Product Name

  • Name

    3-(4-bromophenyl)-N-phenylcarbazole

  • EINECS 807-969-6
  • CAS No. 1028647-93-9
  • Article Data59
  • CAS DataBase
  • Density 1.329 g/cm3
  • Solubility
  • Melting Point 136.0 to 140.0 °C
  • Formula C24H16BrN
  • Boiling Point 560.518 °C at 760 mmHg
  • Molecular Weight 398.302
  • Flash Point 292.791 °C
  • Transport Information
  • Appearance
  • Safety
  • Risk Codes
  • Molecular Structure Molecular Structure of 1028647-93-9 (3-(4-bromophenyl)-N-phenylcarbazole)
  • Hazard Symbols
  • Synonyms 3-(4-bromophenyl)-N-phenyl-9H-Carbazole;
  • PSA 4.93000
  • LogP 7.21320

Synthetic route

N-phenyl-9H-carbazol-3-boronic acid
854952-58-2

N-phenyl-9H-carbazol-3-boronic acid

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 60℃; for 3h;92%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene at 90℃; for 8h; Inert atmosphere;88%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran for 24h; Reflux;78%
N-phenyl-9H-carbazol-3-boronic acid
854952-58-2

N-phenyl-9H-carbazol-3-boronic acid

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; sodium t-butanolate In toluene at 110℃; for 8h; Inert atmosphere;85.6%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

9-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-9H-carbazole
1126522-69-7

9-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 12h; Inert atmosphere; Reflux;81%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 12h; Inert atmosphere; Reflux;81%
With tetrakis(triphenylphosphine) palladium(0); sodium hydroxide In tetrahydrofuran; water at 80℃; Suzuki Coupling;77%
3-bromo-9-phenyl-9H-carbazole
1153-85-1

3-bromo-9-phenyl-9H-carbazole

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Stage #1: 1,4-bromoiodobenzene With iodine; magnesium In tetrahydrofuran for 2h; Inert atmosphere; Reflux;
Stage #2: 3-bromo-9-phenyl-9H-carbazole at 50 - 85℃; for 16h; Inert atmosphere;		77.4%
Stage #1: 3-bromo-9-phenyl-9H-carbazole With iodine; magnesium In tetrahydrofuran for 1h; Inert atmosphere; Reflux;
Stage #2: 1,4-bromoiodobenzene at 50 - 85℃; for 16h; Inert atmosphere;		75.3%
4-Bromophenylboronic acid
5467-74-3

4-Bromophenylboronic acid

3-iodo-9-phenyl-9H-carbazole
502161-03-7

3-iodo-9-phenyl-9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 65℃; for 7h;76%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 65℃; for 7h;76%
With potassium carbonate; palladium diacetate; tris-(o-tolyl)phosphine In 1,2-dimethoxyethane; water at 80℃; for 9.5h; Suzuki Coupling;49%
N-phenyl-9H-carbazol-3-boronic acid
854952-58-2

N-phenyl-9H-carbazol-3-boronic acid

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

A

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

B

1,4-bis(9-phenyl-9H-carbazol-3-yl)benzene

1,4-bis(9-phenyl-9H-carbazol-3-yl)benzene

Conditions
ConditionsYield
With potassium carbonate; palladium diacetate; tris-(o-tolyl)phosphine In ethanol; water; toluene at 80℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere;A 75%
B n/a
With potassium carbonate; palladium diacetate; tris-(o-tolyl)phosphine In ethanol; water; toluene at 80℃; for 6h; Inert atmosphere;
...Expand
3-iodo-9-phenyl-9H-carbazole
502161-03-7

3-iodo-9-phenyl-9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: n-butyllithium / toluene; hexane; diethyl ether / 1 h / -45 - -5 °C / Inert atmosphere
1.2: 2 h / -45 °C
1.3: 20 °C
2.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Reflux; Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1.1: n-butyllithium / toluene; hexane; diethyl ether / 1 h / -45 - -5 °C / Inert atmosphere
1.2: 2 h / -45 °C / Inert atmosphere
1.3: 20 °C / Inert atmosphere
2.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 2 steps
1.1: n-butyllithium / toluene; hexane / 1 h / -45 - -5 °C / Inert atmosphere
1.2: 2 h / -45 °C
1.3: 20 °C
2.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Inert atmosphere; Reflux
View Scheme
N-phenylcarbazole
1150-62-5

N-phenylcarbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: potassium iodide; sulfuric acid; potassium iodate / ethanol / 2 h / 75 °C
2.1: n-butyllithium / toluene; hexane; diethyl ether / 1 h / -45 - -5 °C / Inert atmosphere
2.2: 2 h / -45 °C
2.3: 20 °C
3.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Reflux; Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1.1: potassium iodide; sulfuric acid; potassium iodate / ethanol / 2 h / 75 °C
2.1: n-butyllithium / toluene; hexane; diethyl ether / 1 h / -45 - -5 °C / Inert atmosphere
2.2: 2 h / -45 °C / Inert atmosphere
2.3: 20 °C / Inert atmosphere
3.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 3 steps
1.1: potassium iodide; sulfuric acid; potassium iodate / ethanol / 2 h / 75 °C
2.1: n-butyllithium / toluene; hexane / 1 h / -45 - -5 °C / Inert atmosphere
2.2: 2 h / -45 °C
2.3: 20 °C
3.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; water / 10 h / Inert atmosphere; Reflux
View Scheme
3-bromo-9-phenyl-9H-carbazole
1153-85-1

3-bromo-9-phenyl-9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -73 °C / Inert atmosphere
1.2: 4 h / Inert atmosphere
2.1: potassium phosphate; triphenylphosphine; palladium diacetate / toluene; ethanol; water / 2 h / 75 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 24 h
2: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / Reflux
View Scheme
Multi-step reaction with 2 steps
1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 24 h
2: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / Reflux
View Scheme
3-bromo-9-phenyl-9H-carbazole
1153-85-1

3-bromo-9-phenyl-9H-carbazole

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
With potassium carbonate; palladium In toluene at 80℃; for 12h; Inert atmosphere;
5-bromo-2-nitro-biphenyl
105971-15-1

5-bromo-2-nitro-biphenyl

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
2.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C
3.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C
3.2: 12 h / -78 - 20 °C
4.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux
2.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
3.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
3.2: 12 h / -78 - 20 °C / Inert atmosphere
4.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux
2.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
3.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
3.2: 12 h / -78 - 20 °C / Inert atmosphere
4.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 4 steps
1: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / N,N-dimethyl-formamide / 90 °C
2: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
3: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
4: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C
View Scheme
3-bromo-9H-carbazole
1592-95-6

3-bromo-9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C
2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C
2.2: 12 h / -78 - 20 °C
3.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Reflux
View Scheme
Multi-step reaction with 3 steps
1.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
2.2: 12 h / -78 - 20 °C / Inert atmosphere
3.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 3 steps
1.1: tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate / toluene / 24 h / 100 °C
2.1: n-butyllithium / hexane; diethyl ether / 0.5 h / -78 °C
2.2: -78 °C
2.3: 20 °C
3.1: sodium hydroxide; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran; water / 80 - 90 °C
View Scheme
Multi-step reaction with 3 steps
1.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
2.2: 12 h / -78 - 20 °C / Inert atmosphere
3.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 3 steps
1: sodium sulfate; potassium carbonate; copper / nitrobenzene / 195 °C
2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 90 °C
3: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / 80 °C
View Scheme
phenylboronic acid
98-80-6

phenylboronic acid

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 24 h / 80 °C
2.1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
3.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C
4.2: 12 h / -78 - 20 °C
5.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Reflux
View Scheme
Multi-step reaction with 5 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / Inert atmosphere; Reflux
2.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux
3.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
4.2: 12 h / -78 - 20 °C / Inert atmosphere
5.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 5 steps
1.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
2.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux
3.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
4.2: 12 h / -78 - 20 °C / Inert atmosphere
5.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 5 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
2: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / N,N-dimethyl-formamide / 90 °C
3: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
4: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
5: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C
View Scheme
2-iodo-1-nitro-4-bromobenzene
343864-78-8

2-iodo-1-nitro-4-bromobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 24 h / 80 °C
2.1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
3.1: potassium carbonate; sodium sulfate; copper / nitrobenzene / 200 °C
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C
4.2: 12 h / -78 - 20 °C
5.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Reflux
View Scheme
Multi-step reaction with 5 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / Inert atmosphere; Reflux
2.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux
3.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
4.2: 12 h / -78 - 20 °C / Inert atmosphere
5.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 5 steps
1.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
2.1: triphenylphosphine / 1,2-dichloro-benzene / Inert atmosphere; Reflux
3.1: potassium carbonate; copper / nitrobenzene / 16 h / Inert atmosphere; Reflux
4.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
4.2: 12 h / -78 - 20 °C / Inert atmosphere
5.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 24 h / Inert atmosphere; Reflux
View Scheme
Multi-step reaction with 5 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
2: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / N,N-dimethyl-formamide / 90 °C
3: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
4: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
5: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C
View Scheme
iodobenzene
591-50-4

iodobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate / toluene / 24 h / 100 °C
2.1: n-butyllithium / hexane; diethyl ether / 0.5 h / -78 °C
2.2: -78 °C
2.3: 20 °C
3.1: sodium hydroxide; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran; water / 80 - 90 °C
View Scheme
Multi-step reaction with 3 steps
1: sodium sulfate; potassium carbonate; copper / nitrobenzene / 195 °C
2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 90 °C
3: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / 80 °C
View Scheme
9H-carbazole
86-74-8

9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 24 h / 140 °C
2.1: iodine; sulfuric acid / water; methanol / 20 h
3.1: magnesium / tetrahydrofuran / 12 h / 75 - 80 °C
3.2: 5 h / 0 °C
3.3: 2 h / 20 °C / Cooling
4.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / water; toluene / 12 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 24 h / 140 °C
2.1: iodine; sulfuric acid / methanol; water / 20 h / 5 °C / Cooling
3.1: magnesium; water / tetrahydrofuran / 12 h / 75 - 80 °C
3.2: 5 h / -20 - 0 °C
3.3: 2 h / 0 - 20 °C
4.1: potassium carbonate; triethylamine; tetrakis(triphenylphosphine) palladium(0) / toluene; water / 12 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1: sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine / toluene / 24 h / 100 °C
2: N-Bromosuccinimide / dichloromethane / 24 h / 20 °C
3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 24 h
4: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / Reflux
View Scheme
bromobenzene
108-86-1

bromobenzene

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 24 h / 140 °C
2.1: iodine; sulfuric acid / water; methanol / 20 h
3.1: magnesium / tetrahydrofuran / 12 h / 75 - 80 °C
3.2: 5 h / 0 °C
3.3: 2 h / 20 °C / Cooling
4.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / water; toluene / 12 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1.1: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 24 h / 140 °C
2.1: iodine; sulfuric acid / methanol; water / 20 h / 5 °C / Cooling
3.1: magnesium; water / tetrahydrofuran / 12 h / 75 - 80 °C
3.2: 5 h / -20 - 0 °C
3.3: 2 h / 0 - 20 °C
4.1: potassium carbonate; triethylamine; tetrakis(triphenylphosphine) palladium(0) / toluene; water / 12 h / Reflux
View Scheme
Multi-step reaction with 4 steps
1: sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine / toluene / 24 h / 100 °C
2: N-Bromosuccinimide / dichloromethane / 24 h / 20 °C
3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 24 h
4: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / Reflux
View Scheme
C18H20BNO4

C18H20BNO4

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 80 °C
2: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
3: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C
View Scheme
C18H12BrNO2

C18H12BrNO2

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: triphenylphosphine / 1,2-dichloro-benzene / 200 °C
2: sodium sulfate; copper; potassium carbonate / nitrobenzene / 200 °C
View Scheme
iodobenzene
591-50-4

iodobenzene

3-(4-bromophenyl)-9H-carbazole

3-(4-bromophenyl)-9H-carbazole

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

Conditions
ConditionsYield
With copper; potassium carbonate; sodium sulfate In nitrobenzene at 200℃;
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

9-phenyl-3-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole

9-phenyl-3-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In 1,4-dioxane at 100℃; for 12h; Inert atmosphere;99%
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In N,N-dimethyl-formamide for 8h; Inert atmosphere; Reflux;91%
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In N,N-dimethyl-formamide at 80℃; for 8h; Inert atmosphere;91%
dibenzothiophen-2-ylamine
7428-91-3

dibenzothiophen-2-ylamine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)dibenzo[b,d]thiophen-2-amine

N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)dibenzo[b,d]thiophen-2-amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere;96%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

4-Aminobiphenyl
92-67-1

4-Aminobiphenyl

N‐[4‐(9‐phenyl‐9H‐carbazol‐3‐yl)phenyl]‐[1,1'‐biphenyl]‐4‐amine
1160294-96-1

N‐[4‐(9‐phenyl‐9H‐carbazol‐3‐yl)phenyl]‐[1,1'‐biphenyl]‐4‐amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere;95%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; potassium tert-butylate In toluene at 85℃; for 2h;83%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; potassium tert-butylate In toluene at 85℃; for 1h;80%
9-ethyl-9H-carbazol-3-ylamine
132-32-1

9-ethyl-9H-carbazol-3-ylamine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

9-ethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-carbazol-3-amine

9-ethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-carbazol-3-amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere;95%
9,9-dimethyl-9H-fluoren-2-ylamine
108714-73-4

9,9-dimethyl-9H-fluoren-2-ylamine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

9,9-dimethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

9,9-dimethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Catalytic behavior; Inert atmosphere;94%
With 1,1'-bis(diisopropylphosphino)ferrocene; [Pd(dippf)(maleimide)]; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere; Sealed tube; Schlenk technique;94%
With 1,1'-bis(diisopropylphosphino)ferrocene; 1,1′-bis(diisopropylphosphino)ferrocene palladium(0)-maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Temperature; Buchwald-Hartwig Coupling; Schlenk technique; Sealed tube; Inert atmosphere;94%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 100℃; for 5h;85%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 90℃; for 6h; Inert atmosphere;74%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

9,9-diphenyl-9H-fluoren-2-ylamine

9,9-diphenyl-9H-fluoren-2-ylamine

9,9-diphenyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

9,9-diphenyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 24h; Inert atmosphere;93%
phenoxazine
135-67-1

phenoxazine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

C36H24N2O

C36H24N2O

Conditions
ConditionsYield
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 12h; Inert atmosphere; Reflux;92%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 12h; Inert atmosphere; Reflux;92%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

2-aminofluorene
153-78-6

2-aminofluorene

N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere;92%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

C24H15BrIN

C24H15BrIN

Conditions
ConditionsYield
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 2h;
Stage #2: With iodine In tetrahydrofuran at 0 - 20℃; for 20h;		90%
8-amino quinoline
578-66-5

8-amino quinoline

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

N,N-bis(4-(9-phenyl-9H-carbazol-3-yl)phenyl)quinolin-8-amine

N,N-bis(4-(9-phenyl-9H-carbazol-3-yl)phenyl)quinolin-8-amine

Conditions
ConditionsYield
With sodium hydroxide; nickel dichloride In N,N-dimethyl-formamide at 150℃; for 16h; Inert atmosphere; Glovebox; Sealed tube; Schlenk technique;90%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid
1240963-55-6

4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid

Conditions
ConditionsYield
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h; Inert atmosphere;
Stage #2: With Trimethyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 20h;
Stage #3: With hydrogenchloride In tetrahydrofuran; hexane; water for 7h;		88%
Trimethyl borate
121-43-7

Trimethyl borate

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid
1240963-55-6

4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid

Conditions
ConditionsYield
Stage #1: Trimethyl borate; 3-(4-bromophenyl)-9-phenyl-9H-carbazole In tetrahydrofuran at -78 - 20℃; for 20h; Inert atmosphere;
Stage #2: With hydrogenchloride In tetrahydrofuran; water for 7h;		88%
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 20h;
Stage #3: With hydrogenchloride In tetrahydrofuran; hexane; water for 7h; Inert atmosphere;		88%
dibenzo[b,d]furan-2-amine
3693-22-9

dibenzo[b,d]furan-2-amine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)dibenzo[b,d]furan-2-amine

N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)dibenzo[b,d]furan-2-amine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere;88%
Trimethyl borate
121-43-7

Trimethyl borate

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

water
7732-18-5

water

4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid
1240963-55-6

4-(9-phenyl-9H-carbazol-3-yl)phenylboronic acid

Conditions
ConditionsYield
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 14h; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 20h;
Stage #3: water With hydrogenchloride In tetrahydrofuran; hexane for 7h;		88%
Stage #1: 3-(4-bromophenyl)-9-phenyl-9H-carbazole With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Inert atmosphere;
Stage #2: Trimethyl borate at -78℃; Inert atmosphere;
Stage #3: water With hydrogenchloride for 0.5h; Inert atmosphere;		83.1%
...Expand
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

9-(naphthalen-2-yl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole

9-(naphthalen-2-yl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole

C46H30N2

C46H30N2

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 120℃; for 4h;87%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 120℃; for 4h;37%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 120℃; for 4h;37%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

1-Naphthylboronic acid
13922-41-3

1-Naphthylboronic acid

3-[4-(naphthalen-1-yl)phenyl]-9-phenyl-9H-carbazole
1365452-27-2

3-[4-(naphthalen-1-yl)phenyl]-9-phenyl-9H-carbazole

Conditions
ConditionsYield
With potassium carbonate; palladium diacetate; tris-(o-tolyl)phosphine In ethanol; water; toluene at 90℃; for 14h; Suzuki-Miyaura reaction; Inert atmosphere;86%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

C46H55NO4

C46H55NO4

C70H70N2O4

C70H70N2O4

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene; hexane at 100℃; for 8h; Inert atmosphere;86%
N‑(biphenyl‑4‑yl)‑9,9‑dimethyl‑9H‑fluorene‑2‑amine
897671-69-1

N‑(biphenyl‑4‑yl)‑9,9‑dimethyl‑9H‑fluorene‑2‑amine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

N-(1,1‘-biphenyl-4-yl)-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9,9-dimethyl-9H-fluoren-2-amine
1242056-42-3

N-(1,1‘-biphenyl-4-yl)-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9,9-dimethyl-9H-fluoren-2-amine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate In toluene at 100℃; for 24h;85%
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate In toluene at 100℃; for 24h;85%
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate In toluene at 100℃; for 24h;85%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

C34H23N3

C34H23N3

C58H38N4

C58H38N4

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene; toluene at 145℃;84%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

N-phenyl-1,2-benzenediamine
534-85-0

N-phenyl-1,2-benzenediamine

N1-phenyl-N2-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)benzene-1,2-diamine

N1-phenyl-N2-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)benzene-1,2-diamine

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; Pd(dippf)maleimide; sodium t-butanolate In toluene at 70℃; for 20h; Inert atmosphere;84%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

3-(3'-chloro-1,1'-biphenyl-4-yl)-9-phenyl-9H-carbazole

3-(3'-chloro-1,1'-biphenyl-4-yl)-9-phenyl-9H-carbazole

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; tris-(o-tolyl)phosphine In ethanol; water; toluene at 60 - 80℃; for 12h; Inert atmosphere;84%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

5,8-dihydro-5-phenyl-5,8-diazaindeno[2,1-c]fluorene

5,8-dihydro-5-phenyl-5,8-diazaindeno[2,1-c]fluorene

C48H31N3

C48H31N3

Conditions
ConditionsYield
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 16h; Reflux; Inert atmosphere;83%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene for 12h; Inert atmosphere; Reflux;77%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene; toluene for 12h; Reflux; Inert atmosphere;77%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

C38H27N

C38H27N

C62H42N2

C62H42N2

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 100℃; Buchwald-Hartwig Coupling;83%
N-[4-(1-naphthalenyl)phenyl]-phenyl-4-amine
897671-78-2

N-[4-(1-naphthalenyl)phenyl]-phenyl-4-amine

3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

(4-(1-naphthyl)-phenyl)-(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-phenyl-amine
1160294-63-2

(4-(1-naphthyl)-phenyl)-(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-phenyl-amine

Conditions
ConditionsYield
With sodium t-butanolate; tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0) In hexane; xylene at 120℃; for 4.5h; Product distribution / selectivity; Buchwald-Hartwig reaction;82%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

3,6-di(benzothiophen-4-yl)-9H-carbazole
1365891-56-0

3,6-di(benzothiophen-4-yl)-9H-carbazole

9-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-3,6-di(benzothiophen-4-yl)carbazole

9-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-3,6-di(benzothiophen-4-yl)carbazole

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; (1R,2R)-1,2-diaminocyclohexane In 1,4-dioxane for 24h; Reflux;82%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

1-(4'-aminophenyl)naphthalene
125404-00-4

1-(4'-aminophenyl)naphthalene

4-(1-naphthyl)-4'-(9-phenyl-9H-carbazol-3-yl)diphenylamine

4-(1-naphthyl)-4'-(9-phenyl-9H-carbazol-3-yl)diphenylamine

Conditions
ConditionsYield
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In hexane; toluene at 80 - 110℃; for 8h; Inert atmosphere;80%
With sodium t-butanolate; tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0) In hexane; toluene at 60 - 80℃; for 3h; Hartwig-Buchwald reaction; Inert atmosphere;63%
3-(4-bromophenyl)-9-phenyl-9H carbazole
1028647-93-9

3-(4-bromophenyl)-9-phenyl-9H carbazole

C34H23N3

C34H23N3

C58H38N4

C58H38N4

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene; toluene at 145℃;80%

3-(4-Bromophenyl)-9-phenyl-9H-Carbazole Specification

The 3-(4-Bromophenyl)-9-phenyl-9H-Carbazole, with the CAS registry number 1028647-93-9, has the molecular formula C24H16BrN. In addition, its molecular weight is 398.2945. Its systematic name is called 3-(4-bromophenyl)-9-phenyl-carbazole.

Physical properties of 3-(4-Bromophenyl)-9-phenyl-9H-Carbazole: (1)ACD/LogP: 8.22; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 8.218; (4)ACD/LogD (pH 7.4): 8.218; (5)ACD/BCF (pH 5.5): 1000000; (6)ACD/BCF (pH 7.4): 1000000; (7)ACD/KOC (pH 5.5): 703901.313; (8)ACD/KOC (pH 7.4): 703901.313; (9)#H bond acceptors: 1; (10)#Freely Rotating Bonds: 2; (11)Index of Refraction: 1.67; (12)Molar Refractivity: 111.922 cm3; (13)Molar Volume: 299.596 cm3; (14)Surface Tension: 47.057 dyne/cm; (15)Density: 1.329 g/cm3; (16)Flash Point: 292.791 °C; (17)Enthalpy of Vaporization: 84.312 kJ/mol; (18)Boiling Point: 560.518 °C at 760 mmHg; (19)Vapour Pressure: 0 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: c1ccc(cc1)n2c3ccccc3c4c2ccc(c4)c5ccc(cc5)Br
(2)InChI: InChI=1/C24H16BrN/c25-19-13-10-17(11-14-19)18-12-15-24-22(16-18)21-8-4-5-9-23(21)26(24)20-6-2-1-3-7-20/h1-16H
(3)InChIKey: JEYLGFCAZBGCMC-UHFFFAOYAI

Related Products

Hot Products

Post buying leads

About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia

Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog

©2008 LookChem.com,License: ICP

NO.:Zhejiang16009103

complaints:service@lookchem.com Desktop View