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Nanyang Junhao Chemical Co.,Ltd

3-Fluorobenzyl chlorideProduct name: 3-Fluorobenzyl chlorideCAS: 456-42-8Structural formula:Quality specification:Appearance: Colorless transparent liquidContent: 99.0%(Gc)minIsomer: 0.2% maxAppearance:Colorless transparent liquid Storage:Sealed and

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:0

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

3-Fluorobenzyl chloride Manufacturer/High quality/Best price/In stock

Cas:456-42-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 3-Fluorobenzyl Chloride? supplier in China

Cas:456-42-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

Top grade 3-Fluorobenzyl chloride CAS 456-42-8 with large quantity in stock Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Foo

Top grade 3-Fluorobenzyl chloride CAS 456-42-8 with large quantity in stock

Cas:456-42-8

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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EAST CHEMSOURCES LIMITED

3-Fluorobenzyl chloride Product name: 3-Fluorobenzyl chloride CAS: 456-42-8 Structural formula: Quality specification: Appearance: Colorless transparent liquid Content: 99.0%(Gc)min Isomer: 0.2% max Our Server 1. Competitive offers

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply α-chloro-p-fluorotoluene

Cas:456-42-8

Min.Order:1

Negotiable

Type:Other

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Tianfu Chemical, built in 2009, is a professional supplier for API materials in China. With 10 years development, we have bulit our own factory and lab to produce a certain of products. And we have established stable business relationship

TIANFU CHEM 456-42-8 3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:1 Kilogram

FOB Price: $200.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 456-42-8 with best quality

Cas:456-42-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:1 Kilogram

FOB Price: $50.0 / 100.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name 3-Fluorobenzyl chloride Synonyms m-Fluorobenzyl chloride; alpha-Chloro-m-fluorotoluene; 1-(Chloromethyl)-3-fluoro-benzene CAS NO. 456-42-8 Molecular For

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-(chloromethyl)-3-fluoro- 456-42-8

Cas:456-42-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

3-Fluorobenzyl chloride 99%

Cas:456-42-8

Min.Order:1 Kilogram

FOB Price: $76.0 / 85.0

Type:Trading Company

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1-(chloromethyl)-3-fluoro-

Cas:456-42-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzene,1-(chloromethyl)-3-fluoro-

Cas:456-42-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

3-Fluorobenzyl Chloride

Cas:456-42-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

1-(Chloromethyl)-3-fluorobenzeneAppearance:white powder Storage:Keep away of light, cool place Package:according to customers' requirements Application:pharmaceutical intermediates Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FO

1-(Chloromethyl)-3-fluorobenzene

Cas:456-42-8

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:Colorless to light yellow liquid Storage:sealed & stored in cool & dry place Package:200kg/drum, or as per your request. Application:For medicine , pesticide intermediates Transp

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 3-Fluorobenzyl Chloride CAS No.: 456-42-8 Molecule Formula:C7H6ClF Molecule Weight:144.57 Purity: 99.0% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard

Lower Price 3-Fluorobenzyl Chloride

Cas:456-42-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

3-Fluorobenzyl chloride Chemical Properties Melting point 34.5-36 °C Boiling point 176-177 °C density 1.194 g/mL at 25 °C(lit.) refractive index n20/D 1.511(lit.) Fp 138 °F storage temp. Store below +30°C.

3-Fluorobenzyl Chloride

Cas:456-42-8

Min.Order:1 Gram

FOB Price: $65.0

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

3-Fluorobenzyl chloride

Cas:456-42-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

m-Fluorotoluene
352-70-5

m-Fluorotoluene

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

Conditions
ConditionsYield
With methanol; tetrachloromethane; iron(II) chloride tetrahydrate; formamide at 180℃; for 6h; Reagent/catalyst; Inert atmosphere; Sealed tube; Autoclave; chemoselective reaction;35%
at 147℃; Irradiation.Einleiten von Chlor;
at 147℃; Einleiten von Chlor;
m-Fluorotoluene
352-70-5

m-Fluorotoluene

A

1-dichloromethyl-3-fluoro-benzene
402-64-2

1-dichloromethyl-3-fluoro-benzene

B

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

Conditions
ConditionsYield
Chlorierung;
3-fluoro-benzenemethanol
456-47-3

3-fluoro-benzenemethanol

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

Conditions
ConditionsYield
With pyridine; thionyl chloride
1-fluoro-3-(iodomethyl)benzene
28490-56-4

1-fluoro-3-(iodomethyl)benzene

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

Conditions
ConditionsYield
With pyridine; tributyltin chloride at 50℃; Thermodynamic data; Equilibrium constant; Δ G;28 % Spectr.
m-fluorobenzyl ion
65108-06-7

m-fluorobenzyl ion

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

Conditions
ConditionsYield
With tertiary butyl chloride In gaseous matrix at 600℃; chloride affinity;
1-(Bromomethyl)-3-fluorobenzene
456-41-7

1-(Bromomethyl)-3-fluorobenzene

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

Conditions
ConditionsYield
With pyridine; tributyltin chloride at 50℃; Thermodynamic data; Equilibrium constant; Δ G;65 % Spectr.
1-bromomethyl-4-nitro-benzene
100-11-8

1-bromomethyl-4-nitro-benzene

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

Conditions
ConditionsYield
With pyridine; tributyltin chloride at 50℃; Thermodynamic data; Equilibrium constant; Δ G;65 % Spectr.
1-(1-chloro-2,2,2-trifluoroethyl)-4-chlorobenzene
394-54-7

1-(1-chloro-2,2,2-trifluoroethyl)-4-chlorobenzene

m-fluorobenzyl ion
65108-06-7

m-fluorobenzyl ion

A

C8H5ClF3(1+)
128408-33-3

C8H5ClF3(1+)

B

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

Conditions
ConditionsYield
at 69.85℃; Thermodynamic data; chloride-transfer;
1-(1-Chloro-2,2,2-trifluoro-ethyl)-3-methyl-benzene
191402-55-8

1-(1-Chloro-2,2,2-trifluoro-ethyl)-3-methyl-benzene

m-fluorobenzyl ion
65108-06-7

m-fluorobenzyl ion

A

C9H8F3(1+)
128408-28-6

C9H8F3(1+)

B

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

Conditions
ConditionsYield
at 69.85℃; Thermodynamic data; chloride-transfer;
1-(1-Chloro-2,2,2-trifluoro-ethyl)-4-fluoro-benzene
81577-13-1

1-(1-Chloro-2,2,2-trifluoro-ethyl)-4-fluoro-benzene

m-fluorobenzyl ion
65108-06-7

m-fluorobenzyl ion

A

C8H5F4(1+)
128408-32-2

C8H5F4(1+)

B

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

Conditions
ConditionsYield
at 69.85℃; Thermodynamic data; chloride-transfer;
2-Chloro-4-(1-chloro-2,2,2-trifluoro-ethyl)-1-methyl-benzene

2-Chloro-4-(1-chloro-2,2,2-trifluoro-ethyl)-1-methyl-benzene

m-fluorobenzyl ion
65108-06-7

m-fluorobenzyl ion

A

C9H7ClF3(1+)
128408-27-5

C9H7ClF3(1+)

B

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

Conditions
ConditionsYield
at 69.85℃; Thermodynamic data; chloride-transfer;
3-fluoro-toluene-vapour

3-fluoro-toluene-vapour

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

Conditions
ConditionsYield
With chlorine
(Z)-6-methoxy-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one
1178094-73-9

(Z)-6-methoxy-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

(Z)-1-(3-fluorobenzyl)-4-((6-methoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)pyridinium chloride
1250364-30-7

(Z)-1-(3-fluorobenzyl)-4-((6-methoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)pyridinium chloride

Conditions
ConditionsYield
In acetonitrile Reflux;100%
(Z)-6-ethoxy-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one
1250364-18-1

(Z)-6-ethoxy-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

(Z)-1-(3-fluorobenzyl)-4-((6-ethoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)pyridinium chloride
1250364-43-2

(Z)-1-(3-fluorobenzyl)-4-((6-ethoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)pyridinium chloride

Conditions
ConditionsYield
In acetonitrile Reflux;100%
(Z)-6-propoxy-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one
1250364-19-2

(Z)-6-propoxy-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

(Z)-1-(3-fluorobenzyl)-4-((6-propoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)pyridinium chloride
1250364-55-6

(Z)-1-(3-fluorobenzyl)-4-((6-propoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)pyridinium chloride

Conditions
ConditionsYield
In acetonitrile Reflux;100%
mercaptoacetic acid
68-11-1

mercaptoacetic acid

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

2-(3-fluorobenzylthio)acetic acid

2-(3-fluorobenzylthio)acetic acid

Conditions
ConditionsYield
With sodium hydroxide In methanol at 20℃; for 1h;98.1%
carbon dioxide
124-38-9

carbon dioxide

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

(3-fluorophenyl)acetic acid
331-25-9

(3-fluorophenyl)acetic acid

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; manganese; palladium diacetate; magnesium chloride In N,N-dimethyl-formamide under 760.051 Torr; for 12h; Inert atmosphere; Schlenk technique;96%
m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

C19H22Cl3NO3
214326-07-5

C19H22Cl3NO3

C26H27Cl3FNO3
214325-98-1

C26H27Cl3FNO3

Conditions
ConditionsYield
With potassium carbonate In ethanol Heating;95%
4-hydroxy-benzaldehyde
123-08-0

4-hydroxy-benzaldehyde

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

4-(3-fluoro-benzyloxy)-benzaldehyde
66742-57-2

4-(3-fluoro-benzyloxy)-benzaldehyde

Conditions
ConditionsYield
With potassium carbonate; sodium iodide In ethanol for 5.41667h; Product distribution / selectivity; Heating / reflux;95%
With sodium hydroxide In ethanol for 6.75h; Product distribution / selectivity; Heating / reflux;95%
With potassium carbonate; sodium iodide In ethanol for 5.41667h; Product distribution / selectivity; Heating / reflux;95%
m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

(E)-3-(pyridin-4-ylmethylene)indolin-2-one
128564-78-3

(E)-3-(pyridin-4-ylmethylene)indolin-2-one

(E)-1-(3-fluorobenzyl)-4-((2-oxoindolin-3-ylidene)methyl)pyridinium chloride
1621102-53-1

(E)-1-(3-fluorobenzyl)-4-((2-oxoindolin-3-ylidene)methyl)pyridinium chloride

Conditions
ConditionsYield
In acetonitrile at 60 - 70℃;95%
2-amino-benzenethiol
137-07-5

2-amino-benzenethiol

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

2-(3-fluorophenyl)benzo[d]thiazole
1629-07-8

2-(3-fluorophenyl)benzo[d]thiazole

Conditions
ConditionsYield
With pyridine; sulfur at 130℃; for 20h; Inert atmosphere;95%
2-Chloronitrobenzene
88-73-3

2-Chloronitrobenzene

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

2-(3-fluorophenyl)benzo[d]thiazole
1629-07-8

2-(3-fluorophenyl)benzo[d]thiazole

Conditions
ConditionsYield
With N-methylcyclohexylamine; sulfur at 110℃; for 24h; Sealed tube; Inert atmosphere;95%
m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

C44H45FN2O6*2HCl

C44H45FN2O6*2HCl

Conditions
ConditionsYield
Stage #1: demethyltetrandrine; m-fluorobenzyl chloride With tetrabutylammomium bromide In water at 120℃; for 1h; Sonication;
Stage #2: With hydrogenchloride In water Reagent/catalyst; Solvent; Temperature; Molecular sieve;
94.77%
2-amino-4-methoxy-N-(8-azabicyclo<3,2,1>oct-3 β-yl)-5-pyrimidine carboxamide
76352-25-5

2-amino-4-methoxy-N-(8-azabicyclo<3,2,1>oct-3 β-yl)-5-pyrimidine carboxamide

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

2-Amino-4-methoxy-pyrimidine-5-carboxylic acid [(1R,3S,5S)-8-(3-fluoro-benzyl)-8-aza-bicyclo[3.2.1]oct-3-yl]-amide
84922-97-4

2-Amino-4-methoxy-pyrimidine-5-carboxylic acid [(1R,3S,5S)-8-(3-fluoro-benzyl)-8-aza-bicyclo[3.2.1]oct-3-yl]-amide

Conditions
ConditionsYield
With potassium carbonate In acetone for 36h; Heating;94%
m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

1-(4-fluoro-phenyl)-2-(tetrahydro-pyrimidin-2-ylidene)-ethanone
251940-05-3

1-(4-fluoro-phenyl)-2-(tetrahydro-pyrimidin-2-ylidene)-ethanone

3-(3'-fluorophenyl)-1-(4'-fluoro-phenyl)-2-(tetrahydropyrimidin-2'-ylidene)-propan-1-one

3-(3'-fluorophenyl)-1-(4'-fluoro-phenyl)-2-(tetrahydropyrimidin-2'-ylidene)-propan-1-one

Conditions
ConditionsYield
In toluene at 65℃; for 2h;94%
6,7-dimethoxyisoquinoline-1(2H)-one
16101-63-6

6,7-dimethoxyisoquinoline-1(2H)-one

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

2-(3-fluorobenzyl)-6,7-dimethoxyisoquinolin-1(2H)-one

2-(3-fluorobenzyl)-6,7-dimethoxyisoquinolin-1(2H)-one

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 20℃; for 0.5h; Inert atmosphere;93.1%
1-phenyl-2-(tetrahydropyrimidin-2(1H)-ylidene)ethan-1-one
82100-30-9

1-phenyl-2-(tetrahydropyrimidin-2(1H)-ylidene)ethan-1-one

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

3-(3'-fluoro-phenyl)-1-phenyl-2-(tetrahydropyrimidin-2'-ylidene)-propan-1-one

3-(3'-fluoro-phenyl)-1-phenyl-2-(tetrahydropyrimidin-2'-ylidene)-propan-1-one

Conditions
ConditionsYield
In toluene at 60℃; for 2h;93%
N,2,5-trimethoxy-N-methylbenzamide
1146443-78-8

N,2,5-trimethoxy-N-methylbenzamide

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

1-(2,5-dimethoxyphenyl)-2-(3-fluorophenyl)ethanone
1097077-65-0

1-(2,5-dimethoxyphenyl)-2-(3-fluorophenyl)ethanone

Conditions
ConditionsYield
Stage #1: m-fluorobenzyl chloride With magnesium In diethyl ether at 0 - 20℃; for 4h;
Stage #2: N,2,5-trimethoxy-N-methylbenzamide In tetrahydrofuran; diethyl ether at 0℃; for 1h;
93%
Stage #1: m-fluorobenzyl chloride With iodine; magnesium In tetrahydrofuran at 0℃;
Stage #2: N,2,5-trimethoxy-N-methylbenzamide In tetrahydrofuran at 0℃; for 1h;
2‐amino‐4‐(pyridin‐4‐yl)‐5‐oxo‐4H,5H‐pyrano[3,2‐c]chromene‐3‐carbonitrile

2‐amino‐4‐(pyridin‐4‐yl)‐5‐oxo‐4H,5H‐pyrano[3,2‐c]chromene‐3‐carbonitrile

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

4-(2-amino-3-cyano-5-oxo-4,5-dihydropyrano[3,2-c]chromen-4-yl)-1-(3-fluorobenzyl)pyridinium chloride

4-(2-amino-3-cyano-5-oxo-4,5-dihydropyrano[3,2-c]chromen-4-yl)-1-(3-fluorobenzyl)pyridinium chloride

Conditions
ConditionsYield
With potassium iodide In acetonitrile Reflux;93%
8-chloro-[1,2,4]triazolo[4,3-a]pyridine-3(2H)-thione
22841-91-4

8-chloro-[1,2,4]triazolo[4,3-a]pyridine-3(2H)-thione

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

8-chloro-3-((3-fluorobenzyl)thio)-[1,2,4]triazolo[4,3-a]pyridine

8-chloro-3-((3-fluorobenzyl)thio)-[1,2,4]triazolo[4,3-a]pyridine

Conditions
ConditionsYield
With sodium hydroxide In N,N-dimethyl-formamide at 90℃; for 0.25h; Microwave irradiation;93%
With sodium hydroxide In N,N-dimethyl-formamide at 90℃; for 0.25h; Microwave irradiation;81%
2-iodophenylamine
615-43-0

2-iodophenylamine

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

2-(3-fluorophenyl)benzo[d]thiazole
1629-07-8

2-(3-fluorophenyl)benzo[d]thiazole

Conditions
ConditionsYield
With copper(II) acetate monohydrate; sodium carbonate; sulfur In dimethyl sulfoxide at 130℃; for 24h; Schlenk technique; Inert atmosphere;93%
2-methylamino-5-mercapto-1,3,4-thiadiazole
27386-01-2

2-methylamino-5-mercapto-1,3,4-thiadiazole

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

2-(3-fluorobenzylthio)-5-methylamino-1,3,4-thiadiazole
97773-03-0

2-(3-fluorobenzylthio)-5-methylamino-1,3,4-thiadiazole

Conditions
ConditionsYield
With potassium hydroxide In methanol for 0.5h; Ambient temperature;92%
oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

3-(3-fluorophenyl)-2-oxopropionic acid ethyl ester

3-(3-fluorophenyl)-2-oxopropionic acid ethyl ester

Conditions
ConditionsYield
Stage #1: m-fluorobenzyl chloride With magnesium In diethyl ether for 0.166667h; Heating;
Stage #2: oxalic acid diethyl ester In diethyl ether at 20℃; for 2h; Grignard reaction;
92%
CH3C6H3OCHCNC(CONH)
918156-44-2

CH3C6H3OCHCNC(CONH)

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

CH3C6H3OCHCNC(CON)CH2C6H4F

CH3C6H3OCHCNC(CON)CH2C6H4F

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 20℃; for 12h;92%
N-methylacetohydroxamic acid
13115-24-7

N-methylacetohydroxamic acid

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

N-((3-fluorobenzyl)oxy)-N-methylacetamide
1352918-96-7

N-((3-fluorobenzyl)oxy)-N-methylacetamide

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 12h; Inert atmosphere;92%
allylbenzene
300-57-2

allylbenzene

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

1-(2-benzylallyl)-3-fluorobenzene
1419174-93-8

1-(2-benzylallyl)-3-fluorobenzene

Conditions
ConditionsYield
With trimethylsilyl trifluoromethanesulfonate; trans-bis(dicyclohexylphenylphosphine)(2-methylphenyl)nickel(II) chloride; triethylamine In dichloromethane at 20℃; for 4h; Heck Reaction; regioselective reaction;92%
5-chloro-2-benzoxazolinone
95-25-0

5-chloro-2-benzoxazolinone

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

5-chloro-3-(3-fluorobenzyl)benzo[d]oxazol-2(3H)-one

5-chloro-3-(3-fluorobenzyl)benzo[d]oxazol-2(3H)-one

Conditions
ConditionsYield
Stage #1: 5-chloro-2-benzoxazolinone With potassium carbonate In N,N-dimethyl-formamide at 90℃; for 1h;
Stage #2: m-fluorobenzyl chloride In N,N-dimethyl-formamide at 60℃; for 7h;
92%
aniline
62-53-3

aniline

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

N-(3-fluorobenzyl)aniline
83444-26-2

N-(3-fluorobenzyl)aniline

Conditions
ConditionsYield
With sodium carbonate at 110℃; for 1h;90%
2-fluorophenol
367-12-4

2-fluorophenol

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

C13H10F2O

C13H10F2O

Conditions
ConditionsYield
With sodium In ethanol for 2h; Heating;90%
(3R,6S)-hexahydrofuro[3,2-b]furan-3,6-diol
1214839-99-2

(3R,6S)-hexahydrofuro[3,2-b]furan-3,6-diol

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

(3R,6S)-3,6-Bis-(3-fluoro-benzyloxy)-hexahydro-furo[3,2-b]furan

(3R,6S)-3,6-Bis-(3-fluoro-benzyloxy)-hexahydro-furo[3,2-b]furan

Conditions
ConditionsYield
With potassium hydroxide; tetrabutylammomium bromide In xylene at 125℃; for 0.0833333h; Alkylation; microwave irradiation;90%
1-(4-chlorophenyl)-2-(tetrahydropyrimidin-2(1H)-ylidene)ethan-1-one
107165-83-3

1-(4-chlorophenyl)-2-(tetrahydropyrimidin-2(1H)-ylidene)ethan-1-one

m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

1-(4'-chloro-phenyl)-3-(3'-fluoro-phenyl)-2-(tetrahydropyrimidin-2'-ylidene)-propan-1-one

1-(4'-chloro-phenyl)-3-(3'-fluoro-phenyl)-2-(tetrahydropyrimidin-2'-ylidene)-propan-1-one

Conditions
ConditionsYield
In toluene at 65℃; for 3h;90%
m-fluorobenzyl chloride
456-42-8

m-fluorobenzyl chloride

5-nitroindazole
5401-94-5

5-nitroindazole

A

1-(3-fluorobenzyl)-5-nitro-1H-carbazole
529508-58-5

1-(3-fluorobenzyl)-5-nitro-1H-carbazole

B

1-(3-fluorobenzyl)-1H-indazol-5-ylamine
202197-31-7

1-(3-fluorobenzyl)-1H-indazol-5-ylamine

Conditions
ConditionsYield
With Ki; potassium carbonate In water; N,N-dimethyl-formamideA 33%
B 90%
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