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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

5-Bromo-2-methylaniline Manufacturer/High quality/Best price/In stock

Cas:39478-78-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

2-Amino-4-bromotoluene

Cas:39478-78-9

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:Whit

5-Bromo-2-methylaniline

Cas:39478-78-9

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 39478-78-9 5-Bromo-2-methylaniline Manufacturer

Cas:39478-78-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

5-Bromo-2-methylaniline

Cas:39478-78-9

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

5-Bromo-2-Methylaniline

Cas:39478-78-9

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

5-Bromo-o-toluidine (NH2=1)

Cas:39478-78-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company engages in Sodium Tripolyphosphate (STPP) and Sodium Hexametabphosphate (SHMP) production; development of noble metal catalysts, synthesis of electronic chemical materials and general chemicals Imp&Exp trading business. The company

TIANFU-CHEM - 5-Bromo-2-methylaniline

Cas:39478-78-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 39478-78-9 with best quality

Cas:39478-78-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shijiazhuang Sdyano Fine Chemical Co., Ltd

1. Best prices with satisfied quality; 2. It's clients' right to choose the package's Courier (EMS, DHL, FedEx, UPS); 3.It's clients' right to choose the packing way for his produccts from many recent effective packing ways;

5-Bromo-2-methylaniline

Cas:39478-78-9

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzenamine,5-bromo-2-methyl- 39478-78-9

Cas:39478-78-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Pharmaceutical Intermediate, 5-Bromo-2-methylaniline CAS:39478-78-9

Cas:39478-78-9

Min.Order:1 Kilogram

FOB Price: $76.0 / 84.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

5-Bromo-2-methylaniline CAS:39478-78-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

5-Bromo-2-methylaniline CAS:39478-78-9

Cas:39478-78-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzenamine,5-bromo-2-methyl-

Cas:39478-78-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:39478-78-9

Cas:39478-78-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

5-Bromo-2-methylaniline

Cas:39478-78-9

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

5-Bromo-2-methylaniline

Cas:39478-78-9

Min.Order:1 Kilogram

FOB Price: $40.0 / 50.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

5-Bromo-2-methylaniline

Cas:39478-78-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

5-bromo-2-methylaniline

Cas:39478-78-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

5-Bromo-2-methylaniline

Cas:39478-78-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 5-Bromo-2-methylaniline

Cas:39478-78-9

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

5-Bromo-2-methylaniline

Cas:39478-78-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

5-Bromo-2-methylaniline

Cas:39478-78-9

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply 5-bromo-o-toluidine

Cas:39478-78-9

Min.Order:0

Negotiable

Type:Other

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Product Name:5-Bromo-2-methylaniline CAS No:39478-7

5-Bromo-2-methylaniline

Cas:39478-78-9

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

5-Bromo-2-methylaniline Basic information Product Name: 5-Bromo-2-methylaniline Synonyms: 2-AMINO-4-BROMOTOLUENE;5-BROMO-2-METHYLANILINE;5-BROMO-O-TOLUIDINE;2-Amino-4-Bromotoluene 5-Bromo-2-Methylaniline;2-Methyl-5-Bromoaniline99%;2-Methyl-5-Bromoan

5-bromo-2-methylaniline

Cas:39478-78-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

5-bromo-2-methylaniline

Cas:39478-78-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

5-Bromo-2-methylaniline

Cas:39478-78-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

5-bromo-2-methylaniline

Cas:39478-78-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

5-bromo-2-methylaniline

Cas:39478-78-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Synthetic route

4-bromo-2-nitrotoluene
60956-26-5

4-bromo-2-nitrotoluene

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

Conditions
ConditionsYield
With tin(II) chloride dihdyrate In ethyl acetate at 0℃; for 4h; Reflux;97%
With stannous chloride hydrate In ethyl acetate at 30℃;93%
With iron; ammonium chloride for 48h; Heating;92%
para-bromotoluene
106-38-7

para-bromotoluene

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

Conditions
ConditionsYield
With CH5NO3S*CHF3O3S; iron(II) sulfate In water; acetonitrile at 20℃; for 16h;71%
hydrogenchloride
7647-01-0

hydrogenchloride

4-bromo-2-nitrotoluene
60956-26-5

4-bromo-2-nitrotoluene

tin

tin

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

4-Methyl-3-nitroanilin
119-32-4

4-Methyl-3-nitroanilin

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: H2SO4; NaNO2
1.2: 57.5 percent / CuBr
2.1: 84.5 percent / Fe; CH3COOH
View Scheme
4-bromo-2-nitrotoluene
60956-26-5

4-bromo-2-nitrotoluene

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

Conditions
ConditionsYield
With ammonium chloride In ethanol; water
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

5-bromo-2-methyl aniline hydrochloride

5-bromo-2-methyl aniline hydrochloride

Conditions
ConditionsYield
With hydrogenchloride In dichloromethane for 3h;100%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

2,5-hexanedione
110-13-4

2,5-hexanedione

1-(5-bromo-2-methyl-phenyl)-2,5-dimethyl-pyrrole
1157455-13-4

1-(5-bromo-2-methyl-phenyl)-2,5-dimethyl-pyrrole

Conditions
ConditionsYield
With hydrogenchloride In ethanol; water for 24h; Reflux;100%
hydrogenchloride In ethanol; water for 18h; Reflux;60%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

5-azido-2-methylbenzeneamine

5-azido-2-methylbenzeneamine

Conditions
ConditionsYield
With copper(l) iodide; sodium azide; sodium L-ascorbate; (1S,2S)-N,N'-dimethyl-1,2-diaminocyclohexane In ethanol for 0.5h; Heating;99%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

trifluoroacetic anhydride
407-25-0

trifluoroacetic anhydride

N-(5-bromo-2-methylphenyl)-2,2,2-trifluoroacetamide
338451-90-4

N-(5-bromo-2-methylphenyl)-2,2,2-trifluoroacetamide

Conditions
ConditionsYield
With triethylamine In dichloromethane for 1h;99%
In dichloromethane at 0℃; for 1h;76%
In dichloromethane at 20℃; for 1h;9.3 g
In dichloromethane at 20℃; for 1h;
3-acetylenephenylamine
54060-30-9

3-acetylenephenylamine

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

5-{4-(3-aminophenyl)-[1,2,3]triazol-1-yl}-2-methylphenylamine

5-{4-(3-aminophenyl)-[1,2,3]triazol-1-yl}-2-methylphenylamine

Conditions
ConditionsYield
With sodium azide; trans-N,N'-dimethylcyclohexane-1,2-diamine; sodium L-ascorbate; copper(l) iodide In dimethyl sulfoxide at 70℃; for 12h;98%
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

tert-butyl (5-bromo-2-methylphenyl)carbamate

tert-butyl (5-bromo-2-methylphenyl)carbamate

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 24h;98%
Stage #1: 5-bromo-2-methylaniline With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.416667h;
Stage #2: di-tert-butyl dicarbonate In N,N-dimethyl-formamide at 0 - 40℃; for 22h;
In tetrahydrofuran at 75℃; for 12h;
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

N-(5-bromo-2-methylphenyl)iminodiacetic acid diethyl ester
1190891-69-0

N-(5-bromo-2-methylphenyl)iminodiacetic acid diethyl ester

Conditions
ConditionsYield
96%
n-propanesulfonyl chloride
10147-36-1

n-propanesulfonyl chloride

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

N-(5-bromo-2-methylphenyl)propane-1-sulfonamide

N-(5-bromo-2-methylphenyl)propane-1-sulfonamide

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 20℃; for 16h;96%
With pyridine; dmap In dichloromethane at 20℃; for 40h; Inert atmosphere;96%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

C7H7N5O2

C7H7N5O2

C11H11BrN4O2

C11H11BrN4O2

Conditions
ConditionsYield
In 1-methyl-pyrrolidin-2-one at 120℃; for 24h;94.8%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

allyl bromide
106-95-6

allyl bromide

N,N-diallyl-5-bromo-2-methylaniline
1332626-19-3

N,N-diallyl-5-bromo-2-methylaniline

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 70℃; for 6h; Inert atmosphere;94%
N-(tert-butoxycarbonyl)sarcosine
13734-36-6

N-(tert-butoxycarbonyl)sarcosine

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

tert-butyl 2-(5-bromo-2-methylphenylamino)-2-oxoethyl(methyl)carbamate
1172620-97-1

tert-butyl 2-(5-bromo-2-methylphenylamino)-2-oxoethyl(methyl)carbamate

Conditions
ConditionsYield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 25℃; for 15h;92%
(2-{[4-chloro-2-(methoxycarbonyl)phenyl]amino}-2-oxoethoxy)acetic acid
1103929-71-0

(2-{[4-chloro-2-(methoxycarbonyl)phenyl]amino}-2-oxoethoxy)acetic acid

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

methyl 2-[({2-[(5-bromo-2-methylphenyl)amino]-2-oxoethoxy}acetyl)amino]-5-chlorobenzoate
1190222-29-7

methyl 2-[({2-[(5-bromo-2-methylphenyl)amino]-2-oxoethoxy}acetyl)amino]-5-chlorobenzoate

Conditions
ConditionsYield
Stage #1: (2-{[4-chloro-2-(methoxycarbonyl)phenyl]amino}-2-oxoethoxy)acetic acid With oxalyl dichloride; N,N-dimethyl-formamide In tetrahydrofuran at 0℃; for 0.5h;
Stage #2: 5-bromo-2-methylaniline In N,N-dimethyl acetamide at 0 - 20℃;
92%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

7-chloro-2-morpholino-N-(pyridin-2-ylmethyl)quinazolin-4-amine

7-chloro-2-morpholino-N-(pyridin-2-ylmethyl)quinazolin-4-amine

7-(3-amino-4-methylphenyl)-2-morpholino-N-(pyridin-2-ylmethyl)quinazolin-4-amine

7-(3-amino-4-methylphenyl)-2-morpholino-N-(pyridin-2-ylmethyl)quinazolin-4-amine

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methylaniline With magnesium; ethylene dibromide In tetrahydrofuran at 60 - 80℃; for 0.25h; Inert atmosphere;
Stage #2: 7-chloro-2-morpholino-N-(pyridin-2-ylmethyl)quinazolin-4-amine With bis(triphenylphosphine)nickel(II) chloride In tetrahydrofuran at 60℃; for 3h; Kumada Cross-Coupling; Inert atmosphere;
91%
methyl 2-phenyl-2-(2-tosylhydrazono)acetate
18793-81-2

methyl 2-phenyl-2-(2-tosylhydrazono)acetate

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

methyl 2-((5-bromo-2-methylphenyl)amino)-2-phenylacetate

methyl 2-((5-bromo-2-methylphenyl)amino)-2-phenylacetate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 24h; Irradiation;87%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

6-bromo-1H-indazole
79762-54-2

6-bromo-1H-indazole

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methylaniline With sodium tetrafluoroborate; sodium nitrite
Stage #2: With 18-crown-6 ether; potassium acetate In chloroform
85%
Stage #1: 5-bromo-2-methylaniline With potassium acetate; acetic anhydride In chloroform at 60 - 65℃; for 0.5h;
Stage #2: With potassium acetate; isopentyl nitrite In chloroform at 60℃; for 15h;
Stage #3: With hydrogenchloride In methanol; water at 60℃; for 2h;
51%
Stage #1: 5-bromo-2-methylaniline With tetrafluoroboric acid; sodium nitrite In water at 0℃;
Stage #2: With 18-crown-6 ether; potassium acetate In chloroform at 20℃; Further stages.;
Multi-step reaction with 2 steps
1: tetrafluoroboric acid; sodium nitrite / water / 0.5 h / 0 - 20 °C
2: 18-crown-6 ether; potassium acetate / chloroform / 2 h / 20 °C
View Scheme
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

acryloyl chloride
814-68-6

acryloyl chloride

N-(5-bromo-2-methylphenyl)acrylamide

N-(5-bromo-2-methylphenyl)acrylamide

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In dichloromethane at -78 - 20℃;85%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

acetic anhydride
108-24-7

acetic anhydride

4'-bromo-2'-methylacetanilide
24106-05-6

4'-bromo-2'-methylacetanilide

Conditions
ConditionsYield
In benzene for 3.5h;84.4%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

dicyanozinc
557-21-1

dicyanozinc

5-cyano-2-methylaniline
60710-80-7

5-cyano-2-methylaniline

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 80℃; for 2h;84%
(Z)-(2,3-dibromoprop-1-en-1-yl)benzene
23970-90-3, 96725-21-2, 21003-54-3

(Z)-(2,3-dibromoprop-1-en-1-yl)benzene

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

N-(5-bromo-2-methylphenyl)-N-[(Z)-2-bromo-3-phenylprop-2-enyl]amine
1380159-20-5

N-(5-bromo-2-methylphenyl)-N-[(Z)-2-bromo-3-phenylprop-2-enyl]amine

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 4h;84%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

phenylboronic acid
98-80-6

phenylboronic acid

4-methyl-[1,1'-biphenyl]-3-amine
80938-67-6

4-methyl-[1,1'-biphenyl]-3-amine

Conditions
ConditionsYield
With potassium carbonate In water at 70℃; for 2h; Suzuki Coupling; Inert atmosphere;82%
With potassium carbonate In water at 70℃; for 2h; Suzuki Coupling; Inert atmosphere;81%
With potassium carbonate In water at 70℃; for 2h; Suzuki Coupling; Inert atmosphere; Green chemistry;80%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water for 5h; Reflux; Inert atmosphere;
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

acetic anhydride
108-24-7

acetic anhydride

isopentyl nitrite
110-46-3

isopentyl nitrite

1-(6-bromo-1H-indazol-1-yl)ethanone

1-(6-bromo-1H-indazol-1-yl)ethanone

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methylaniline; acetic anhydride In chloroform at 0 - 5℃;
Stage #2: acetic anhydride; isopentyl nitrite With potassium acetate In chloroform Heating / reflux;
Stage #3: With sodium hydrogencarbonate In chloroform; water pH=7;
81%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

ethanolamine
141-43-5

ethanolamine

chloroacetyl chloride
79-04-9

chloroacetyl chloride

N1-(5-bromo-2-methylphenyl)-N2-(2-hydroxyethyl)glycinamide
1146412-41-0

N1-(5-bromo-2-methylphenyl)-N2-(2-hydroxyethyl)glycinamide

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methylaniline; chloroacetyl chloride With potassium carbonate In tetrahydrofuran; water at 5 - 20℃; for 1.25h;
Stage #2: ethanolamine In tetrahydrofuran at 5 - 50℃; Product distribution / selectivity;
81%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

2-Nitrobenzenesulfonyl chloride
1694-92-4

2-Nitrobenzenesulfonyl chloride

N-(5-bromo-2-methylphenyl)-2-nitrobenzenesulfonamide
1023210-61-8

N-(5-bromo-2-methylphenyl)-2-nitrobenzenesulfonamide

Conditions
ConditionsYield
With pyridine In dichloromethane at 0℃; for 3h;81%
CYANAMID
420-04-2

CYANAMID

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

5-bromo-2-methylphenylguanidine nitrate
1206604-19-4

5-bromo-2-methylphenylguanidine nitrate

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methylaniline With nitric acid In methanol at 60℃; for 0.5h;
Stage #2: CYANAMID In methanol; water for 6h; Reflux;
79.9%
2-bromo-1-cyclopropylethan-1-one
69267-75-0

2-bromo-1-cyclopropylethan-1-one

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

2-((5-bromo-2-methylphenyl)amino)-1-cyclopropylethan-1-one

2-((5-bromo-2-methylphenyl)amino)-1-cyclopropylethan-1-one

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine at 100℃; for 15h;78.4%
Stage #1: 5-bromo-2-methylaniline With potassium carbonate; potassium iodide In N,N-dimethyl-formamide at 20℃; for 0.5h;
Stage #2: 2-bromo-1-cyclopropylethan-1-one In N,N-dimethyl-formamide at 60℃; for 3h;
45%
2,6-Diacetylpyridine
1129-30-2

2,6-Diacetylpyridine

5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

2,6-bis-[1-(5-bromo-2-methylphenylimino)-ethyl]-pyridine

2,6-bis-[1-(5-bromo-2-methylphenylimino)-ethyl]-pyridine

Conditions
ConditionsYield
toluene-4-sulfonic acid In toluene for 72h; Heating / reflux;78%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

N-(5-bromo-2-methylphenyl)methanesulfonamide

N-(5-bromo-2-methylphenyl)methanesulfonamide

Conditions
ConditionsYield
With pyridine In dichloromethane at 0℃; for 2h;78%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

5-bromo-2-methyl-phenylhydrazine hydrochloride

5-bromo-2-methyl-phenylhydrazine hydrochloride

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methylaniline With hydrogenchloride; sodium nitrite at 0℃;
Stage #2: With hydrogenchloride; tin(ll) chloride at 0℃; for 1h;
75%
5-bromo-2-methylaniline
39478-78-9

5-bromo-2-methylaniline

sodium nitrite
7632-00-0

sodium nitrite

5-bromo-2-methyl-phenylhydrazine hydrochloride

5-bromo-2-methyl-phenylhydrazine hydrochloride

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methylaniline; sodium nitrite With hydrogenchloride In water at 0℃; for 0.5h;
Stage #2: With hydrogenchloride; tin(ll) chloride In water at 0℃; for 1.83333h;
Stage #3: With hydrogenchloride; sodium hydroxide more than 3 stages;
75%

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