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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Chloro-4-Fluorobenzoic Acid

Cas:2252-51-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed produc

High Quality 2-Chloro-4-fluorobenzoic acid 2252-51-9 Manufacturer

Cas:2252-51-9

Min.Order:1 Kilogram

FOB Price: $4.0

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Chloro-4-fluorobenzoic acid Manufacturer/High quality/Best price/In stock

Cas:2252-51-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Chloro-4-Fluorobenzoic Acid supplier in China

Cas:2252-51-9

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

2-Chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Intermediates Transportation:by air or by sea Port:shanghai

2-Chloro-4-fluorobenzoic acid 2252-51-9

Cas:2252-51-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

2-Chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2-Chloro-4-Fluorobenzoic Acid

Cas:2252-51-9

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--2252-51-9--2-Chloro-4-fluorobenzoic acid factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable busi

TIANFUCHEM--2252-51-9--2-Chloro-4-fluorobenzoic acid factory price

Cas:2252-51-9

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

2-Chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 2252-51-9 with fast shipping

Cas:2252-51-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

2-Chloro-4-fluorobenzoic acid CAS2252-51-9

Cas:2252-51-9

Min.Order:1 Kilogram

FOB Price: $7.0 / 9.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

CAS No. 2252-51-9 Name 2-Chloro-4-fluorobenzoic acid MF C7H4ClFO2 Type Syntheses Material Intermediates Purity 99%

2-Chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzoicacid, 2-chloro-4-fluoro- 2252-51-9

Cas:2252-51-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

2-Chloro-4-fluorobenzoic acid Chemical Properties Melting point 181-183 °C (lit.) Boiling point 271.9±20.0 °C(Predicted) density 1.4016 (estimate) storage temp. Sealed in dry,Room Temperature solubility 95% ethanol:

2-Chloro-4-fluorobenzoic acid.

Cas:2252-51-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

2-Chloro-4-fluorobenzoic acid 99%

Cas:2252-51-9

Min.Order:1 Kilogram

FOB Price: $85.0 / 100.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

Beluga chemical professional supply 2-Chloro-4-fluorobenzoic acid CAS 2252-51-9 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2. Made in China

2-Chloro-4-fluorobenzoic acid CAS 2252-51-9

Cas:2252-51-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:2252-51-9

Cas:2252-51-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and qua

2-chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

cas 2252-51-9 2-Chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

2-CHLORO-4-FLUOROBENZOIC ACID

Cas:2252-51-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

2-Chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd

2-Chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 2-Chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2-Chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-Chloro-4-fluorobenzoic acid

Cas:2252-51-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Synthetic route

4-amino-2-chlorobenzoic acid
2457-76-3

4-amino-2-chlorobenzoic acid

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

Conditions
ConditionsYield
Stage #1: 4-amino-2-chlorobenzoic acid With dihydrogen peroxide In water at 40 - 50℃; for 3h; Ionic liquid;
Stage #2: With potassium fluoride In water at 40 - 50℃; for 3h; Temperature;
97.5%
2-chloro-4-fluorotoluene
452-73-3

2-chloro-4-fluorotoluene

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

Conditions
ConditionsYield
With di-tert-butyl peroxide; hydrogen bromide; oxygen; cobalt(II) acetate; manganese(II) acetate In acetic acid at 130 - 160℃; under 15514.4 Torr; for 3h;92%
With potassium dichromate; sulfuric acid
2-chloro-4-fluorobenzaldehyde
84194-36-5

2-chloro-4-fluorobenzaldehyde

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

Conditions
ConditionsYield
With hydrogenchloride; sodium chlorite In water; acetonitrile at 0 - 80℃; for 1h;90.8%
carbon monoxide
201230-82-2

carbon monoxide

2-chloro-4-fluoro-1-iodobenzene
101335-11-9

2-chloro-4-fluoro-1-iodobenzene

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

Conditions
ConditionsYield
With water; palladium diacetate; triethylamine; triphenylphosphine In 1,4-dioxane at 110℃; under 11251.1 Torr; for 2h; Flow reactor;89%
2'-chloro-4'-fluoroacetophenone
700-35-6

2'-chloro-4'-fluoroacetophenone

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

Conditions
ConditionsYield
With sodium hypobromide
3-chlorofluorobenzene
625-98-9

3-chlorofluorobenzene

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: AlCl3 / CS2 / Heating
2: aq. sodium hypobromite
View Scheme
disodium hydrogenphosphate

disodium hydrogenphosphate

phenyl 2-chloro-4-fluorobenzoate
157165-30-5

phenyl 2-chloro-4-fluorobenzoate

2-chloro-4-fluoro-4'-methylbenzophenone

2-chloro-4-fluoro-4'-methylbenzophenone

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

Conditions
ConditionsYield
With sulfuric acid; acetic anhydride; urea In dichloromethane; water
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

2-chloro-4-fluoro-5-nitrobenzoic acid
114776-15-7

2-chloro-4-fluoro-5-nitrobenzoic acid

Conditions
ConditionsYield
With sulfuric acid; nitric acid at 0 - 10℃; for 2h;99%
Stage #1: 2-choro-4-fluorobenzoic acid With zirconium chloride; sulfuric acid; cobalt(II) chloride In ethanol; water at 25℃; for 1h;
Stage #2: With nitric acid In ethanol; water at -5 - 8℃; for 1h; Temperature;
97.1%
With sulfuric acid; nitric acid at 20℃; for 1h;96%
methanol
67-56-1

methanol

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

methyl 2-chloro-4-fluorobenzoate
85953-29-3

methyl 2-chloro-4-fluorobenzoate

Conditions
ConditionsYield
With chloro-trimethyl-silane at 20℃; for 24h;99%
With sulfuric acid at 60℃; for 17h;96%
With thionyl chloride95%
With sulfuric acid at 60℃; for 10h;92%
With sulfuric acid
4-Fluorophenol
371-41-5

4-Fluorophenol

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

4-fluoro-2-(4-fluorophenoxy)benzoic acid

4-fluoro-2-(4-fluorophenoxy)benzoic acid

Conditions
ConditionsYield
With pyridine; copper(l) iodide; copper; potassium carbonate In water for 2h; Heating / reflux;99%
With pyridine; copper(l) iodide; copper; potassium carbonate In water for 2h; Heating / reflux;99%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

2-chloro-4-fluoro-5-iodobenzoic acid
264927-52-8

2-chloro-4-fluoro-5-iodobenzoic acid

Conditions
ConditionsYield
With sodium iodate; iodine In sulfuric acid at 20℃; for 8h;99%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

N,O-dimethylhydroxylamine*hydrochloride
6638-79-5

N,O-dimethylhydroxylamine*hydrochloride

2-chloro-4-fluoro-N-methoxy-N-methylbenzamide

2-chloro-4-fluoro-N-methoxy-N-methylbenzamide

Conditions
ConditionsYield
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In dichloromethane at 15℃; for 3h;98.66%
2-amino-benzthiazole
136-95-8

2-amino-benzthiazole

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

3-fluoro-12H-[1,3]benzothiazolo-[2,3-b]quinazolin-12-one

3-fluoro-12H-[1,3]benzothiazolo-[2,3-b]quinazolin-12-one

Conditions
ConditionsYield
With copper; potassium carbonate In N,N-dimethyl-formamide at 25℃; for 0.416667h; sonication;93%
With copper Ullmann condensation; Sonication;
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

N-t-Butyl-2-chloro-4-fluorobenzamide
223444-50-6

N-t-Butyl-2-chloro-4-fluorobenzamide

Conditions
ConditionsYield
93%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

2-(3-formyl-2-oxoquinolin-1(2H)-yl)acetohydrazide

2-(3-formyl-2-oxoquinolin-1(2H)-yl)acetohydrazide

1-((5-(2-chloro-4-fluorophenyl)-1,3,4-oxadiazol-2-yl)methyl)-1,2-dihydro-2-oxoquinoline-3-carbaldehyde

1-((5-(2-chloro-4-fluorophenyl)-1,3,4-oxadiazol-2-yl)methyl)-1,2-dihydro-2-oxoquinoline-3-carbaldehyde

Conditions
ConditionsYield
With trichlorophosphate at 110 - 120℃; Reflux;93%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

benzylamine
100-46-9

benzylamine

4-fluoro-N-benzylanthranilic acid
1002965-92-5

4-fluoro-N-benzylanthranilic acid

Conditions
ConditionsYield
With copper(I) oxide; copper; potassium carbonate In various solvent(s) at 130℃; for 24h;92%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

(2-chloro-4-fluorophenyl)methanol
208186-84-9

(2-chloro-4-fluorophenyl)methanol

Conditions
ConditionsYield
With borane-THF In tetrahydrofuran at 0 - 20℃; for 2h;91.3%
pyrrolidine
123-75-1

pyrrolidine

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

4-fluoro-2-(1-pyrrolidinyl)benzoic acid

4-fluoro-2-(1-pyrrolidinyl)benzoic acid

Conditions
ConditionsYield
With copper; potassium carbonate In N,N-dimethyl-formamide at 25℃; for 0.25h; Ullmann condensation; ultrasonic irradiation;89%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

(2-Carboxy-6-fluorophenyl)propanedioic acid dimethyl ester

(2-Carboxy-6-fluorophenyl)propanedioic acid dimethyl ester

Conditions
ConditionsYield
With NaH; copper(I) bromide In water; mineral oil89%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

benzylamine
100-46-9

benzylamine

2-chloro-N-benzyl-4-fluorobenzamide
886624-05-1

2-chloro-N-benzyl-4-fluorobenzamide

Conditions
ConditionsYield
Stage #1: 2-choro-4-fluorobenzoic acid With triethylamine; isobutyl chloroformate In dichloromethane for 0.25h; Inert atmosphere; Schlenk technique;
Stage #2: benzylamine In dichloromethane at 0℃;
89%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

(E)-2-(tert-butyldiphenylsilyloxymethyl)-4-hydroxy-2-butenenitrile
639008-45-0

(E)-2-(tert-butyldiphenylsilyloxymethyl)-4-hydroxy-2-butenenitrile

2-chloro-4-fluoro-benzoic acid 4-(tert-butyl-diphenyl-silanyloxy)-3-cyano-but-2-enyl ester

2-chloro-4-fluoro-benzoic acid 4-(tert-butyl-diphenyl-silanyloxy)-3-cyano-but-2-enyl ester

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In toluene88%
propylamine
107-10-8

propylamine

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

4-fluoro-2-(propylamino)benzoic acid

4-fluoro-2-(propylamino)benzoic acid

Conditions
ConditionsYield
With copper; potassium carbonate In N,N-dimethyl-formamide at 25℃; for 0.416667h; Ullmann condensation; ultrasonic irradiation;87%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

4-chloro-3-[5-(trifluoromethyl)pyridin-2-yl]aniline

4-chloro-3-[5-(trifluoromethyl)pyridin-2-yl]aniline

2-chloro-N-{4-chloro-3-[5-(trifluoromethyl)pyridin-2-yl]phenyl}-4-fluorobenzamide

2-chloro-N-{4-chloro-3-[5-(trifluoromethyl)pyridin-2-yl]phenyl}-4-fluorobenzamide

Conditions
ConditionsYield
With 2-(7-azobenzotriazolyl)-N,N,N’,N’-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 0 - 20℃; for 16h;86.4%
piperidine
110-89-4

piperidine

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

4-fluoro-2-(1-piperidinyl)benzoic acid
865471-09-6

4-fluoro-2-(1-piperidinyl)benzoic acid

Conditions
ConditionsYield
With copper; potassium carbonate In N,N-dimethyl-formamide at 25℃; for 0.25h; Ullmann condensation; ultrasonic irradiation;86%
1-(tert-butyl)-2-iodobenzene
62171-59-9

1-(tert-butyl)-2-iodobenzene

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

3-fluoro-9,9-dimethyl-9,10-dihydrophenanthrene

3-fluoro-9,9-dimethyl-9,10-dihydrophenanthrene

Conditions
ConditionsYield
With tetrabutyl-ammonium chloride; palladium diacetate; potassium carbonate; Tri(p-tolyl)phosphine In N,N-dimethyl-formamide at 140℃; for 12h; Schlenk technique; Inert atmosphere;86%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

C7H4ClFO5S
714968-44-2

C7H4ClFO5S

Conditions
ConditionsYield
With chlorosulfonic acid at 150℃; for 6h;85%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide
572-09-8

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

1-O-(2-chloro-4-fluorobenzoyl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranose

1-O-(2-chloro-4-fluorobenzoyl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranose

Conditions
ConditionsYield
With tetraethylammonium bromide; potassium carbonate In dichloromethane at 20℃; Molecular sieve;85%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

m-Anisidine
536-90-3

m-Anisidine

C14H12FNO3

C14H12FNO3

Conditions
ConditionsYield
With copper; potassium carbonate In pentan-1-ol at 20℃; for 5h; Reflux;85%
(S)-Leu-OMe
2666-93-5

(S)-Leu-OMe

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

methyl (2-chloro-4-fluorobenzoyl)-L-leucinate

methyl (2-chloro-4-fluorobenzoyl)-L-leucinate

Conditions
ConditionsYield
Stage #1: 2-choro-4-fluorobenzoic acid With N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate In N,N-dimethyl-formamide at 0℃;
Stage #2: (S)-Leu-OMe In N,N-dimethyl-formamide at 0 - 20℃;
84%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

3,5-dimethylphenyl iodide
22445-41-6

3,5-dimethylphenyl iodide

3-chloro-5-fluoro-3',5'-dimethyl-1,1'-biphenyl
1344681-42-0

3-chloro-5-fluoro-3',5'-dimethyl-1,1'-biphenyl

Conditions
ConditionsYield
With palladium diacetate; acetic acid; silver carbonate at 130℃; for 16h; regioselective reaction;83%
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

methyl 2-(4-chloro-6-fluoro-3-oxo-1,3-dihydroisobenzofuran-1-yl)acetate

methyl 2-(4-chloro-6-fluoro-3-oxo-1,3-dihydroisobenzofuran-1-yl)acetate

Conditions
ConditionsYield
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; oxygen; potassium hydrogencarbonate; acetic acid In 1,2-dichloro-ethane at 60℃; for 24h; Schlenk technique; Inert atmosphere;83%
morpholine
110-91-8

morpholine

2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

4-fluoro-2-(4-morpholinyl)benzoic acid

4-fluoro-2-(4-morpholinyl)benzoic acid

Conditions
ConditionsYield
With copper; potassium carbonate In N,N-dimethyl-formamide at 25℃; for 0.25h; Ullmann condensation; ultrasonic irradiation;82%
With copper(l) iodide; potassium carbonate In N,N-dimethyl-formamide at 90℃; for 2h;13%
With copper(l) iodide; potassium carbonate In N,N-dimethyl-formamide at 90℃; for 2h;
2-choro-4-fluorobenzoic acid
2252-51-9

2-choro-4-fluorobenzoic acid

[1,1'-biphenyl]-2,2'-iodonium trifluoromethanesulfonate
189999-35-7

[1,1'-biphenyl]-2,2'-iodonium trifluoromethanesulfonate

2-fluorotriphenylene
439-23-6

2-fluorotriphenylene

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate In 1-methyl-pyrrolidin-2-one at 110℃; for 12h;81%
With palladium diacetate; potassium carbonate In 1-methyl-pyrrolidin-2-one at 110℃; for 17h;81%

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