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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

Di-tert-butyl phosphite

Cas:13086-84-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Bis(1,1-dimethylethyl) phosphonate

Cas:13086-84-5

Min.Order:1

Negotiable

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: DI-TERT-BUTYL PHOSPHITE Synonyms: DI-TERT-BUTYL PHOSPHITE;Di(tert-butyl) hydrogen phosphite;di-t-Butyl phosphite;Phosphonic acid, bis(1,1-dimethylethyl) ester;Phosphorous acid di-tert-butyl ester;bis(1,1-dimethylethyl) phosphon

13086-84-5 DI-TERT-BUTYL PHOSPHITE

Cas:13086-84-5

Min.Order:1 Kilogram

FOB Price: $8900.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

DI-TERT-BUTYL PHOSPHITE

Cas:13086-84-5

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 13086-84-5 with best quality

Cas:13086-84-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

DI-TERT-BUTYL PHOSPHITE

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

Di-tert-butyl Phosphite

Cas:13086-84-5

Min.Order:1 Kilogram

FOB Price: $40.0 / 50.0

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Phosphonic acid,bis(1,1-dimethylethyl) ester

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

DI-TERT-BUTYL PHOSPHITE

Cas:13086-84-5

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...)

DI-TERT-BUTYL PHOSPHITE CAS NO.: 13086-84-5

Cas:13086-84-5

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

DI-TERT-BUTYLPHOSPHITE

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Di-tert-butylphosphite Cas no.13086-84-5 98%

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Sibian Chemical Technology Co., Ltd

The process is mature and can be mass produced to 100 kg, with good quality and purity up to 99%.The product has a large stock and can be supplied stably. Package:bottle Application:Drug R&D Transportation:Sealed drying(25℃) Port:ShangHai

DI-TERT-BUTYL PHOSPHITE

Cas:13086-84-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

di-tert-Butyl phosphite

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Di-tert-butyl phosphite

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec DI-TERT-BUTYL PHOSPHITE 100g

Cas:13086-84-5

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Di-Tert-Butyl Phosphite

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

DI-TERT-BUTYL PHOSPHITE

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Di-tert-butyl phosphite

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

DI-TERT-BUTYL PHOSPHITE

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Other

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

Di-tert-butyl Phosphite

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:White to Off-White Solid Storage:Keep it in dry,shady and cool place Package:as your requirement Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by Sea

DI-TERT-BUTYL PHOSPHITE

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white to beige crystals Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use a

Di-tert-butyl phosphite

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Di-tert-butyl phosphite cas 13086-84-5Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Di-tert-butyl phosphite cas 13086-84-5

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

DI-TERT-BUTYL PHOSPHITE

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

13086-84-5 Application:intermediate

Phosphonic acid, bis(1,1-dimethylethyl) ester

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

low price and high purityAppearance:solid or liquid Storage:in sealed air resistant place Package:As customer require Application:Pharma;Industry;Agricultural Transportation:by sea or by airplane Port:any port in China

Di-tert-butyl phosphite, 95% 13086-84-5

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:1g Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any port

Di-Tert-Butyl Phosphite

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

DI-TERT-BUTYL PHOSPHITE

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

home-produced Application:medicine

DI-TERT-BUTYL PHOSPHITE

Cas:13086-84-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

bis(N,N-diisopropylamino)phosphine
86660-77-7

bis(N,N-diisopropylamino)phosphine

tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

B

bis(trimethylsiloxy)phosphine
2171-76-8

bis(trimethylsiloxy)phosphine

Conditions
ConditionsYield
In benzene for 168h; Heating; Title compound not separated from byproducts;A 97%
B 3%
tri(tert-butyl)phosphite
15205-62-6

tri(tert-butyl)phosphite

acrylic acid
79-10-7

acrylic acid

A

di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

B

3-(di-tert-butoxyphosphoryl)propionic acid

3-(di-tert-butoxyphosphoryl)propionic acid

C

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
In dichloromethane for 2h; Heating;A 95%
B n/a
C n/a
Dimethyl phosphite
868-85-9

Dimethyl phosphite

tert-butyl alcohol
75-65-0

tert-butyl alcohol

di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

Conditions
ConditionsYield
With calcium hydroxide at 130℃; under 760.051 Torr; Reflux; Inert atmosphere;91.5%
sodium t-butanolate
865-48-5

sodium t-butanolate

di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

Conditions
ConditionsYield
With phosphorus trichloride In 2-methyltetrahydrofuran at 0 - 20℃; for 1h; Reagent/catalyst; Solvent; Schlenk technique; Inert atmosphere;85%
tert-butyl alcohol
75-65-0

tert-butyl alcohol

di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

Conditions
ConditionsYield
With triethylamine; Petroleum ether; phosphorus trichloride
With pyridine; diethyl ether; phosphorus trichloride
With triethylamine; phosphorus trichloride
tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

B

tri(tert-butyl)phosphite
15205-62-6

tri(tert-butyl)phosphite

Conditions
ConditionsYield
With triethylamine; Petroleum ether; phosphorus trichloride
tri(tert-butyl)phosphite
15205-62-6

tri(tert-butyl)phosphite

di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

Conditions
ConditionsYield
Heating;
With sulfuric acid Heating;
With diethyl phosphorylchloridite at 50℃;
tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

B

phosphonic acid mono-tert-butyl ester
16540-40-2

phosphonic acid mono-tert-butyl ester

Conditions
ConditionsYield
With P4O6 for 1h;
With P4O6 for 1h; Title compound not separated from byproducts;
tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

B

C4H11O3P*H3N
56317-67-0

C4H11O3P*H3N

Conditions
ConditionsYield
With P4O6; ammonia 1.) 1 h; Multistep reaction;
2,4,6-tris(2,6-di-tert-butyl-4-methylphenoxy)-1,3,5,2,4,6,trioxatriphosphorinane
96357-74-3

2,4,6-tris(2,6-di-tert-butyl-4-methylphenoxy)-1,3,5,2,4,6,trioxatriphosphorinane

tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

B

C19H33O3P

C19H33O3P

Conditions
ConditionsYield
1.) 300-350 deg C, 1E-6 to 1E-5 torr, 2.) -195 deg C to r.t.; Multistep reaction. Title compound not separated from byproducts;
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

7-Formyl-naphthalene-2-carboxylic acid benzyl ester
219316-53-7

7-Formyl-naphthalene-2-carboxylic acid benzyl ester

7-[(Di-tert-butoxy-phosphoryl)-hydroxy-methyl]-naphthalene-2-carboxylic acid benzyl ester
219316-54-8

7-[(Di-tert-butoxy-phosphoryl)-hydroxy-methyl]-naphthalene-2-carboxylic acid benzyl ester

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran at -78℃; for 2.5h;98%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

formaldehyd
50-00-0

formaldehyd

Triphenylmethylamin
5824-40-8

Triphenylmethylamin

di-tert-butyl ((tritylamino)methyl)phosphonate

di-tert-butyl ((tritylamino)methyl)phosphonate

Conditions
ConditionsYield
Stage #1: formaldehyd; Triphenylmethylamin In water; toluene at 20℃; for 20h; Inert atmosphere;
Stage #2: di-tert-butyl phosphite With triethylamine In toluene Inert atmosphere; Dean-Stark; Reflux;
97%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

1-bromomethyl-4-bromobenzene
589-15-1

1-bromomethyl-4-bromobenzene

[(4-bromophenyl)methyl]-phosphonoic acid bis(tert-butyl) ester
300583-37-3

[(4-bromophenyl)methyl]-phosphonoic acid bis(tert-butyl) ester

Conditions
ConditionsYield
Stage #1: di-tert-butyl phosphite With sodium hydride In tetrahydrofuran at 0℃; for 0.5h;
Stage #2: 1-bromomethyl-4-bromobenzene In tetrahydrofuran for 20h; Heating; Further stages.;
95%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

(4-methylbenzyl)phosphonic acid di-tert-butyl ester
174969-89-2

(4-methylbenzyl)phosphonic acid di-tert-butyl ester

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran for 20h; Heating;94%
With tetra-(n-butyl)ammonium iodide; caesium carbonate In N,N-dimethyl-formamide at 20℃; for 48h;90%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

(trifluoromethyl)trimethylsilane
81290-20-2

(trifluoromethyl)trimethylsilane

di-tert-butyl (difluoro(trimethylsilyl)methyl)phosphonate

di-tert-butyl (difluoro(trimethylsilyl)methyl)phosphonate

Conditions
ConditionsYield
Stage #1: di-tert-butyl phosphite With lithium chloride; lithium tert-butoxide In N,N-dimethyl-formamide at 20℃; for 0.166667h; Inert atmosphere; Sealed tube; Glovebox;
Stage #2: (trifluoromethyl)trimethylsilane In N,N-dimethyl-formamide at 20℃; for 0.5h; Inert atmosphere; Sealed tube; Glovebox;
94%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

benzoyl azide
582-61-6

benzoyl azide

di-tert-butyl benzoylphosphoramidate

di-tert-butyl benzoylphosphoramidate

Conditions
ConditionsYield
With chloro-trimethyl-silane; triethylamine In dichloromethane at 20℃; for 18h;93%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

6-formyl-2-naphthalenecarboxylic acid benzyl ester
219316-43-5

6-formyl-2-naphthalenecarboxylic acid benzyl ester

6-[(Di-tert-butoxy-phosphoryl)-hydroxy-methyl]-naphthalene-2-carboxylic acid benzyl ester
219316-44-6

6-[(Di-tert-butoxy-phosphoryl)-hydroxy-methyl]-naphthalene-2-carboxylic acid benzyl ester

Conditions
ConditionsYield
With aluminum oxide at 75℃; for 1h;91%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

L-perillaldehyde
5503-12-8

L-perillaldehyde

(R)-(p-menth-1,8-dien-7-ol-7-yl)phosphonic acid di-tert-butyl ester
226997-01-9

(R)-(p-menth-1,8-dien-7-ol-7-yl)phosphonic acid di-tert-butyl ester

Conditions
ConditionsYield
With sodium ethanolate; triethylamine In ethanol; benzene for 0.25h; Ambient temperature;91%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

formaldehyd
50-00-0

formaldehyd

di-tert-butyl (hydroxymethyl)phosphonate
115989-10-1

di-tert-butyl (hydroxymethyl)phosphonate

Conditions
ConditionsYield
With triethylamine In water at 20℃; Temperature; Reagent/catalyst;91%
With triethylamine In water
With triethylamine In water
With triethylamine In water at 20℃;
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

phosphoric acid di-tert-butyl ester
33494-81-4

phosphoric acid di-tert-butyl ester

Conditions
ConditionsYield
With potassium permanganate; sodium hydrogencarbonate In water89%
With potassium permanganate; sodium hydrogencarbonate In water Cooling with ice;89%
Stage #1: di-tert-butyl phosphite With sodium hydrogencarbonate In water at 0℃; for 0.333333h;
Stage #2: With potassium permanganate at 20℃; for 1h;
89%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

6-bromo-2-phenylimidazo[1,2-a]pyridine
4044-98-8

6-bromo-2-phenylimidazo[1,2-a]pyridine

di-tert-butyl (2-phenylimidazo[1,2-a]pyridin-6-yl)phosphonate

di-tert-butyl (2-phenylimidazo[1,2-a]pyridin-6-yl)phosphonate

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); triethylamine; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 110℃; for 2h; Inert atmosphere;89%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

diphenyl phosphoryl azide
26386-88-9

diphenyl phosphoryl azide

di-tert-butyl diphenyl imidodiphosphate

di-tert-butyl diphenyl imidodiphosphate

Conditions
ConditionsYield
With chloro-trimethyl-silane; triethylamine In dichloromethane at 20℃; for 18h;89%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

2-(4-trifluoromethylphenyl)-3,5,7-trihydroxy-8-(3-methyl-2-buten-1-yl)-4H-chromen-4-one

2-(4-trifluoromethylphenyl)-3,5,7-trihydroxy-8-(3-methyl-2-buten-1-yl)-4H-chromen-4-one

C29H34F3O8P

C29H34F3O8P

Conditions
ConditionsYield
With dmap; N-ethyl-N,N-diisopropylamine In tetrachloromethane; dichloromethane at 0℃; for 5h; Inert atmosphere;88%
2-aminopyridine
504-29-0

2-aminopyridine

di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

ferrocenecarboxaldehyde
12093-10-6

ferrocenecarboxaldehyde

fc-CH(C5H5N2)-PO(OC(CH3)3)2

fc-CH(C5H5N2)-PO(OC(CH3)3)2

Conditions
ConditionsYield
room temp.;86%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

Benzeneselenol
645-96-5

Benzeneselenol

C14H23O3PSe

C14H23O3PSe

Conditions
ConditionsYield
With tetrabutylammomium bromide In acetonitrile at 20℃; for 6h; Electrochemical reaction;86%
hexamethylene imine
111-49-9

hexamethylene imine

di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

C14H30NO3P
1384959-08-3

C14H30NO3P

Conditions
ConditionsYield
Stage #1: hexamethylene imine With tetrachloromethane; triethylamine at 0℃; Todd-Atherton reaction;
Stage #2: di-tert-butyl phosphite at 0 - 20℃; for 2h; Todd-Atherton reaction;
85%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

di-tert-butyl phosphorobromidate
59346-65-5

di-tert-butyl phosphorobromidate

Conditions
ConditionsYield
With sodium hydroxide; carbon tetrabromide; N-benzyl-N,N,N-triethylammonium chloride In dichloromethane; water at 25℃; for 3.33333h;84%
With sodium hydroxide; carbon tetrabromide; N-benzyl-N,N,N-triethylammonium chloride
With carbon tetrabromide; N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide In dichloromethane; water at 25℃; for 3h;
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

2,2,8-trimethyl-4H-[1,3]dioxino[4,5-c]pyridine-5-carboxaldehyde
6560-65-2

2,2,8-trimethyl-4H-[1,3]dioxino[4,5-c]pyridine-5-carboxaldehyde

[hydroxy-(2,2,8-trimethyl-4H-[1,3]dioxino[4,5-c]pyridin-5-yl)methyl]phosphonic acid di-tert-butyl ester
357966-07-5

[hydroxy-(2,2,8-trimethyl-4H-[1,3]dioxino[4,5-c]pyridin-5-yl)methyl]phosphonic acid di-tert-butyl ester

Conditions
ConditionsYield
Stage #1: di-tert-butyl phosphite With sodium hydride In tetrahydrofuran at 20℃; for 0.25h;
Stage #2: 2,2,8-trimethyl-4H-[1,3]dioxino[4,5-c]pyridine-5-carboxaldehyde In tetrahydrofuran at 0 - 20℃; for 1h;
82%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

[1,1’-biphenyl]-4-yl sulfurofluoridate
51451-35-5

[1,1’-biphenyl]-4-yl sulfurofluoridate

C20H27O3P

C20H27O3P

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; N-ethyl-N,N-diisopropylamine In acetonitrile at 80℃; for 5h; Sealed tube;80%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

C19H24O6

C19H24O6

C27H43O9P

C27H43O9P

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane for 1.5h; Michael Addition; Darkness; stereoselective reaction;80%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

sodium naphthalen-2-ylsulfinate
63735-42-2

sodium naphthalen-2-ylsulfinate

di(tert-butyl) naphthalen-2-ylphosphonate
1600534-25-5

di(tert-butyl) naphthalen-2-ylphosphonate

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; tetrabutyl-ammonium chloride; silver carbonate In dimethyl sulfoxide at 80℃; for 9h; Schlenk technique;78%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

methyl iodide
74-88-4

methyl iodide

Di-tert-butyl methylphosphonate
17123-05-6

Di-tert-butyl methylphosphonate

Conditions
ConditionsYield
Stage #1: di-tert-butyl phosphite With sodium hydride In acetonitrile; mineral oil at 20℃; for 0.5h;
Stage #2: methyl iodide In acetonitrile; mineral oil at 50℃; Cooling with ice;
76%
Stage #1: di-tert-butyl phosphite With sodium hydride In acetonitrile; mineral oil at 20℃; for 0.5h;
Stage #2: methyl iodide In acetonitrile; mineral oil at 50℃;
76%
Stage #1: di-tert-butyl phosphite With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1.16667h;
Stage #2: methyl iodide In tetrahydrofuran; mineral oil at 0 - 20℃;
57.5%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

phosphorus oxychloride di-tert-butyl ester
56119-60-9

phosphorus oxychloride di-tert-butyl ester

Conditions
ConditionsYield
With tetrachloromethane; N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide In dichloromethane; water at 20 - 25℃;75%
With tetrachloromethane; sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

N-cyclohexyl-cyclohexanamine
101-83-7

N-cyclohexyl-cyclohexanamine

dicyclohexylammonium O,O-di-tert-butyl phosphorothioate
85254-21-3

dicyclohexylammonium O,O-di-tert-butyl phosphorothioate

Conditions
ConditionsYield
With sulfur for 24h; Ambient temperature;75%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

4-(5,6,7,8-tetrahydronaphthyloxy)benzaldehyde
181059-89-2

4-(5,6,7,8-tetrahydronaphthyloxy)benzaldehyde

{Hydroxy-[4-(5,6,7,8-tetrahydro-naphthalen-1-yloxy)-phenyl]-methyl}-phosphonic acid di-tert-butyl ester
219658-86-3

{Hydroxy-[4-(5,6,7,8-tetrahydro-naphthalen-1-yloxy)-phenyl]-methyl}-phosphonic acid di-tert-butyl ester

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran; hexane at -78 - 20℃;75%
di-tert-butyl phosphite
13086-84-5

di-tert-butyl phosphite

1-bromo-5-<(tert-butyldiphenylsilyl)oxy>-pentane
125010-60-8

1-bromo-5-<(tert-butyldiphenylsilyl)oxy>-pentane

C29H47O4PSi

C29H47O4PSi

Conditions
ConditionsYield
Stage #1: di-tert-butyl phosphite With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.166667h; Inert atmosphere;
Stage #2: 1-bromo-5-<(tert-butyldiphenylsilyl)oxy>-pentane In N,N-dimethyl-formamide at 20℃; for 16h;
75%

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