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Hangzhou Sartort Biopharma Co., Ltd

Appearance:clear colorless liquid Storage:R.T Package:200kg/Barrel Application:Mainly used for UV polymerization, coating and resin synthesis Transportation:Express/Sea/Air Port:Any port in China

Factory supply 3-Ethyl-3-oxetanemethanol with best price

Cas:3047-32-3

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

3-Ethyl-3-oxetanemethanol Manufacturer/High quality/Best price/In stock

Cas:3047-32-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3-ethyloxetane-3-methanol

Cas:3047-32-3

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Ethyl-3-(hydroxymethyl)-oxetane

Cas:3047-32-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

3-ETHYL-3-OXETANEMETHANOL

Cas:3047-32-3

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: 3-Ethyl-3-oxethanemethanol CAS:3047-32-3 MF: C6H12O2 Appearance:Colorless Transparent Liquid Storage: Preserve in well-closed, light-resistant and airtight containers. Package:25kg Application:UV/EB Monomer Transportation:By sea Port:Qingdao

3-Ethyl-3-oxethanemethanol

Cas:3047-32-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

3047-32-3 3-ETHYL-3-OXETANEMETHANOL

Cas:3047-32-3

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 3047-32-3 with best quality

Cas:3047-32-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

3-Oxetanemethanol,3-ethyl- 3047-32-3

Cas:3047-32-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

3-Oxetanemethanol,3-ethyl-

Cas:3047-32-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:3047-32-3

Cas:3047-32-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

3-Ethyl-(hydroxymethyl)oxetane

Cas:3047-32-3

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

3-ETHYL-3-OXETANEMETHANOL

Cas:3047-32-3

Min.Order:1 Kilogram

FOB Price: $11.0 / 15.0

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

3-Ethyl-3-Oxetanemethanol

Cas:3047-32-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Ethyl-(hydroxymethyl)oxetane

Cas:3047-32-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

(3-ethyloxetan-3-yl)methanol

Cas:3047-32-3

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd

OXT 101

Cas:3047-32-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Oxetanemethanol,3-ethyl-

Cas:3047-32-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and als

3-ETHYL-3-OXETANEMETHANOL

Cas:3047-32-3

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

3-Ethyl-(hydroxymethyl)oxetane

Cas:3047-32-3

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality moderate price & quick delivery Appearance:CLEAR colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used to

3-Oxetanemethanol,3-ethyl-

Cas:3047-32-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: 3-Ethyl-(Hydroxymethyl)Oxetane CAS No.:3047-32-3 Molecule Formula:C6H12O2 Molecule Weight:116.16 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS

High Quality 3-Ethyl-(Hydroxymethyl)Oxetane on stock

Cas:3047-32-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Product Name:3-Ethyl-3-oxetanemethanol CAS No:3047-

3-Ethyl-3-oxetanemethanol

Cas:3047-32-3

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

3-Ethyl-(hydroxymethyl)oxetane

Cas:3047-32-3

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Hangzhou Huarong Pharm Co., Ltd.

We Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O

3-ETHYL-3-OXETANEMETHANOL

Cas:3047-32-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

3-Ethyl-(hydroxymethyl)oxetane

Cas:3047-32-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

3047-32-3 CAS NO.3047-32-3

Cas:3047-32-3

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

3-ETHYL-3-OXETANEMETHANOL

Cas:3047-32-3

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Shanghai Finebiotech Co.,Ltd.

Shanghai Finebiotech Co.,Ltd.was established in 2020, which providing professional chemical services. As a customer-oriented company, we have distinguished ourself from others in providing worldwide customers with cost-effective and efficient service

(3-ethyloxetan-3-yl)methanol

Cas:3047-32-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

3-Ethyl-(hydroxymethyl)oxetane

Cas:3047-32-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

1,1,1-tri(hydroxymethyl)propane
77-99-6

1,1,1-tri(hydroxymethyl)propane

3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
With potassium carbonate; Diethyl carbonate at 110℃;72%
With potassium hydroxide; Diethyl carbonate In ethanol for 2h; Reflux;64.7%
1,1,1-tri(hydroxymethyl)propane
77-99-6

1,1,1-tri(hydroxymethyl)propane

Diethyl carbonate
105-58-8

Diethyl carbonate

3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
With potassium hydroxide at 180℃; unter vermindertem Druck;
With potassium hydroxide
With potassium carbonate
1,1,1-tri(hydroxymethyl)propane
77-99-6

1,1,1-tri(hydroxymethyl)propane

Diethyl carbonate
105-58-8

Diethyl carbonate

ethanolic KOH-solution

ethanolic KOH-solution

3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
Erhitzen des Reaktionsprodukts auf Temperaturen oberhalb von 180grad;
1,1,1-tri(hydroxymethyl)propane
77-99-6

1,1,1-tri(hydroxymethyl)propane

Diethyl carbonate
105-58-8

Diethyl carbonate

A

3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

B

trimethylolpropane cyclic monocarbonate

trimethylolpropane cyclic monocarbonate

Conditions
ConditionsYield
Stage #1: 1,1,1-tri(hydroxymethyl)propane; Diethyl carbonate With potassium hydroxide at 120℃;
Stage #2: at 250℃; under 6.00048 Torr; Title compound not separated from byproducts;
1,1,1-tri(hydroxymethyl)propane
77-99-6

1,1,1-tri(hydroxymethyl)propane

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
With potassium hydroxide
trimethylene oxide
503-30-0

trimethylene oxide

carbon dioxide
124-38-9

carbon dioxide

3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
With bis(acetylacetonate)oxovanadium; tetrabutylammomium bromide In toluene at 60℃; under 26252.6 Torr; for 8h; Autoclave; Cooling with ice; chemoselective reaction;
1,1,1-tri(hydroxymethyl)propane
77-99-6

1,1,1-tri(hydroxymethyl)propane

A

3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

B

3,9-diethyl-3,9-dihydroxymethyl-1,5,7,11-tetraoxaspiro[5,5]undecane
65282-19-1

3,9-diethyl-3,9-dihydroxymethyl-1,5,7,11-tetraoxaspiro[5,5]undecane

C

3,3,7,7-tetra(hydroxymethyl)-5-oxanonane
23235-61-2

3,3,7,7-tetra(hydroxymethyl)-5-oxanonane

Conditions
ConditionsYield
Stage #1: 1,1,1-tri(hydroxymethyl)propane With urea In water at 100 - 150℃; under 300 - 600 Torr; Alkaline conditions; Large scale;
Stage #2: In water at 100 - 195℃; under 45 Torr; Pyrolysis; Large scale;
1,1,1-tri(hydroxymethyl)propane
77-99-6

1,1,1-tri(hydroxymethyl)propane

A

3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

B

3,9-diethyl-3,9-dihydroxymethyl-1,5,7,11-tetraoxaspiro[5,5]undecane
65282-19-1

3,9-diethyl-3,9-dihydroxymethyl-1,5,7,11-tetraoxaspiro[5,5]undecane

Conditions
ConditionsYield
Stage #1: 1,1,1-tri(hydroxymethyl)propane With zinc diacetate; urea; potassium hydroxide at 140℃; under 300 Torr;
Stage #2: at 195 - 215℃; under 10 - 50 Torr; Pyrolysis;
A 42 %Spectr.
B 18 %Spectr.
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

(3-ethyl-3-oxetanyl)methyl methanesulfonate
3893-75-2

(3-ethyl-3-oxetanyl)methyl methanesulfonate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 25℃; for 2h; Product distribution / selectivity; Inert atmosphere;99%
With triethylamine In toluene at 5 - 20℃; for 6h;95%
With triethylamine In dichloromethane at 0 - 20℃; for 2h; Concentration; Temperature;93%
With triethylamine
With triethylamine In diethyl ether for 1h;
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

3-ethyl-3-(acryloyloxymethyl)oxetane
41988-14-1

3-ethyl-3-(acryloyloxymethyl)oxetane

Conditions
ConditionsYield
With mesoporous silica gel supported organotin catalyst for 6h; Reflux;98.5%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

(3-ethyloxetan-3-yl)methyl 4-methylbenzenesulfonate
237403-65-5

(3-ethyloxetan-3-yl)methyl 4-methylbenzenesulfonate

Conditions
ConditionsYield
Stage #1: p-toluenesulfonyl chloride With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In water; toluene at 5℃;
Stage #2: 3-ethyl-3-(hydroxymethyl)oxetane In water; toluene at 10 - 20℃; for 6h;
95%
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 4h; Inert atmosphere;91%
With sodium hydroxide; tetramethylammonium bromide In water; toluene at 5 - 20℃; for 17.5h;90%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

9,10-epoxy-18-hydroxyoctadecanoic acid
3233-92-9

9,10-epoxy-18-hydroxyoctadecanoic acid

hexanedioic acid dimethyl ester
627-93-0

hexanedioic acid dimethyl ester

A

C72H126O15

C72H126O15

B

C126H222O24

C126H222O24

Conditions
ConditionsYield
With Candida antarctica lipase B at 85℃; for 2h; Enzymatic reaction;A 94%
B 65%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

3-ethyl-3-[(allyloxy)methyl]oxetane

3-ethyl-3-[(allyloxy)methyl]oxetane

Conditions
ConditionsYield
With potassium hydroxide In tetrabutylammomium bromide; water; allyl bromide92%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 5078 Da, PDI 1.60, degree of branching 42 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 5078 Da, PDI 1.60, degree of branching 42 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 30℃; for 48h;91%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

C48H48Cl4F12O4

C48H48Cl4F12O4

C72H92F12O12

C72H92F12O12

Conditions
ConditionsYield
Stage #1: 3-ethyl-3-(hydroxymethyl)oxetane With sodium hydride In hexane; mineral oil at 20℃; for 1h; Inert atmosphere;
Stage #2: C48H48Cl4F12O4 In hexane; N,N-dimethyl-formamide; mineral oil at 50℃; for 4h;
90.3%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

2-(bromomethyl)-2-ethyl-1,3-propanediol
32321-45-2

2-(bromomethyl)-2-ethyl-1,3-propanediol

Conditions
ConditionsYield
With hydrogen bromide In tetrahydrofuran; water at 25℃; for 5h;90%
With hydrogen bromide In tetrahydrofuran; water at 0 - 20℃;81%
With hydrogen bromide
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 4731 Da, PDI 1.61, degree of branching 36 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 4731 Da, PDI 1.61, degree of branching 36 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 0℃; for 48h;90%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 5374 Da, PDI 1.42, degree of branching 41 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 5374 Da, PDI 1.42, degree of branching 41 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 48h;90%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

propargyl alcohol
107-19-7

propargyl alcohol

C158H314O53

C158H314O53

Conditions
ConditionsYield
Stage #1: propargyl alcohol With boron trifluoride diethyl etherate In dichloromethane at 35℃; Inert atmosphere;
Stage #2: 3-ethyl-3-(hydroxymethyl)oxetane In dichloromethane for 24h; Inert atmosphere;
90%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

2-(chloromethyl)-2-ethyl-1,3-propanediol
16081-43-9

2-(chloromethyl)-2-ethyl-1,3-propanediol

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran; water at 0 - 20℃;89%
With hydrogenchloride
With hydrogenchloride In chloroform
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 4890 Da, PDI 1.54, degree of branching 15 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 4890 Da, PDI 1.54, degree of branching 15 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at -30℃; for 48h;89%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 5266 Da, PDI 1.45, degree of branching 39 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 5266 Da, PDI 1.45, degree of branching 39 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 10℃; for 48h;87%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 5412 Da, PDI 1.46, degree of branching 31 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 5412 Da, PDI 1.46, degree of branching 31 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at -10℃; for 48h;86%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

3-ethyloxetane-3-carboxylic acid
28562-61-0

3-ethyloxetane-3-carboxylic acid

Conditions
ConditionsYield
With Jones reagent In acetone at -5 - 25℃; for 6h;86%
With Jones reagent In acetone at 0 - 20℃; for 6h;50.4%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

Hexafluorobenzene
392-56-3

Hexafluorobenzene

3-ethyl-3-(2,3,4,5,6-pentafluorophenoxymethyl)oxetan

3-ethyl-3-(2,3,4,5,6-pentafluorophenoxymethyl)oxetan

Conditions
ConditionsYield
With potassium hydride In toluene at 20℃; for 22h; Inert atmosphere; Cooling with ice;86%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

trifluoromethanol
1493-11-4

trifluoromethanol

1,3-dimethylperfluorobenzene
80979-93-7

1,3-dimethylperfluorobenzene

C15H17F5O3

C15H17F5O3

Conditions
ConditionsYield
Stage #1: 3-ethyl-3-(hydroxymethyl)oxetane; 2,4,5,6-tetrafluoro-m-xylene With potassium hydride In tetrahydrofuran at 20℃; for 22h; Inert atmosphere; Cooling with ice;
Stage #2: trifluoromethanol With potassium hydride In tetrahydrofuran at 20℃; for 20h;
86%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

C19H19BrCl2

C19H19BrCl2

C31H41BrO4

C31H41BrO4

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 24h; Inert atmosphere;86%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

C19H19BrCl2

C19H19BrCl2

C31H41BrO4

C31H41BrO4

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 24h; Inert atmosphere;86%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 5243 Da, PDI 1.38, degree of branching 22 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 5243 Da, PDI 1.38, degree of branching 22 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at -20℃; for 48h;85%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 5425 Da, PDI 1.33, degree of branching 9 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 5425 Da, PDI 1.33, degree of branching 9 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at -50℃; for 48h;84%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

2,2,3,3,4,4,4-heptafluorobutoxypentafluorobenzene

2,2,3,3,4,4,4-heptafluorobutoxypentafluorobenzene

C16H13F11O3

C16H13F11O3

Conditions
ConditionsYield
With potassium hydride In toluene at 20℃; for 20h; Inert atmosphere; Cooling with ice;84%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 4987 Da, PDI 1.57, degree of branching 11 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

polymer, Mn 4987 Da, PDI 1.57, degree of branching 11 percent; monomer(s): 3-ethyl-3-(hydroxymethyl)oxetane

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at -40℃; for 48h;83%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

3-ethyloxetane-3-carbaldehyde
98485-37-1

3-ethyloxetane-3-carbaldehyde

Conditions
ConditionsYield
With pyridinium chlorochromate In dichloromethane at 20℃; for 5h;82.3%
With oxalyl dichloride; dimethyl sulfoxide; triethylamine 1.) CH2Cl2, 2.) CH2Cl2; Multistep reaction;
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

epichlorohydrin
106-89-8

epichlorohydrin

3-ethyl-3-[(ethylene oxide)(methoxy)methyl]oxetane
15957-34-3

3-ethyl-3-[(ethylene oxide)(methoxy)methyl]oxetane

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate for 5.5h;82%
With sodium hydroxide at 0 - 50℃; for 15h;72%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

allyl bromide
106-95-6

allyl bromide

3-ethyl-3-[(allyloxy)methyl]oxetane

3-ethyl-3-[(allyloxy)methyl]oxetane

Conditions
ConditionsYield
Stage #1: 3-ethyl-3-(hydroxymethyl)oxetane With sodium hydride In dichloromethane at 0℃;
Stage #2: allyl bromide In dichloromethane at 20℃; for 24h;
81%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

(2E)-but-2-enedioic acid
110-17-8

(2E)-but-2-enedioic acid

bis(3-ethyl-3-hydroxymethyloxetane)fumarate

bis(3-ethyl-3-hydroxymethyloxetane)fumarate

Conditions
ConditionsYield
Stage #1: (2E)-but-2-enedioic acid With thionyl chloride at 70℃; for 5h;
Stage #2: 3-ethyl-3-(hydroxymethyl)oxetane at 20℃; for 10h;
81%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

3-ethyl-3-(5-norbornene-2-carbonyloxymethyl)-1-oxetane

3-ethyl-3-(5-norbornene-2-carbonyloxymethyl)-1-oxetane

Conditions
ConditionsYield
Stage #1: 5-norbornene-endo-2-carboxylic acid With thionyl chloride at 75℃; for 6h;
Stage #2: 3-ethyl-3-(hydroxymethyl)oxetane With triethylamine In dichloromethane at 20℃; for 12h; Temperature; Inert atmosphere;
81%
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

3-methyl-bicyclo<2,2,1>-5-hepten-2-carboxylic acid
53624-84-3

3-methyl-bicyclo<2,2,1>-5-hepten-2-carboxylic acid

5-norbornene-3-methyl-2-carboxylic acid glycidyl ester

5-norbornene-3-methyl-2-carboxylic acid glycidyl ester

Conditions
ConditionsYield
Stage #1: 3-methyl-bicyclo<2,2,1>-5-hepten-2-carboxylic acid With oxalyl dichloride at 80℃; for 4h;
Stage #2: 3-ethyl-3-(hydroxymethyl)oxetane With triethylamine In dichloromethane at 0 - 20℃; for 16h; Inert atmosphere;
81%

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