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Henan Tianfu Chemical Co., Ltd.

High Quality Best price Fast Delivery Good Service Welcome to Henan Tianfu Chemical Co., Ltd. website. Our company engages in Sodium Tripolyphosphate (STPP) and Sodium Hexametabphosphate (SHMP) production; developm

N-Methyl-8-azabicyclo[3.2.1]octane

Cas:529-17-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

8-Azabicyclo[3.2.1]octane,8-methyl-

Cas:529-17-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

8-METHYL-8-AZABICYCLO[3.2.1]OCTANE

Cas:529-17-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

8-Azabicyclo[3.2.1]octane,8-methyl-

Cas:529-17-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

8-METHYL-8-AZABICYCLO[3.2.1]OCTANE

Cas:529-17-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

hight degree of purity Application:Fine chemical intermediates, used as the main raw material for he synthesis of various pesticides, medicines, surfactants, polymer monomers, Ond Ontifungal agents

8-Azabicyclo[3.2.1]octane,8-methyl-

Cas:529-17-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

8-METHYL-8-AZABICYCLO[3.2.1]OCTANE

Cas:529-17-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 8-METHYL-8-AZABICYCLO[3.2.1]OCTANE, CAS:529-17-9 with the most competitive price and

8-METHYL-8-AZABICYCLO[3.2.1]OCTANE

Cas:529-17-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Topbatt Chemical Co., Ltd.

Topbatt Chemical Co., Ltd., Established in 2019, located in Shenzhen, Guangdong Province, is a Manufacturer and Trading company which specialized in fine chemicals like Pharmaceutical Reference Standards and Stable Isotopes. Our Stable Isotopes produ

Tropane

Cas:529-17-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

tropinone
532-24-1

tropinone

tropane
529-17-9

tropane

Conditions
ConditionsYield
With hydrogenchloride; hydrogen; platinum(IV) oxide under 1.5 Torr; for 35h;100%
With potassium hydroxide; hydrazine In 2,2'-[1,2-ethanediylbis(oxy)]bisethanol for 8h; Wolff-Kischener reduction; Heating;
carbon monoxide
201230-82-2

carbon monoxide

tropidine
529-18-0

tropidine

A

tropane
529-17-9

tropane

B

tropan-2-yl-methanol
68969-37-9

tropan-2-yl-methanol

C

3-hydroxymethyl-8-methyl-8-azabicyclo[3.2.1]octane
90949-82-9, 888716-28-7

3-hydroxymethyl-8-methyl-8-azabicyclo[3.2.1]octane

D

Tropan-3β-carboxaldehyd
93047-52-0, 99658-61-4

Tropan-3β-carboxaldehyd

Conditions
ConditionsYield
With hydrogen; di-μ-chlorobis(norbornadiene)dirhodium(I); tributylphosphine In benzene at 100℃; under 60004.8 Torr; for 6h;A 2%
B n/a
C n/a
D 92%
carbon monoxide
201230-82-2

carbon monoxide

tropidine
529-18-0

tropidine

A

tropane
529-17-9

tropane

B

tropan-2-yl-methanol
68969-37-9

tropan-2-yl-methanol

C

3-hydroxymethyl-8-methyl-8-azabicyclo[3.2.1]octane
90949-82-9, 888716-28-7

3-hydroxymethyl-8-methyl-8-azabicyclo[3.2.1]octane

D

Tropan-3β-carboxaldehyd
93047-52-0, 99658-61-4

Tropan-3β-carboxaldehyd

E

8-Methyl-8-aza-bicyclo[3.2.1]octane-2-carbaldehyde

8-Methyl-8-aza-bicyclo[3.2.1]octane-2-carbaldehyde

Conditions
ConditionsYield
With hydrogen; carbonylhydridetris(triphenylphosphine)rhodium(I) In benzene at 100℃; under 60004.8 Torr; for 6h; Product distribution; various catalysts, formed in situ from various phosphines;A 2%
B n/a
C n/a
D 86%
E 10%
N-<(benzoyloxy)carbonyl>nortropane
95799-01-2

N-<(benzoyloxy)carbonyl>nortropane

tropane
529-17-9

tropane

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran for 24h; Ambient temperature;72%
1-<(methyl(4-cycloheptenyl)carbamoyl)oxy>-2(1H)-pyridinethione
122709-62-0

1-<(methyl(4-cycloheptenyl)carbamoyl)oxy>-2(1H)-pyridinethione

A

tropane
529-17-9

tropane

B

2-(2-pyridylthio)tropane
128729-93-1

2-(2-pyridylthio)tropane

Conditions
ConditionsYield
With 2-methylpropan-2-thiol; acetic acid In acetonitrile at 25℃; Irradiation;A 68%
B 3 % Chromat.
carbon monoxide
201230-82-2

carbon monoxide

tropidine
529-18-0

tropidine

A

tropane
529-17-9

tropane

B

Tropan-3β-carboxaldehyd
93047-52-0, 99658-61-4

Tropan-3β-carboxaldehyd

C

8-Methyl-8-aza-bicyclo[3.2.1]octane-2-carbaldehyde

8-Methyl-8-aza-bicyclo[3.2.1]octane-2-carbaldehyde

Conditions
ConditionsYield
With hydrogen; di-μ-chlorobis(norbornadiene)dirhodium(I); tricyclohexylphosphine In benzene at 100℃; under 60004.8 Torr; for 6h;A 22%
B 67%
C 11%
1-<(methyl(4-cycloheptenyl)carbamoyl)oxy>-2(1H)-pyridinethione
122709-62-0

1-<(methyl(4-cycloheptenyl)carbamoyl)oxy>-2(1H)-pyridinethione

tropane
529-17-9

tropane

Conditions
ConditionsYield
With 2-methylpropan-2-thiol; acetic acid In benzene at 4℃;67%
N-methyl-N-cycloheptylamine
42870-65-5

N-methyl-N-cycloheptylamine

tropane
529-17-9

tropane

Conditions
ConditionsYield
With chlorine Erwaermen des erhaltenen Chlor-cycloheptyl-methyl-amins mit 84%ig. wss. Schwefelsaeure;
Conditions
ConditionsYield
With diethyl ether; platinum Hydrogenation;
3-tropanol
120-29-6

3-tropanol

tropane
529-17-9

tropane

Conditions
ConditionsYield
With phosphonium iodide; hydrogen iodide at 195 - 200℃; im Rohr;
(1S,4R)-4-Methylamino-cycloheptanol

(1S,4R)-4-Methylamino-cycloheptanol

tropane
529-17-9

tropane

Conditions
ConditionsYield
With thionyl chloride 1.) CDCl3, 0 deg C to room temperature, 19.5 h, 2.) 12 h; Yield given. Multistep reaction;
hydroscopolin

hydroscopolin

tropane
529-17-9

tropane

Conditions
ConditionsYield
With phosphonium iodide; hydrogen iodide at 195 - 205℃; im Rohr;
tropane-6,7-diol
103392-59-2

tropane-6,7-diol

hydrogen iodide
10034-85-2

hydrogen iodide

phosphonium iodide

phosphonium iodide

tropane
529-17-9

tropane

Conditions
ConditionsYield
at 195 - 205℃;
hydrogen iodide
10034-85-2

hydrogen iodide

3-tropanol
120-29-6

3-tropanol

phosphonium iodide

phosphonium iodide

tropane
529-17-9

tropane

Conditions
ConditionsYield
at 195 - 200℃;
diethyl ether
60-29-7

diethyl ether

tropidine
529-18-0

tropidine

platinum black

platinum black

tropane
529-17-9

tropane

Conditions
ConditionsYield
Hydrogenation;
tropane chloromethylate

tropane chloromethylate

tropane
529-17-9

tropane

Conditions
ConditionsYield
Bei der trocknen Destillation;
hydriodide of 3-iodo-tropane

hydriodide of 3-iodo-tropane

A

tropane
529-17-9

tropane

Conditions
ConditionsYield
With hydrogenchloride; zinc
With hydrogen iodide; zinc
hydrobromide of α-tropidine hydrobromide

hydrobromide of α-tropidine hydrobromide

A

tropane
529-17-9

tropane

Conditions
ConditionsYield
With sulfuric acid; zinc
With hydrogen iodide; zinc
3-iodo-tropane

3-iodo-tropane

hydrogenchloride
7647-01-0

hydrogenchloride

zinc dust

zinc dust

A

tropane
529-17-9

tropane

sulfuric acid
7664-93-9

sulfuric acid

tropinone
532-24-1

tropinone

A

tropane
529-17-9

tropane

B

3-tropanol
120-29-6

3-tropanol

C

pseudotropine
135-97-7

pseudotropine

Conditions
ConditionsYield
elektrolytische Reduktion an einer Bleikathode;
tropinone
532-24-1

tropinone

hydrogen iodide
10034-85-2

hydrogen iodide

zinc

zinc

A

tropane
529-17-9

tropane

B

3-tropanol
120-29-6

3-tropanol

C

pseudotropine
135-97-7

pseudotropine

tropinone
532-24-1

tropinone

A

tropane
529-17-9

tropane

B

tropine, pseudotropine

tropine, pseudotropine

Conditions
ConditionsYield
elektrolytische Reduktion;
With hydrogen iodide; zinc
3exo-bromo-tropane
2292-11-7

3exo-bromo-tropane

sulfuric acid
7664-93-9

sulfuric acid

zinc

zinc

A

tropane
529-17-9

tropane

tropane iodomethylate

tropane iodomethylate

A

tropane
529-17-9

tropane

B

cyclohept-3-enyl-dimethyl-amine
855405-70-8

cyclohept-3-enyl-dimethyl-amine

Conditions
ConditionsYield
With silver(l) oxide durch Destillation der entstandenen stark alkal. Loesung der Ammoniumbase;
cis-4-[(benzyloxycarbonyl)amino]cyclohept-2-enol
113340-14-0, 146309-07-1

cis-4-[(benzyloxycarbonyl)amino]cyclohept-2-enol

tropane
529-17-9

tropane

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 66 percent / LiAlH4 / tetrahydrofuran / 10 h / Heating
2: 90 percent / H2 / 5percent Pd on charcoal / methanol / 16 h
3: 1.) SOCl2, 2.) TABD / 1.) CDCl3, 0 deg C to room temperature, 19.5 h, 2.) 12 h
View Scheme
6-Oxa-7-aza-bicyclo[3.2.2]non-8-ene-7-carboxylic acid benzyl ester
146309-04-8

6-Oxa-7-aza-bicyclo[3.2.2]non-8-ene-7-carboxylic acid benzyl ester

tropane
529-17-9

tropane

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 67 percent / LiAlH4 / tetrahydrofuran / 10 h / Heating
2: 87 percent / Zn / acetic acid / 4 h / 50 - 60 °C
3: 90 percent / H2 / 5percent Pd on charcoal / methanol / 16 h
4: 1.) SOCl2, 2.) TABD / 1.) CDCl3, 0 deg C to room temperature, 19.5 h, 2.) 12 h
View Scheme
(1S,4R)-4-Methylamino-cyclohept-2-enol

(1S,4R)-4-Methylamino-cyclohept-2-enol

tropane
529-17-9

tropane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 90 percent / H2 / 5percent Pd on charcoal / methanol / 16 h
2: 1.) SOCl2, 2.) TABD / 1.) CDCl3, 0 deg C to room temperature, 19.5 h, 2.) 12 h
View Scheme
N-methyl-8-oxa-9-azabicyclo[3.2.2]non-6-ene
214326-04-2

N-methyl-8-oxa-9-azabicyclo[3.2.2]non-6-ene

tropane
529-17-9

tropane

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 87 percent / Zn / acetic acid / 4 h / 50 - 60 °C
2: 90 percent / H2 / 5percent Pd on charcoal / methanol / 16 h
3: 1.) SOCl2, 2.) TABD / 1.) CDCl3, 0 deg C to room temperature, 19.5 h, 2.) 12 h
View Scheme
1-chloro-1-nitrosocyclohexane
695-64-7

1-chloro-1-nitrosocyclohexane

tropane
529-17-9

tropane

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: 68 percent / ethanol; CCl4 / 48 h / -10 °C
2: 98 percent / H2 / 5percent Pd/C / methanol / 7 h / 760 Torr
3: 80 percent / Na2CO3 / CHCl3; H2O / 1.) 0 deg C, 30 min, 2.) RT, 2h
4: 12 percent / SOCl2 / CHCl3 / 48 h / Ambient temperature
5: 78 percent / potassium tert-butoxide / benzene; hexamethylphosphoric acid triamide / 2 h / Ambient temperature
6: 72 percent / LiALH4 / tetrahydrofuran / 24 h / Ambient temperature
View Scheme
Multi-step reaction with 6 steps
1: 68 percent / ethanol; CCl4 / 48 h / -10 °C
2: 98 percent / H2 / 5percent Pd/C / methanol / 7 h / 760 Torr
3: 80 percent / Na2CO3 / CHCl3; H2O / 1.) 0 deg C, 30 min, 2.) RT, 2h
4: SOCl2, pyridine / diethyl ether / 14 h / Ambient temperature
5: 78 percent / potassium tert-butoxide / benzene; hexamethylphosphoric acid triamide / 2 h / Ambient temperature
6: 72 percent / LiALH4 / tetrahydrofuran / 24 h / Ambient temperature
View Scheme
Multi-step reaction with 5 steps
1: 68 percent / ethanol; CCl4 / 48 h / -10 °C
2: 98 percent / H2 / 5percent Pd/C / methanol / 7 h / 760 Torr
3: 80 percent / Na2CO3 / CHCl3; H2O / 1.) 0 deg C, 30 min, 2.) RT, 2h
5: 72 percent / LiALH4 / tetrahydrofuran / 24 h / Ambient temperature
View Scheme
tropane
529-17-9

tropane

chloroformic acid ethyl ester
541-41-3

chloroformic acid ethyl ester

N-(ethoxycarbonyl)nortropane
6760-98-1

N-(ethoxycarbonyl)nortropane

Conditions
ConditionsYield
In benzene95%
tropane
529-17-9

tropane

norborn-2-ene
498-66-8

norborn-2-ene

C15H25N

C15H25N

Conditions
ConditionsYield
With scandium tris(ortho-N,N-dimethylaminobenzyl); trityl tetrakis(pentafluorophenyl)borate In toluene at 70℃; for 24h; regiospecific reaction;90%
tropane
529-17-9

tropane

8-azabicyclo[3.2.1]octane
280-05-7

8-azabicyclo[3.2.1]octane

Conditions
ConditionsYield
With carbonochloridic acid 1-chloro-ethyl ester In DCE at 0℃; for 4.08333h; Heating / reflux;83%
With hypochloric acid Reduktion des entstandenen N-Chlor-nortropans;
tropane
529-17-9

tropane

2-(nonafluoro-tert-butoxy)ethyl acrylate

2-(nonafluoro-tert-butoxy)ethyl acrylate

6-((1R,5S)-8-azabicyclo[3.2.1]octan-8-yl)-1-((1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-yl)oxy)hexan-3-one

6-((1R,5S)-8-azabicyclo[3.2.1]octan-8-yl)-1-((1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-yl)oxy)hexan-3-one

Conditions
ConditionsYield
With benzophenone; copper diacetate In acetonitrile at 35℃; for 3h; Giese Free Radical Synthesis; Darkness; Inert atmosphere; Irradiation; Sealed tube;83%
tropane
529-17-9

tropane

methyl vinyl ketone
78-94-4

methyl vinyl ketone

5-((1R,5S)-8-azabicyclo[3.2.1]octan-8-yl)pentan-2-one

5-((1R,5S)-8-azabicyclo[3.2.1]octan-8-yl)pentan-2-one

Conditions
ConditionsYield
With benzophenone; copper diacetate In acetonitrile at 35℃; for 16h; Giese Free Radical Synthesis; Darkness; Inert atmosphere; Irradiation; Sealed tube;73%
tropane
529-17-9

tropane

8-azabicyclo[3.2.1]octane hydrochloride
6760-99-2

8-azabicyclo[3.2.1]octane hydrochloride

Conditions
ConditionsYield
Stage #1: tropane With chloroformic acid ethyl ester In toluene at 80℃; for 24h;
Stage #2: With hydrogenchloride In water at 100℃; for 2h;
72%
Multi-step reaction with 2 steps
1: Et3N / CH2Cl2
2: MeOH
View Scheme
Multi-step reaction with 2 steps
1: 95 percent / benzene
2: 90 percent / aq. HCl / Heating
View Scheme
tropane
529-17-9

tropane

acetic anhydride
108-24-7

acetic anhydride

8-acetyl-nortropane
769-04-0

8-acetyl-nortropane

Conditions
ConditionsYield
palladium diacetate at 80℃; for 14h; Neat (no solvent);70%
tropane
529-17-9

tropane

acrylonitrile
107-13-1

acrylonitrile

4-(8-azabicyclo[3.2.1]octan-8-yl)butanenitrile

4-(8-azabicyclo[3.2.1]octan-8-yl)butanenitrile

Conditions
ConditionsYield
With benzophenone; copper diacetate In acetonitrile at 35℃; for 5h; Giese Free Radical Synthesis; Darkness; Inert atmosphere; Irradiation; Sealed tube;69%
tropane
529-17-9

tropane

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

8-benzyl-8-azabicyclo[3.2.1]octane
19079-79-9

8-benzyl-8-azabicyclo[3.2.1]octane

Conditions
ConditionsYield
Stage #1: tropane With 1,4-diaza-bicyclo[2.2.2]octane; tri(4-tolyl)aminium hexafluorophosphate In acetonitrile at -5℃; Inert atmosphere;
Stage #2: phenylmagnesium bromide In tetrahydrofuran; acetonitrile at 0℃; for 0.0833333h; Inert atmosphere; regioselective reaction;
66%
tropane
529-17-9

tropane

ethyl acrylate
140-88-5

ethyl acrylate

ethyl 4-(8-azabicyclo[3.2.1]octan-8-yl)butanoate

ethyl 4-(8-azabicyclo[3.2.1]octan-8-yl)butanoate

Conditions
ConditionsYield
With benzophenone; copper diacetate In acetonitrile at 35℃; for 3h; Giese Free Radical Synthesis; Darkness; Inert atmosphere; Irradiation; Sealed tube;61%
tropane
529-17-9

tropane

phenyl chloroformate
1885-14-9

phenyl chloroformate

8-Aza-bicyclo[3.2.1]octane-8-carboxylic acid phenyl ester

8-Aza-bicyclo[3.2.1]octane-8-carboxylic acid phenyl ester

Conditions
ConditionsYield
In dichloromethane Ambient temperature;60%
tropane
529-17-9

tropane

benzophenone
119-61-9

benzophenone

A

tetraphenylethane-1,2-diol
464-72-2

tetraphenylethane-1,2-diol

B

1,2-bis(8-azabicyclo<3,2,1>oct-8-yl)ethane

1,2-bis(8-azabicyclo<3,2,1>oct-8-yl)ethane

C

2-(8-Aza-bicyclo[3.2.1]oct-8-yl)-1,1-diphenyl-ethanol

2-(8-Aza-bicyclo[3.2.1]oct-8-yl)-1,1-diphenyl-ethanol

Conditions
ConditionsYield
In benzene at 22 - 25℃; for 11h; Irradiation;A n/a
B 15%
C 56%
tropane
529-17-9

tropane

A

tetraphenylethane-1,2-diol
464-72-2

tetraphenylethane-1,2-diol

B

1,2-bis(8-azabicyclo<3,2,1>oct-8-yl)ethane

1,2-bis(8-azabicyclo<3,2,1>oct-8-yl)ethane

C

2-(8-Aza-bicyclo[3.2.1]oct-8-yl)-1,1-diphenyl-ethanol

2-(8-Aza-bicyclo[3.2.1]oct-8-yl)-1,1-diphenyl-ethanol

Conditions
ConditionsYield
With benzophenone In benzene at 22 - 25℃; for 11h; Irradiation;A n/a
B 15%
C 56%
tropane
529-17-9

tropane

8-formyl-nortropane
56771-95-0

8-formyl-nortropane

Conditions
ConditionsYield
With ruthenium tetroxide In tetrachloromethane for 2h;49%
tropane
529-17-9

tropane

bromocyane
506-68-3

bromocyane

nortropane-8-carbonitrile

nortropane-8-carbonitrile

Conditions
ConditionsYield
With diethyl ether
tropane
529-17-9

tropane

3-(N,N,N-trimethylammonio)propyl bromide
131732-22-4

3-(N,N,N-trimethylammonio)propyl bromide

8ξ-methyl-8ξ-(3-trimethylammonio-propyl)-nortropanium; dibromide
109286-69-3

8ξ-methyl-8ξ-(3-trimethylammonio-propyl)-nortropanium; dibromide

Conditions
ConditionsYield
With acetonitrile
tropane
529-17-9

tropane

benzoic acid
65-85-0

benzoic acid

8-benzoyl-8-azabicyclo<3.2.1>octane
95687-85-7

8-benzoyl-8-azabicyclo<3.2.1>octane

Conditions
ConditionsYield
at 190℃;
tropane
529-17-9

tropane

3-Phenylpropionic acid
501-52-0

3-Phenylpropionic acid

8-(3-phenyl-propionyl)-nortropane

8-(3-phenyl-propionyl)-nortropane

Conditions
ConditionsYield
at 190℃;
tropane
529-17-9

tropane

methyl iodide
74-88-4

methyl iodide

8,8-dimethyl-nortropanium; iodide
18600-24-3

8,8-dimethyl-nortropanium; iodide

Conditions
ConditionsYield
With methanol
tropane
529-17-9

tropane

tropane-8-oxide

tropane-8-oxide

Conditions
ConditionsYield
With dihydrogen peroxide

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