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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

3-Bromothioanisole Manufacturer/High quality/Best price/In stock

Cas:33733-73-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Bromothioanisole

Cas:33733-73-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our advantage:Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scient

TIANFU-CHEM 3-Bromothioanisole

Cas:33733-73-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 33733-73-2 with best quality

Cas:33733-73-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1-bromo-3-(methylthio)-

Cas:33733-73-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:33733-73-2

Cas:33733-73-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

3-Bromo thioanisole

Cas:33733-73-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Bromo thioanisole

Cas:33733-73-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3-Bromothioanisole

Cas:33733-73-2

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzene,1-bromo-3-(methylthio)-

Cas:33733-73-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 3-Bromothioanisole

Cas:33733-73-2

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

3-Bromo thioanisole

Cas:33733-73-2

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 3-Bromothioanisole Synonyms: 3-BROMOPHENYL METHYL SULFIDE;3-BROMOTHIOANISOLE;1-BROMO-3-(METHYLTHIO)BENZENE;M-BROMO(METHYLTHIO)BENZENE;M-BROMOTHIOANISOLE;3-Bromophenyl methyl sulphide, 1-Bromo-3-(methylsulphanyl)benzene, 1-Bromo-3-

3-Bromothioanisole 33733-73-2 C7H7BrS

Cas:33733-73-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

3-Bromo thioanisole

Cas:33733-73-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

3-Bromothioanisole

Cas:33733-73-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

3-Bromo thioanisole

Cas:33733-73-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

3-Bromo thioanisole

Cas:33733-73-2

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

3-Bromothioanisole

Cas:33733-73-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

3-Bromo thioanisole

Cas:33733-73-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

3-BROMO THIOANISOLE cas no. 33733-73-2 98%

Cas:33733-73-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

3-Bromo thioanisole

Cas:33733-73-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

3-Bromothioanisole

Cas:33733-73-2

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

3-BroMothioanisole

Cas:33733-73-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

3-bromothioanisole

Cas:33733-73-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Fandachem Co.,Ltd

FandaChem , a China-based chemical company, specialize in exporting 3-Bromothioanisole cas 33733-73-2 (Fandachem), Please contact us by email freely. Appearance:white crystalline powder Storage:Store in dry, dark and ve

3-Bromothioanisole cas 33733-73-2 (Fandachem)

Cas:33733-73-2

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Benzene,1-bromo-3-(methylthio)-

Cas:33733-73-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

3-Bromo thioanisole

Cas:33733-73-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white crystals powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as

3-Bromo-thioanisole

Cas:33733-73-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

33733-73-2

Cas:33733-73-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

3-Bromothioanisole

Cas:33733-73-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

3-Bromothiophenol
6320-01-0

3-Bromothiophenol

methyl iodide
74-88-4

methyl iodide

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

Conditions
ConditionsYield
With potassium carbonate In acetone for 4h; Heating;100%
Stage #1: 3-Bromothiophenol With sodium methylate In methanol at 20℃; for 0.5h;
Stage #2: methyl iodide In methanol at 20℃; Further stages.;
86.1%
With sodium hydroxide
Dimethyldisulphide
624-92-0

Dimethyldisulphide

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

Conditions
ConditionsYield
With potassium tert-butylate In acetonitrile at 50℃; for 6h; Sealed tube;80%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

1-bromo-3-[(3-bromophenyl)disulfanyl]benzene
19742-90-6

1-bromo-3-[(3-bromophenyl)disulfanyl]benzene

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

Conditions
ConditionsYield
In acetonitrile at 120℃; for 12h; Inert atmosphere; Schlenk technique; Green chemistry;67%
Dimethyldisulphide
624-92-0

Dimethyldisulphide

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

Conditions
ConditionsYield
With tetrabutylammomium bromide; copper(II) acetate monohydrate; potassium hydroxide In water at 100℃; for 12h; Sealed tube;60%
With n-butyllithium 1.) THF, -78 deg C, 2 h, 2.) THF, from -75 deg C to RT; Yield given. Multistep reaction;
Dimethyldisulphide
624-92-0

Dimethyldisulphide

(3-bromophenyl)boronic acid
89598-96-9

(3-bromophenyl)boronic acid

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

Conditions
ConditionsYield
With di-tert-butyl peroxide In acetonitrile at 120℃; for 12h; Sealed tube;60%
Dimethyldisulphide
624-92-0

Dimethyldisulphide

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

Conditions
ConditionsYield
With potassium tert-butylate In acetonitrile at 50℃; for 6h; Sealed tube;42%
3-Bromothiophenol
6320-01-0

3-Bromothiophenol

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

Conditions
ConditionsYield
With potassium hydroxide; dimethyl sulfate
3-methylmercaptoaniline
1783-81-9

3-methylmercaptoaniline

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

Conditions
ConditionsYield
With sulfuric acid Diazotization.Erwaermen der Diazoniumsalz-Loesung mit CuBr und KBr auf 60-70grad;
3-Bromothiophenol
6320-01-0

3-Bromothiophenol

dimethyl sulfate
77-78-1

dimethyl sulfate

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

6,6-dibromobicylo[3.1.0]hexane
2568-36-7

6,6-dibromobicylo[3.1.0]hexane

B

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

C

2-bromo-1-(methylsulfanyl)benzene
19614-16-5

2-bromo-1-(methylsulfanyl)benzene

D

1,6-dibromocyclohex-1-ene
17202-32-3

1,6-dibromocyclohex-1-ene

Conditions
ConditionsYield
In dimethyl sulfoxide at 125℃; for 0.5h; Mechanism; var. of conditions;
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

sodium thiomethoxide
5188-07-8

sodium thiomethoxide

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

Conditions
ConditionsYield
In 1-methyl-pyrrolidin-2-one at 50 - 64℃; for 4h; Inert atmosphere; Large scale;
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

1-bromo-3-methanesulfinyl-benzene
29959-92-0

1-bromo-3-methanesulfinyl-benzene

Conditions
ConditionsYield
With 1,3-dimethylalloxan; dihydrogen peroxide; magnesium sulfate In dichloromethane at 25℃; for 0.5h;99%
With 1,6,8-trihydroxy-3-methyl-9,10-anthraquinone In methanol at 20℃; for 6h; Irradiation;98%
With dihydrogen peroxide; phenol for 0.00833333h;96%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

2,2,2-trichloroethyl-N-methanesulfonyloxycarbamate

2,2,2-trichloroethyl-N-methanesulfonyloxycarbamate

S-methyl-S-3-bromophenyl-N-(2,2,2-trichloroethoxycarbonyl)sulfilimine

S-methyl-S-3-bromophenyl-N-(2,2,2-trichloroethoxycarbonyl)sulfilimine

Conditions
ConditionsYield
With 1-Butylimidazole; iron(II) chloride hydrate In ethyl acetate at 80℃; for 0.25h; Sealed tube;99%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

3-phenyl-5H-1,4,2-dioxazol-5-one
19226-36-9

3-phenyl-5H-1,4,2-dioxazol-5-one

(-)-N-benzoyl 3-bromophenyl methyl sulfimide

(-)-N-benzoyl 3-bromophenyl methyl sulfimide

Conditions
ConditionsYield
Stage #1: 3-bromo-1-(methylthio)benzene With C61H40F4N2O3Ru In tetrahydrofuran at 25℃; for 0.5h; Molecular sieve; Schlenk technique; Inert atmosphere;
Stage #2: 3-phenyl-5H-1,4,2-dioxazol-5-one In tetrahydrofuran at 25℃; for 18h; Molecular sieve; Schlenk technique; Inert atmosphere; enantioselective reaction;
99%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

3-methylthiophenylboronic acid
128312-11-8

3-methylthiophenylboronic acid

3,3'-di(methylthio)biphenyl
10075-91-9

3,3'-di(methylthio)biphenyl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate at 80℃; Suzuki-Miyaura Coupling;98%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

1-bromo-3-methanesulphonylbenzene
34896-80-5

1-bromo-3-methanesulphonylbenzene

Conditions
ConditionsYield
Stage #1: 3-bromo-1-(methylthio)benzene With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0℃;
Stage #2: With sodium thiosulfate In dichloromethane; water
97%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0℃;97%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere;96%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

4-methoxy-3'-(methylthio)-1,1'-biphenyl
95391-98-3

4-methoxy-3'-(methylthio)-1,1'-biphenyl

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate In tetrahydrofuran; water for 10h; Suzuki-Miyaura coupling; Inert atmosphere; Reflux;97%
benzenesulfonamide
98-10-2

benzenesulfonamide

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

N-(3-(methylthio)phenyl)benzenesulfonamide
528576-23-0

N-(3-(methylthio)phenyl)benzenesulfonamide

Conditions
ConditionsYield
With (1,2-dimethoxyethane)dichloronickel(II); (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; 4,4'-di-tert-butyl-2,2'-bipyridine; N,N,N',N'-tetramethylguanidine In acetonitrile at 55℃; for 48h; Temperature; Inert atmosphere; Irradiation; Glovebox;97%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

phenylacetylene
536-74-3

phenylacetylene

1-methylsulfanyl-3-(phenylethynyl)benzene

1-methylsulfanyl-3-(phenylethynyl)benzene

Conditions
ConditionsYield
With di-tert-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine; potassium phosphate monohydrate; bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)] In water at 45℃; for 5h; Sonogashira Cross-Coupling; Inert atmosphere;96%
With potassium phosphate monohydrate; bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; C64H118O20 In water at 45℃; for 6h; Sonogashira Cross-Coupling; Inert atmosphere;91%
With copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride at 90℃; Sonogashira coupling;65%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

copper(I) cyanide
544-92-3

copper(I) cyanide

3-cyanophenyl methyl sulfide
65052-48-4

3-cyanophenyl methyl sulfide

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 150℃; Product distribution; Rate constant; other solvent;95%
In N,N-dimethyl-formamide at 150℃;
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

tert-butyldimethyl(((3-phenylpropyl)sulfonyl)methoxy)silane

tert-butyldimethyl(((3-phenylpropyl)sulfonyl)methoxy)silane

methyl(3-((3-phenylpropyl)sulfonyl)phenyl)sulfane

methyl(3-((3-phenylpropyl)sulfonyl)phenyl)sulfane

Conditions
ConditionsYield
With copper(l) iodide; cesium fluoride; L-proline; sodium hydroxide In dimethyl sulfoxide at 95℃; for 24h;94%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

trimethyl(3-(methylthio)phenyl)silane
22515-28-2

trimethyl(3-(methylthio)phenyl)silane

Conditions
ConditionsYield
Stage #1: 3-bromo-1-(methylthio)benzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at -78 - 25℃;
93%
With magnesium In N,N,N,N,N,N-hexamethylphosphoric triamide
N,N-diethyl-2,2,2-trifluoroacetamide
360-92-9

N,N-diethyl-2,2,2-trifluoroacetamide

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

2,2,2-trifluoro-1-(3-methylsulfanylphenyl)ethanone

2,2,2-trifluoro-1-(3-methylsulfanylphenyl)ethanone

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; cyclohexane at -78℃; for 1h;93%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

bromoacetic acid methyl ester
96-32-2

bromoacetic acid methyl ester

methyl 2-((3-bromophenyl)thio)acetate

methyl 2-((3-bromophenyl)thio)acetate

Conditions
ConditionsYield
In 2,2,2-trifluoroethanol at 100℃; for 24h;93%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

potassium cyanide
151-50-8

potassium cyanide

3-cyanophenyl methyl sulfide
65052-48-4

3-cyanophenyl methyl sulfide

Conditions
ConditionsYield
With 18-crown-6 ether; tetrakis(triphenylphosphine) palladium(0) In benzene at 80℃; for 50h; Product distribution; Rate constant;92%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

(R)-1-bromo-3-(methylsulfinyl)benzene
188539-86-8

(R)-1-bromo-3-(methylsulfinyl)benzene

Conditions
ConditionsYield
Stage #1: 3-bromo-1-(methylthio)benzene With manganese(II) triflate; N1,N2-bis(2-((R)-4-isopropyl-4,5-dihydrooxazol-2-yl)phenyl)benzene-1,2-diamine In acetonitrile at 20℃; for 6h; Inert atmosphere; Green chemistry;
Stage #2: With 1-Adamantanecarboxylic acid; dihydrogen peroxide In isopropyl alcohol; acetonitrile at -20℃; for 2h; Inert atmosphere; Green chemistry; enantioselective reaction;
92%
With manganese(II) triflate; 1-Adamantanecarboxylic acid; C30H34N4O2; dihydrogen peroxide In water; isopropyl alcohol; acetonitrile at 20℃; for 0.0166667h; Flow reactor; enantioselective reaction;90%
With manganese(II) triflate; C30H34N4O2; dihydrogen peroxide; acetic acid In dichloromethane; water at 0℃; for 1h; Inert atmosphere; enantioselective reaction;80%
With titanium(IV) isopropylate; Diethyl tartrate; Cumene hydroperoxide In dichloromethane; water at -20℃; for 3h; Oxidation;67%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

(S)-1-bromo-3-(methylsulfinyl)benzene

(S)-1-bromo-3-(methylsulfinyl)benzene

Conditions
ConditionsYield
Stage #1: 3-bromo-1-(methylthio)benzene With iron(III) trifluoromethanesulfonate; C59H88N4O4 In tetrahydrofuran at 35℃; for 0.5h; Inert atmosphere;
Stage #2: With dihydrogen peroxide In tetrahydrofuran; water at 25℃; for 4h; Inert atmosphere; enantioselective reaction;
92%
With Cumene hydroperoxide; titanium BINOL derivative In tetrachloromethane at 25℃; for 72h;36.5%
6-chloro-N-(pyridin-3-ylmethyl)pyridine-3-amine

6-chloro-N-(pyridin-3-ylmethyl)pyridine-3-amine

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

6-chloro-N-(dipyridin-3-ylmethyl)-N-[3-(methylthio)phenyl]pyridine-3-amine

6-chloro-N-(dipyridin-3-ylmethyl)-N-[3-(methylthio)phenyl]pyridine-3-amine

Conditions
ConditionsYield
With sodium t-butanolate; bis(tri-t-butylphosphine)palladium(0) In 1,4-dioxane at 100℃; for 4h;91%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

aniline
62-53-3

aniline

N-(3-methylthiophenyl)phenylamine
13313-45-6

N-(3-methylthiophenyl)phenylamine

Conditions
ConditionsYield
With nickel(II) bromide trihydrate; N,N-dimethyl-cyclohexanamine; Eosin Y In 1,2-dimethoxyethane; N,N-dimethyl-formamide at 50℃; for 12h; Inert atmosphere;91%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

9H-carbazole
86-74-8

9H-carbazole

C19H15NS

C19H15NS

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; potassium carbonate In N,N-dimethyl-formamide at 130℃; for 10h; Inert atmosphere;89.6%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

(S)-1-phenyl-2,2,2-trichloroethyl-N-mesyloxycarbamate
1644186-25-3

(S)-1-phenyl-2,2,2-trichloroethyl-N-mesyloxycarbamate

(S)-S-methyl-S-(3-bromophenyl)-N-(((S)-2,2,2-trichloro-1-phenylethoxy)carbonyl)sulfilimine

(S)-S-methyl-S-(3-bromophenyl)-N-(((S)-2,2,2-trichloro-1-phenylethoxy)carbonyl)sulfilimine

Conditions
ConditionsYield
With dmap; tetrakis[μ-(αS)-α-(1,1-dimethylethyl)-2,3-dihydro-1H-naphtho[1,8-cd]pyridine-2-acetato-κO:.kappaO']dirhodium(II)(Rh-Rh); 1,1’-methylenebis(4-dimethylaminopyridinium) dichloride; potassium carbonate In Isopropyl acetate; water at 23℃; for 4h; stereoselective reaction;89%
With dmap; tetrakis[μ-(αS)-α-(1,1-dimethylethyl)-2,3-dihydro-1H-naphtho[1,8-cd]pyridine-2-acetato-κO:.kappaO']dirhodium(II)(Rh-Rh); 1,1’-methylenebis(4-dimethylaminopyridinium) dichloride; potassium carbonate In Isopropyl acetate; water at 25℃; for 4h; diastereoselective reaction;89%
Methyl 2-acetamidoacrylate
35356-70-8

Methyl 2-acetamidoacrylate

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

C13H16BrNO3S

C13H16BrNO3S

Conditions
ConditionsYield
With 3,6‐di‐tert‐butyl‐9‐mesityl‐10‐phenylacridin‐10‐ium tetrafluoroborate; sodium 2,2,2-trifluoroacetate In methanol; dichloromethane at 30℃; Irradiation;89%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

3-methylsulfanylphenol
3463-03-4

3-methylsulfanylphenol

Conditions
ConditionsYield
Stage #1: 3-bromo-1-(methylthio)benzene With potassium hydroxide; tris-(dibenzylideneacetone)dipalladium(0); 2-((di-adamantan-1-yl)phosphaneyl)-1-(2,6-diisopropylphenyl)-1H-imidazole In 1,4-dioxane; water at 100℃; for 20h; Inert atmosphere;
Stage #2: With hydrogenchloride In 1,4-dioxane; water at 20℃; Inert atmosphere;
88%
[bis(acetoxy)iodo]benzene
3240-34-4

[bis(acetoxy)iodo]benzene

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

((3-bromophenyl)thio)methyl acetate

((3-bromophenyl)thio)methyl acetate

Conditions
ConditionsYield
With (triphenylphosphine)gold(I) chloride In 1,2-dichloro-ethane at 130℃; Schlenk technique;88%
CYANAMID
420-04-2

CYANAMID

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

C8H7BrN2S

C8H7BrN2S

Conditions
ConditionsYield
With N-Bromosuccinimide; potassium tert-butylate In methanol at 20℃; for 1h;87%
With N-Bromosuccinimide; potassium tert-butylate In methanol at 20℃; for 1h;87%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

methyl trifluoromethanesulfonate
333-27-7

methyl trifluoromethanesulfonate

CF3O3S(1-)*C8H10BrS(1+)

CF3O3S(1-)*C8H10BrS(1+)

Conditions
ConditionsYield
In 1,2-dichloro-ethane at 60℃; for 12h;87%
2,2-dimethylmalononitrile
7321-55-3

2,2-dimethylmalononitrile

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

3-cyanophenyl methyl sulfide
65052-48-4

3-cyanophenyl methyl sulfide

Conditions
ConditionsYield
Stage #1: 3-bromo-1-(methylthio)benzene With magnesium; lithium chloride In tetrahydrofuran at 23℃;
Stage #2: 2,2-dimethylmalononitrile In tetrahydrofuran at 0 - 23℃; for 0.5h;
84%
Stage #1: 3-bromo-1-(methylthio)benzene With magnesium; lithium chloride In tetrahydrofuran at 25℃; for 0.5h; Inert atmosphere;
Stage #2: 2,2-dimethylmalononitrile In tetrahydrofuran at 0 - 25℃; Inert atmosphere;
65%
3-methyl-2,5-dihydrothiophen-1,1-dioxide
1193-10-8

3-methyl-2,5-dihydrothiophen-1,1-dioxide

3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

(Z)-methyl(3-(2-methylbuta-1,3-dien-1-yl)phenyl)sulfane

(Z)-methyl(3-(2-methylbuta-1,3-dien-1-yl)phenyl)sulfane

Conditions
ConditionsYield
Stage #1: 3-methyl-2,5-dihydrothiophen-1,1-dioxide With o-phenylenebis(diphenylphosphine); potassium methanolate; palladium diacetate; potassium carbonate In tetrahydrofuran at 20℃; for 0.0833333h; Sealed tube; Inert atmosphere;
Stage #2: 3-bromo-1-(methylthio)benzene In tetrahydrofuran at 20 - 110℃; for 37.3333h; Sealed tube; diastereoselective reaction;
84%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

tert-butyl 2-oxopyrrolidine-1-carboxylate
85909-08-6

tert-butyl 2-oxopyrrolidine-1-carboxylate

[4-(3-methylsulfanyl-phenyl)-4-oxo-butyl]-carbamic acid tert-butyl ester
914954-35-1

[4-(3-methylsulfanyl-phenyl)-4-oxo-butyl]-carbamic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: 3-bromo-1-(methylthio)benzene With n-butyllithium In tetrahydrofuran; hexanes at -78℃; for 1.66667h;
Stage #2: tert-butyl 2-oxopyrrolidine-1-carboxylate In tetrahydrofuran; hexanes at -78℃; for 2h;
83%
3-bromo-1-(methylthio)benzene
33733-73-2

3-bromo-1-(methylthio)benzene

iodobenzene dimethacrylate

iodobenzene dimethacrylate

((3-bromophenyl)thio)methyl methacrylate

((3-bromophenyl)thio)methyl methacrylate

Conditions
ConditionsYield
With (triphenylphosphine)gold(I) chloride In 1,2-dichloro-ethane at 130℃; Schlenk technique;83%

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