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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

DISULFURYL FLUORIDEDISCONTINUED WHEN STOCK SOLD 4/10/00 CAS 13036-75-4

Cas:13036-75-4

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS 13036-75-4 ,disulfuryl difluoride

Cas:13036-75-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Disulfuryl fluoride

Cas:13036-75-4

Min.Order:1 Gram

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Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Disulfuryl fluoride

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

disulfuryl difluoride

Cas:13036-75-4

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Disulfuryl fluoride

Cas:13036-75-4

Min.Order:10 Gram

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Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

disulfuryl difluoride

Cas:13036-75-4

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

DISULFURYL FLUORIDEDISCONTINUED WHEN STOCK SOLD 4/10/00

Cas:13036-75-4

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

disulfuryl difluoride

Cas:13036-75-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

disulfuryl difluoride

Cas:13036-75-4

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis:

Disulfuryl fluoride

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

disulfuryl difluoride

Cas:13036-75-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

Disulfuryl fluoride

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Trading Company

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Disulfuryl fluoride

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

DISULFURYL FLUORIDEDISCONTINUED WHEN STOCK SOLD 4/10/00

Cas:13036-75-4

Min.Order:0

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Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Disulfuryl fluoride

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

DISULFURYL FLUORIDEDISCONTINUED WHEN STOCK SOLD 4/10/00

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

factory?direct?sale Application:healing drugs

Disulfuryl fluoride

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

disulfuryl difluoride

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

disulfuryl difluoride Application:disulfuryl difluoride

disulfuryl difluoride

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Other

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DB BIOTECH CO., LTD

best seller Application:API

DISULFURYL FLUORIDEDISCONTINUED WHEN STOCK SOLD 4/10/00

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Trading Company

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

DISULFURYL FLUORIDEDISCONTINUED WHEN STOCK SOLD 4/10/00

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. is focused on customization, research and development and production of APIs and advanced intermediates, which can effectively compensate for the deficiencies of traditional CRO and CMO. Priority of high-tech barri

disulfuryl difluoride

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hunan Longxianng Runhui Trading Co.,Ltd

disulfuryl difluorideAppearance:ASK Storage:Keep in dry and cool condition Package:foil aluminium bag/vacuum packing Application:intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airpor

disulfuryl difluoride

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

13036-75-4

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Saiwante (shanghai) New Material Technology Co., Ltd.

Stable supply of goods and provision of high-quality services Application:As raw materials in the field of medicine and biology

disulfuryl difluoride

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Trading Company

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Hebei Muhuang Technology Co., Ltd

best seller Application:API

DISULFURYL FLUORIDEDISCONTINUED WHEN STOCK SOLD 4/10/00

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

DISULFURYL FLUORIDEDISCONTINUED WHEN STOCK SOLD 4/10/00

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Disulfuryl fluoride

Cas:13036-75-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jusheng Technology Co., Ltd.,

1,Best Quality: Our products have exported to Germany, Spain, UK, USA, Australia, Middle East, and so on other countries, and we have got very good feedback from our customers.so

disulfuryl difluoride

Cas:13036-75-4

Min.Order:10 Gram

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Synthetic route

chlorine fluorosulfate
13997-90-5

chlorine fluorosulfate

Dichlorodifluoromethane
75-71-8

Dichlorodifluoromethane

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

Conditions
ConditionsYield
With SbF5 In fluorosulphonic acid byproducts: CF2O; bubbling CF2Cl2 through a mixt. of ClOSO2F, SbF5, and HSO3F, <=40°C, 2 h;81.5%
platinum tetrakis(fluorosulfate)

platinum tetrakis(fluorosulfate)

carbon monoxide
201230-82-2

carbon monoxide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

tetrakis(carbonyl)platinum(II) hexakis(fluorosulfato)platinate(IV)

tetrakis(carbonyl)platinum(II) hexakis(fluorosulfato)platinate(IV)

Conditions
ConditionsYield
In fluorosulphonic acid byproducts: CO2; condensing CO into a reactor contg. a soln. of Pt(SO3F)4 in HSO3F to give an initial pressure of 2 atm and stirring the soln. at room temp. overnight; removal of all volatiles in vacuo and further addn. of CO to the soln., formation of a yellow ppt. after CO additions over 2 d, filtn. of the ppt. and drying in vacuo over 2 d at ambient temp., elem. anal.;A n/a
B 80%
bis(fluorosulfuryl) peroxide
13709-32-5

bis(fluorosulfuryl) peroxide

trifluoromethylsulfide
1493-15-8

trifluoromethylsulfide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

C

sulfur dioxide
7446-09-5

sulfur dioxide

D

sulfur
7704-34-9

sulfur

Conditions
ConditionsYield
CF3SH:S2O6F2 molar ratio 1:1, from -183 to +25°C;A n/a
B 30%
C n/a
D n/a
dinitrogen difluoride
10578-16-2

dinitrogen difluoride

sulfur dioxide
7446-09-5

sulfur dioxide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

fluorosulfonyl fluoride
640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

C

thionyl tetrafluoride
173009-97-7, 118492-84-5, 13709-54-1

thionyl tetrafluoride

D

thionyl fluoride
7783-42-8

thionyl fluoride

Conditions
ConditionsYield
byproducts: N2O, N2;
difluoroether
7783-41-7

difluoroether

sulfur trioxide
7446-11-9

sulfur trioxide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

fluorosulfonyl fluoride
640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

C

sulfuryl difluoroperoxyde
13997-94-9

sulfuryl difluoroperoxyde

Conditions
ConditionsYield
Irradiation (UV/VIS); excess OF2;A n/a
B n/a
C <1
difluoroether
7783-41-7

difluoroether

sulfur trioxide
7446-11-9

sulfur trioxide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

sulfuryl difluoroperoxyde
13997-94-9

sulfuryl difluoroperoxyde

Conditions
ConditionsYield
Irradiation (UV/VIS); 365 nm, room temp.;A n/a
B >99
sulfur trioxide
7446-11-9

sulfur trioxide

sodium fluoride

sodium fluoride

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

Conditions
ConditionsYield
150°C for 3 h with excess SO3;
3 h boiling of NaF and excess SO3 under backflow;
fluorosulfuryl hypofluorite
13536-85-1

fluorosulfuryl hypofluorite

sulfur dioxide
7446-09-5

sulfur dioxide

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

Conditions
ConditionsYield
in nitrogen stream, in Ni-apparatus, 195°C, the reaction takes place at 25°C in 6 d;
fluorosulfuryl hypofluorite
13536-85-1

fluorosulfuryl hypofluorite

sulfur dioxide
7446-09-5

sulfur dioxide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

fluorosulfonyl fluoride
640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

C

trisulfuryl fluoride
13709-33-6

trisulfuryl fluoride

Conditions
ConditionsYield
Kinetics; in nitrogen stream, in Ni-apparatus, 60-120°C;
fluorosulfuryl hypofluorite
13536-85-1

fluorosulfuryl hypofluorite

sulfur dioxide
7446-09-5

sulfur dioxide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

fluorosulfonyl fluoride
640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

C

trisulfuryl fluoride
13709-33-6

trisulfuryl fluoride

D

bis(fluorosulfuryl) peroxide
13709-32-5

bis(fluorosulfuryl) peroxide

Conditions
ConditionsYield
other Radiation; photochemical reaction with 253.7 nm radiation, 15-25°C, if the conc. of SO2 very small more FSO2OOSO2F forms;
boron trifluoride
7637-07-2

boron trifluoride

sulfur trioxide
7446-11-9

sulfur trioxide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

trisulfuryl fluoride
13709-33-6

trisulfuryl fluoride

C

S4O11F2
13709-34-7

S4O11F2

D

S5O14F2

S5O14F2

E

S6O17F2

S6O17F2

Conditions
ConditionsYield
With sulfuric acid room temp., 70% H2SO4, further products;
calcium fluoride

calcium fluoride

sulfur trioxide
7446-11-9

sulfur trioxide

A

calcium sulfate

calcium sulfate

B

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

Conditions
ConditionsYield
byproducts: H2SO4; 100-300°C with excess SO3, then -25°C with 60-98% H2SO4;
byproducts: H2SO4; 100-300°C with excess SO3, then -25°C with 60-98% H2SO4;
sodium fluorosulfonate
14483-63-7

sodium fluorosulfonate

sulfur trioxide
7446-11-9

sulfur trioxide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

sodium fluoride

sodium fluoride

C

sodium sulfate
7757-82-6

sodium sulfate

Conditions
ConditionsYield
140°C;
sulfur tetrafluoride
7783-60-0

sulfur tetrafluoride

sulfur trioxide
7446-11-9

sulfur trioxide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

fluorosulfonyl fluoride
640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

C

thionyl fluoride
7783-42-8

thionyl fluoride

Conditions
ConditionsYield
50-150 °C, exclusion of oxygen, SO3:SF4 = 1:2;
50-150 °C, exclusion of oxygen, SO3:SF4 = 1:2;
sulfur trioxide
7446-11-9

sulfur trioxide

antimony pentafluoride
7783-70-2

antimony pentafluoride

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

fluorosulfonyl fluoride
640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

C

trisulfuryl fluoride
13709-33-6

trisulfuryl fluoride

D

S4O11F2
13709-34-7

S4O11F2

E

SbF4(1+)*SO3F(1-)=SbF4(SO3F)
16056-51-2

SbF4(1+)*SO3F(1-)=SbF4(SO3F)

Conditions
ConditionsYield
further products;
further products;
sulfur trioxide
7446-11-9

sulfur trioxide

antimony pentafluoride
7783-70-2

antimony pentafluoride

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

Sb2O(SO4)4

Sb2O(SO4)4

Conditions
ConditionsYield
antimony dichloride trifluoride
7791-16-4

antimony dichloride trifluoride

sulfur trioxide
7446-11-9

sulfur trioxide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

fluorosulfonylchloride
13637-84-8

fluorosulfonylchloride

Conditions
ConditionsYield
sulfur trioxide
7446-11-9

sulfur trioxide

fluorosulphonic acid
7789-21-1

fluorosulphonic acid

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

Conditions
ConditionsYield
In further solvent(s) 100°C, some h, closed tube in H2SO3F;
In further solvent(s) 100°C, some h, closed tube in H2SO3F;
vanadium pentafluoride
7783-72-4, 44247-54-3

vanadium pentafluoride

sulfur trioxide
7446-11-9

sulfur trioxide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

vanadium(V) oxytrifluoride
13709-31-4, 20888-71-5

vanadium(V) oxytrifluoride

Conditions
ConditionsYield
room temp.;
room temp.;
sulfur trioxide
7446-11-9

sulfur trioxide

iodine pentafluoride

iodine pentafluoride

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

Conditions
ConditionsYield
in a steel bomb;
sulfur trioxide
7446-11-9

sulfur trioxide

iodine pentafluoride

iodine pentafluoride

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

trisulfuryl fluoride
13709-33-6

trisulfuryl fluoride

C

bis(fluorosulfuryl) peroxide
13709-32-5

bis(fluorosulfuryl) peroxide

D

BrF2(1+)*SO3F(1-)=BrF2SO3F
31299-19-1

BrF2(1+)*SO3F(1-)=BrF2SO3F

E

bromine(I) fluorosulfate
13997-93-8

bromine(I) fluorosulfate

Conditions
ConditionsYield
byproducts: Br2(1+); liquid N2 temp.;
sulfur trioxide
7446-11-9

sulfur trioxide

potassium tetrafluoroborate
14075-53-7

potassium tetrafluoroborate

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

trisulfuryl fluoride
13709-33-6

trisulfuryl fluoride

C

S4O11F2
13709-34-7

S4O11F2

D

S5O14F2

S5O14F2

E

S6O17F2

S6O17F2

Conditions
ConditionsYield
With sulfuric acid room temp., 70% H2SO4, further products;
sulfur trioxide
7446-11-9

sulfur trioxide

fluorine
7782-41-4

fluorine

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

Conditions
ConditionsYield
silver(II) fluoride In neat (no solvent) heating a SO3/N2/F2 at 100°C;;
silver(II) fluoride In neat (no solvent) heating a SO3/N2/F2 at 100°C;;
sulfur trioxide
7446-11-9

sulfur trioxide

fluorine
7782-41-4

fluorine

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

fluorosulfuryl hypofluorite
13536-85-1

fluorosulfuryl hypofluorite

C

bis(fluorosulfuryl) peroxide
13709-32-5

bis(fluorosulfuryl) peroxide

Conditions
ConditionsYield
In gas 170 °C, 2 equiv. of SO3;A n/a
B <1
C n/a
Irradiation (UV/VIS); λ=313 nm, excess F2;
bis(fluoroxy)difluoromethane
16282-67-0

bis(fluoroxy)difluoromethane

sulfur trioxide
7446-11-9

sulfur trioxide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

Carbonyl fluoride
353-50-4

Carbonyl fluoride

C

oxygen
80937-33-3

oxygen

Conditions
ConditionsYield
Irradiation (UV/VIS); at UV light;
selenium
7782-49-2

selenium

bis(fluorosulfuryl) peroxide
13709-32-5

bis(fluorosulfuryl) peroxide

A

selenium(IV) oxide
7446-08-4

selenium(IV) oxide

B

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

Conditions
ConditionsYield
detected by electrical conductivity, freezing point and absorption spectrum;
pyrosulfuryl chloride
7791-27-7

pyrosulfuryl chloride

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

fluorosulfonyl fluoride
640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

C

fluorosulfonylchloride
13637-84-8

fluorosulfonylchloride

Conditions
ConditionsYield
In not givenA 0%
B n/a
C n/a
In not givenA 0%
B n/a
C n/a
fluorosulfonyl radical
12159-89-6

fluorosulfonyl radical

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

Conditions
ConditionsYield
In neat (no solvent, gas phase) Kinetics; Irradiation (UV/VIS); kinetics studied at 298 K; FSO2 and FSO3 radicals generated by 193-nm laser flash photolysis of FS(O2)O(O2)SF at total CO pressure ranging from 130 to 800 mbar; not isolated, detected by absorption spectroscopy;
bis(fluorosulfuryl) peroxide
13709-32-5

bis(fluorosulfuryl) peroxide

mercury(II) oxide

mercury(II) oxide

A

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

B

mercury(II) fluorosulphate

mercury(II) fluorosulphate

Conditions
ConditionsYield
byproducts: O2;
byproducts: O2;
calcium fluoride

calcium fluoride

sulfur trioxide
7446-11-9

sulfur trioxide

fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

Conditions
ConditionsYield
In neat (no solvent) excess SO3; 100-300°C;;
In neat (no solvent) excess SO3; 100-300°C;;
fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

sodium pentacarbonyl manganate
13859-41-1

sodium pentacarbonyl manganate

A

fluorosulfonyl fluoride
640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

B

dimanganese decacarbonyl
10170-69-1

dimanganese decacarbonyl

acetonitril-O,O-sulfitomanganese(II) tricarbonyl
195135-41-2

acetonitril-O,O-sulfitomanganese(II) tricarbonyl

D

carbon monoxide
201230-82-2

carbon monoxide

E

sulfur dioxide
7446-09-5

sulfur dioxide

Conditions
ConditionsYield
In methyl cyclohexane N2 atm.; cooling (1 h, -78°C), stirring (room temp., 72 h); evapn. (1E-4 torr), extraction (pentane, toluene (25°C, 20 torr)), acetonitrile (30°C, 50 torr)), concn., crystn. (-20°C);A n/a
B n/a
C 18%
D n/a
E n/a
fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

sodium pentacarbonyl manganate
13859-41-1

sodium pentacarbonyl manganate

A

sodium fluorosulfonate
14483-63-7

sodium fluorosulfonate

acetonitril-O,O-sulfitomanganese(II) tricarbonyl
195135-41-2

acetonitril-O,O-sulfitomanganese(II) tricarbonyl

C

μ-disulfito-dimanganesedecacarbonyl

μ-disulfito-dimanganesedecacarbonyl

Conditions
ConditionsYield
In methyl cyclohexane N2 atm.; cooling (1 h, -78°C), stirring (room temp., 72 h); evapn. (1E-4 torr), extraction (pentane, toluene (25°C, 20 torr)), acetonitrile (30°C, 50 torr)), concn., crystn. (-20°C);A n/a
B 18%
C n/a
fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

sodium pentacarbonyl manganate
13859-41-1

sodium pentacarbonyl manganate

A

fluorosulfonyl fluoride
640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

B

sodium fluorosulfonate
14483-63-7

sodium fluorosulfonate

acetonitril-O,O-sulfitomanganese(II) tricarbonyl
195135-41-2

acetonitril-O,O-sulfitomanganese(II) tricarbonyl

D

carbon monoxide
201230-82-2

carbon monoxide

E

sulfur dioxide
7446-09-5

sulfur dioxide

Conditions
ConditionsYield
In acetonitrile N2 atm.; cooling (-78°C), heating (30 min, -40°C), stirring (2 h); extraction (pentane, toluene), dissoln. (CH3CN), centrifugation, addn. of toluene; elem. anal.;A n/a
B n/a
C 10%
D n/a
E n/a
fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

sodium pentacarbonyl manganate
13859-41-1

sodium pentacarbonyl manganate

A

dimanganese decacarbonyl
10170-69-1

dimanganese decacarbonyl

acetonitril-O,O-sulfitomanganese(II) tricarbonyl
195135-41-2

acetonitril-O,O-sulfitomanganese(II) tricarbonyl

C

μ-disulfito-dimanganesedecacarbonyl

μ-disulfito-dimanganesedecacarbonyl

Conditions
ConditionsYield
In acetonitrile N2 atm.; cooling (-78°C), heating (30 min, -40°C), stirring (2 h); extraction (pentane, toluene), dissoln. (CH3CN), centrifugation, addn. of toluene; elem. anal.;A n/a
B 10%
C n/a
fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

Na[CpMo(CO)3]
12107-35-6

Na[CpMo(CO)3]

A

fluorosulfonyl fluoride
640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

B

sodium fluorosulfonate
14483-63-7

sodium fluorosulfonate

C

2Mo(2+)*2C5H5(1-)*6CO*S2O5(2-)*99CH3CN=[Mo(C5H5)(CO)3(SO2)]2O*99CH3CN

2Mo(2+)*2C5H5(1-)*6CO*S2O5(2-)*99CH3CN=[Mo(C5H5)(CO)3(SO2)]2O*99CH3CN

D

carbon monoxide
201230-82-2

carbon monoxide

E

sulfur dioxide
7446-09-5

sulfur dioxide

Conditions
ConditionsYield
In methyl cyclohexane N2 atm.; cooling (1 h, -78°C), stirring (room temp., 72 h); extraction (toluene (30°C, 30 torr), acetonitrile (vac.)), concn.(0.05 torr, 25°C), centrifugation, crystn. (PhMe/CH3CN, 10/1-1/3 );A n/a
B n/a
C 5%
D n/a
E n/a
fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

Na[CpMo(CO)3]
12107-35-6

Na[CpMo(CO)3]

A

cyclopentadienylmolybdenum tricarbonyl dimer

cyclopentadienylmolybdenum tricarbonyl dimer

B

2Mo(2+)*2C5H5(1-)*6CO*S2O5(2-)*99CH3CN=[Mo(C5H5)(CO)3(SO2)]2O*99CH3CN

2Mo(2+)*2C5H5(1-)*6CO*S2O5(2-)*99CH3CN=[Mo(C5H5)(CO)3(SO2)]2O*99CH3CN

Conditions
ConditionsYield
In methyl cyclohexane N2 atm.; cooling (1 h, -78°C), stirring (room temp., 72 h); extraction (toluene (30°C, 30 torr), acetonitrile (vac.)), concn.(0.05 torr, 25°C), centrifugation, crystn. (PhMe/CH3CN, 10/1-1/3 );A n/a
B 5%
fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

sodium(η5-cyclopentadienyl)tricarbonyltungstate(II)
12107-36-7

sodium(η5-cyclopentadienyl)tricarbonyltungstate(II)

A

bis(tricarbonyl(η-cyclopentadienyl)tungsten)

bis(tricarbonyl(η-cyclopentadienyl)tungsten)

B

bis(η5-cyclopentadienyl)-μ-disulfito-ditungsten hexacarbonyl

bis(η5-cyclopentadienyl)-μ-disulfito-ditungsten hexacarbonyl

Conditions
ConditionsYield
In acetonitrile N2 atm.; cooling (-78°C), heating (30 min, -40°C), stirring (2 h); extraction (toluene, CH3CN), centrifugation, addn. of toluene, pentane, Et2O, drying (vac., 40°C); elem. anal.;A n/a
B 2.5%
fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

sodium(η5-cyclopentadienyl)tricarbonyltungstate(II)
12107-36-7

sodium(η5-cyclopentadienyl)tricarbonyltungstate(II)

A

fluorosulfonyl fluoride
640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

B

sodium fluorosulfonate
14483-63-7

sodium fluorosulfonate

C

bis(η5-cyclopentadienyl)-μ-disulfito-ditungsten hexacarbonyl

bis(η5-cyclopentadienyl)-μ-disulfito-ditungsten hexacarbonyl

D

carbon monoxide
201230-82-2

carbon monoxide

E

sulfur dioxide
7446-09-5

sulfur dioxide

Conditions
ConditionsYield
In acetonitrile N2 atm.; cooling (-78°C), heating (30 min, -40°C), stirring (2 h); extraction (toluene, CH3CN), centrifugation, addn. of toluene, pentane, Et2O, drying (vac., 40°C); elem. anal.;A n/a
B n/a
C 2.5%
D n/a
E n/a
fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

(1S-trans)-methyl 1-(1,3-benzodioxol-5-yl)-2,3-dihydro-3-oxo-5-propoxy-1H-indene-2-carboxylate

(1S-trans)-methyl 1-(1,3-benzodioxol-5-yl)-2,3-dihydro-3-oxo-5-propoxy-1H-indene-2-carboxylate

(S)-methyl 1-(1,3-benzodioxol-5-yl)-3-[(fluorosulfonyl)oxy]-5-propoxy-1H-indene-2-carboxylate

(S)-methyl 1-(1,3-benzodioxol-5-yl)-3-[(fluorosulfonyl)oxy]-5-propoxy-1H-indene-2-carboxylate

Conditions
ConditionsYield
With acetic acid In dichloromethane55%, 99%
fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

diphenylmethyl 7-phenoxyacetamido-3-hydroxy-3-cephem-4-carboxylate

diphenylmethyl 7-phenoxyacetamido-3-hydroxy-3-cephem-4-carboxylate

3-methyl-N-(3-methylbutyl)-1-butanamine
544-00-3

3-methyl-N-(3-methylbutyl)-1-butanamine

diphenylmethyl 7-phenoxyacetamido-3-[(fluorosulfonyl)oxy]-3-cephem-4-carboxylate

diphenylmethyl 7-phenoxyacetamido-3-[(fluorosulfonyl)oxy]-3-cephem-4-carboxylate

Conditions
ConditionsYield
In dichloromethane; water2.2 g (96%)
fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

diphenylmethyl 2-<(3R,4R)-4-(2-benzothiazolyldithio)-2-oxo-3-(phenylacetylamino)-1-azetidinyl>-3-hydroxy-2-butenoate

diphenylmethyl 2-<(3R,4R)-4-(2-benzothiazolyldithio)-2-oxo-3-(phenylacetylamino)-1-azetidinyl>-3-hydroxy-2-butenoate

diphenylmethyl 2-[(3R,4R)-4-[(benzothiazol-2-yl)dithio]-3-phenylacetamido-2-oxo-azetidin-1-yl]-3-fluorosulfonyloxy-2-butenoate

diphenylmethyl 2-[(3R,4R)-4-[(benzothiazol-2-yl)dithio]-3-phenylacetamido-2-oxo-azetidin-1-yl]-3-fluorosulfonyloxy-2-butenoate

Conditions
ConditionsYield
With triethylamine In dichloromethane2.67 g (95%)
With triethylamine In dichloromethane2.67 g (95%)
fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

diphenylmethyl 3-hydroxy-2-<(3R,4R)-2-oxo-3-(phenoxyacetylamino)-4-(p-tolylsulfonylthio)-1-azetidinyl>-2-butenoate
57561-96-3

diphenylmethyl 3-hydroxy-2-<(3R,4R)-2-oxo-3-(phenoxyacetylamino)-4-(p-tolylsulfonylthio)-1-azetidinyl>-2-butenoate

Diphenylmethyl 2-<(3R,4R)-<(p-toluenesulfonyl)thio>-3-(phenoxyacetamido)-2-oxoazetidin-1-yl>-3-<(fluorosulfonyl)oxy>-2-butenoate

Diphenylmethyl 2-<(3R,4R)-<(p-toluenesulfonyl)thio>-3-(phenoxyacetamido)-2-oxoazetidin-1-yl>-3-<(fluorosulfonyl)oxy>-2-butenoate

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In dichloromethane; ethyl acetate9.18 g (82%)
fluorosulfonyl anhydride
13036-75-4

fluorosulfonyl anhydride

A

fluorosulfonyl fluoride
640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

B

sulfur trioxide
7446-11-9

sulfur trioxide

Conditions
ConditionsYield
500°C;
500°C;

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