We supply good quality 3-(4-Bromophenyl)-9-phenyl-9H-carbazole cas# 1028647-93-9 at competitive price. Our 3-(4-Bromophenyl)-9-phenyl-9H-carbazole cas# 1028647-93-9 has been exported to many countries and regions. If you are looking for 3-(4-Br
Cas:1028647-93-9
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inquiry1.Product introduction Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalys
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inquiryDayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryProduct Description Product Name 3-(4-Bromophenyl)-9-phenyl-9H-carbazole CAS No. 1028647-93-9 Appearance White powder Assay ≥99% Capacity 100mt/year Min.packing 1
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inquiryHebei yanxi chemical co., LTD is a professional research, development and production 2-phenylacetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carbon environ
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inquiryUnique advantages for 3-(4-Bromophenyl)-9-phenyl-9H-carbazole Cas 1028647-93-9 Guaranteed the purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Powder Storage:Store at room Package:25kg/drum A
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inquiryhigh quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:OLED Intermediate Transportation:by air or by sea Port:Shanghai, Qingdao
Cas:1028647-93-9
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inquiry3-(4-Bromophenyl)-9-phenyl-9H-carbazole CAS No.:1028647-93-9 Name: 3-(4-Bromophenyl)-9-phenyl-9H-carbazole Molecular Structure: Molecular Formula: C24H16BrN Molecular Weight: 398.29 CAS Regis
Cas:1028647-93-9
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inquiryISO9001 Exporting Japan, Korea regularly. Appearance:Gray powder Storage:-- Package:25kg/ fibre drum Application:OLED intermediates Transportation:--- Port:Chinese port
1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
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inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
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inquiryProduct Name: 3-(4-bromophenyl)-N-phenylcarbazole Synonyms: 3-(4-bromophenyl)-N-phenylcarbazole;3-(4-Bromophenyl)-9-phenyl-9H-carbazole;3-(4-broMophenyl)-9-phenyl Carbazole;N-phenyl-3-(4-broMophenyl)carbazole;3-(4-broMophenyl)-9-phenyl
Cas:1028647-93-9
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inquiryAbout Product Details Item Specification Test Results Appearance White crystalline powder Conform
Cas:1028647-93-9
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inquiry3-(4-bromophenyl)-N-phenylcarbazole Basic information Product Name: 3-(4-bromophenyl)-N-phenylcarbazole Synonyms: 3-(4-bromophenyl)-N-phenylcarbazole;3-(4-Bromophenyl)-9-phenyl-9H-carbazole;3-(4-broM
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
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inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
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inquiryName: 3-(4-Bromophenyl)-9-phenyl-carbazole Synonyms: 3-(4-bromophenyl)-9-phenyl-9H-Carbazole CAS:1028647-93-9 MF: C24H16BrN Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:OLED o
Cas:1028647-93-9
Min.Order:1 Kilogram
FOB Price: $1.0
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inquiryAppearance:Off-white solid Storage:R.T Package:100G/Bottle, 500G/Bottle, 1KG/Bottle or at customers reqirement. Application:Chemicals Transportation:Express/Sea/Air Port:Any port in China
Cas:1028647-93-9
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inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
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inquiry3-(4-bromophenyl)-N-phenylcarbazole CAS: 1028647-93-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high qu
Cas:1028647-93-9
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
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inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:As
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inquiryA substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
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Cas:1028647-93-9
Min.Order:100 Gram
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inquiryFast Delivery 1028647-93-9 best quality 3-(4-bromophenyl)-9-phenyl-9H-Carbazole in bulk supply 3-(4-bromophenyl)-9-phenylcarbazole is a white solid powder with a melting point of 136.0-140.0 °C, a boiling point of 560.5±32.0 °C(Predi
Cas:1028647-93-9
Min.Order:1 Gram
Negotiable
Type:Other
inquiryN-phenyl-9H-carbazol-3-boronic acid
1,4-bromoiodobenzene
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 60℃; for 3h; | 92% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene at 90℃; for 8h; Inert atmosphere; | 88% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran for 24h; Reflux; | 78% |
N-phenyl-9H-carbazol-3-boronic acid
1.4-dibromobenzene
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; sodium t-butanolate In toluene at 110℃; for 8h; Inert atmosphere; | 85.6% |
1,4-bromoiodobenzene
9-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-9H-carbazole
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 12h; Inert atmosphere; Reflux; | 81% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 12h; Inert atmosphere; Reflux; | 81% |
With tetrakis(triphenylphosphine) palladium(0); sodium hydroxide In tetrahydrofuran; water at 80℃; Suzuki Coupling; | 77% |
3-bromo-9-phenyl-9H-carbazole
1,4-bromoiodobenzene
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Stage #1: 1,4-bromoiodobenzene With iodine; magnesium In tetrahydrofuran for 2h; Inert atmosphere; Reflux; Stage #2: 3-bromo-9-phenyl-9H-carbazole at 50 - 85℃; for 16h; Inert atmosphere; | 77.4% |
Stage #1: 3-bromo-9-phenyl-9H-carbazole With iodine; magnesium In tetrahydrofuran for 1h; Inert atmosphere; Reflux; Stage #2: 1,4-bromoiodobenzene at 50 - 85℃; for 16h; Inert atmosphere; | 75.3% |
4-Bromophenylboronic acid
3-iodo-9-phenyl-9H-carbazole
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 65℃; for 7h; | 76% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 65℃; for 7h; | 76% |
With potassium carbonate; palladium diacetate; tris-(o-tolyl)phosphine In 1,2-dimethoxyethane; water at 80℃; for 9.5h; Suzuki Coupling; | 49% |
N-phenyl-9H-carbazol-3-boronic acid
1,4-bromoiodobenzene
A
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With potassium carbonate; palladium diacetate; tris-(o-tolyl)phosphine In ethanol; water; toluene at 80℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere; | A 75% B n/a |
With potassium carbonate; palladium diacetate; tris-(o-tolyl)phosphine In ethanol; water; toluene at 80℃; for 6h; Inert atmosphere; |
3-iodo-9-phenyl-9H-carbazole
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: n-butyllithium / toluene; hexane; diethyl ether / 1 h / -45 - -5 °C / Inert atmosphere 1.2: 2 h / -45 °C 1.3: 20 °C 2.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Reflux; Inert atmosphere View Scheme | |
Multi-step reaction with 2 steps 1.1: n-butyllithium / toluene; hexane; diethyl ether / 1 h / -45 - -5 °C / Inert atmosphere 1.2: 2 h / -45 °C / Inert atmosphere 1.3: 20 °C / Inert atmosphere 2.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 2 steps 1.1: n-butyllithium / toluene; hexane / 1 h / -45 - -5 °C / Inert atmosphere 1.2: 2 h / -45 °C 1.3: 20 °C 2.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Inert atmosphere; Reflux View Scheme |
N-phenylcarbazole
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1.1: potassium iodide; sulfuric acid; potassium iodate / ethanol / 2 h / 75 °C 2.1: n-butyllithium / toluene; hexane; diethyl ether / 1 h / -45 - -5 °C / Inert atmosphere 2.2: 2 h / -45 °C 2.3: 20 °C 3.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Reflux; Inert atmosphere View Scheme | |
Multi-step reaction with 3 steps 1.1: potassium iodide; sulfuric acid; potassium iodate / ethanol / 2 h / 75 °C 2.1: n-butyllithium / toluene; hexane; diethyl ether / 1 h / -45 - -5 °C / Inert atmosphere 2.2: 2 h / -45 °C / Inert atmosphere 2.3: 20 °C / Inert atmosphere 3.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 3 steps 1.1: potassium iodide; sulfuric acid; potassium iodate / ethanol / 2 h / 75 °C 2.1: n-butyllithium / toluene; hexane / 1 h / -45 - -5 °C / Inert atmosphere 2.2: 2 h / -45 °C 2.3: 20 °C 3.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Inert atmosphere; Reflux View Scheme |
3-bromo-9-phenyl-9H-carbazole
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -73 °C / Inert atmosphere 1.2: 4 h / Inert atmosphere 2.1: potassium phosphate; triphenylphosphine; palladium diacetate / toluene; ethanol; water / 2 h / 75 °C / Inert atmosphere View Scheme | |
Multi-step reaction with 2 steps 1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 24 h 2: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / Reflux View Scheme | |
Multi-step reaction with 2 steps 1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 24 h 2: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / Reflux View Scheme |
3-bromo-9-phenyl-9H-carbazole
1.4-dibromobenzene
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With potassium carbonate; palladium In toluene at 80℃; for 12h; Inert atmosphere; |
5-bromo-2-nitro-biphenyl
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C 2.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C 3.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C 3.2: 12 h / -78 - 20 °C 4.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Reflux View Scheme | |
Multi-step reaction with 4 steps 1.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux 2.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux 3.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere 3.2: 12 h / -78 - 20 °C / Inert atmosphere 4.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 4 steps 1.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux 2.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux 3.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere 3.2: 12 h / -78 - 20 °C / Inert atmosphere 4.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 4 steps 1: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / N,N-dimethyl-formamide / 90 °C 2: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C 3: triphenylphosphine / 1,2-dichloro-benzene / 200 °C 4: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C View Scheme |
3-bromo-9H-carbazole
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C 2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C 2.2: 12 h / -78 - 20 °C 3.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Reflux View Scheme | |
Multi-step reaction with 3 steps 1.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux 2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere 2.2: 12 h / -78 - 20 °C / Inert atmosphere 3.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 3 steps 1.1: tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate / toluene / 24 h / 100 °C 2.1: n-butyllithium / hexane; diethyl ether / 0.5 h / -78 °C 2.2: -78 °C 2.3: 20 °C 3.1: sodium hydroxide; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran; water / 80 - 90 °C View Scheme | |
Multi-step reaction with 3 steps 1.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux 2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere 2.2: 12 h / -78 - 20 °C / Inert atmosphere 3.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 3 steps 1: sodium sulfate; potassium carbonate; copper / nitrobenzene / 195 °C 2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 90 °C 3: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / 80 °C View Scheme |
phenylboronic acid
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 24 h / 80 °C 2.1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C 3.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C 4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C 4.2: 12 h / -78 - 20 °C 5.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Reflux View Scheme | |
Multi-step reaction with 5 steps 1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / Inert atmosphere; Reflux 2.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux 3.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux 4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere 4.2: 12 h / -78 - 20 °C / Inert atmosphere 5.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 5 steps 1.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux 2.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux 3.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux 4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere 4.2: 12 h / -78 - 20 °C / Inert atmosphere 5.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 5 steps 1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C 2: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / N,N-dimethyl-formamide / 90 °C 3: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C 4: triphenylphosphine / 1,2-dichloro-benzene / 200 °C 5: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C View Scheme |
2-iodo-1-nitro-4-bromobenzene
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 24 h / 80 °C 2.1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C 3.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C 4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C 4.2: 12 h / -78 - 20 °C 5.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Reflux View Scheme | |
Multi-step reaction with 5 steps 1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / Inert atmosphere; Reflux 2.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux 3.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux 4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere 4.2: 12 h / -78 - 20 °C / Inert atmosphere 5.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 5 steps 1.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux 2.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux 3.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux 4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere 4.2: 12 h / -78 - 20 °C / Inert atmosphere 5.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux View Scheme | |
Multi-step reaction with 5 steps 1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C 2: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / N,N-dimethyl-formamide / 90 °C 3: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C 4: triphenylphosphine / 1,2-dichloro-benzene / 200 °C 5: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C View Scheme |
iodobenzene
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1.1: tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate / toluene / 24 h / 100 °C 2.1: n-butyllithium / hexane; diethyl ether / 0.5 h / -78 °C 2.2: -78 °C 2.3: 20 °C 3.1: sodium hydroxide; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran; water / 80 - 90 °C View Scheme | |
Multi-step reaction with 3 steps 1: sodium sulfate; potassium carbonate; copper / nitrobenzene / 195 °C 2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 90 °C 3: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / 80 °C View Scheme |
9H-carbazole
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 24 h / 140 °C 2.1: iodine; sulfuric acid / water; methanol / 20 h 3.1: magnesium / tetrahydrofuran / 12 h / 75 - 80 °C 3.2: 5 h / 0 °C 3.3: 2 h / 20 °C / Cooling 4.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / water; toluene / 12 h / Reflux View Scheme | |
Multi-step reaction with 4 steps 1.1: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 24 h / 140 °C 2.1: iodine; sulfuric acid / methanol; water / 20 h / 5 °C / Cooling 3.1: magnesium; water / tetrahydrofuran / 12 h / 75 - 80 °C 3.2: 5 h / -20 - 0 °C 3.3: 2 h / 0 - 20 °C 4.1: potassium carbonate; triethylamine; tetrakis(triphenylphosphine) palladium(0) / toluene; water / 12 h / Reflux View Scheme | |
Multi-step reaction with 4 steps 1: sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine / toluene / 24 h / 100 °C 2: N-Bromosuccinimide / dichloromethane / 24 h / 20 °C 3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 24 h 4: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / Reflux View Scheme |
bromobenzene
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 24 h / 140 °C 2.1: iodine; sulfuric acid / water; methanol / 20 h 3.1: magnesium / tetrahydrofuran / 12 h / 75 - 80 °C 3.2: 5 h / 0 °C 3.3: 2 h / 20 °C / Cooling 4.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / water; toluene / 12 h / Reflux View Scheme | |
Multi-step reaction with 4 steps 1.1: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 24 h / 140 °C 2.1: iodine; sulfuric acid / methanol; water / 20 h / 5 °C / Cooling 3.1: magnesium; water / tetrahydrofuran / 12 h / 75 - 80 °C 3.2: 5 h / -20 - 0 °C 3.3: 2 h / 0 - 20 °C 4.1: potassium carbonate; triethylamine; tetrakis(triphenylphosphine) palladium(0) / toluene; water / 12 h / Reflux View Scheme | |
Multi-step reaction with 4 steps 1: sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine / toluene / 24 h / 100 °C 2: N-Bromosuccinimide / dichloromethane / 24 h / 20 °C 3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 24 h 4: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / Reflux View Scheme |
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C 2: triphenylphosphine / 1,2-dichloro-benzene / 200 °C 3: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C View Scheme |
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C 2: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C View Scheme |
iodobenzene
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With copper; potassium carbonate; sodium sulfate In nitrobenzene at 200℃; |
3-(4-bromophenyl)-9-phenyl-9H carbazole
bis(pinacol)diborane
Conditions | Yield |
---|---|
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In 1,4-dioxane at 100℃; for 12h; Inert atmosphere; | 99% |
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In N,N-dimethyl-formamide for 8h; Inert atmosphere; Reflux; | 91% |
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In N,N-dimethyl-formamide at 80℃; for 8h; Inert atmosphere; | 91% |
dibenzothiophen-2-ylamine
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere; | 96% |
3-(4-bromophenyl)-9-phenyl-9H carbazole
4-Aminobiphenyl
N‐[4‐(9‐phenyl‐9H‐carbazol‐3‐yl)phenyl]‐[1,1'‐biphenyl]‐4‐amine
Conditions | Yield |
---|---|
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere; | 95% |
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; potassium tert-butylate In toluene at 85℃; for 2h; | 83% |
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; potassium tert-butylate In toluene at 85℃; for 1h; | 80% |
9-ethyl-9H-carbazol-3-ylamine
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere; | 95% |
9,9-dimethyl-9H-fluoren-2-ylamine
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Catalytic behavior; Inert atmosphere; | 94% |
With 1,1'-bis(diisopropylphosphino)ferrocene; [Pd(dippf)(maleimide)]; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere; Sealed tube; Schlenk technique; | 94% |
With 1,1'-bis(diisopropylphosphino)ferrocene; 1,1′-bis(diisopropylphosphino)ferrocene palladium(0)-maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Temperature; Buchwald-Hartwig Coupling; Schlenk technique; Sealed tube; Inert atmosphere; | 94% |
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 100℃; for 5h; | 85% |
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 90℃; for 6h; Inert atmosphere; | 74% |
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 24h; Inert atmosphere; | 93% |
Conditions | Yield |
---|---|
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 12h; Inert atmosphere; Reflux; | 92% |
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 12h; Inert atmosphere; Reflux; | 92% |
3-(4-bromophenyl)-9-phenyl-9H carbazole
2-aminofluorene
Conditions | Yield |
---|---|
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere; | 92% |
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 2h; Stage #2: With iodine In tetrahydrofuran at 0 - 20℃; for 20h; | 90% |
8-amino quinoline
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With sodium hydroxide; nickel dichloride In N,N-dimethyl-formamide at 150℃; for 16h; Inert atmosphere; Glovebox; Sealed tube; Schlenk technique; | 90% |
3-(4-bromophenyl)-9-phenyl-9H carbazole
4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid
Conditions | Yield |
---|---|
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h; Inert atmosphere; Stage #2: With Trimethyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 20h; Stage #3: With hydrogenchloride In tetrahydrofuran; hexane; water for 7h; | 88% |
Trimethyl borate
3-(4-bromophenyl)-9-phenyl-9H carbazole
4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid
Conditions | Yield |
---|---|
Stage #1: Trimethyl borate; 3-(4-bromophenyl)-9-phenyl-9H-carbazole In tetrahydrofuran at -78 - 20℃; for 20h; Inert atmosphere; Stage #2: With hydrogenchloride In tetrahydrofuran; water for 7h; | 88% |
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h; Inert atmosphere; Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 20h; Stage #3: With hydrogenchloride In tetrahydrofuran; hexane; water for 7h; Inert atmosphere; | 88% |
dibenzo[b,d]furan-2-amine
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere; | 88% |
Trimethyl borate
3-(4-bromophenyl)-9-phenyl-9H carbazole
water
4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid
Conditions | Yield |
---|---|
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 14h; Inert atmosphere; Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 20h; Stage #3: water With hydrogenchloride In tetrahydrofuran; hexane for 7h; | 88% |
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Inert atmosphere; Stage #2: Trimethyl borate at -78℃; Inert atmosphere; Stage #3: water With hydrogenchloride for 0.5h; Inert atmosphere; | 83.1% |
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 120℃; for 4h; | 87% |
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 120℃; for 4h; | 37% |
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 120℃; for 4h; | 37% |
3-(4-bromophenyl)-9-phenyl-9H carbazole
1-Naphthylboronic acid
3-[4-(naphthalen-1-yl)phenyl]-9-phenyl-9H-carbazole
Conditions | Yield |
---|---|
With potassium carbonate; palladium diacetate; tris-(o-tolyl)phosphine In ethanol; water; toluene at 90℃; for 14h; Suzuki-Miyaura reaction; Inert atmosphere; | 86% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene; hexane at 100℃; for 8h; Inert atmosphere; | 86% |
N‑(biphenyl‑4‑yl)‑9,9‑dimethyl‑9H‑fluorene‑2‑amine
3-(4-bromophenyl)-9-phenyl-9H carbazole
N-(1,1‘-biphenyl-4-yl)-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9,9-dimethyl-9H-fluoren-2-amine
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate In toluene at 100℃; for 24h; | 85% |
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate In toluene at 100℃; for 24h; | 85% |
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate In toluene at 100℃; for 24h; | 85% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene; toluene at 145℃; | 84% |
3-(4-bromophenyl)-9-phenyl-9H carbazole
N-phenyl-1,2-benzenediamine
Conditions | Yield |
---|---|
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere; | 84% |
3-(4-bromophenyl)-9-phenyl-9H carbazole
3-chlorophenylboronic acid
Conditions | Yield |
---|---|
With palladium diacetate; potassium carbonate; tris-(o-tolyl)phosphine In ethanol; water; toluene at 60 - 80℃; for 12h; Inert atmosphere; | 84% |
3-(4-bromophenyl)-9-phenyl-9H carbazole
Conditions | Yield |
---|---|
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 16h; Reflux; Inert atmosphere; | 83% |
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene for 12h; Inert atmosphere; Reflux; | 77% |
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene; toluene for 12h; Reflux; Inert atmosphere; | 77% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 100℃; Buchwald-Hartwig Coupling; | 83% |
N-[4-(1-naphthalenyl)phenyl]-phenyl-4-amine
3-(4-bromophenyl)-9-phenyl-9H carbazole
(4-(1-naphthyl)-phenyl)-(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-phenyl-amine
Conditions | Yield |
---|---|
With sodium t-butanolate; tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0) In hexane; xylene at 120℃; for 4.5h; Product distribution / selectivity; Buchwald-Hartwig reaction; | 82% |
3-(4-bromophenyl)-9-phenyl-9H carbazole
3,6-di(benzothiophen-4-yl)-9H-carbazole
Conditions | Yield |
---|---|
With potassium phosphate; copper(l) iodide; (1R,2R)-1,2-diaminocyclohexane In 1,4-dioxane for 24h; Reflux; | 82% |
3-(4-bromophenyl)-9-phenyl-9H carbazole
1-(4'-aminophenyl)naphthalene
Conditions | Yield |
---|---|
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In hexane; toluene at 80 - 110℃; for 8h; Inert atmosphere; | 80% |
With sodium t-butanolate; tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0) In hexane; toluene at 60 - 80℃; for 3h; Hartwig-Buchwald reaction; Inert atmosphere; | 63% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene; toluene at 145℃; | 80% |
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