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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

3-tert-Butylphenol

Cas:585-34-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3-tert-butylphenol

Cas:585-34-2

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-tert-Butylphenol

Cas:585-34-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

3-tert-Butylphenol 585-34-2

Cas:585-34-2

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

3-tert-Butylphenol Basic information Product Name: 3-tert-Butylphenol Synonyms: 3-TERT-BUTYLPHENOL;3-(1,1-dimethylethyl)-pheno;3-(1,1-dimethylethyl)-Phenol;3-t-Butylphenol;Phenol, 3-tert

585-34-2

Cas:585-34-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 585-34-2 with best quality

Cas:585-34-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

3-tert-Butylphenol 585-34-2

Cas:585-34-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

3-tert-Butylphenol CAS:585-34-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermed

3-tert-Butylphenol CAS:585-34-2

Cas:585-34-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

3-tert-Butylphenol

Cas:585-34-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Leader Biochemical Group

Overview of Our Factories Our Factories production lines Our Factories R&D ability Our Factories warehouse Our Factorie

China Biggest Factory & Manufacturer supply 3-Tert-Butylphenol

Cas:585-34-2

Min.Order:1 Kilogram

FOB Price: $30.0 / 35.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

3-tert-Butylphenol

Cas:585-34-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

3-tert-Butylphenol

Cas:585-34-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-tent-butylphehol

Cas:585-34-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Tert-butylphenol

Cas:585-34-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

3-tert-Butylphenol

Cas:585-34-2

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

3-Tert-butylphenol

Cas:585-34-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 3-Tent-Butylphehol CAS No.:585-34-2 Molecule Formula:C10H14O Molecule Weight:150.22 Purity: 99.0% Package: 25kg/drum Description:White or off-white powder Manufacture Standards:Enterprise Standard TESTING ITEMS

High Quality 3-Tent-Butylphehol on stock

Cas:585-34-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

3-tert-Butylphenol

Cas:585-34-2

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

3-tert-Butylphenol Chemical Properties Melting point 44-46 °C (lit.) Boiling point 125-130 °C/20 mmHg (lit.) density 0.9688 (estimate) refractive index 1.5108 (estimate) Fp 228 °F form Crystalline Powder pka 10.

3-tert-Butylphenol

Cas:585-34-2

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Pure quality 585-34-2 3-tert-Butylphenol

Cas:585-34-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Pure quality 585-34-2 3-tert-Butylphenol

Cas:585-34-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Pure quality 585-34-2 3-tert-Butylphenol

Cas:585-34-2

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

3-tert-Butylphenol

Cas:585-34-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Pure quality 585-34-2 3-tert-Butylphenol

Cas:585-34-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

3-tert-Butylphenol

Cas:585-34-2

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

3-tert-Butylphenol

Cas:585-34-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

3-tert-Butylphenol

Cas:585-34-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

3-Tert-Butylphenol

Cas:585-34-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

3-tert-Butylphenol

Cas:585-34-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

3-Tert-Butylphenol

Cas:585-34-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

2,4‑diamino‑5‑hydroxy-tert-butylbenzene

2,4‑diamino‑5‑hydroxy-tert-butylbenzene

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

Conditions
ConditionsYield
Stage #1: 2,4‑diamino‑5‑hydroxy-tert-butylbenzene With sulfuric acid; copper(II) oxide In isopropyl alcohol at 60℃; for 0.5h;
Stage #2: With sodium nitrite In water; isopropyl alcohol for 4h; Reagent/catalyst;
90.2%
(+)-cis-(1S,2R)-3-t-butyl-3,5-cyclohexadiene-1,2-diol

(+)-cis-(1S,2R)-3-t-butyl-3,5-cyclohexadiene-1,2-diol

A

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

B

2-tert-Butylphenol
88-18-6

2-tert-Butylphenol

Conditions
ConditionsYield
With sodium hydroxide In water at 25℃;A 87%
B n/a
3-hydroxy-2-pyrone
496-64-0

3-hydroxy-2-pyrone

2-(tert-butyl)-1-nitroethene
20429-42-9

2-(tert-butyl)-1-nitroethene

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

Conditions
ConditionsYield
With aluminum (III) chloride; 2,6-di-tert-butyl-4-methyl-phenol In 1,2-dichloro-benzene at 150℃; for 16h; Inert atmosphere; Sealed tube;85%
2-(3-(tert-butyl)phenoxy)pyridine

2-(3-(tert-butyl)phenoxy)pyridine

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

Conditions
ConditionsYield
Stage #1: 2-(3-(tert-butyl)phenoxy)pyridine With methyl trifluoromethanesulfonate In toluene at 100℃; for 2h; Inert atmosphere;
Stage #2: With sodium In methanol for 0.25h; Inert atmosphere; Reflux;
81%
Stage #1: 2-(3-(tert-butyl)phenoxy)pyridine With methyl trifluoromethanesulfonate In toluene at 100℃; for 24h; Inert atmosphere;
Stage #2: With sodium In methanol for 0.25h; Reflux;
81%
tert-butylbenzene
253185-03-4, 253185-04-5

tert-butylbenzene

A

3-tert-butylfuran-2,5-dione
18261-07-9

3-tert-butylfuran-2,5-dione

B

para-tert-butylphenol
98-54-4

para-tert-butylphenol

C

2-tert-butyl-1,4-benzoquinone
3602-55-9

2-tert-butyl-1,4-benzoquinone

D

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

E

4-tert-Butylcatechol
98-29-3

4-tert-Butylcatechol

Conditions
ConditionsYield
With Fe2(N,N-bis(pyridin-2-ylmethyl)prop-2-yn-1-amine)2(μ2-Cl)2Cl2; dihydrogen peroxide In acetonitrile at 70℃; for 2h;A 5%
B 52%
C 15%
D 17%
E 18%
isobutene
115-11-7

isobutene

phenol
108-95-2

phenol

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

Conditions
ConditionsYield
aluminium trichloride at 80℃; molar ratio 1:1;48.5%
tert-butylbenzene
253185-03-4, 253185-04-5

tert-butylbenzene

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

Conditions
ConditionsYield
With water; copper(II) sulfate at 330℃;
Multi-step reaction with 3 steps
1.1: sulfuric acid; nitric acid / 2 h / 0 - 20 °C
2.1: Al#dotZn; sulfuric acid / water / 1 h / 90 °C
3.1: sulfuric acid; copper(II) oxide / isopropyl alcohol / 0.5 h / 60 °C
3.2: 4 h
View Scheme
3-tert-butylaniline
5369-19-7

3-tert-butylaniline

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

Conditions
ConditionsYield
With sulfuric acid; sodium nitrite Eintragen des Reaktionsgemisches in wss. H2SO4 unter Einleiten von Wasserdampf;
Stage #1: 3-tert-butylaniline With sulfuric acid at 20 - 25℃; for 0.5h; Industrial scale;
Stage #2: With sodium nitrite In water at 0℃; for 0.5h; Industrial scale;
Stage #3: With sulfuric acid In water at 90℃; for 1h; Industrial scale;
chlorobenzene
108-90-7

chlorobenzene

isobutyryl chloride
513-36-0

isobutyryl chloride

A

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

B

2-tert-Butylphenol
88-18-6

2-tert-Butylphenol

Conditions
ConditionsYield
With aluminium trichloride Erhitzen des Reaktionsprodukts mit wss. NaOH und Cu2O auf 250grad;
tert-butylbenzene
253185-03-4, 253185-04-5

tert-butylbenzene

A

para-tert-butylphenol
98-54-4

para-tert-butylphenol

B

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

C

2-tert-Butylphenol
88-18-6

2-tert-Butylphenol

Conditions
ConditionsYield
With hydrogen fluoride; boron trifluoride; dihydrogen peroxide at -60℃; for 0.5h; Product distribution;A 56 % Chromat.
B 14 % Chromat.
C 30 % Chromat.
Stage #1: tert-butylbenzene With 6,7-dichlorobenzo[d][1,2]dioxine-1,4-dione Heating;
Stage #2: With sodium hydrogencarbonate In methanol; water at 50℃; Overall yield = 59 %;
With [(smifH)2Fe](OTf)2; dihydrogen peroxide; barium(II) perchlorate In acetonitrile at 25℃; for 1.5h;A n/a
B n/a
C 6 %Chromat.
With [(smifH)2Fe](OTf)2; dihydrogen peroxide In water; acetonitrile at 25℃; for 1.5h; Reagent/catalyst;A n/a
B n/a
C 8.2 %Chromat.
tert-butylbenzene
253185-03-4, 253185-04-5

tert-butylbenzene

A

para-tert-butylphenol
98-54-4

para-tert-butylphenol

B

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

C

2-tert-Butylphenol
88-18-6

2-tert-Butylphenol

D

isopropenylbenzene
98-83-9

isopropenylbenzene

Conditions
ConditionsYield
With oxygen in plasma generated by radiofrequency discharge; Yield given. Further byproducts given. Yields of byproduct given;
tert-butylbenzene
253185-03-4, 253185-04-5

tert-butylbenzene

A

para-tert-butylphenol
98-54-4

para-tert-butylphenol

B

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

C

2-tert-Butylphenol
88-18-6

2-tert-Butylphenol

D

phenol
108-95-2

phenol

Conditions
ConditionsYield
With helium; oxygen at -30℃; under 4 Torr; for 2h; Product distribution; Rate constant;
para-tert-butylphenol
98-54-4

para-tert-butylphenol

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

Conditions
ConditionsYield
Ku-2-8chS at 100℃; for 73h; Equilibrium constant; Product distribution; other catalysis, other temperature, other time;
at 80 - 180℃; Equilibrium constant;
With aluminum (III) chloride at 80℃; for 5h; Green chemistry;
3-(tert-butyl)phenyl acetate
13189-51-0

3-(tert-butyl)phenyl acetate

A

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

B

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
With sodium hydroxide In water at 25℃; Rate constant;
With Carbonate buffer; β‐cyclodextrin In water; dimethyl sulfoxide at 25℃; Rate constant;
3,5-Di-tert-butylphenol
1138-52-9

3,5-Di-tert-butylphenol

phenol
108-95-2

phenol

A

para-tert-butylphenol
98-54-4

para-tert-butylphenol

B

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

Conditions
ConditionsYield
aluminium trichloride at 180℃; for 2h; Equilibrium constant; Product distribution; other catalysis, other temperature, other time;
at 80 - 180℃; Equilibrium constant;
2,5-di-tert-butylphenol
5875-45-6

2,5-di-tert-butylphenol

phenol
108-95-2

phenol

A

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

B

2-tert-Butylphenol
88-18-6

2-tert-Butylphenol

Conditions
ConditionsYield
Equilibrium constant;
at 80 - 180℃; Equilibrium constant;
trans-Crotonaldehyde
123-73-9

trans-Crotonaldehyde

tert-butylbenzene
253185-03-4, 253185-04-5

tert-butylbenzene

A

para-tert-butylphenol
98-54-4

para-tert-butylphenol

B

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

C

2-tert-Butylphenol
88-18-6

2-tert-Butylphenol

D

trans-crotonic acid-(4-tert-butyl-phenyl ester)

trans-crotonic acid-(4-tert-butyl-phenyl ester)

E

(E)-But-2-enoic acid 2-tert-butyl-phenyl ester

(E)-But-2-enoic acid 2-tert-butyl-phenyl ester

F

(E)-But-2-enoic acid 3-tert-butyl-phenyl ester

(E)-But-2-enoic acid 3-tert-butyl-phenyl ester

Conditions
ConditionsYield
With peracetic acid; oxygen; VO(nbuac)2 In butanone under 760 Torr; for 14h; Product distribution; Ambient temperature; other benzenes, other catalysts, var. conditions;
3-(tert-butyl)phenyl acetate
13189-51-0

3-(tert-butyl)phenyl acetate

A

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

B

monoacetylated β-cyclodextrin

monoacetylated β-cyclodextrin

Conditions
ConditionsYield
With Na2CO3 buffer; sodium hydrogencarbonate In water at 25℃; Rate constant;
3-(tert-butyl)phenyl acetate
13189-51-0

3-(tert-butyl)phenyl acetate

cyclohepta(6-N-methylformamido)amylose
55137-66-1

cyclohepta(6-N-methylformamido)amylose

A

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

B

monoacetylated Me-capped β-cyclodextrin

monoacetylated Me-capped β-cyclodextrin

Conditions
ConditionsYield
With Na2CO3 buffer; sodium hydrogencarbonate In water at 25℃; Rate constant;
methylphosphine borane
14975-23-6

methylphosphine borane

3-tert-Butyl-phenol anion
51067-66-4

3-tert-Butyl-phenol anion

A

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

B

CH7BP(1-)

CH7BP(1-)

Conditions
ConditionsYield
at 57.84℃; Equilibrium constant; Gas phase;
tert-butylbenzene
253185-03-4, 253185-04-5

tert-butylbenzene

A

para-tert-butylphenol
98-54-4

para-tert-butylphenol

B

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

Conditions
ConditionsYield
With perchloric acid; 4C16H36N(1+)*HO40PV2W10(4-); dihydrogen peroxide In water; acetonitrile; tert-butyl alcohol at 59.84℃; under 760.051 Torr; for 1h; Inert atmosphere; regioselective reaction;
With dihydrogen peroxide; barium(II) perchlorate; 2CF3O3S(1-)*C38H34FeN6O2(2+) In acetonitrile at 25℃; for 1.5h; Reagent/catalyst; Overall yield = 15 percentChromat.;
C28H29NO2

C28H29NO2

A

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

B

6-methoxy-4-methyl-2-(p-tolyl)quinoline
117839-39-1

6-methoxy-4-methyl-2-(p-tolyl)quinoline

C

6-Methoxy-2-p-tolyl-quinoline-4-carbaldehyde
112500-20-6

6-Methoxy-2-p-tolyl-quinoline-4-carbaldehyde

D

2-(p-tolyl)-6-methoxy-4-quinolinemethanol
84666-27-3

2-(p-tolyl)-6-methoxy-4-quinolinemethanol

Conditions
ConditionsYield
With methylene blue; triethylamine In methanol; water for 0.166667h; Inert atmosphere; Irradiation;A 98 %Chromat.
B n/a
C n/a
D n/a
phenol
108-95-2

phenol

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: copper(l) iodide; 2-Picolinic acid; potassium phosphate / dimethyl sulfoxide / 24 h / 90 °C / Inert atmosphere
2.1: (adamant-1-yl)-acetic acid; potassium carbonate; [RhCl2(p-cymene)]2 / benzene / 24 h / 120 °C / Sealed tube; Inert atmosphere
3.1: methyl trifluoromethanesulfonate / toluene / 2 h / 100 °C / Inert atmosphere
3.2: 0.25 h / Inert atmosphere; Reflux
View Scheme
tert-butylbenzene
253185-03-4, 253185-04-5

tert-butylbenzene

A

para-tert-butylphenol
98-54-4

para-tert-butylphenol

B

2-tert-butyl-1,4-benzoquinone
3602-55-9

2-tert-butyl-1,4-benzoquinone

C

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

D

2-tert-Butylphenol
88-18-6

2-tert-Butylphenol

Conditions
ConditionsYield
With C27H19N3O7OsS; dihydrogen peroxide; acetic acid In dichloromethane at 23℃; for 0.416667h; Inert atmosphere; Overall yield = 87 %;
4-(tert-butyl)chlorobenzene
3972-56-3

4-(tert-butyl)chlorobenzene

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: sulfuric acid; nitric acid / 0 - 25 °C / Autoclave; Industrial scale
2.1: hydrogen; palladium on activated charcoal / ethanol / 10 h / 20 - 25 °C / 1520.1 Torr / Autoclave; Industrial scale
3.1: sulfuric acid / 0.5 h / 20 - 25 °C / Industrial scale
3.2: 0.5 h / 0 °C / Industrial scale
3.3: 1 h / 90 °C / Industrial scale
View Scheme
tertiary butyl chloride
507-20-0

tertiary butyl chloride

phenol
108-95-2

phenol

A

para-tert-butylphenol
98-54-4

para-tert-butylphenol

B

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

Conditions
ConditionsYield
With sulfuric acid at 150℃; for 3h; Green chemistry;
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

2-bromo-5-(1,1-dimethylethyl)phenol
20942-68-1

2-bromo-5-(1,1-dimethylethyl)phenol

Conditions
ConditionsYield
With bromine In dichloromethane for 1h;100%
With bromine In tetrachloromethane at 5℃; for 1h;92%
With bromine In dichloromethane Inert atmosphere;90%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

3-tert-butyl-1-methoxybenzene
33733-83-4

3-tert-butyl-1-methoxybenzene

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 90℃; Inert atmosphere;100%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

thianthrene cation radical perchlorate
35787-71-4

thianthrene cation radical perchlorate

5-(4-tert-Butyl-2-hydroxy-phenyl)-thianthren-5-ium; perchlorate

5-(4-tert-Butyl-2-hydroxy-phenyl)-thianthren-5-ium; perchlorate

Conditions
ConditionsYield
In acetonitrile for 0.5h;99%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

5-tert-butyl-2,4-diiodophenol
1017608-26-2

5-tert-butyl-2,4-diiodophenol

Conditions
ConditionsYield
With sodium hydroxide; Iodine monochloride In methanol at 20℃;99%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

tert-butyl(3-(tert-butyl)phenoxy)dimethylsilane
1254941-68-8

tert-butyl(3-(tert-butyl)phenoxy)dimethylsilane

Conditions
ConditionsYield
With 1H-imidazole In N,N-dimethyl-formamide at 20℃;99%
2-chloro-5-nitropyridine
4548-45-2

2-chloro-5-nitropyridine

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

2-(3-(tert-butyl)phenoxy)-5-nitropyridine

2-(3-(tert-butyl)phenoxy)-5-nitropyridine

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 20℃; for 70h;99%
With potassium carbonate In dimethyl sulfoxide at 20℃; for 70h;99%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

3-tert-butylphenyl tosylate

3-tert-butylphenyl tosylate

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran; water at 0 - 20℃; for 2h; Reagent/catalyst; Green chemistry;99%
triisopropylsilyl chloride
13154-24-0

triisopropylsilyl chloride

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

tri(1-methylethyl)-(3-(1,1-dimethylethyl)phenoxy)silane

tri(1-methylethyl)-(3-(1,1-dimethylethyl)phenoxy)silane

Conditions
ConditionsYield
With 1H-imidazole In dichloromethane at 20℃; Sealed tube;99%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

2-iodo-5-(1,1-dimethylethyl)phenol
20942-70-5

2-iodo-5-(1,1-dimethylethyl)phenol

Conditions
ConditionsYield
With potassium iodate; iodine In water; acetic acid for 48h; Ambient temperature;98%
With potassium iodate; iodine; acetic acid In water at 20℃; for 48h;94%
With potassium iodate; iodine; acetic acid In water at 40 - 90℃;94%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

3-tert-butylcyclohexanol
4534-70-7

3-tert-butylcyclohexanol

Conditions
ConditionsYield
With hydrogen; Rh on carbon In methanol98%
With hydrogen; platinum(IV) oxide In acetic acid
With Ru/Al2O3; hydrogen under 15201 - 38002.6 Torr;
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

3-tert-butylphenyl mesylate
1071592-74-9

3-tert-butylphenyl mesylate

Conditions
ConditionsYield
With triethylamine In ethyl acetate at 0 - 20℃; for 0.166667h; Green chemistry;98%
With triethylamine In toluene at 10 - 25℃; for 0.333333h;88%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

methanesulfonic acid 2,2-difluoroethyl ester
163035-65-2

methanesulfonic acid 2,2-difluoroethyl ester

C12H16F2

C12H16F2

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide; toluene for 4h; Reflux;97.6%
4-chloro-4'-fluorobutyrophenone-2,2-dimethylpropylene ketal

4-chloro-4'-fluorobutyrophenone-2,2-dimethylpropylene ketal

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

A

bis(phenyl) carbonate
102-09-0

bis(phenyl) carbonate

B

4-Fluoro-α-[3-(2-methyl-2-propyl)phenoxy]propylbenzenemethanol

4-Fluoro-α-[3-(2-methyl-2-propyl)phenoxy]propylbenzenemethanol

Conditions
ConditionsYield
With hydrogenchloride In methanol; N,N-dimethyl-formamideA 97%
B n/a
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

palladium
7440-05-3

palladium

3-Tert.-butylcyclohexylamine
83451-66-5

3-Tert.-butylcyclohexylamine

Conditions
ConditionsYield
97%
diethyl sulfate
64-67-5

diethyl sulfate

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

1-(tert-butyl)-3-ethoxybenzene

1-(tert-butyl)-3-ethoxybenzene

Conditions
ConditionsYield
Stage #1: 3-tert-butylphenyol With potassium hydroxide In toluene at 70℃;
Stage #2: diethyl sulfate Heating;
97%
trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

3-(tert-butyl)phenyl trifluoromethanesulfonate
201851-06-1

3-(tert-butyl)phenyl trifluoromethanesulfonate

Conditions
ConditionsYield
With pyridine In dichloromethane at 0 - 25℃; for 5h; Inert atmosphere;96%
With pyridine at 0 - 20℃; for 12h;96%
With 2,6-dimethylpyridine In dichloromethane for 0.5h;95%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

propargyl bromide
106-96-7

propargyl bromide

1-(tert-butyl)-3-(prop-2-yn-1-yloxy)benzene

1-(tert-butyl)-3-(prop-2-yn-1-yloxy)benzene

Conditions
ConditionsYield
With caesium carbonate In acetonitrile96%
Stage #1: 3-tert-butylphenyol With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 0.5h; Inert atmosphere;
Stage #2: propargyl bromide In N,N-dimethyl-formamide at 20℃; Inert atmosphere;
90%
With potassium carbonate In N,N-dimethyl-formamide; toluene at 20℃; for 7h; Inert atmosphere;90%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

2,6-difluoro-1-nitrobenzene
19064-24-5

2,6-difluoro-1-nitrobenzene

3,3'-((2-nitro-1,3-phenylene)bis(oxy))bis(tert-butylbenzene)

3,3'-((2-nitro-1,3-phenylene)bis(oxy))bis(tert-butylbenzene)

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 90℃; Inert atmosphere;96%
formaldehyd
50-00-0

formaldehyd

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

benzylamine
100-46-9

benzylamine

3-benzyl-7-tert-butyl-3,4-dihydro-2H-benzo[e][1,3]oxazine

3-benzyl-7-tert-butyl-3,4-dihydro-2H-benzo[e][1,3]oxazine

Conditions
ConditionsYield
In ethanol; water for 8h; Mannich reaction; Heating;95%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

diphenyldisulfane
882-33-7

diphenyldisulfane

5-tert-butyl-2-(phenylthio)phenol
1350814-78-6

5-tert-butyl-2-(phenylthio)phenol

Conditions
ConditionsYield
With iron(III) chloride; oxygen In dichloromethane at 25℃; for 7h;95%
2,6-Dibromopyridine
626-05-1

2,6-Dibromopyridine

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

2,6-bis(3-tert-butylphenoxy)pyridine

2,6-bis(3-tert-butylphenoxy)pyridine

Conditions
ConditionsYield
With copper(l) iodide; caesium carbonate In 1-methyl-pyrrolidin-2-one at 160℃; for 24h; Inert atmosphere; Schlenk technique;95%
styrene
292638-84-7

styrene

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

5-(tert-butyl)-2-(1-phenylethyl)phenol

5-(tert-butyl)-2-(1-phenylethyl)phenol

Conditions
ConditionsYield
With phosphorous acid In water; 1,2-dichloro-ethane at 100℃; for 18h; Schlenk technique; regioselective reaction;95%
With phosphonic Acid In water; 1,2-dichloro-ethane at 100℃; for 18h;95%
With silver tetrafluoroborate In 1,2-dichloro-ethane at 100℃; for 24h; Inert atmosphere; Sealed tube; regioselective reaction;84%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

C38H34F2N2O2

C38H34F2N2O2

C58H60N2O4

C58H60N2O4

Conditions
ConditionsYield
With caesium carbonate In dimethylsulfoxide-d6 at 100℃; for 18h; Inert atmosphere;95%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

butan-1-ol
71-36-3

butan-1-ol

n-butyl 3-tert-butylphenyl ether
136-60-7

n-butyl 3-tert-butylphenyl ether

Conditions
ConditionsYield
With di-tert-butyl-diazodicarboxylate; diphenyl(p-ferrocenylphenyl)phosphine In tetrahydrofuran at 20℃; for 12h; Mitsunobu reaction;94%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

3-(tert-butyl)phenyl trifluoromethanesulfonate
201851-06-1

3-(tert-butyl)phenyl trifluoromethanesulfonate

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In dichloromethane Ambient temperature;93%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

Ethanesulfonyl chloride
594-44-5

Ethanesulfonyl chloride

3-tert-butylphenyl ethanesulfonate
1071592-79-4

3-tert-butylphenyl ethanesulfonate

Conditions
ConditionsYield
With triethylamine In toluene at 10 - 25℃; for 0.333333h;93%
carbon dioxide
124-38-9

carbon dioxide

3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

2-hydroxy-4-tert-butyl-benzoic acid
4578-63-6

2-hydroxy-4-tert-butyl-benzoic acid

Conditions
ConditionsYield
Stage #1: 3-tert-butylphenyol With Mesitol; sodium hydride In mineral oil at 100℃; for 0.0833333h; Glovebox;
Stage #2: carbon dioxide In mineral oil at 185℃; under 3800.26 Torr; for 2h;
93%
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

4-(tert-butyl)-5-[3-(tert-butyl)phenoxy]cyclohexa-3,5-diene-1,2-dione
1638114-33-6

4-(tert-butyl)-5-[3-(tert-butyl)phenoxy]cyclohexa-3,5-diene-1,2-dione

Conditions
ConditionsYield
With tetrakis(actonitrile)copper(I) hexafluorophosphate; N,N'-di-tert-butylethylenediamine; oxygen In dichloromethane at 23℃; under 760.051 Torr; for 4h; Reagent/catalyst;92%
With N,N'-di-tert-butylethylenediamine; oxygen; copper(II) acetate monohydrate In dichloromethane at 25℃; under 1520.1 Torr; for 4h; Catalytic behavior; Glovebox;80%
With C33H39CuN5(1+)*F6P(1-); oxygen; triethylamine In dichloromethane at 20℃; Catalytic behavior; Reagent/catalyst; Inert atmosphere;
With [Cu(MeCN)2(2-[(1H-pyrazol-1-yl)methyl]pyridine)]PF6; oxygen; triethylamine In dichloromethane at 20℃; for 6h; Catalytic behavior; Reagent/catalyst; Glovebox;
With C16H22CuN6(1+)*F6P(1-); oxygen; triethylamine In dichloromethane at 20℃; Catalytic behavior; Reagent/catalyst;
3-tert-butylphenyol
585-34-2

3-tert-butylphenyol

5-chloropyrazine-2,3-dicarbonitrile
72111-57-0

5-chloropyrazine-2,3-dicarbonitrile

5-(3-tert-Butyl-phenoxy)-pyrazine-2,3-dicarbonitrile

5-(3-tert-Butyl-phenoxy)-pyrazine-2,3-dicarbonitrile

Conditions
ConditionsYield
With sodium hydroxide In water; acetone91%

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