]‐4‐amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere;95%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; potassium tert-butylate In toluene at 85℃; for 2h;83%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; potassium tert-butylate In toluene at 85℃; for 1h;80%
9-ethyl-9H-carbazol-3-ylamine
132-32-1

9-ethyl-9H-carbazol-3-ylamine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

9-ethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-carbazol-3-amine

9-ethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-carbazol-3-amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere;95%
9,9-dimethyl-9H-fluoren-2-ylamine
108714-73-4

9,9-dimethyl-9H-fluoren-2-ylamine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

9,9-dimethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

9,9-dimethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Catalytic behavior; Inert atmosphere;94%
With 1,1'-bis(diisopropylphosphino)ferrocene; [Pd(dippf)(maleimide)]; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere; Sealed tube; Schlenk technique;94%
With 1,1'-bis(diisopropylphosphino)ferrocene; 1,1′-bis(diisopropylphosphino)ferrocene palladium(0)-maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Temperature; Buchwald-Hartwig Coupling; Schlenk technique; Sealed tube; Inert atmosphere;94%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 100℃; for 5h;85%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 90℃; for 6h; Inert atmosphere;74%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

9,9-diphenyl-9H-fluoren-2-ylamine

9,9-diphenyl-9H-fluoren-2-ylamine

9,9-diphenyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

9,9-diphenyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 24h; Inert atmosphere;93%
phenoxazine
135-67-1

phenoxazine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

C36H24N2O

C36H24N2O

Conditions
ConditionsYield
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 12h; Inert atmosphere; Reflux;92%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 12h; Inert atmosphere; Reflux;92%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

2-aminofluorene
153-78-6

2-aminofluorene

N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere;92%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

C24H15BrIN

C24H15BrIN

Conditions
ConditionsYield
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 2h;
Stage #2: With iodine In tetrahydrofuran at 0 - 20℃; for 20h;
90%
8-amino quinoline
578-66-5

8-amino quinoline

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

N,N-bis(4-(9-phenyl-9H-carbazol-3-yl)phenyl)quinolin-8-amine

N,N-bis(4-(9-phenyl-9H-carbazol-3-yl)phenyl)quinolin-8-amine

Conditions
ConditionsYield
With sodium hydroxide; nickel dichloride In N,N-dimethyl-formamide at 150℃; for 16h; Inert atmosphere; Glovebox; Sealed tube; Schlenk technique;90%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid
1240963-55-6

4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid

Conditions
ConditionsYield
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h; Inert atmosphere;
Stage #2: With Trimethyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 20h;
Stage #3: With hydrogenchloride In tetrahydrofuran; hexane; water for 7h;
88%
Trimethyl borate
121-43-7

Trimethyl borate

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid
1240963-55-6

4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid

Conditions
ConditionsYield
Stage #1: Trimethyl borate; 3-(4-bromophenyl)-9-phenyl-9H-carbazole In tetrahydrofuran at -78 - 20℃; for 20h; Inert atmosphere;
Stage #2: With hydrogenchloride In tetrahydrofuran; water for 7h;
88%
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 20h;
Stage #3: With hydrogenchloride In tetrahydrofuran; hexane; water for 7h; Inert atmosphere;
88%
dibenzo[b,d]furan-2-amine
3693-22-9

dibenzo[b,d]furan-2-amine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)dibenzo[b,d]furan-2-amine

N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)dibenzo[b,d]furan-2-amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere;88%
Trimethyl borate
121-43-7

Trimethyl borate

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

water
7732-18-5

water

4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid
1240963-55-6

4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid

Conditions
ConditionsYield
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 14h; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 20h;
Stage #3: water With hydrogenchloride In tetrahydrofuran; hexane for 7h;
88%
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Inert atmosphere;
Stage #2: Trimethyl borate at -78℃; Inert atmosphere;
Stage #3: water With hydrogenchloride for 0.5h; Inert atmosphere;
83.1%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

9-(naphthalen-2-yl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole

9-(naphthalen-2-yl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole

C46H30N2

C46H30N2

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 120℃; for 4h;87%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 120℃; for 4h;37%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 120℃; for 4h;37%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

1-Naphthylboronic acid
13922-41-3

1-Naphthylboronic acid

3-[4-(naphthalen-1-yl)phenyl]-9-phenyl-9H-carbazole
1365452-27-2

3-[4-(naphthalen-1-yl)phenyl]-9-phenyl-9H-carbazole

Conditions
ConditionsYield
With potassium carbonate; palladium diacetate; tris-(o-tolyl)phosphine In ethanol; water; toluene at 90℃; for 14h; Suzuki-Miyaura reaction; Inert atmosphere;86%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

C46H55NO4

C46H55NO4

C70H70N2O4

C70H70N2O4

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene; hexane at 100℃; for 8h; Inert atmosphere;86%
N‑(biphenyl‑4‑yl)‑9,9‑dimethyl‑9H‑fluorene‑2‑amine
897671-69-1

N‑(biphenyl‑4‑yl)‑9,9‑dimethyl‑9H‑fluorene‑2‑amine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

N-(1,1‘-biphenyl-4-yl)-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9,9-dimethyl-9H-fluoren-2-amine
1242056-42-3

N-(1,1‘-biphenyl-4-yl)-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9,9-dimethyl-9H-fluoren-2-amine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate In toluene at 100℃; for 24h;85%
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate In toluene at 100℃; for 24h;85%
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate In toluene at 100℃; for 24h;85%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

C34H23N3

C34H23N3

C58H38N4

C58H38N4

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene; toluene at 145℃;84%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

N-phenyl-1,2-benzenediamine
534-85-0

N-phenyl-1,2-benzenediamine

N1-phenyl-N2-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)benzene-1,2-diamine

N1-phenyl-N2-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)benzene-1,2-diamine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere;84%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

3-(3'-chloro-1,1'-biphenyl-4-yl)-9-phenyl-9H-carbazole

3-(3'-chloro-1,1'-biphenyl-4-yl)-9-phenyl-9H-carbazole

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; tris-(o-tolyl)phosphine In ethanol; water; toluene at 60 - 80℃; for 12h; Inert atmosphere;84%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

5,8-dihydro-5-phenyl-5,8-diazaindeno[2,1-c]fluorene

5,8-dihydro-5-phenyl-5,8-diazaindeno[2,1-c]fluorene

C48H31N3

C48H31N3

Conditions
ConditionsYield
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 16h; Reflux; Inert atmosphere;83%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene for 12h; Inert atmosphere; Reflux;77%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene; toluene for 12h; Reflux; Inert atmosphere;77%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

C38H27N

C38H27N

C62H42N2

C62H42N2

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 100℃; Buchwald-Hartwig Coupling;83%
N-[4-(1-naphthalenyl)phenyl]-phenyl-4-amine
897671-78-2

N-[4-(1-naphthalenyl)phenyl]-phenyl-4-amine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

(4-(1-naphthyl)-phenyl)-(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-phenyl-amine
1160294-63-2

(4-(1-naphthyl)-phenyl)-(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-phenyl-amine

Conditions
ConditionsYield
With sodium t-butanolate; tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0) In hexane; xylene at 120℃; for 4.5h; Product distribution / selectivity; Buchwald-Hartwig reaction;82%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

3,6-di(benzothiophen-4-yl)-9H-carbazole
1365891-56-0

3,6-di(benzothiophen-4-yl)-9H-carbazole

9-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-3,6-di(benzothiophen-4-yl)carbazole

9-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-3,6-di(benzothiophen-4-yl)carbazole

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; (1R,2R)-1,2-diaminocyclohexane In 1,4-dioxane for 24h; Reflux;82%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

1-(4'-aminophenyl)naphthalene
125404-00-4

1-(4'-aminophenyl)naphthalene

4-(1-naphthyl)-4'-(9-phenyl-9H-carbazol-3-yl)diphenylamine

4-(1-naphthyl)-4'-(9-phenyl-9H-carbazol-3-yl)diphenylamine

Conditions
ConditionsYield
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In hexane; toluene at 80 - 110℃; for 8h; Inert atmosphere;80%
With sodium t-butanolate; tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0) In hexane; toluene at 60 - 80℃; for 3h; Hartwig-Buchwald reaction; Inert atmosphere;63%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

C34H23N3

C34H23N3

C58H38N4

C58H38N4

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene; toluene at 145℃;80%

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