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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Ethanone,2,2-dichloro-1-phenyl- Manufacturer/High quality/Best price/In stock

Cas:2648-61-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2,2-Dichloroacetophenone

Cas:2648-61-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

2,2-DICHLOROACETOPHENONE CAS 2648-61-5

Cas:2648-61-5

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 2648-61-5 with competitive price

Cas:2648-61-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Ethanone,2,2-dichloro-1-phenyl-

Cas:2648-61-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Ethanone,2,2-dichloro-1-phenyl-

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2,2-Dichloroacetophenone

Cas:2648-61-5

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2,2-Dichloroacetophenone

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

In Bulk Supply2,2-DICHLOROACETOPHENONE

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: 2,2-DICHLOROACETOPHENONE Synonyms: 2,2-dichloro-acetophenon;Acetophenone, 2,2-dichloro-;Ethanone, 2,2-dichloro-1-phenyl-;Ethanone,2,2-dichloro-1-phenyl-;omega,omega-Dichloroacetophenone;alpha,alpha-Dichloroacetophenone,97%;à,

2648-61-5---2,2-DICHLOROACETOPHENONE

Cas:2648-61-5

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2,2-DICHLOROACETOPHENONE

Cas:2648-61-5

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2,2-Dichloroacetophenone

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

2,2-DICHLOROACETOPHENONE

Cas:2648-61-5

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2,2-dichloroacetophenon

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2,2-Dichloroacetophenone

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2,2-Dichloroacetophenone

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

2,2-DICHLOROACETOPHENONE

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world.2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%.3,our staff consists of highly qualified in

2,2-DICHLOROACETOPHENONE

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2,2-Dichloroacetophenone

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

DB BIOTECH CO., LTD

best seller Application:API

2,2-DICHLOROACETOPHENONE

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Ethanone,2,2-dichloro-1-phenyl- cas 2648-61-5Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Ethanone,2,2-dichloro-1-phenyl- cas 2648-61-5

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2,2-DICHLOROACETOPHENONE

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

2,2-Dichloroacetophenone

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Helios Biomedical Science and Technology Co.,LTD.

Changzhou Helios Biochemical Co., Ltd is a leading manufacturer and supplier for medical intermediates and pesticide intermediates . We specialize in custom synthesis of benzene ring, pyridine and pyrimidine derivatives to help customers to accelerat

2,2-DICHLOROACETOPHENONE

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:5g Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any port

2,2-Dichloroacetophenone

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Muhuang Technology Co., Ltd

best seller Application:API

2,2-DICHLOROACETOPHENONE

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

2,2-Dichloroacetophenone 2648-61-5

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shenzhen Foris Technology Co. LTD

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

2,2-Dichloroacetophenone 2648-61-5

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2,2-DICHLOROACETOPHENONE

Cas:2648-61-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

2,2-dichloro-1-phenylethanone

Cas:2648-61-5

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

N-(2,2-dichloro-3-oxo-1,3-diphenylpropyl)phenylsulfonamide
907563-74-0

N-(2,2-dichloro-3-oxo-1,3-diphenylpropyl)phenylsulfonamide

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With potassium hydroxide In tetrahydrofuran; water at 20℃; for 4h; retro-aldol reaction;100%
acetophenone
98-86-2

acetophenone

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With chlorine In methanol at 40℃; under 760.051 - 1520.1 Torr; Solvent; Temperature;99.1%
With 1-methyl-3-(4-sulfonylbutyl)-1H-imidazol-3-ium trifluoromethanesulfonate; N-chloro-succinimide at 70℃; Green chemistry;96%
With chlorine In acetic acid at 51 - 56℃; for 4.5h;95.5%
phenylacetylene
536-74-3

phenylacetylene

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With Oxone; potassium chloride In water; acetonitrile at 20℃; for 0.166667h; Reagent/catalyst;98%
With trichloroisocyanuric acid; p-methylphenylthiourea; water at 20℃; for 0.333333h; Reagent/catalyst; Temperature; Sealed tube; Sonication; Green chemistry; chemoselective reaction;92%
With hydrogenchloride; sulfuric acid; lithium perchlorate In water; acetonitrile at 10 - 20℃; for 4.25h; Mechanism; Reagent/catalyst; Electrochemical reaction; Electrolysis; Green chemistry;92%
2,2,2-trichloroacetophenone
2902-69-4

2,2,2-trichloroacetophenone

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With methanol; triphenylphosphine In dichloromethane at 0℃; for 0.166667h; Appel Halogenation; Inert atmosphere; chemoselective reaction;97%
With 10% Pt/activated carbon; hydrogen In N,N-dimethyl acetamide at 25℃; under 760.051 Torr; for 0.7h; Catalytic behavior; chemoselective reaction;89%
With palladium 10% on activated carbon; hydrogen In N,N-dimethyl acetamide at 25℃; under 760.051 Torr; for 0.7h; chemoselective reaction;88%
dichloromethane
75-09-2

dichloromethane

N-methoxy-N-methylbenzamide
6919-61-5

N-methoxy-N-methylbenzamide

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With methyllithium lithium bromide; diisopropylamine In tetrahydrofuran at -78℃; for 1h; Inert atmosphere; chemoselective reaction;90%
2,4-Xylidine
95-68-1

2,4-Xylidine

benzoyl(dichloro)acetaldehyde
160663-32-1

benzoyl(dichloro)acetaldehyde

A

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

B

N-(2,4-dimethylphenyl)formamide
60397-77-5

N-(2,4-dimethylphenyl)formamide

Conditions
ConditionsYield
In tetrachloromethane for 12h; Ambient temperature;A 80%
B 89%
benzoyl(dichloro)acetaldehyde
160663-32-1

benzoyl(dichloro)acetaldehyde

A

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

B

N-(2,4-dimethylphenyl)formamide
60397-77-5

N-(2,4-dimethylphenyl)formamide

Conditions
ConditionsYield
With 2,4-Xylidine In tetrachloromethane for 12h; Ambient temperature;A 80%
B 89%
1-Phenyl-2-(trimethylsilyl)acetylene
2170-06-1

1-Phenyl-2-(trimethylsilyl)acetylene

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With trichloroisocyanuric acid; p-methylphenylthiourea; water at 20℃; for 0.333333h; Sealed tube; Sonication; Green chemistry; chemoselective reaction;88%
2-(dimethyl(oxo)-λ6-sulfaneylidene)-1-phenylethan-1-one
20718-17-6

2-(dimethyl(oxo)-λ6-sulfaneylidene)-1-phenylethan-1-one

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With trichloroisocyanuric acid; tetrabutyl-ammonium chloride In tetrahydrofuran at 0 - 25℃; for 24h; Sealed tube;87%
acetophenone
98-86-2

acetophenone

A

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

B

1-chloroacetophenone
532-27-4

1-chloroacetophenone

Conditions
ConditionsYield
With hydrogenchloride; dihydrogen peroxide In ethanol at 91 - 93℃; for 0.25h; Product distribution; Further Variations:; Solvents; Temperatures; time;A 85%
B 4.5%
With N-chloro-succinimide; 1-(n-butyl)-3-methylimidazolium triflate at 70℃; for 0.5h; Catalytic behavior; Reagent/catalyst; Concentration; Green chemistry;A n/a
B 74%
With N-chloro-succinimide; toluene-4-sulfonic acid at 20℃; for 24h;A 4%
B 70%
3-oxo-3-phenylpropanamide
3446-58-0

3-oxo-3-phenylpropanamide

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With N-chloro-succinimide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium tert-butylate In tetrahydrofuran at 80℃; for 4h; Reagent/catalyst; Time; Solvent; Temperature; Concentration;83%
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; N-chloro-succinimide; potassium tert-butylate In tetrahydrofuran at 80℃; for 4h; Reagent/catalyst; Solvent; Temperature;83%
Multi-step reaction with 2 steps
1: N-chloro-succinimide / methanol / 5 h / 20 °C
2: N-chloro-succinimide; potassium tert-butylate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / tetrahydrofuran / 4 h / 80 °C
View Scheme
Multi-step reaction with 2 steps
1: N-chloro-succinimide / methanol / 5 h / 20 °C
2: potassium tert-butylate / tetrahydrofuran / 4 h / 80 °C
View Scheme
1-iodo-2-phenylethyne
932-88-7

1-iodo-2-phenylethyne

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With iodine; sodium chloride In dimethyl sulfoxide at 20℃; for 4h;81%
2,2-dichloro-1-phenyl-2-(phenylsulfinyl)-1-ethanol
86002-02-0

2,2-dichloro-1-phenyl-2-(phenylsulfinyl)-1-ethanol

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
In neat (no solvent) at 150℃; under 1 Torr; for 0.0833333h;80%
1-phenyl-3-dimethylaminoprop-2-enone
1201-93-0

1-phenyl-3-dimethylaminoprop-2-enone

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With N-chloro-succinimide; dibenzoyl peroxide In para-xylene at 60℃; for 12h;80%
1-Phenylethanol
98-85-1, 13323-81-4

1-Phenylethanol

A

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

B

1-chloroacetophenone
532-27-4

1-chloroacetophenone

C

acetophenone
98-86-2

acetophenone

Conditions
ConditionsYield
With methanol; trichloroisocyanuric acid In dichloromethane at 20℃; for 5h;A 10 %Chromat.
B 78%
C 8 %Chromat.
phenylacetylene
536-74-3

phenylacetylene

A

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

B

1-chloroacetophenone
532-27-4

1-chloroacetophenone

Conditions
ConditionsYield
With iodine; sodium chloride In dimethyl sulfoxide at 20℃; for 4h;A 78%
B 9%
With hydrogenchloride; iodine In dimethyl sulfoxide at 20℃; for 16h;A 19%
B 73%
2-chloro-3-oxo-3-phenylpropanamide

2-chloro-3-oxo-3-phenylpropanamide

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With N-chloro-succinimide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium tert-butylate In tetrahydrofuran at 80℃; for 4h; Reagent/catalyst;77%
(2,2-Dichloro-1-ethoxy-vinyl)-benzene
78176-13-3

(2,2-Dichloro-1-ethoxy-vinyl)-benzene

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With trifluoroacetic acid In water at 65℃; for 7h;76%
2,2-dichloro-1-phenylethanol
2612-36-4

2,2-dichloro-1-phenylethanol

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen In tert-butyl methyl ether at 20℃; under 760.051 Torr; for 24h; Kinetics; Thermodynamic data; Concentration; pH-value; Reagent/catalyst; Solvent; Temperature; Time; Enzymatic reaction;76%
α-Phenyl-β,β-dichlorvinyl-methylether
27904-75-2

α-Phenyl-β,β-dichlorvinyl-methylether

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With sulfuric acid In 1,4-dioxane; water Heating;75%
methanol
67-56-1

methanol

benzaldehyde
100-52-7

benzaldehyde

A

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

B

α-chloroacetophenone dimethyl acetal
33604-55-6

α-chloroacetophenone dimethyl acetal

Conditions
ConditionsYield
With piperidine; 1,3-dichloro-5,5-dimethylhydantoin for 12h; Molecular sieve; Reflux;A 7 %Spectr.
B 72%
C9H7Cl2NO2

C9H7Cl2NO2

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran at 80℃; for 4h; Reagent/catalyst;71%
1-Phenyl-4,4,4-trifluorobutane-1,3-dione
326-06-7

1-Phenyl-4,4,4-trifluorobutane-1,3-dione

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With N-chloro-N-methoxybenzenesulfonamide; potassium carbonate In acetonitrile at 20℃;70%
benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

dichloromethane
75-09-2

dichloromethane

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With lithium dicyclohexylamide In tetrahydrofuran at -78℃; for 0.333333h;66%
N-(2,2-Dichloro-1-hydroxy-3-oxo-3-phenyl-propyl)-acetamide
184970-72-7

N-(2,2-Dichloro-1-hydroxy-3-oxo-3-phenyl-propyl)-acetamide

A

acetamide
60-35-5

acetamide

B

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With sodium hydroxide In ethanol for 12h; Ambient temperature;A n/a
B 60%
N-(2,2-Dichloro-1-hydroxy-3-oxo-3-phenyl-propyl)-benzamide
184970-73-8

N-(2,2-Dichloro-1-hydroxy-3-oxo-3-phenyl-propyl)-benzamide

A

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

B

benzamide
55-21-0

benzamide

Conditions
ConditionsYield
With sodium hydroxide In ethanol for 12h; Ambient temperature;A 60%
B n/a
dichloroacethyl chloride
79-36-7

dichloroacethyl chloride

benzene
71-43-2

benzene

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With aluminium trichloride for 3h; Ambient temperature;55.2%
With aluminium trichloride
2,2,2-trichloroacetophenone
2902-69-4

2,2,2-trichloroacetophenone

lithium thiophenoxide
2973-86-6

lithium thiophenoxide

A

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

B

ω,ω-bis(phenylthio)acetophenone
22805-27-2

ω,ω-bis(phenylthio)acetophenone

Conditions
ConditionsYield
In tetrahydrofuran at -78℃; for 0.166667h;A 40%
B 50%
α-bromoacetophenone
70-11-1

α-bromoacetophenone

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
ConditionsYield
With antimonypentachloride In tetrachloromethane for 8h; Heating;47%
benzoyl(dichloro)acetaldehyde
160663-32-1

benzoyl(dichloro)acetaldehyde

sodium 1-propanethiolate
6898-84-6

sodium 1-propanethiolate

A

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

B

3-chloro-1-phenyl-3-propylthio-1,2-propanedione

3-chloro-1-phenyl-3-propylthio-1,2-propanedione

Conditions
ConditionsYield
In diethyl ether for 1h; Heating;A 40%
B 40%
2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

4,4,5,5-tetramethyl-2-(2-methylallyl)-1,3,2-dioxaborolane
167773-10-6

4,4,5,5-tetramethyl-2-(2-methylallyl)-1,3,2-dioxaborolane

(R)-1,1-dichloro-4-methyl-2-phenylpent-4-en-2-ol

(R)-1,1-dichloro-4-methyl-2-phenylpent-4-en-2-ol

Conditions
ConditionsYield
With methanol; (S)-N-(3-(tert-butyl)-2-hydroxybenzyl)-1-(dimethylamino)-3-methyl-1-oxobutan-2-aminium; zinc dimethoxide In toluene at -40℃; for 18h; Inert atmosphere; Glovebox; enantioselective reaction;98%
2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

isovaleraldehyde
590-86-3

isovaleraldehyde

(E)-5-methyl-1-phenyl-hex-2-en-1-one
15175-34-5

(E)-5-methyl-1-phenyl-hex-2-en-1-one

Conditions
ConditionsYield
With chromium dichloride In tetrahydrofuran for 2h; Heating;97%
furfural
98-01-1

furfural

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Furfuralacetophenon
22488-76-2

Furfuralacetophenon

Conditions
ConditionsYield
With chromium dichloride In tetrahydrofuran for 2h; Heating;96%
methanol
67-56-1

methanol

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

2,2-dimethoxy-1-phenylethanone
6956-56-5

2,2-dimethoxy-1-phenylethanone

Conditions
ConditionsYield
With sodium carbonate at 80℃; for 12h; Green chemistry;96%
methanol
67-56-1

methanol

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

phenylglyoxal dimethylacetal
19159-39-8

phenylglyoxal dimethylacetal

Conditions
ConditionsYield
With sodium methylate for 4h; Ambient temperature;95%
With sodium methylate Ambient temperature;51%
2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

2,2,2-trichloroacetophenone
2902-69-4

2,2,2-trichloroacetophenone

Conditions
ConditionsYield
With manganese triacetate; lithium chloride In acetic acid for 3.5h; Product distribution; Mechanism; Heating; without LiCl; other time and molar ratio;;95%
94%
2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

phenylacetaldehyde
122-78-1

phenylacetaldehyde

(E)-1,4-diphenylbut-2-en-1-one
34587-61-6

(E)-1,4-diphenylbut-2-en-1-one

Conditions
ConditionsYield
With chromium dichloride In tetrahydrofuran for 2h; Heating;95%
2-Methylbutyraldehyde
96-17-3, 57456-98-1

2-Methylbutyraldehyde

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

(E)-4-Methyl-1-phenyl-hex-2-en-1-one

(E)-4-Methyl-1-phenyl-hex-2-en-1-one

Conditions
ConditionsYield
With chromium dichloride In tetrahydrofuran for 2h; Heating;94%
2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

-α-(Dichlormethyl)benzolmethanol

-α-(Dichlormethyl)benzolmethanol

Conditions
ConditionsYield
With trimethylaluminum; C44H42O2; isopropyl alcohol In pentane at -10℃; for 24h; Meerwein-Ponndorf-Verley Reduction; Molecular sieve; enantioselective reaction;94%
With alcohol dehydrogenase from Lactobacillus brevis; isopropyl alcohol In aq. phosphate buffer; dimethyl sulfoxide at 30℃; for 48h; pH=7.5; Kinetics; Enzymatic reaction; enantioselective reaction;n/a
With alcohol dehydrogenase from Lactobacillus brevis; NADPH; magnesium chloride In isopropyl alcohol at 30℃; for 24h; pH=7.5; Reagent/catalyst; Enzymatic reaction; enantioselective reaction;n/a
With glucose dehydrogenase; D-Glucose; Sporobolomyces salmonicolor carbonyl reductase S224A; nicotinamide adenine dinucleotide phosphate In aq. phosphate buffer; dimethyl sulfoxide at 20℃; pH=7; Reagent/catalyst; Enzymatic reaction; enantioselective reaction;n/a
3-Bromopyridine
626-55-1

3-Bromopyridine

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

dimethyl 9-bromo-2-(dichloromethyl)-2-phenyl-2H,9aH-pyrido[2,1-b][1,3]oxazine-3,4-dicarboxylate
1401312-79-5

dimethyl 9-bromo-2-(dichloromethyl)-2-phenyl-2H,9aH-pyrido[2,1-b][1,3]oxazine-3,4-dicarboxylate

Conditions
ConditionsYield
In diethyl ether; dichloromethane at 20℃; stereoselective reaction;93%
tert-butylisonitrile
119072-55-8, 7188-38-7

tert-butylisonitrile

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

acetylenedicarboxylic acid diethyl ester
762-21-0

acetylenedicarboxylic acid diethyl ester

diethyl 5-(tert-butylimino)-2-(dichloromethyl)-2-phenyl-2,5-dihydrofuran-3,4-dicarboylate
1379588-53-0

diethyl 5-(tert-butylimino)-2-(dichloromethyl)-2-phenyl-2,5-dihydrofuran-3,4-dicarboylate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 1h; chemoselective reaction;92%
2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

((2RS,3RS)-2-chloro-3-(4-nitrophenyl)oxiran-2-yl)(phenyl)methanone

((2RS,3RS)-2-chloro-3-(4-nitrophenyl)oxiran-2-yl)(phenyl)methanone

Conditions
ConditionsYield
Stage #1: 2,2-dichloroacetophenone With sodium hydride In tetrahydrofuran; mineral oil at 20℃; Inert atmosphere;
Stage #2: 4-nitrobenzaldehdye In tetrahydrofuran; mineral oil at 20℃; Inert atmosphere;
92%
2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

dimethyl 1-benzoyl-7-(dimethylamino)indolizine-2,3-dicarboxylate

dimethyl 1-benzoyl-7-(dimethylamino)indolizine-2,3-dicarboxylate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h; chemoselective reaction;92%
isoquinoline
119-65-3

isoquinoline

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

dimethyl 2-(dichloromethyl)-2-phenyl-2H,11bH-[1,3]oxazino[2,3-a]isoquinoline-3,4-dicarboxylate

dimethyl 2-(dichloromethyl)-2-phenyl-2H,11bH-[1,3]oxazino[2,3-a]isoquinoline-3,4-dicarboxylate

Conditions
ConditionsYield
In diethyl ether; dichloromethane at 20℃; for 4h; diastereoselective reaction;92%
2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

2-Phenylpropanal
34713-70-7

2-Phenylpropanal

(E)-(4RS)-1,4-diphenylpent-2-en-1-one
114245-62-4

(E)-(4RS)-1,4-diphenylpent-2-en-1-one

Conditions
ConditionsYield
With chromium dichloride In tetrahydrofuran for 2h; Heating;91%
3-Chloropyridine
626-60-8

3-Chloropyridine

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

dimethyl 9-chloro-2-(dichloromethyl)-2-phenyl-2H,9aH-pyrido[2,1-b][1,3]oxazine-3,4-dicarboxylate
1401312-83-1

dimethyl 9-chloro-2-(dichloromethyl)-2-phenyl-2H,9aH-pyrido[2,1-b][1,3]oxazine-3,4-dicarboxylate

Conditions
ConditionsYield
In diethyl ether; dichloromethane at 20℃; stereoselective reaction;91%
4-aminopyridine
504-24-5

4-aminopyridine

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

dimethyl 7-amino-1-benzoylindolizine-2,3-dicarboxylate

dimethyl 7-amino-1-benzoylindolizine-2,3-dicarboxylate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; chemoselective reaction;91%
2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

phenacylacetophenone
495-71-6

phenacylacetophenone

Conditions
ConditionsYield
With indium(I) bromide In tetrahydrofuran at 20℃; for 24h;90%
Octanal
124-13-0

Octanal

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

(E)‐1‐phenyldec‐2‐en‐1‐one

(E)‐1‐phenyldec‐2‐en‐1‐one

Conditions
ConditionsYield
With chromium dichloride In tetrahydrofuran for 2h; Heating;90%
tert-butylisonitrile
119072-55-8, 7188-38-7

tert-butylisonitrile

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

dimethyl 5-(tert-butylimino)-2-(dichloromethyl)-2-phenyl-2,5-dihydrofuran-3,4-dicarboxylate
1379588-52-9

dimethyl 5-(tert-butylimino)-2-(dichloromethyl)-2-phenyl-2,5-dihydrofuran-3,4-dicarboxylate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 1h; chemoselective reaction;90%
2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

acetylenedicarboxylic acid diethyl ester
762-21-0

acetylenedicarboxylic acid diethyl ester

diethyl 1-benzoyl-7-(dimethylamino)indolizine-2,3-dicarboxylate

diethyl 1-benzoyl-7-(dimethylamino)indolizine-2,3-dicarboxylate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; chemoselective reaction;90%
2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

2,2-dichloro-1-phenylethanol
2612-36-4

2,2-dichloro-1-phenylethanol

Conditions
ConditionsYield
With sodium hydroxide; sodium tetrahydroborate In ethanol -> 28 deg C (10 min.), 10 min.;88.1%
With formic acid; 4-methoxy-N-(1-(naphthalen-2-yl)ethylidene)aniline; sodium formate In water at 80℃; for 18h; pH=4.5; Inert atmosphere; chemoselective reaction;87%
With sodium tetrahydroborate In ethanol at 20 - 22℃; for 17.33h; Cooling with ice;73%

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