Taizhou FredChem Co. Ltd. is a high-tech enterprise located in China Medical City specializing in R&D, manufacturing, sales of new APIS, pharmaceutical intermediates and fine chemicals. All of our company is committed to provide high quality ch
Cas:13329-40-3
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:13329-40-3
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inquiryWe can provide GMP validation service that complies with SFDA, FDA, WHO and EU EMPA.Excellent registration team could help us easlily to register our products in different countries.If you and your customer are interested in some products or need C
Cas:13329-40-3
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inquiryhigh quality Appearance:white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai
As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis
Cas:13329-40-3
Min.Order:1 Kilogram
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inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:13329-40-3
Min.Order:5 Kiloliter
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inquiry4'-Iodoacetophenone Basic information Product Name: 4'-Iodoacetophenone Synonyms: 1-(4-IODOPHENYL)ETHANONE;4'-IODOACETOPHENONE;4-IODOACETOPHENONE;Ethanone, 1-(4-iodophenyl)-;
WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:13329-40-3
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inquiryName: 4'-Iodoacetophenone Synonyms: 1-(4-iodophenyl)ethan-1-one CAS:13329-40-3 MF: C8H7IO Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg/drum Application:Agrochemical Intermediates, Dyestuf
Cas:13329-40-3
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inquiryOur advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva
Cas:13329-40-3
Min.Order:1 Kilogram
FOB Price: $9.0 / 99.0
Type:Trading Company
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:13329-40-3
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inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese
Cas:13329-40-3
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Type:Trading Company
inquiry4'-Iodoacetophenone CAS:13329-40-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i
Cas:13329-40-3
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:13329-40-3
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inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Cas:13329-40-3
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inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:13329-40-3
Min.Order:10 Gram
FOB Price: $100.0
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h
Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:13329-40-3
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiry1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea
Cas:13329-40-3
Min.Order:1 Gram
FOB Price: $2.0
Type:Lab/Research institutions
inquiryProduct Name: 4'-Iodoacetophenone CAS: 13329-40-3 MF: C8H7IO MW: 246.05 EINECS: 236-372-8 Mol File: 13329-40-3.mol 4'-Iodoacetophenone Structure 4'-Iodoacetophenone Chemical Properties Melting point 82-84 °C(li
Cas:13329-40-3
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryAppearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea
High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use
Our company is engaged in customizing the benzene ring and pyridine derivative organic intermediates, and the quantity is flexible according to customer's needs. It mainly provides high-quality intermediates for domestic and foreign pharmaceutical an
Cas:13329-40-3
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Type:Lab/Research institutions
inquiryStock products, own laboratoryAppearance:White to light yellow crystal Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai
Cas:13329-40-3
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re
4'-Iodoacetophenone,cas:13329-40-3 from fandachem Appearance:Brown crystalline powder Storage:Store in dry, dark and ventilated place Application:intermediate Transportation:by air, by sea, by express
Cas:13329-40-3
Min.Order:0 Metric Ton
Negotiable
Type:Other
inquiryOur clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
1-(4-iodophenyl)ethanol
4-Iodoacetophenone
Conditions | Yield |
---|---|
With silica-supported Jones reagent In dichloromethane for 0.00269444h; | 99.6% |
With 1,10-Phenanthroline; iron(III)-acetylacetonate; potassium carbonate In toluene for 48h; Reflux; Green chemistry; | 94% |
With [bis({2‐[bis(propan‐2‐yl)phosphanyl]ethyl})amine](borohydride)(carbonyl)(hydride)iron(II) In toluene at 120℃; for 12h; Glovebox; Schlenk technique; Inert atmosphere; | 94% |
1-ethynyl-4-iodobenzene
4-Iodoacetophenone
Conditions | Yield |
---|---|
With tetrakis(p-sulfonatophenyl)porphyrin cobalt(III) trisodium salt hexahydrate; water; bis(trifluoromethanesulfonyl)amide In methanol at 80℃; for 12h; Sealed tube; | 97% |
4-Aminoacetophenone
4-Iodoacetophenone
Conditions | Yield |
---|---|
Stage #1: p-aminobenzophenone With hydrogenchloride In water at 0 - 5℃; for 0.166667h; Stage #2: With 1-methyl-3-(2-[2-(1-methyl-1H-imidazol-3-ium-3-yl)ethyloxy]ethyl)-1H-imidazol-3-ium dinitrite In water for 0.166667h; Stage #3: With potassium iodide In water at 20℃; for 0.166667h; Ionic liquid; | 95% |
With toluene-4-sulfonic acid; sodium iodide In water; acetonitrile at 10 - 20℃; for 2h; Inert atmosphere; | 94% |
With N-iodo-succinimide; sodium nitrite In N,N-dimethyl-formamide at 20℃; for 4h; Reagent/catalyst; Temperature; Solvent; | 92% |
1-(p-acetophenyl)-3,3-diethyl-1-triazene
A
4-Iodoacetophenone
B
benzene
Conditions | Yield |
---|---|
With sulfonic acid resin (H+ form, Bio-Rad AG 50W-12); sodium iodide In acetonitrile at 75℃; for 0.133333h; | A 95% B n/a |
1-(3,4-Diiodocyclohexa-1,3-dienyl)ethanone
4-Iodoacetophenone
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene | 95% |
1,2,2-triphenyl-1-iodoethylene
4-Iodoacetophenone
Conditions | Yield |
---|---|
With thallium(I) acetate; cesium fluoride; bis(dibenzylideneacetone)-palladium(0) In toluene; acetonitrile at 90℃; for 8h; | 95% |
4-acetophenyl triflate
4-Iodoacetophenone
Conditions | Yield |
---|---|
With [Cp*Ru(CH3CN)3]OTf; sodium iodide at 120℃; for 12h; Inert atmosphere; | 95% |
With iodine; lithium fluoride; sodium iodide In acetonitrile at 25℃; for 24h; Inert atmosphere; UV-irradiation; Schlenk technique; | 20% |
Multi-step reaction with 2 steps 1: KOAc / PdCl2(dppf) / dimethylsulfoxide / 3 h / 80 °C 2: 30 percent / aq. NaI; chloramine-T / tetrahydrofuran / 6 h View Scheme |
1-(p-acetophenyl)-3,3-diethyl-1-triazene
A
4-Iodoacetophenone
B
acetophenone
Conditions | Yield |
---|---|
With cation exchange resin BioRad AG 50W-X12 (H+); sodium iodide In acetonitrile at 75℃; Product distribution; further solvent: THF, DMSO; | A 94% B 6% |
para-bromoacetophenone
4-Iodoacetophenone
Conditions | Yield |
---|---|
With copper(I) oxide; L-proline; potassium iodide In ethanol at 110℃; for 30h; Schlenk technique; Inert atmosphere; Sealed tube; | 92% |
With tributylphosphine; potassium iodide; nickel dibromide In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide at 50℃; for 1.5h; | 66% |
With N,N,N,N,N,N-hexamethylphosphoric triamide; copper(l) iodide; potassium iodide at 150 - 160℃; for 5h; | 60% |
1-(p-acetophenyl)-3,3-diethyl-1-triazene
4-Iodoacetophenone
Conditions | Yield |
---|---|
With chloro-trimethyl-silane; sodium iodide In acetonitrile at 60℃; for 0.0833333h; | 92% |
4-acetylphenylboronic acid
4-Iodoacetophenone
Conditions | Yield |
---|---|
With iodine; potassium carbonate In acetonitrile at 80℃; for 8h; Inert atmosphere; Schlenk technique; Sealed tube; | 91% |
With sodium nitrite In acetonitrile at 80℃; for 5h; Sealed tube; | 86% |
With 1,10-Phenanthroline; oxygen; potassium iodide; copper(ll) bromide In N,N-dimethyl-formamide at 80℃; for 20h; | 76% |
1-(4-acetylphenyl)diazonium tetrafluoroborate
4-Iodoacetophenone
Conditions | Yield |
---|---|
With N-iodo-succinimide; sodium nitrite In dimethyl sulfoxide at 20℃; for 2.5h; | 90% |
With diiodomethane; tetrabutylammonium perchlorate In methanol; N,N-dimethyl-formamide at 20℃; for 3h; Sandmeyer Reaction; Electrochemical reaction; | 87% |
iodobenzene
4-(phenylethynyl)nitrobenzene
2-(trimethylsilyl)phenyl trifluoromethanesulfonate
4-Iodoacetophenone
Conditions | Yield |
---|---|
With thallium(I) acetate; cesium fluoride; bis(dibenzylideneacetone)-palladium(0) In toluene; acetonitrile at 90℃; for 8h; | 89% |
1-iodo-4-(prop-1-en-2-yl)benzene
4-Iodoacetophenone
Conditions | Yield |
---|---|
With sodium tetrafluoroborate; [Cu(salicylate)2(NCMe)]2; tetrabutyl-ammonium chloride; oxygen In tetrahydrofuran at 60℃; for 12h; | 85% |
carbon monoxide
para-diiodobenzene
methylmercury(II) iodide
4-Iodoacetophenone
Conditions | Yield |
---|---|
With dichloro bis(acetonitrile) palladium(II); tetra-(n-butyl)ammonium iodide In N,N,N,N,N,N-hexamethylphosphoric triamide under 760 Torr; for 5.5h; Ambient temperature; | 83% |
4-Aminoacetophenone
bis(trifluoromethanesulfonyl)amide
4-Iodoacetophenone
Conditions | Yield |
---|---|
Stage #1: bis(trifluoromethanesulfonyl)amide With tert.-butylnitrite; acetic acid In ethanol Cooling with ice; Stage #2: p-aminobenzophenone With tetraethylammonium iodide In water at 20℃; | 81% |
carbon monoxide
tetramethylstannane
4-iodobenzenediazonium tetrafluoroborate
4-Iodoacetophenone
Conditions | Yield |
---|---|
palladium diacetate In acetonitrile under 6619.6 Torr; for 1.5h; Heating; | 79% |
With palladium diacetate In acetonitrile for 0.5h; Ambient temperature; | 79% |
4-(2-methyl-[1,3]dioxolan-2-yl)-phenylamine
4-Iodoacetophenone
Conditions | Yield |
---|---|
With N-iodo-succinimide; sodium nitrite In N,N-dimethyl-formamide at 20℃; for 4h; | 75% |
Multi-step reaction with 2 steps 1: sodium nitrite; N-iodo-succinimide / N,N-dimethyl-formamide / 4 h / 20 °C 2: sodium nitrite; N-iodo-succinimide / N,N-dimethyl-formamide / 4 h / 20 °C View Scheme | |
Multi-step reaction with 3 steps 1: sodium nitrite; N-iodo-succinimide / N,N-dimethyl-formamide / 4 h / 20 °C 2: tert.-butylnitrite / water; ethanol / 2 h / 0 - 20 °C 3: sodium nitrite; N-iodo-succinimide / dimethyl sulfoxide / 2.5 h / 20 °C View Scheme |
4-ethyl-1-iodobenzene
A
4-Iodoacetophenone
B
1-(4-iodophenyl)ethanol
Conditions | Yield |
---|---|
With 1-hydroxy-1,2-benzodioxol-3-(1H)-one; tris(2,2'-bipyridyl)ruthenium dichloride; water at 30℃; for 10h; Reagent/catalyst; Irradiation; Inert atmosphere; | A 8% B 71% |
2-(4-iodophenyl)propan-2-ol
4-Iodoacetophenone
Conditions | Yield |
---|---|
With bismuth(lll) trifluoromethanesulfonate; dipotassium peroxodisulfate; silver nitrate In water at 30℃; for 24h; Inert atmosphere; Green chemistry; | 71% |
4-ethyl-1-iodobenzene
4-Iodoacetophenone
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; C26H23ClN8ORu In water at 20℃; for 2h; Catalytic behavior; Schlenk technique; | 66% |
With tert.-butylhydroperoxide at 90℃; for 5h; Neat (no solvent); | |
With calcined praseodymium incorporated AlPO-5 molecular sieves ((Al+P)/Pr = 25); air In neat liquid at 120℃; for 6h; Green chemistry; | |
With oxygen; Langlois reagent In acetonitrile at 25℃; under 760.051 Torr; for 12h; Irradiation; Green chemistry; | 96 %Chromat. |
1,1,1,3',3',3'-hexafluoro-propanol
1-(4-(dichloro-λ3-iodanyl)phenyl)ethan-1-one
A
4-Iodoacetophenone
B
Hexafluoroacetone
Conditions | Yield |
---|---|
In dichloromethane-d2 at 20℃; for 20h; Inert atmosphere; | A 65% B n/a |
4-(2-methyl-[1,3]dioxolan-2-yl)-phenylamine
A
4-Iodoacetophenone
B
4-Aminoacetophenone
Conditions | Yield |
---|---|
With N-iodo-succinimide; sodium nitrite In N,N-dimethyl-formamide at 20℃; for 4h; | A 31% B 62% |
4-acetyl-benzoic acid
4-Iodoacetophenone
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); 1-iodo-butane; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; chloro-N,N,N',N'-bis(tetramethylene)formamidinium hexafluorophosphate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 120℃; for 16h; Sealed tube; Inert atmosphere; | 62% |
4-Iodoacetophenone
Conditions | Yield |
---|---|
With chloroamine-T; sodium iodide In tetrahydrofuran; water at 20℃; for 1.5h; | 60% |
α-(benzoyloxy)-p-iodoacetophenone
A
4-Iodoacetophenone
B
phenacyl benzoate
Conditions | Yield |
---|---|
With 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole; azobisisobutyronitrile In acetonitrile at 61℃; for 19h; Rate constant; | A 19.6% B 35% |
1-(4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)phenyl)ethan-1-one
4-Iodoacetophenone
Conditions | Yield |
---|---|
With chloroamine-T; sodium iodide In tetrahydrofuran for 6h; | 30% |
Conditions | Yield |
---|---|
With carbon disulfide; aluminium trichloride | |
With aluminium trichloride | |
With aluminum (III) chloride In dichloromethane at 40℃; for 24h; Friedel-Crafts Acylation; Sealed tube; Inert atmosphere; |
Conditions | Yield |
---|---|
(i) CuI, Et2O, (ii) /BRN= 774718/, MeOH; Multistep reaction; |
iodobenzene
4-Iodoacetophenone
4-Iodoacetophenone
2-bromo-1-(4-iodophenyl)ethanone
Conditions | Yield |
---|---|
With bromine In 1,4-dioxane at 20℃; for 1h; | 100% |
With bromine In 1,4-dioxane at 0 - 20℃; for 1 - 1.66667h; Product distribution / selectivity; | 100% |
With bromine In chloroform at 20℃; for 4h; | 94% |
4-Iodoacetophenone
4-methoxy-benzaldehyde
(E)-1-(4-iodophenyl)-3-(4-methoxyphenyl)prop-2-en-1-one
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol; water at 20℃; for 4.25h; Cooling with ice; | 100% |
With sodium hydroxide In methanol at 0 - 20℃; for 4h; Claisen-Schmidt condensation; | 91% |
With SiO2-H3PO4 Aldol Condensation; Microwave irradiation; | 88% |
4-Iodoacetophenone
1-(4-iodophenyl)ethanol
Conditions | Yield |
---|---|
With zirconium dioxide hydrate; isopropyl alcohol at 130℃; for 0.366667h; Meerwein-Ponndorf-Verley Reduction; | 100% |
With C9H8BrMnN2O3; potassium tert-butylate In isopropyl alcohol at 30℃; for 168h; Inert atmosphere; Schlenk technique; Glovebox; | 99% |
With sodium tetrahydroborate In ethanol for 5h; | 98.7% |
4-Iodoacetophenone
acetophenone
Conditions | Yield |
---|---|
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride In 2-pentanol at 100℃; for 36h; Inert atmosphere; | 100% |
With triethylamine In toluene at 20℃; for 24h; Inert atmosphere; Irradiation; Sealed tube; | 83.4% |
With tris-(trimethylsilyl)silane In acetonitrile Schlenk technique; Inert atmosphere; Irradiation; | 80% |
Conditions | Yield |
---|---|
With tetrabutylammonium acetate; copper aluminum In N,N-dimethyl-formamide at 110℃; for 24h; Sonogashira coupling; | 100% |
With copper(l) iodide; triethylamine; triphenylphosphine In water at 60℃; for 24h; Sonogashira Cross-Coupling; Schlenk technique; Inert atmosphere; | 100% |
With sodium phosphate dodecahydrate In water; isopropyl alcohol at 80℃; for 1h; Reagent/catalyst; Sonogashira Cross-Coupling; Inert atmosphere; | 100% |
4-Iodoacetophenone
acrylic acid methyl ester
methyl (2E)-3-(4-acetylphenyl)acrylate
Conditions | Yield |
---|---|
With PdCl2[4,4'-bis(n-C10F21CH2OCH2)-2,2'-bipyridine]; triethylamine In N,N-dimethyl-formamide at 145℃; for 0.167h; Catalytic behavior; Reagent/catalyst; Heck Reaction; Microwave irradiation; | 100% |
With trihexyl(tetradecyl)phosphonium chloride; sodium acetate; palladium diacetate In water at 50℃; for 2h; Heck reaction; | 99% |
With C42H50Cl2N6Pd; sodium formate; triethylamine In N,N-dimethyl-formamide at 80℃; Heck Reaction; diastereospecific reaction; | 99% |
4-Iodoacetophenone
biphenyl-4-acetaldehyde
Conditions | Yield |
---|---|
bis(η3-allyl-μ-chloropalladium(II)) In N,N-dimethyl-formamide at 95℃; for 21h; | 100% |
4-Iodoacetophenone
(R)-(+)-1-(4-iodophenyl)ethanol
Conditions | Yield |
---|---|
With magnesium chloride In isopropyl alcohol at 25℃; pH=7; Catalytic behavior; | 100% |
With (S,S)-RuCl2(2,2'-bis(di-3,5-xylylphosphino)-1,1'-binaphthyl)(1,1-dianisyl-2-isopropyl-1,2-ethylenediamine); potassium tert-butylate; hydrogen In isopropyl alcohol at 26 - 30℃; under 6080 Torr; for 4h; | 99.7% |
With C37H40MnN2O2P2(1+)*Br(1-); sodium t-butanolate In isopropyl alcohol at 50℃; for 3h; Inert atmosphere; Schlenk technique; enantioselective reaction; | 98% |
4-Iodoacetophenone
(E)-2-pyridyldimethyl-(2-thien-2-ylethenyl)silane
(E)-1-(4-acetyl)phenyl-2-(2-thienyl)ethene
Conditions | Yield |
---|---|
With bis(benzonitrile)palladium(II) dichloride; tetrabutyl ammonium fluoride In tetrahydrofuran at 60℃; Hiyama coupling; | 100% |
acrylic acid n-butyl ester
4-Iodoacetophenone
(E)-3-(4-acetylphenyl)acrylic acid butyl ester
Conditions | Yield |
---|---|
With C29H33Cl2N5Pd; tetrabutylammomium bromide; sodium carbonate In N,N-dimethyl acetamide at 140℃; for 3h; Heck reaction; Inert atmosphere; | 100% |
With tributyl-amine; chloro-[2-(9-phenyl-1,10-phenanthrolin-2-yl)phenyl]palladium In 1-methyl-pyrrolidin-2-one at 140℃; for 15h; Heck Reaction; Inert atmosphere; | 100% |
With phenyl carbamate; potassium carbonate; palladium diacetate In N,N-dimethyl-formamide at 130℃; for 2h; Heck-type reaction; | 99% |
4-Iodoacetophenone
2-Methoxyphenylboronic acid
4-acetyl-2'-methoxybiphenyl
Conditions | Yield |
---|---|
With trihexyl(tetradecyl)phosphonium chloride; potassium phosphate; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In toluene at 50℃; for 1h; Suzuki cross-coupling; | 100% |
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Suzuki cross-coupling reaction; Heating; |
Conditions | Yield |
---|---|
With trihexyl(tetradecyl)phosphonium chloride; potassium phosphate; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In toluene at 50℃; for 1h; Suzuki cross-coupling; | 100% |
Stage #1: 4-Iodoacetophenone With tetrakis(triphenylphosphine) palladium(0) In 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide at 20 - 110℃; Suzuki coupling; Inert atmosphere; Ionic liquid; Stage #2: phenylboronic acid With triethylamine In 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide; water at 20 - 110℃; Suzuki coupling; Ionic liquid; Inert atmosphere; | 100% |
With potassium carbonate In ethanol; water at 20℃; for 0.5h; Suzuki-Miyaura reaction; in air; | 100% |
4-Iodoacetophenone
2-methyl-but-3-yn-2-ol
1-(4-acetylphenyl)-3-methyl-1-butyn-3-ol
Conditions | Yield |
---|---|
With copper(l) iodide; 1-isobutyl-2,2,6,6-tetramethyl-phosphorinane*HBF4; diisopropylamine; bis(benzonitrile)palladium(II) dichloride In 1,4-dioxane at 20℃; for 6h; Sonogashira reaction; | 100% |
With piperidine; copper(l) iodide; polystyrene-N(CH2PPh2)2PdCl2 In 1,4-dioxane at 60℃; for 2h; Sonogashira coupling reaction; | 94% |
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; Inert atmosphere; | 90% |
4-Iodoacetophenone
4-Ethynylaniline
4-((4-aminophenyl)ethynyl)acetophenone
Conditions | Yield |
---|---|
With triethylamine In water at 80℃; for 0.5h; Sonogashira Cross-Coupling; | 100% |
With triethylamine; Nd2.04Cu0.95Pd0.05O4 In N,N-dimethyl-formamide at 120℃; for 16h; Sonogashira reaction; | 92% |
With Pd/SiO2; triethylamine In diethyl ether; water at 20℃; for 10h; Sonogashira Cross-Coupling; | 86% |
4-Iodoacetophenone
4-Hydroxyacetophenone
Conditions | Yield |
---|---|
With sodium hydroxide; copper(l) iodide; L-proline In water at 20 - 300℃; microwave irradiation; | 100% |
Stage #1: 4-Iodoacetophenone With copper(l) iodide; tetra(n-butyl)ammonium hydroxide In water at 60℃; for 24h; Inert atmosphere; Sealed tube; Stage #2: With hydrogenchloride In water; ethyl acetate at 20℃; for 2h; Inert atmosphere; chemoselective reaction; | 96% |
With copper(l) iodide; potassium hydroxide In water at 100℃; Inert atmosphere; | 96% |
N,N,N,N,-tetramethylethylenediamine
4-Iodoacetophenone
bis(dibenzylideneacetone)-palladium(0)
PdI(4-MeCOC6H4)(N,N,N',N'-tetramethylethylenediamine)
Conditions | Yield |
---|---|
In not given byproducts: dibenzylideneacetone; N2-atmosphere; according to Markies, A. J. et al.: J. Organomet. Chem. 482 (1994) 191; elem. anal.; | 100% |
tert-Butyl acrylate
4-Iodoacetophenone
(E)-tert-butyl 3-(4-acetylphenyl)prop-2-enoate
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride; palladium dichloride at 40℃; for 3h; Heck reaction; Inert atmosphere; neat (no solvent); | 100% |
With tributyl-amine In N,N-dimethyl-formamide at 120℃; Heck-Mizoroki reaction; | 99% |
With di-μ-iodobis(tri-tert-butylphosphino)dipalladium(l); N-ethyl-N,N-diisopropylamine In toluene at 100℃; for 15h; Heck Reaction; Inert atmosphere; Sealed tube; Glovebox; | 99% |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 0.25h; Heck Reaction; | 100% |
With triethylamine In water; acetonitrile at 120℃; for 3h; Heck Reaction; Green chemistry; | 99% |
With 3C22H14N3O2(1-)*Ho(3+)*Pd(2+)*2Cl(1-); potassium carbonate In N,N-dimethyl-formamide at 100℃; for 1h; Heck Reaction; | 99% |
(4-methylphenyl)gold(triphenylphosphine)
4-Iodoacetophenone
1-{4-[2-(4-methylphenyl)ethynyl]phenyl}ethanone
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; diisopropylamine; 1,2-bis-(diphenylphosphino)ethane In toluene at 130℃; for 16h; Sonogashira coupling; Inert atmosphere; | 100% |
4-Iodoacetophenone
4,4-dimethyl-1-phenyl-1-(pyridin-2-yl)pent-2-yn-1-ol
2-(4-acetylphenyl)-3-tert-butyl-8a-phenylindolizin-1(8aH)-one
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In acetonitrile at 90℃; for 13h; | 100% |
4-Iodoacetophenone
3-phenyl-1,1-di(pyridin-2-yl)prop-2-yn-1-ol
2-(4-acetylphenyl)-3-phenyl-8a-(pyridin-2-yl)indolizin-1(8aH)-one
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In acetonitrile at 90℃; for 13h; | 100% |
4-Iodoacetophenone
1-(4-iodophenyl)ethan-1-one oxime
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride; sodium acetate In ethanol; water at 95℃; | 100% |
With hydroxylamine hydrochloride; sodium hydroxide In methanol at 20℃; Green chemistry; | 78% |
With hydroxylamine hydrochloride; sodium acetate In ethanol; water for 1h; Reflux; |
Conditions | Yield |
---|---|
With potassium carbonate In water; N,N-dimethyl-formamide at 80℃; for 0.333333h; Suzuki-Miyaura Coupling; Green chemistry; | 100% |
With potassium carbonate In water at 25℃; for 2h; Suzuki Coupling; Schlenk technique; | 98% |
With potassium carbonate In water at 20℃; for 4h; Catalytic behavior; Suzuki-Miyaura Coupling; | 100 %Chromat. |
4,7-dichloroisatin
4-Iodoacetophenone
4,7-dichloro-3-hydroxyl-3-[2-(4-iodophenyl-2-oxoethyl)]-1,3-dihydroindol-2-one
Conditions | Yield |
---|---|
With diethylamine In methanol at 20℃; | 100% |
4-Iodoacetophenone
Conditions | Yield |
---|---|
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium hydroxide In tetrahydrofuran at 20℃; for 12h; Inert atmosphere; Schlenk technique; | 100% |
4-Iodoacetophenone
4,4'-diacetylbiphenyl
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine; [2-(Pd-Cl)-4,4'-dichlorobenzophenone oxime]2 In decane; N,N-dimethyl-formamide at 110℃; for 5h; Ullmann homocoupling; | 99% |
With potassium iodide; nickel dibromide; zinc In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide at 50℃; for 3h; | 98% |
With potassium phosphate In water at 110℃; for 48h; Ullmann Condensation; | 98% |
n-butyllithium
4-Iodoacetophenone
2-(4-iodophenyl)-2-hexanol
Conditions | Yield |
---|---|
With cerium(III) triiodide In tetrahydrofuran; hexane at -65℃; for 3h; | 99% |
Stage #1: n-butyllithium With cerium(III) chloride at -78℃; Stage #2: 4-Iodoacetophenone at -78℃; | 93% |
With cerium(III) triiodide in THF, 1) -65 deg C, 30 min., 2) -65 deg C, 3h; Yield given. Multistep reaction; |
ethanol
4-Iodoacetophenone
carbon monoxide
ethyl-4-acetylbenzoate
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene; palladium diacetate at 20 - 125℃; under 7500.75 - 22502.3 Torr; for 0.333333h; microwave irradiation; | 99% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene; palladium diacetate at 125℃; under 7757.43 Torr; for 0.333333h; microwave irradiation; | 97% |
With triethylamine at 100℃; under 3750.38 Torr; for 1.5h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
With potassium hydroxide In water at 90℃; for 5h; Mizoroki-Heck reaction; | 99% |
With potassium hydroxide In methanol at 80℃; for 24h; Heck reaction; | 65% |
With sodium carbonate; palladium dichloride In water at 100℃; Yield given; | |
With palladium diacetate; potassium carbonate In water at 120℃; for 0.416667h; Heck reaction; Microwave irradiation; | |
With potassium carbonate In water at 90℃; for 12h; Heck Reaction; Inert atmosphere; |
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