High Quality Best price Fast Delivery Good Service Welcome to Henan Tianfu Chemical Co., Ltd. website. Our company engages in Sodium Tripolyphosphate (STPP) and Sodium Hexametabphosphate (SHMP) production; developm
Cas:529-17-9
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
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Cas:529-17-9
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
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Cas:529-17-9
Min.Order:0 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:529-17-9
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryhigh quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
hight degree of purity Application:Fine chemical intermediates, used as the main raw material for he synthesis of various pesticides, medicines, surfactants, polymer monomers, Ond Ontifungal agents
Cas:529-17-9
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 8-METHYL-8-AZABICYCLO[3.2.1]OCTANE, CAS:529-17-9 with the most competitive price and
Topbatt Chemical Co., Ltd., Established in 2019, located in Shenzhen, Guangdong Province, is a Manufacturer and Trading company which specialized in fine chemicals like Pharmaceutical Reference Standards and Stable Isotopes. Our Stable Isotopes produ
Conditions | Yield |
---|---|
With hydrogenchloride; hydrogen; platinum(IV) oxide under 1.5 Torr; for 35h; | 100% |
With potassium hydroxide; hydrazine In 2,2'-[1,2-ethanediylbis(oxy)]bisethanol for 8h; Wolff-Kischener reduction; Heating; |
carbon monoxide
tropidine
A
tropane
B
tropan-2-yl-methanol
C
3-hydroxymethyl-8-methyl-8-azabicyclo[3.2.1]octane
D
Tropan-3β-carboxaldehyd
Conditions | Yield |
---|---|
With hydrogen; di-μ-chlorobis(norbornadiene)dirhodium(I); tributylphosphine In benzene at 100℃; under 60004.8 Torr; for 6h; | A 2% B n/a C n/a D 92% |
carbon monoxide
tropidine
A
tropane
B
tropan-2-yl-methanol
C
3-hydroxymethyl-8-methyl-8-azabicyclo[3.2.1]octane
D
Tropan-3β-carboxaldehyd
Conditions | Yield |
---|---|
With hydrogen; carbonylhydridetris(triphenylphosphine)rhodium(I) In benzene at 100℃; under 60004.8 Torr; for 6h; Product distribution; various catalysts, formed in situ from various phosphines; | A 2% B n/a C n/a D 86% E 10% |
N-<(benzoyloxy)carbonyl>nortropane
tropane
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In tetrahydrofuran for 24h; Ambient temperature; | 72% |
1-<(methyl(4-cycloheptenyl)carbamoyl)oxy>-2(1H)-pyridinethione
A
tropane
B
2-(2-pyridylthio)tropane
Conditions | Yield |
---|---|
With 2-methylpropan-2-thiol; acetic acid In acetonitrile at 25℃; Irradiation; | A 68% B 3 % Chromat. |
carbon monoxide
tropidine
A
tropane
B
Tropan-3β-carboxaldehyd
Conditions | Yield |
---|---|
With hydrogen; di-μ-chlorobis(norbornadiene)dirhodium(I); tricyclohexylphosphine In benzene at 100℃; under 60004.8 Torr; for 6h; | A 22% B 67% C 11% |
1-<(methyl(4-cycloheptenyl)carbamoyl)oxy>-2(1H)-pyridinethione
tropane
Conditions | Yield |
---|---|
With 2-methylpropan-2-thiol; acetic acid In benzene at 4℃; | 67% |
N-methyl-N-cycloheptylamine
tropane
Conditions | Yield |
---|---|
With chlorine Erwaermen des erhaltenen Chlor-cycloheptyl-methyl-amins mit 84%ig. wss. Schwefelsaeure; |
Tropidin
tropane
Conditions | Yield |
---|---|
With diethyl ether; platinum Hydrogenation; |
Conditions | Yield |
---|---|
With phosphonium iodide; hydrogen iodide at 195 - 200℃; im Rohr; |
tropane
Conditions | Yield |
---|---|
With thionyl chloride 1.) CDCl3, 0 deg C to room temperature, 19.5 h, 2.) 12 h; Yield given. Multistep reaction; |
tropane
Conditions | Yield |
---|---|
With phosphonium iodide; hydrogen iodide at 195 - 205℃; im Rohr; |
Conditions | Yield |
---|---|
at 195 - 205℃; |
Conditions | Yield |
---|---|
at 195 - 200℃; |
Conditions | Yield |
---|---|
Hydrogenation; |
tropane
Conditions | Yield |
---|---|
Bei der trocknen Destillation; |
A
tropane
Tropidin
Conditions | Yield |
---|---|
With hydrogenchloride; zinc | |
With hydrogen iodide; zinc |
A
tropane
Tropidin
Conditions | Yield |
---|---|
With sulfuric acid; zinc | |
With hydrogen iodide; zinc |
sulfuric acid
tropinone
A
tropane
B
3-tropanol
C
pseudotropine
Conditions | Yield |
---|---|
elektrolytische Reduktion an einer Bleikathode; |
tropinone
hydrogen iodide
A
tropane
B
3-tropanol
C
pseudotropine
Conditions | Yield |
---|---|
elektrolytische Reduktion; | |
With hydrogen iodide; zinc |
3exo-bromo-tropane
sulfuric acid
A
tropane
Tropidin
A
tropane
B
cyclohept-3-enyl-dimethyl-amine
Conditions | Yield |
---|---|
With silver(l) oxide durch Destillation der entstandenen stark alkal. Loesung der Ammoniumbase; |
cis-4-[(benzyloxycarbonyl)amino]cyclohept-2-enol
tropane
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 66 percent / LiAlH4 / tetrahydrofuran / 10 h / Heating 2: 90 percent / H2 / 5percent Pd on charcoal / methanol / 16 h 3: 1.) SOCl2, 2.) TABD / 1.) CDCl3, 0 deg C to room temperature, 19.5 h, 2.) 12 h View Scheme |
6-Oxa-7-aza-bicyclo[3.2.2]non-8-ene-7-carboxylic acid benzyl ester
tropane
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 67 percent / LiAlH4 / tetrahydrofuran / 10 h / Heating 2: 87 percent / Zn / acetic acid / 4 h / 50 - 60 °C 3: 90 percent / H2 / 5percent Pd on charcoal / methanol / 16 h 4: 1.) SOCl2, 2.) TABD / 1.) CDCl3, 0 deg C to room temperature, 19.5 h, 2.) 12 h View Scheme |
tropane
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 90 percent / H2 / 5percent Pd on charcoal / methanol / 16 h 2: 1.) SOCl2, 2.) TABD / 1.) CDCl3, 0 deg C to room temperature, 19.5 h, 2.) 12 h View Scheme |
N-methyl-8-oxa-9-azabicyclo[3.2.2]non-6-ene
tropane
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 87 percent / Zn / acetic acid / 4 h / 50 - 60 °C 2: 90 percent / H2 / 5percent Pd on charcoal / methanol / 16 h 3: 1.) SOCl2, 2.) TABD / 1.) CDCl3, 0 deg C to room temperature, 19.5 h, 2.) 12 h View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 6 steps 1: 68 percent / ethanol; CCl4 / 48 h / -10 °C 2: 98 percent / H2 / 5percent Pd/C / methanol / 7 h / 760 Torr 3: 80 percent / Na2CO3 / CHCl3; H2O / 1.) 0 deg C, 30 min, 2.) RT, 2h 4: 12 percent / SOCl2 / CHCl3 / 48 h / Ambient temperature 5: 78 percent / potassium tert-butoxide / benzene; hexamethylphosphoric acid triamide / 2 h / Ambient temperature 6: 72 percent / LiALH4 / tetrahydrofuran / 24 h / Ambient temperature View Scheme | |
Multi-step reaction with 6 steps 1: 68 percent / ethanol; CCl4 / 48 h / -10 °C 2: 98 percent / H2 / 5percent Pd/C / methanol / 7 h / 760 Torr 3: 80 percent / Na2CO3 / CHCl3; H2O / 1.) 0 deg C, 30 min, 2.) RT, 2h 4: SOCl2, pyridine / diethyl ether / 14 h / Ambient temperature 5: 78 percent / potassium tert-butoxide / benzene; hexamethylphosphoric acid triamide / 2 h / Ambient temperature 6: 72 percent / LiALH4 / tetrahydrofuran / 24 h / Ambient temperature View Scheme | |
Multi-step reaction with 5 steps 1: 68 percent / ethanol; CCl4 / 48 h / -10 °C 2: 98 percent / H2 / 5percent Pd/C / methanol / 7 h / 760 Torr 3: 80 percent / Na2CO3 / CHCl3; H2O / 1.) 0 deg C, 30 min, 2.) RT, 2h 5: 72 percent / LiALH4 / tetrahydrofuran / 24 h / Ambient temperature View Scheme |
Conditions | Yield |
---|---|
In benzene | 95% |
Conditions | Yield |
---|---|
With scandium tris(ortho-N,N-dimethylaminobenzyl); trityl tetrakis(pentafluorophenyl)borate In toluene at 70℃; for 24h; regiospecific reaction; | 90% |
Conditions | Yield |
---|---|
With carbonochloridic acid 1-chloro-ethyl ester In DCE at 0℃; for 4.08333h; Heating / reflux; | 83% |
With hypochloric acid Reduktion des entstandenen N-Chlor-nortropans; |
tropane
Conditions | Yield |
---|---|
With benzophenone; copper diacetate In acetonitrile at 35℃; for 3h; Giese Free Radical Synthesis; Darkness; Inert atmosphere; Irradiation; Sealed tube; | 83% |
Conditions | Yield |
---|---|
With benzophenone; copper diacetate In acetonitrile at 35℃; for 16h; Giese Free Radical Synthesis; Darkness; Inert atmosphere; Irradiation; Sealed tube; | 73% |
Conditions | Yield |
---|---|
Stage #1: tropane With chloroformic acid ethyl ester In toluene at 80℃; for 24h; Stage #2: With hydrogenchloride In water at 100℃; for 2h; | 72% |
Multi-step reaction with 2 steps 1: Et3N / CH2Cl2 2: MeOH View Scheme | |
Multi-step reaction with 2 steps 1: 95 percent / benzene 2: 90 percent / aq. HCl / Heating View Scheme |
Conditions | Yield |
---|---|
palladium diacetate at 80℃; for 14h; Neat (no solvent); | 70% |
Conditions | Yield |
---|---|
With benzophenone; copper diacetate In acetonitrile at 35℃; for 5h; Giese Free Radical Synthesis; Darkness; Inert atmosphere; Irradiation; Sealed tube; | 69% |
Conditions | Yield |
---|---|
Stage #1: tropane With 1,4-diaza-bicyclo[2.2.2]octane; tri(4-tolyl)aminium hexafluorophosphate In acetonitrile at -5℃; Inert atmosphere; Stage #2: phenylmagnesium bromide In tetrahydrofuran; acetonitrile at 0℃; for 0.0833333h; Inert atmosphere; regioselective reaction; | 66% |
Conditions | Yield |
---|---|
With benzophenone; copper diacetate In acetonitrile at 35℃; for 3h; Giese Free Radical Synthesis; Darkness; Inert atmosphere; Irradiation; Sealed tube; | 61% |
Conditions | Yield |
---|---|
In dichloromethane Ambient temperature; | 60% |
Conditions | Yield |
---|---|
In benzene at 22 - 25℃; for 11h; Irradiation; | A n/a B 15% C 56% |
Conditions | Yield |
---|---|
With benzophenone In benzene at 22 - 25℃; for 11h; Irradiation; | A n/a B 15% C 56% |
tropane
8-formyl-nortropane
Conditions | Yield |
---|---|
With ruthenium tetroxide In tetrachloromethane for 2h; | 49% |
Conditions | Yield |
---|---|
With diethyl ether |
tropane
3-(N,N,N-trimethylammonio)propyl bromide
8ξ-methyl-8ξ-(3-trimethylammonio-propyl)-nortropanium; dibromide
Conditions | Yield |
---|---|
With acetonitrile |
Conditions | Yield |
---|---|
at 190℃; |
Conditions | Yield |
---|---|
at 190℃; |
Conditions | Yield |
---|---|
With methanol |
tropane
Conditions | Yield |
---|---|
With dihydrogen peroxide |
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