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inquiryItems Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------
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inquiryProduct Description Product website: http://www.finerchem.com Product Name 1,2,3,4-Tetrahydro-1-naphthalenone CAS No. 529-34-0
Hot selling 1-Tetralone CAS 529-34-0 with competitive price Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed additives
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inquiryName: Alpha-Tetralone Synonyms: 1,2,3,4-Tetrahydro-1-naphthalenone; 3,4-Dihydro-1(2H)-naphthalenone; 1-Tetralone; α-Tetralone; a-Tetralon CAS: 529-34-0 MF: C10H10O Appearance:Colorless Clear Liquid Storage: RT. Package:25KG/Drum Application:
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inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments
Conditions | Yield |
---|---|
With water; iron(III) chloride In acetone at 0℃; for 5h; Irradiation; | 100% |
With water; iron(III) chloride In acetone at 0℃; for 5h; Product distribution; Irradiation; also other reactant (indan, diphenylmethane, toluene, ethylbenzene and isochromane), and also other reaction times; | 100% |
With Iron(III) nitrate nonahydrate; 1-hydroxy-pyrrolidine-2,5-dione; oxygen In benzonitrile at 90℃; for 28h; | 99% |
Conditions | Yield |
---|---|
With Amberlyst A-26 In chlorobenzene at 110℃; for 1h; | 100% |
With iron(II) sulfate | |
With lead(IV) acetate; acetic acid at 30℃; |
Conditions | Yield |
---|---|
With n-butyltriphenylphosphonium permanganate In acetonitrile at 20℃; for 0.25h; | 100% |
With butyltriphenylphosphonium chlorochromate In acetonitrile for 0.583333h; Heating; | 100% |
With air; potassium carbonate In water at 26.84℃; for 1h; | 100% |
Conditions | Yield |
---|---|
With tetrachlorosilane; 4-(trifluoromethyl)benzoic anhydride; silver perchlorate In dichloromethane for 24h; Ambient temperature; | 100% |
With tetrachlorosilane; 4-(trifluoromethyl)benzoic anhydride; silver perchlorate In dichloromethane for 24h; Ambient temperature; | 100% |
With trifluorormethanesulfonic acid at 5 - 20℃; for 2h; Cyclization; acylation; | 98% |
1-tetralone 1,3-dithiane
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With dihydrogen peroxide; tantalum pentachloride; sodium iodide In water; ethyl acetate at 20℃; for 0.3h; | 100% |
With dihydrogen peroxide; tantalum pentachloride; sodium iodide In water; ethyl acetate at 20℃; for 0.3h; | 100% |
With aluminium trichloride; benzyltriphenylphosphonium peroxymonosulfate at 20℃; for 0.166667h; | 97% |
1-tetralone tosylhydrazone
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide In acetone for 8h; Heating; | 100% |
With 1-methyl-1H-imidazole; oxygen; pivalaldehyde; (NMe4)2[Ni(Me2opba)]*4H2O In fluorobenzene at 20℃; for 6h; Oxidation; | 80% |
2-bromo-1-tetralone
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With potassium carbonate; butan-1-ol; palladium diacetate; triphenylphosphine at 100℃; | 99% |
With sodium hydrogen telluride In ethyl acetate for 1h; Ambient temperature; | 96% |
With water; 1-methyl-3-pentyl-1H-imidazolium tetrafluoroborate at 125℃; under 2585.74 Torr; for 0.0666667h; microwave irradiation; | 95% |
1-tetralone oxime
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With ammonium peroxydisulfate; Montmorillonite K10; silver nitrate In hexane at 50℃; for 2.5h; | 99% |
With Glyoxilic acid In water at 20℃; for 1h; | 94% |
With bismuth(III) chloride; benzyltriphenylphosphonium peroxymonosulfate In acetonitrile for 0.833333h; Heating; | 93% |
1',2',3',4'-tetrahydro-spiro(1.3-dioxolane-2,1'-naphthalene)
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With aluminium trichloride; benzyltriphenylphosphonium peroxymonosulfate at 20℃; for 0.0833333h; | 99% |
With Oxone In methanol for 1h; Heating; | 98% |
With aluminium trichloride; tetramethylammonium chlorochromate In acetonitrile for 0.75h; Heating; | 98% |
1,2-diphenylcyclopentene ozonide
A
4-hydroxy-1-phenyl-butan-1-one
B
butyrophenone
C
3,4-dihydronaphthalene-1(2H)-one
D
benzoic acid
Conditions | Yield |
---|---|
With iron(II) sulfate In tetrahydrofuran; water at 20℃; for 16h; Product distribution; Mechanism; other ozonides; 18O-tracer exp. with ethereal oxygen labeled; reduction also in presence of 18O-labeled H2O or D2O; | A 7% B 33% C 19% D 98% |
With iron(II) sulfate In tetrahydrofuran; water at 20℃; for 16h; | A 7% B 33% C 19% D 98% |
(1,2,3,4-tetrahydronaphthalen-1-yloxy)trimethylsilane
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With aluminium trichloride; tetramethylammonium chlorochromate In acetonitrile for 0.916667h; Heating; | 98% |
With n-butyltriphenylphosphonium peroxodisulfate In acetonitrile for 0.5h; Heating; | 97% |
With bismuth(III) chloride; benzyltriphenylphosphonium peroxymonosulfate In dichloromethane for 0.05h; microwave irradiation; | 95% |
2-(phenylsulfonyl)-3,4-dihydronaphthalen-1(2H)-one
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With formic acid; eosin Y bis(tetrabutyl ammonium salt) In acetonitrile at 20℃; Irradiation; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
With trifluorormethanesulfonic acid at 25℃; for 1h; | 97% |
With phosphoric acid; phosphorus pentoxide |
tetralin
A
1-tert-butyl-4-iodobenzene
B
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With 4-tButyl iodoxybenzene In chlorobenzene at 130 - 140℃; for 6h; | A 97% B 60% |
1-ethenylbenzocyclobuten-1-ol
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
In toluene at 110℃; for 0.5h; | 96% |
In toluene for 0.5h; Heating; | 96% |
phenylbutyric acid chloride
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
Nafion-H In benzene for 0.5h; Heating; | 95% |
With Fe-Al-MCM-41 molecular sieve In toluene at 60℃; for 18h; Reagent/catalyst; Green chemistry; | 95.2% |
With Silica gel supported aluminium trichloride In nitrobenzene at 40℃; for 1.5h; | 94% |
1-methylene-1,2,3,4-tetrahydronaphthalene
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
Stage #1: 1-methylene-1,2,3,4-tetrahydronaphthalene With ozone In dichloromethane at -78℃; Stage #2: With Merrifield resin-bound piperidine In dichloromethane at 20℃; for 10h; | 95% |
With tert.-butylhydroperoxide; indium(III) chloride In water at 90℃; for 8h; | 80% |
bei der Ozonspaltung; |
2-(1,2,3,4-tetrahydro-naphthalen-1-yloxy)-tetrahydro-pyran
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With sodium bromate; aluminium trichloride In acetonitrile for 1.5h; Heating; | 95% |
With aluminium trichloride; benzyltriphenylphosphonium chlorate In acetonitrile at 20℃; for 5h; | 91% |
With 1-n-butylpyridinium tetrachloroferrate; pyridinium chlorochromate at 50℃; for 0.366667h; | 91% |
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With Glyoxilic acid; Amberlyst 15 for 0.0333333h; microwave irradiation; | 94% |
With 4-nitrobenzaldehdye; trimethylsilyl trifluoromethanesulfonate In dichloromethane for 0.0833333h; Ambient temperature; | 89% |
With 2,2,6,6-tetramethylpiperidinyl-lithium In tetrahydrofuran; hexane at -78℃; for 1.5h; Concentration; Reagent/catalyst; Temperature; Solvent; Inert atmosphere; | 84% |
With 2,2,2-trifluoroethanol; oxygen; vanadium(V) oxychloride for 17.5h; deprotection; Heating; | 73% |
Conditions | Yield |
---|---|
With dihydrogen peroxide; poly(N-isopropylacrylamide) based tungsten catalyst In toluene at 60℃; | 93% |
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene In dichloromethane at 0 - 20℃; for 0.333333h; Inert atmosphere; Green chemistry; | 87% |
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In dimethyl sulfoxide at 25℃; for 40h; | 79% |
3',4'-dihydro-2'H-spiro[1,3-dithiolane-2,1'-naphthalene]
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With aluminium trichloride; 1-benzyl-1-aza-4-azoniabicyclo<2.2.2>octane periodate at 20℃; for 0.2h; | 93% |
With iron(III) chloride; potassium iodide In methanol for 3h; Heating; | 91% |
With t-butyl thionitrite In acetonitrile at 0℃; for 0.3h; | 90% |
Conditions | Yield |
---|---|
With hydrogenchloride In isopropyl alcohol at 85℃; Inert atmosphere; Sealed tube; | 93% |
1-tetralone 1,3-dithiane
A
1,2,6,7-tetrathiacyclodecane
B
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate; lead dioxide In tetrahydrofuran; water for 0.5h; Ambient temperature; Yields of byproduct given; | A n/a B 91% |
1-tetralone semicarbazone
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With phosphoric acid In water at 95℃; for 3h; | 91% |
With bismuth(III) chloride; benzyltriphenylphosphonium peroxymonosulfate In acetonitrile for 1.5h; Heating; | 90% |
With magnesium hydrogen sulfate; water; silica gel In hexane at 20℃; for 0.75h; | 90% |
1-(2,3-dihydronaphthalen-4(1H)-ylidene)-2,2,-dimethylhydrazine
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With K5 In acetonitrile at 20℃; for 2h; | 91% |
With silica gel; iron(III) chloride for 0.025h; microwave irradiation; | 90% |
With 1-methyl-1H-imidazole; oxygen; pivalaldehyde; (NMe4)2[Ni(Me2opba)]*4H2O In fluorobenzene at 20℃; for 20h; Oxidation; | 88% |
With porcin pancreatic lipase In water; acetone at 20℃; for 96h; Hydrolysis; | 81 % Chromat. |
1-tetralone pivaloyl oxime
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
Stage #1: 1-tetralone pivaloyl oxime With chloro-trimethyl-silane; iron; acetic acid In tetrahydrofuran at 20℃; for 0.5h; Stage #2: With water In tetrahydrofuran at 20℃; for 0.25h; | 91% |
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With hydrogenchloride In 1,4-dioxane; methanol; water at 100℃; Inert atmosphere; | 91% |
Multi-step reaction with 2 steps 1: phenyl 2-(trimethylsilylethynyl)phenyl ketone / 1,4-dioxane / 100 °C / Inert atmosphere 2: hydrogenchloride / methanol; water / 6 h / 20 °C / Inert atmosphere View Scheme |
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With formic acid; eosin Y bis(tetrabutyl ammonium salt) In acetonitrile at 20℃; Irradiation; Inert atmosphere; | 91% |
tert.-butylhydroperoxide
tetralin
A
4-hydroxy-3,4-dihydronaphthalen-1(2H)-one
B
1,2,3,4-Tetrahydro-1-naphthol
C
3,4-dihydronaphthalene-1(2H)-one
D
1-tetralinyl tert-butylperoxide
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; copper dichloride In dichloromethane at 25℃; for 4h; Further byproducts given; | A n/a B n/a C n/a D 90% |
With tetrabutylammomium bromide; copper dichloride In dichloromethane; water at 25℃; for 4h; Yield given. Further byproducts given. Yields of byproduct given; |
3,4-dihydronaphthalene-1(2H)-one
malononitrile
1,2,3,4-tetrahydro-1-naphthylidene malononitrile
Conditions | Yield |
---|---|
With aluminum oxide Inert atmosphere; Neat (no solvent); | 100% |
With ammonium acetate; acetic acid In toluene for 10h; Reflux; Dean-Stark; | 93% |
With 1-butyl-3-methylimidazolium hydroxide at 25 - 30℃; for 0.666667h; Knoevenagel condensation; | 89% |
3,4-dihydronaphthalene-1(2H)-one
2-chloro-1-tetralone
Conditions | Yield |
---|---|
With N-chloro-succinimide; thiourea In methanol at 23℃; for 0.166667h; | 100% |
Stage #1: 3,4-dihydronaphthalene-1(2H)-one With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere; Stage #2: With methyl chlorosulfate In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere; | 100% |
With N-chloro-succinimide; urea-hydrogen peroxide; 1-butyl-3-methylimidazolium Tetrafluoroborate at 60℃; | 98% |
Conditions | Yield |
---|---|
With zinc(II) tetrahydroborate In acetonitrile for 10h; Mechanism; Ambient temperature; | 100% |
With zinc(II) tetrahydroborate In acetonitrile for 10h; Ambient temperature; | 100% |
With sodium tetrahydroborate In methanol for 4h; | 100% |
3,4-dihydronaphthalene-1(2H)-one
1-tetralone oxime
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride | 100% |
With hydroxylamine hydrochloride; sodium acetate In ethanol; water Reflux; | 100% |
With hydroxylamine hydrochloride; sodium acetate In ethanol; water at 95℃; | 100% |
3,4-dihydronaphthalene-1(2H)-one
Diethyl carbonate
2-ethoxycarbonyl-1-tetralone
Conditions | Yield |
---|---|
With sodium hydride In tetrahydrofuran; mineral oil for 16h; Reflux; Inert atmosphere; | 100% |
With sodium hydride In tetrahydrofuran Inert atmosphere; Reflux; | 99% |
With sodium hydride In benzene 1.) RT, 30 min; 2.) reflux, 14 h; | 92% |
trifluoromethylsulfonic anhydride
3,4-dihydronaphthalene-1(2H)-one
3,4-dihydro-1-naphthyl triflate
Conditions | Yield |
---|---|
With 2,6-di-tert-butyl-4-methylpyridine In dichloromethane at 0 - 20℃; for 1.5h; | 100% |
With triethylamine In dichloromethane at 0 - 40℃; for 24h; Sealed tube; Inert atmosphere; | 100% |
With 2-chloropyridine In dichloromethane at 20℃; for 2h; Inert atmosphere; | 99% |
methyl-triphenylphosphonium iodide
3,4-dihydronaphthalene-1(2H)-one
1-methylene-1,2,3,4-tetrahydronaphthalene
Conditions | Yield |
---|---|
With n-butyllithium In tetrahydrofuran; hexane Wittig reaction; Inert atmosphere; Cooling with ice; | 100% |
Stage #1: methyl-triphenylphosphonium iodide With potassium tert-butylate In diethyl ether Stage #2: 3,4-dihydronaphthalene-1(2H)-one In diethyl ether at 20℃; for 4h; Wittig olefination; | 66% |
Stage #1: methyl-triphenylphosphonium iodide; 3,4-dihydronaphthalene-1(2H)-one In tetrahydrofuran for 0.25h; Wittig Olefination; Inert atmosphere; Stage #2: With potassium tert-butylate In tetrahydrofuran at 40℃; for 1.41667h; Inert atmosphere; | 55% |
With sodium hydride; dimethyl sulfoxide 1.) 1 h, 2.) 70 deg C, overnight; Yield given. Multistep reaction; |
3,4-dihydronaphthalene-1(2H)-one
toluene-4-sulfonic acid hydrazide
1-tetralone tosylhydrazone
Conditions | Yield |
---|---|
In methanol at 20℃; Schlenk technique; | 100% |
In methanol at 20℃; | 88% |
Stage #1: 3,4-dihydronaphthalene-1(2H)-one With methanol for 0.25h; Heating / reflux; Stage #2: toluene-4-sulfonic acid hydrazide With toluene-4-sulfonic acid In methanol for 4.5h; Heating / reflux; | 87% |
3,4-dihydronaphthalene-1(2H)-one
carbonic acid dimethyl ester
methyl 1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate
Conditions | Yield |
---|---|
With sodium hydride In methanol; mineral oil at 80℃; for 3h; Inert atmosphere; Further stages; | 100% |
With sodium hydride In toluene; mineral oil at 0 - 120℃; for 18h; | 99% |
With sodium hydride for 0.25h; Heating; | 98% |
3,4-dihydronaphthalene-1(2H)-one
benzylamine
N-(3,4-dihydronaphthalen-1(2H)-ylidene)-1-phenylmethanamine
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In toluene for 12h; Heating; | 100% |
With toluene-4-sulfonic acid In toluene for 12h; Molecular sieve; Reflux; | 100% |
With toluene-4-sulfonic acid In water; toluene Inert atmosphere; Reflux; | 28% |
Conditions | Yield |
---|---|
With hydrogen In ethanol at 39.84℃; under 760.051 Torr; for 5h; | 100% |
With sodium tetrahydroborate; aluminium trichloride In tetrahydrofuran for 2h; Heating; | 97% |
With W-7 Raney-Nickel In ethanol for 6h; Heating; | 95% |
3,4-dihydronaphthalene-1(2H)-one
(S)-1-tetralol
Conditions | Yield |
---|---|
With triethylammonium formate; chiral 'roofed' cis-diamine-Ru(II) at 25℃; for 20h; | 100% |
With dimethylsulfide borane complex; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole In tetrahydrofuran at 0℃; for 0.5h; enantioselective reaction; | 100% |
With formic acid; [RuCl2(hexamethylbenzene)]2; (S)-2-piperidinemethanethiol hydrochloride; triethylamine at 30℃; for 24h; Inert atmosphere; optical yield given as %ee; enantioselective reaction; | 99% |
3,4-dihydronaphthalene-1(2H)-one
(R)-1-tetralol
Conditions | Yield |
---|---|
With borane-THF; (S)-oxazaborolidine In tetrahydrofuran at 0℃; for 0.0833333h; | 100% |
With (1R,2R)-PhCH(NH2)CH(Ph)NH-p-SO2-C6H4-CH2CH2-silica gel; tetrabutylammomium bromide; sodium formate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 at 40℃; | 100% |
With 4 A molecular sieve; (1R,2R,4S,6S)-2-(2-methoxyphenyl)-bicyclo[2.2.2]octane-2,6-diol; benzo[1,3,2]dioxaborole; titanium(IV) isopropylate In tetrahydrofuran at -20℃; for 24h; | 100% |
Triethoxyvinylsilane
3,4-dihydronaphthalene-1(2H)-one
8-(2-triethoxysilyl-ethyl)-3,4-dihydro-2H-naphthalen-1-one
Conditions | Yield |
---|---|
With sodium formate; triphenylphosphine; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 In toluene at 140℃; Murai reaction; | 100% |
With (HCHO+4PPh3)-Ru(II) supported on CeO2 In toluene at 140℃; for 0.5h; Inert atmosphere; Schlenk technique; | 99% |
With carbonyldihydridotris(triphenylphosphine)ruthenium(II) In toluene at 125℃; for 0.5h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
With hydrazine hydrate In ethanol at 120℃; for 2h; Dean-Stark; Reflux; | 100% |
With hydrazine hydrate In chloroform for 4h; Heating; | 99% |
With hydrazine hydrate; triethylamine In neat (no solvent) | 95% |
trimethyl(oct-1-yn-1-yl)silane
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
With carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene at 135℃; for 2h; | 100% |
Conditions | Yield |
---|---|
With sodium hexamethyldisilazane In 1,4-dioxane at 0℃; for 1h; | 100% |
3,4-dihydronaphthalene-1(2H)-one
4-bromo-3,4-dihydro-1(2H)-naphthalenone
Conditions | Yield |
---|---|
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane at 80℃; for 1h; | 100% |
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 0.5h; Heating; | 70% |
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane |
3,4-dihydronaphthalene-1(2H)-one
ethenyltrimethylsilane
8-(2-(trimethylsilyl)ethyl)-3,4-dihydronaphthalen-1(2H)-one
Conditions | Yield |
---|---|
With rhodium(III) chloride hydrate; sodium formate; tris(para-trifluoromethyl)phenyl phosphine In 1,4-dioxane at 100℃; for 20h; Inert atmosphere; | 100% |
With rhodium(III) chloride hydrate; sodium formate; tris(para-trifluoromethyl)phenyl phosphine In 1,4-dioxane; acetone at 100℃; for 40h; Inert atmosphere; | 76% |
With (HCHO+4PPh3)-Ru(II) supported on CeO2 In toluene at 140℃; for 24h; Inert atmosphere; Schlenk technique; | 74% |
5-chloro-pyridin-2-yl hydrazine
3,4-dihydronaphthalene-1(2H)-one
Conditions | Yield |
---|---|
In ethanol for 0.5h; Reflux; | 100% |
Conditions | Yield |
---|---|
With acetic acid In ethanol Reflux; | 100% |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In propan-1-ol for 2h; Reflux; | 100% |
Conditions | Yield |
---|---|
With (difluoroboryl)dimethylglyoximatocobalt(II) bis(acetonitrile); boron trifluoride diethyl etherate; 3-cyano-1-methylquinolinium perchlorate In acetonitrile at 20℃; for 0.5h; Irradiation; Inert atmosphere; Flow reactor; | 99% |
With Oxone; ammonium bromide In dichloromethane | 90% |
With 5 mol% Pd/C; hydrogen; potassium carbonate In N,N-dimethyl acetamide at 150℃; under 608.041 Torr; for 10h; | 81% |
3,4-dihydronaphthalene-1(2H)-one
2-bromo-1-tetralone
Conditions | Yield |
---|---|
With bromine In diethyl ether for 2h; -10 deg C -> RT; | 99% |
With N-Bromosuccinimide; ammonium acetate In diethyl ether at 25℃; for 1.5h; | 99% |
With bromine In diethyl ether Cooling with ice; | 99% |
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